CN107910371A - A kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds - Google Patents

A kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds Download PDF

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CN107910371A
CN107910371A CN201710861928.2A CN201710861928A CN107910371A CN 107910371 A CN107910371 A CN 107910371A CN 201710861928 A CN201710861928 A CN 201710861928A CN 107910371 A CN107910371 A CN 107910371A
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metal
grid
gan hemt
layer
beam direct
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CN107910371B (en
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吴少兵
高建峰
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CETC 55 Research Institute
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/778Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface
    • H01L29/7782Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET
    • H01L29/7783Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface with confinement of carriers by at least two heterojunctions, e.g. DHHEMT, quantum well HEMT, DHMODFET using III-V semiconductor material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/28008Making conductor-insulator-semiconductor electrodes
    • H01L21/28017Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
    • H01L21/28026Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/423Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
    • H01L29/42312Gate electrodes for field effect devices
    • H01L29/42316Gate electrodes for field effect devices for field-effect transistors
    • H01L29/4232Gate electrodes for field effect devices for field-effect transistors with insulated gate
    • H01L29/42372Gate electrodes for field effect devices for field-effect transistors with insulated gate characterised by the conducting layer, e.g. the length, the sectional shape or the lay-out
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66431Unipolar field-effect transistors with a heterojunction interface channel or gate, e.g. HFET, HIGFET, SISFET, HJFET, HEMT

Abstract

The present invention is a kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds, its feature this method comprises the technical steps that:(1)The preparation of element;(2)The preparation of nano thin-layer germanium metal;(3)Electron-beam direct writing grid;(4)The first time of nano thin-layer germanium metal removes;(5)The etching of gate medium, the evaporation and stripping of grid metal;(6)Second of removal of nano thin-layer germanium metal.Advantages of the present invention:1st, using germanium metal as bottom conductive layer, uniformity is good, and thickness controllable precise;On its surface, the electron beam adhesive of coating has good adhesiveness, and is easily removed.2nd, germanium metal can have extraordinary conductive characteristic in below 10nm, to improving GaN HEMT surface electronic beam charge accumulated excellent effects.

Description

A kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds
Technical field
The present invention relates to a kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds, belong to semiconductor Device and field of IC technique.
Background technology
In modem semi-conductor devices manufacturing process, with advances in technology, device size is less and less, and integrated level is more next It is higher.Three generations's semiconductor GaN has broad application prospects in the high frequency field of microwave and millimeter wave chip.Millimeter wave GaN HEMT device has operating voltage height, and output power is up to more than watt level, and power density is high and working frequency can reach The advantages such as 100GHz.GaN HEMT devices, especially AlGaN/GaN HEMT structure, the poorly conductive on its surface.It is moreover, general It is required for growing one layer of fine and close SiN medium on surface before grid are made to protect source and drain metal while reduce surface as far as possible Defect.When preparing the grid less GaN HEMT devices of length, often using electron-beam direct writing technique.And since the densification on surface is situated between The problem of matter and GaN HEMT poorly conductive in itself, electron-beam direct writing can there are charge build-up problems, charge build-up problems meeting Cause direct write alignment deviation even due to can not find mark and can not direct write situation.
In general, it is one layer of conducting resinl of coating to solve the charge build-up problems in direct electron beam process.But conducting resinl Often bring the variation of technique, the drying glue temperature of such as each layer electron beam adhesive, exposure dose, developing time, and some techniques Variation can be such that expected direct write effect does not complete.In addition, prepared by the grid of GaN HEMT generally use electron beam one-pass molding, i.e., Need multilayer electronic beam glue.Need to ensure adhesiveness between multilayer glue, tend not to coating conducting resinl.Meanwhile the baking of conducting resinl Roasting temperature is not necessarily matched with electron beam adhesive, so using above there is certain limitation.In addition, in heavy dose of direct write, it is conductive It is also restrained that the conductive capability deficiency of glue makes it solve the ability of charge accumulated.
And one layer of metal material is prepared on GaN surfaces, conductivity problems can be improved.The metal material of preparation not only will be to electricity The adhesiveness that beamlet glue has had, while there is easy removal, the normal process of electron beam is not influenced.A kind of method is to be coated with One layer of metal, such as metallic aluminium are prepared on the sample of electron beam adhesive again.But this kind of method large variation of technique with belt transect, including When needing to consider the place to go of metallic aluminium in development, and applying multilayer glue, the problems such as the adhesion of upper strata glue and metallic aluminium, chemical reaction. In addition, metallic aluminium is generally required using acids place to go, and acid solution can equally have other metals of device, such as source and drain metal Corrosiveness.Germanium metal is widely used in the semiconductor device, such as one of ohmic metal as GaAs materials.Germanium metal one As using electron beam evaporation process prepare, surfacing, uniformity is good, and thickness controllable precise.In the electricity of its surface coating Beamlet glue has good adhesiveness.After direct write and after grid metal stripping, and it is easier to remove, is relatively good improvement The material of electron-beam direct writing charge accumulated.And germanium metal is prepared before electron beam adhesive gluing, will not bring technique variation and Compatibility issue.
In conclusion when preparing GaN HEMT devices using electron-beam direct writing technique, due to the poorly conductive meeting on its surface There are problems that charge accumulated and bring direct write.Coating conducting resinl method direct-write process can be brought to change, and application method by Limit, conductive capability do not have the metal material good.So the present invention develops electric charge in a kind of improvement GaN HEMT electron-beam direct writings and accumulates The method of tired problem.Direct write alignment can be effectively solved, the problems such as adhesiveness.
The content of the invention
The present invention proposes a kind of method of solution GaN HEMT surface electronic beam charge accumulateds, its purpose aims to solve the problem that electricity The problems such as charge build-up problems during beamlet direct write, while can effectively solve direct write alignment, adhesiveness.
The technical solution of the present invention:Improve the method for GaN HEMT surface electronic beam direct write charge accumulateds, its feature It is when preparing GaN HEMT devices, one layer of nano thin-layer germanium metal is prepared on GaN HEMT surfaces as conductive layer.
Its method, comprises the technical steps that:
(1)The preparation of element;
(2)The preparation of nano thin-layer germanium metal;
(3)Electron-beam direct writing grid;
(4)The first time of nano thin-layer germanium metal removes;
(5)The etching of gate medium, the evaporation and stripping of grid metal;
(6)Second of removal of nano thin-layer germanium metal.
Advantages of the present invention:
1st, using germanium metal as bottom conductive layer, the germanium metal surfacing prepared using electron beam evaporation process, uniformity It is good, and thickness controllable precise;On its surface, the electron beam adhesive of coating has a good adhesiveness, and after direct write and grid metal is shelled From rear, and it is easier to remove;
2nd, the conductive substrate germanium metal used can have an extraordinary conductive characteristic in below 10nm, and with follow-up electronics Beam technique does not have process compatible problem, it improves the positive effect of GaN HEMT surface electronic beam charge accumulateds and is better than conducting resinl.
Brief description of the drawings
Attached drawing 1 is that Ohmic contact and growth protecting dielectric structure schematic diagram are prepared in GaN epitaxial layer.
Attached drawing 2 is growth nano thin-layer germanium metal schematic cross-section.
Attached drawing 3 is to apply electron beam adhesive and direct write development schematic cross-section.
Attached drawing 4 is the nano thin-layer germanium metal schematic diagram that the first step removes grid underfooting portion.
Attached drawing 5 is schematic diagram after grid metal is evaporated and peeled off.
Attached drawing 6 is that second step removes schematic diagram after nano thin-layer germanium metal and growth grid dielectric passivation.
101 be SiC substrate in attached drawing, and 102 be epi channels and barrier layer, and 103 be source-drain electrode, and 104 be source and drain protection SiN media, 201 be germanium metal, and 302 be to apply electron beam adhesive, and 502 be grid metal, and 602 be grid metal dielectric passivation.
Embodiment
A kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds, when preparing GaN HEMT devices, GaN HEMT surfaces prepare one layer of nano thin-layer germanium metal as conductive layer.
The GaN HEMT devices, including GaN epitaxy material, source-drain structure, source and drain protection medium, grid metal, grid are blunt Change medium, capacitance upper/lower electrode metal.
Improve the method for GaN HEMT surface electronic beam direct write charge accumulateds, comprise the technical steps that:
(1)The preparation of element:On GaN HEMT epitaxial materials, using being lithographically derived source and drain figure;Pass through electron beam evaporation, stripping From and the technique such as alloy prepare source and drain metal system;Using enhancing plasma chemical vapor deposition method or coupling inductance chemical gaseous phase Sedimentation prepares one layer of protection medium SiN, and the SiN thickness is 40nm ~ 200nm;Pass through ultraviolet photolithographic, evaporation and sputtering technology It is sequentially prepared resistance metal and capacitor lower electrode metal;
(2)The preparation of nano thin-layer germanium metal:Nano thin-layer germanium metal is prepared using electron beam evaporation process or sputtering technology, thick Spend for 0 ~ 10nm;
(3)Electron-beam direct writing grid:Prepare grid and use electron-beam direct writing technique, prepared grid are T-shaped grid or Y type grid, grid metal Applied in electron-beam direct writing technique no less than 2 layers of electron beam adhesive, using no less than 2 times direct writes;
(4)The first time of nano thin-layer germanium metal removes:Removed using hydrogen peroxide erosion removal or fluorine-containing plasma, remove part Part after developing for grid foot;Oxygen plasma gluing is carried out before corrosion to improve surface wettability.Etching time is 20 ~ 60s;
(5)The etching of gate medium, the evaporation and stripping of grid metal:First to GaN HEMT epitaxial materials carry out grid medium etching, The grooving of potential barrier layer surface, process of surface treatment;Then deposited by electron beam evaporation prepares grid metal;Grid metal is soaked after preparing using acetone Steep to the surface metal of electron beam adhesive and come off naturally;Be respectively adopted afterwards nmp solution, acetone soln, alcoholic solution immersion 5 ~ 10min;Finally take out drying;
(6)Second of removal of nano thin-layer germanium metal:Using hydrogen peroxide erosion removal, it is except complete under grid metal to remove part Piece other parts;Etching time is 1 ~ 60s.
Technical scheme is further described below in conjunction with the accompanying drawings.
Attached drawing 1 is contrasted, source and drain metal is prepared on the GaN HEMT epitaxial materials of SiC substrate and grows compact medium, is made Standby resistive layer and capacitor lower electrode layer.
Attached drawing 2 is contrasted, it is one layer thin that germanium metal 201 is used as conductive layer using electron beam evaporation process evaporation on surface, should The thickness of layer germanium metal is less than or equal to 10nm.
Attached drawing 3 is contrasted, applies electron beam adhesive 302, and carries out electron-beam direct writing, the figure needed after development.
Attached drawing 4 is contrasted, hydrogen peroxide solution processing is carried out or using fluoro plasma to the figure for obtaining electron-beam direct writing Processing, is removed the germanium metal that grid bottom-exposed comes out.
Attached drawing 5 is contrasted, the gate medium on print surface is performed etching to remove the SiN media of grid foot part, is then used Electron beam evaporation process prepares grid metal 502, is peeled off after grid metal evaporation.
Attached drawing 6 is contrasted, full sheet surface is corroded using hydrogen peroxide, since hydrogen peroxide cannot corrode grid metal and SiN Medium, so removing the process of germanium metal will not cause to damage to surfaces of active regions and source and drain metal;Sample table to removing germanium Look unfamiliar long grid metal dielectric passivation 602, then by dielectric openings, prepared by capacitance top electrode etc., completes the system of GaN HEMT devices It is standby.
Embodiment 1
Improve the method for GaN HEMT surface electronic beam direct write charge accumulateds, include the following steps:
1), on the HEMT epitaxial materials of GaN substrate, using being lithographically derived source and drain figure, then by electron beam evaporation, peel off and The techniques such as alloy prepare source and drain metal system, and enhancing plasma chemical gas can be used by then growing one layer of protection medium SiN, SiN Mutually prepared by deposit, thickness 40nm.It is sequentially prepared again by techniques such as ultraviolet photolithographic, evaporation or sputterings under resistance metal and capacitance Electrode metal;
2)The germanium metal of one layer of 5nm thickness is prepared using electron beam evaporation process.Electron beam adhesive is applied again, is toasted, direct write, wherein preparing , it is necessary to apply multilayer glue, simultaneously direct write is multiple using the one-time formed method of electron beam for the small grid length of GaN, and bottom nano thin-layer germanium metal The effect for eliminating charge accumulated is respectively provided with to multiple direct write;
3)Sample after development carries out erosion removal using hydrogen peroxide to the metal of grid foot bottom.It is thorough to guarantee corrosion, Oxygen plasma gluing is carried out before corrosion to improve surface wettability;Corrosion 20 seconds, ensures that bottom corrosion is clean and has certain Sideetching, the purpose of sideetching is to ensure that follow-up grid metal will not be connected with germanium metal;
4)The techniques such as grid medium etching, the grooving of potential barrier layer surface, surface treatment are carried out to the sample after corrosion, use electron beam afterwards Evaporation prepares grid metal;Grid metal uses acetone soak to make to have the surface metal of electron beam adhesive to come off naturally after preparing, afterwards Nmp solution, acetone soln, alcoholic solution immersion 5min is respectively adopted, finally takes out drying;Remove grid bottom in print surface after drying Outside portion, nano thin-layer germanium metal is also covered elsewhere;
5)Erosion removal is carried out to germanium metal using the mixed solution of hydrogen peroxide or hydrogen peroxide and water.According to the corruption of hydrogen peroxide solution Erosion speed determines the complete corrosion of germanium, corrodes 30s;Since hydrogen peroxide is to GaN surfaces, grid metal and SiN media are without corruption Erosion acts on, so surface damage and process compatible sex chromosome mosaicism can't be brought;
6)Dielectric passivation is carried out to the grid structure after corrosion germanium metal.Pass through dielectric openings, the preparation of capacitance top electrode etc. again, complete The preparation of GaN HEMT devices.
Embodiment 2
1)On the HEMT epitaxial materials of GaN substrate, using being lithographically derived source and drain figure, then by electron beam evaporation, peel off and The techniques such as alloy prepare source and drain metal system, and coupling inductance chemical gaseous phase can be used by then growing one layer of protection medium SiN, SiN Prepared by deposition process, thickness 200nm.Resistance metal and electricity are sequentially prepared by techniques such as ultraviolet photolithographic, evaporation or sputterings again Hold electrode metal;
2)The germanium metal of one layer of 10nm thickness is prepared using electron beam transpiration technique.Electron beam adhesive is applied again, is toasted, direct write, wherein making The standby small grid length of GaN generally uses the one-time formed method of electron beam, and, it is necessary to apply multilayer glue, simultaneously direct write is multiple, and bottom nano thin-layer Germanium metal is respectively provided with multiple direct write in the work for eliminating charge accumulated;
3)Sample after development carries out erosion removal using hydrogen peroxide to the metal of grid foot bottom.It is thorough to guarantee corrosion, Oxygen plasma gluing is carried out before corrosion to improve surface wettability;Corrosion 1 minute, ensures that bottom corrosion is clean and has certain Sideetching, the purpose of sideetching is to ensure that follow-up grid metal will not be connected with germanium metal;
4)The techniques such as grid medium etching, the grooving of potential barrier layer surface, surface treatment are carried out to the sample after corrosion, use electron beam afterwards Evaporation prepares grid metal;Grid metal uses acetone soak to make to have the surface metal of electron beam adhesive to come off naturally after preparing, afterwards Nmp solution, acetone soln, alcoholic solution immersion 10min is respectively adopted, finally takes out drying;Remove grid in print surface after drying Outside bottom, nano thin-layer germanium metal is also covered elsewhere;
5)Erosion removal is carried out to germanium metal using the mixed solution of hydrogen peroxide or hydrogen peroxide and water.According to the corruption of hydrogen peroxide solution Erosion speed determines the complete corrosion of germanium, corrodes 1 minute;Since hydrogen peroxide does not have GaN surfaces, grid metal and SiN media Corrosiveness, so surface damage and process compatible sex chromosome mosaicism can't be brought;
6)Dielectric passivation is carried out to the grid structure after corrosion germanium metal;Pass through dielectric openings, the preparation of capacitance top electrode etc. again, complete The preparation of GaN HEMT devices.

Claims (7)

1. a kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds, its feature this method is walked including following technique Suddenly:
(1)The preparation of element;
(2)The preparation of nano thin-layer germanium metal;
(3)Electron-beam direct writing grid;
(4)The first time of nano thin-layer germanium metal removes;
(5)The etching of gate medium, the evaporation and stripping of grid metal;
(6)Second of removal of nano thin-layer germanium metal.
2. a kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds according to claim 1, its feature It is the step(1)The preparation of element:On GaN HEMT epitaxial materials, by being lithographically derived source and drain figure;Pass through electron beam The techniques such as evaporation, stripping and alloy prepare source and drain metal system;By strengthening plasma chemical vapor deposition method or coupling inductance CVD method prepares one layer of protection medium SiN, and the SiN thickness is 40nm ~ 200nm;By ultraviolet photolithographic, evaporation and Sputtering technology is sequentially prepared resistance metal and capacitor lower electrode metal.
3. a kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds according to claim 1, its feature It is the step(2)The preparation of nano thin-layer germanium metal:Nano thin-layer germanium metal uses electron beam evaporation process or sputtering technology Prepare, thickness is 0 ~ 10nm.
4. a kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds according to claim 1, its feature It is the step(3)Electron-beam direct writing grid:Preparing grid and use electron-beam direct writing technique, prepared grid are T-shaped grid or Y type grid, Grid metal is applied in electron-beam direct writing technique no less than 2 layers of electron beam adhesive, using no less than 2 times direct writes.
5. a kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds according to claim 1, its feature It is the step(4)The first time of nano thin-layer germanium metal removes:Removed using hydrogen peroxide erosion removal or fluorine-containing plasma, Part is removed as the part after the development of grid foot;Oxygen plasma gluing is carried out before corrosion to improve surface wettability;Etching time For 20 ~ 60s.
6. a kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds according to claim 1, its feature It is the step(5)The etching of gate medium, the evaporation and stripping of grid metal:Grid Jie is carried out to GaN HEMT epitaxial materials first Matter etching, the grooving of potential barrier layer surface, process of surface treatment;Then deposited by electron beam evaporation prepares grid metal;Grid metal is adopted after preparing Come off naturally with the surface metal of acetone soak to electron beam adhesive;Nmp solution, acetone soln, alcoholic solution are respectively adopted afterwards Soak 5 ~ 10min;Finally take out drying.
7. a kind of method of improvement GaN HEMT surface electronic beam direct write charge accumulateds according to claim 1, its feature It is the step(6)Second of removal of nano thin-layer germanium metal:Using hydrogen peroxide erosion removal, it is except grid gold to remove part The other parts of subordinate;Etching time is 1 ~ 60s.
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CN110571143A (en) * 2019-07-25 2019-12-13 西安电子科技大学 Manufacturing method of novel high-frequency semiconductor grid
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CN109103245A (en) * 2018-07-26 2018-12-28 厦门市三安集成电路有限公司 A kind of double-T shaped grid and production method and application
CN110571145A (en) * 2019-07-25 2019-12-13 西安电子科技大学 preparation method of floating Y-shaped grid
CN110571144A (en) * 2019-07-25 2019-12-13 西安电子科技大学 manufacturing method of novel semiconductor grid
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