CN107901162A - A kind of water-based fire retardant glued board environment-friendly type composite flame-retardant agent, water-based fire retardant glued board, preparation method and application - Google Patents
A kind of water-based fire retardant glued board environment-friendly type composite flame-retardant agent, water-based fire retardant glued board, preparation method and application Download PDFInfo
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- CN107901162A CN107901162A CN201710986361.1A CN201710986361A CN107901162A CN 107901162 A CN107901162 A CN 107901162A CN 201710986361 A CN201710986361 A CN 201710986361A CN 107901162 A CN107901162 A CN 107901162A
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- water
- fire retardant
- glued board
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/30—Fireproofing
Abstract
The invention discloses a kind of water-based fire retardant glued board environment-friendly type composite flame-retardant agent, water-based fire retardant glued board, preparation method and application.The water-based fire retardant glued board environment-friendly type composite flame-retardant agent of the present invention, is made of each component of following weight parts：16~20 parts of phosphorus nitrogen system faintly acid inorganic salts compound, 2~4 parts of phosphorus nitrogen system alkalescent inorganic salts compound, 4~6 parts of boron system inorganic compound, 5~7 parts of nitrogen system Inorganic Ammonium salt compounds, 2~4 parts of multicomponent alcoholics compound, 70~90 parts of liquid pure water.The fire retardant is without halogen, environment-protecting and non-poisonous, do not harden with water-based no aldehyde glue, compatibility is good, cold pressing and the hot pressing effect of the water-based fire retardant glued board of no aldehyde are not interfered with, product bonding strength, dipping and stripping are not influenced, the production for water-based glued board can manufacture high-quality, the high performance no water-based fire retardant glued board of aldehyde.
Description
Technical field
The present invention relates to flame retardant area, and in particular to a kind of water-based fire retardant glued board environment-friendly type composite flame-retardant agent, water
The fire retardant glued board of property, preparation method and application.
Background technology
Water-based glued board is the nearly 2 years new generation of environment protection wood-base fibre and particle panel material products to get up in China's initiative development.It is
Water-based no aldehyde glue is applied to normal plywood and produces and a kind of new product for being derived, due to it in whole production process nothing
The aldehyde like harmful substance such as formaldehyde matter is added, therefore is the green product of real environmental protection.But water-based no aldehyde glue is applied to fire retardant gluing
During the production of plate, the problem of fire retardant of existing type is incompatible with water-based no aldehyde glue is really encountered.It is mainly reflected in following three
A problem：1. suppressing the curing reaction speed of water-based no aldehyde glue, difficult shaping, hot-press gluing intensity difference are cold-pressed；2. with water-based no aldehyde
Glue is incompatible, is in contact and just reacts, and causes the easy dry glue of glue, premature cure, and fire retardant then decomposes, fails in advance；
3. not having the effect of cooperative flame retardant with water-based no aldehyde glue, the original effect of fire retardant is caused to reduce, dosage greatly increases.It is existing fire-retardant
The common ground of agent is poor with the compatibility of water-based no aldehyde glue, synergistic.It is reported that it is not directed to also actually both at home and abroad at present
In water-based no aldehyde glue research and develop successfully and public offering water-based fire retardant glued board fire retardant.Therefore, a kind of energy of research and development and water
Property it is compatible without aldehyde glue, suitable for the fire retardant of water-based fire retardant plywood production, be factory using water-based no aldehyde glue development and production without
The water-based fire retardant glued board of aldehyde has to the technical problem solved.
The content of the invention
To solve above-mentioned the problems of the prior art, the present invention provides a kind of water-based fire retardant compound resistance of glued board environment-friendly type
Fire agent, water-based fire retardant glued board and its preparation method and application.The fire retardant of the present invention, uses, it is free of after can be made into solution
It is halogen, environment-protecting and non-poisonous, it is compatible with water-based no aldehyde glue, it is glued with water-based no aldehyde and touches and will not react, to water-based no aldehyde glue
Curing it is glued there is no harmful effect, cold pressing and the hot pressing effect of the water-based fire retardant glued board of no aldehyde are not interfered with, to product gluing
The physicochemical properties such as intensity, dipping and stripping do not influence significantly, and the production for water-based glued board can manufacture high-quality, Gao Xing
Can without the water-based fire retardant glued board of aldehyde.
Specifically, the present invention provides a kind of water-based fire retardant glued board environment-friendly type composite flame-retardant agent, it is by following weight parts
Each component be made：
16~20 parts of phosphorus nitrogen system faintly acid inorganic salts compound, 2~4 parts of phosphorus nitrogen system alkalescent inorganic salts compound,
4~6 parts of boron system inorganic compound, 5~7 parts of nitrogen system Inorganic Ammonium salt compounds, 2~4 parts of multicomponent alcoholics compound, liquid are pure
70~90 parts of water purification.
Wherein, the phosphorus nitrogen system faintly acid inorganic salts compound is one kind or several in GUP01, GUP02, GUP03
Kind.
In addition, the phosphorus nitrogen system alkalescent inorganic salts compound is one kind or several in ZRK12, ZRK13, ZEK14
Kind.
In addition, the one or more in described boron system inorganic compound BY10, BY11, BY12.
In addition, the one or more in described nitrogen system Inorganic Ammonium salt compound L S01, LS02, LS03.
In addition, the one or more in described multicomponent alcoholics compound PV10, PV11, PV12.
The present invention also provides it is a kind of as described above water-based fire retardant glued board environment-friendly type composite flame-retardant agent preparation method, its
Filtered after all the components are uniformly mixed and water-based fire retardant glued board environment-friendly type composite flame-retardant agent is made.
In addition, the present invention also provides a kind of water-based fire retardant glued board, it is with water-based fire retardant glued board ring as described above
Guarantor's type composite flame-retardant agent is made as fire retardant, and fire retardant drugloading rate is >=60kg/m3。
Except above-mentioned points, the present invention also provides a kind of application of the water-based fire retardant glued board environment-friendly type composite flame-retardant agent,
Wood single-plate is immersed in the fire retardant and fire-retardant veneer is made and further prepares by it in the preparation of water-based fire retardant glued board
Water-based fire retardant glued board, and control the fire retardant drugloading rate >=60kg/m3。
More specifically, water-based fire retardant glued board environment-friendly type composite flame-retardant agent of the invention, with phosphorus nitrogen system's faintly acid without
Machine salt compounds are expansion type flame retardant, and the phosphorus nitrogen system faintly acid inorganic salts compound can be water-based section of Lanzhou section day
One or more in GUP01, GUP02, GUP03 of the production of skill Co., Ltd, preferably quality grade is technical grade high-class product.Should
Main function of the expansion type flame retardant of phosphorus nitrogen system faintly acid inorganic salts compound in composite flame-retardant agent be, heat absorption, it is heat-insulated,
Oxygen barrier, cut-out combustion reaction chain, limitation heat block the generation of naked light or the sprawling of flame to wood internal transmission.
In addition, the water-based fire retardant glued board environment-friendly type composite flame-retardant agent of the present invention, with phosphorus nitrogen system alkalescent inorganic salts
Compound is smoke inhibition fire retardant, and the phosphorus nitrogen system alkalescent inorganic salts compound can be the water-based limited public affairs of science and technology of Lanzhou section day
The one or more in ZRK12, ZRK13, ZEK14 of production are taken charge of, preferably quality grade is technical grade high-class product.The phosphorus nitrogen system is weak
Main function of the smoke inhibition fire retardant of basic mineral salt compound in composite flame-retardant agent is to block flaming combustion, control hair
Smoke, absorbs or dilutes flue gas, runs into pyroreaction and produces non-flammable gases and protective layer.
In addition, the water-based fire retardant glued board environment-friendly type composite flame-retardant agent of the present invention, is anti-using boron system inorganic compound
Drip fire retardant, the boron system inorganic compound can be day water-based Science and Technology Ltd.'s production of Lanzhou section BY10, BY11,
One or more in BY12, preferably quality grade are technical grade high-class product.The anti-dripping melt of the boron system inorganic compound is fire-retardant
Main function of the agent in composite flame-proof agent prescription is to control density flaming droplet, absorbs or dilute heat, runs into pyroreaction production
The non-flammable gases such as unboiled water steam and oxide are heat-insulated, oxygen barrier protective layer.
In addition, the water-based fire retardant glued board environment-friendly type composite flame-retardant agent of the present invention, with nitrogen system Inorganic Ammonium salt compounds
For synergistic flame retardant, the nitrogen system Inorganic Ammonium salt compounds can be the water-based Science and Technology Ltd.'s production of Lanzhou section day LS01,
One or more in LS02, LS03, preferably quality grade are technical grade high-class product.The association of the nitrogen system Inorganic Ammonium salt compounds
It is compatibility, the compatibility for improving each flame retardant compositions to imitate main function of the fire retardant in composite flame-proof agent prescription, is improved single
The antiflaming effect of one component, reduces the usage amount of one-component, can also be played when running into high temperature heat absorption, heat-insulated, oxygen barrier and
It is decomposed to form protective layer, reduces the fire retardation of heat transfer rate.
In addition, the water-based fire retardant glued board environment-friendly type composite flame-retardant agent of the present invention, using multicomponent alcoholics compound as into charcoal
Agent, the carbon forming agent can be the one or more in PV10, PV11, PV12 of the water-based Science and Technology Ltd.'s production of Lanzhou section day,
It is preferred that quality grade is technical grade high-class product.It is main in composite flame-proof agent prescription for the carbon forming agent of the multicomponent alcoholics compound
Effect is to improve timber into the effect of charcoal, makes to quickly form carburization zone when timber is heated, plays the work such as heat absorption, heat-insulated, adiabatic
With reduction naked light, flame or the generation of burning.
In addition, the water-based fire retardant glued board environment-friendly type composite flame-retardant agent of the present invention, with liquid, pure water H2O is medicine
Agent dispersible carrier, the water can be tap water, distilled water etc., and it is dissolving, each recipe ingredient of carrying that it, which is acted on, and makes it scattered
Uniformly.
The preparation method of water-based fire retardant glued board environment-friendly type composite flame-retardant agent of the present invention, include the following steps with
Technical requirements：
A, the first step, stock.According to above-mentioned formula and its technical requirements, prepare required a variety of materials in advance.Each formula
The actual material quantity of component, according to the weight ratio of above-mentioned formula, and the total amount that composite flame-retardant agent need to actually be prepared, carries out
Multiple conversion can draw corresponding numerical value.
B, second step, the dosage component of solid during mixed dissolution is formulated.By the material of each solid chemicals component in formula point
It is not added in dissolving tank, adding order is not restricted.Then, then toward addition in dissolving tank meet formula rate, a certain amount of
Medicament dispersible carrier (the pure water H of liquid2O).Medicament solid constituent and medicament dispersible carrier are all added after completion, you can
Start the blender that dissolving tank carries, material in groove is stirred, is disperseed, is dissolved into the mixed solution being completely dissolved.
C, the 3rd step, retardant solution filtering, store, be stand-by.After composite flame-retardant agent each component completes mixed dissolution, warp
Filtering removes insoluble matter impurity, you can and it is injected into and is stored in dedicated chemical pond, it is stand-by.
According to above-mentioned formula and preparation method, prepared composite flame-proof agent solution, under normal conditions between each component mutually
Compatibility, without obvious smell, its appearance is water white transparency or the settled solution of light yellow clear, its pH value is about 6~8, to nature
Influence, product or the human contact safe non-hazardous suitable with common nitrogen phosphorus boron class agrochemical of environment, timber contact are constant
Color, performance is stablized at normal temperatures and pressures, and high temperature high voltage resistant, is not easily decomposed, volatilizees, effective life is long-term.The compound resistance
Agent is fired, can be now with the current, previously prepared it can also store afterwards stand-by.
The environment-friendly type composite flame-retardant agent, during for producing water-based glued board, method and step that should be as shown in Figure 1 is into enforcement
With, and fire retardant does agent drugloading rate >=60 kilogram/m3When, the flame retardant effect of B1 (B-s1, d0, t1) level can be obtained, model oxygen refers to
Number detected value >=60%.Specifically used method is：1. the characteristics of being porous material using timber, soak glue with retardant solution
The wood single-plate material of plywood production, absorbing wood single-plate has a certain amount of retardant solution.2. then, have one to absorption
The veneer of quantitative retardant solution, is dried processing；Moisture in wood single-plate is heated volatilization, and fire-retardant in wood single-plate
Agent, which then deposits, to be adsorbed in wood internal, wood single-plate is had fire resistance.3. the wood single-plate with fire resistance is used for
The processing of the making sheet process such as the production of water-based glued board, coated water-based no aldehyde glue, assembly, cold pressing, hot pressing, you being made has
The aldehyde-free water-based plywood of fire resistance (i.e. without the water-based fire retardant glued board of aldehyde).It is applied to water-based gluing in the composite flame-retardant agent
Plate, in the production process for manufacturing water-based fire retardant glued board, fire retardant compatible can be copolymerized with water-based no aldehyde glue, when contacting with each other not
It can react, will not suppress or accelerate the curing of water-based formaldehyde-free glue glued；Plate cold pressing, the effect of hot pressing are normal, production
The physicochemical properties such as product bonding strength, dipping and stripping are then not affected by any obvious influence.
The schematic diagram of the fire retardant mechanism of the composite flame-retardant agent, as shown in Figure 2.Specifically fire retardant mechanism is：Work as plate surface
It is subject to the effect of heat source 4, when heating to a certain extent, the fire retardant in plate will be decomposed progressively, and be discharged nontoxic, stingless
Swash property, non-corrosive non-flammable gases and generate other materials with fire retardation, these reaction products can be in plate
Layer protective layer 1 is formed on surface.Non-flammable gases in the protective layer 1, play heat absorption and dilution, the work of isolating oxygen source of the gas 5
With having obstruction effect to burning.And other solid-liquid reactants in protective layer 1, then it can promote and 1 phase of protective layer
Neighbour, certain thickness lumber layer 3 carbonizes, and forms carburization zone 2；This charring layer 2, largely absorbs during formation
Heat, plays the role of heat absorption, is heat-insulated with stopping that internally lumber layer 3 continues to transmit heat.In addition, in the composite flame-retardant agent
Each component is in addition to common flame retardant efficiency, and also emphasize particularly on different fields effect, can be in timber " heated -- charing -- heat
Solution -- catch fire " during respectively or collaboration is played and reduces the generation of naked light, reduce smoke amount, reduce density flaming droplet and cigarette
The effectiveness of gas toxicity, so as to reach the effect of more preferable cooperative flame retardant.
Beneficial effect
The water-based fire retardant glued board environment-friendly type composite flame-retardant agent of the present invention, it is and water-based without halogen, environment-protecting and non-poisonous
It is compatible without aldehyde glue, it is glued with water-based no aldehyde and touches and will not react, the curing to water-based no aldehyde glue is glued without obvious bad
Influence, cold pressing and the hot pressing effect of the water-based fire retardant glued board of no aldehyde are not interfered with, to physics and chemistry such as product bonding strength, dipping and strippings
Performance does not influence significantly, and the production for water-based glued board can manufacture high-quality, the high performance no water-based fire retardant glue of aldehyde
Plywood.This kind of fire retardant also easily buys acquisitions in addition to quality and performance are more excellent with raw material, produce manufacturing cost compared with
Low outstanding feature；Therefore, sexual valence is higher, has higher practicality and promotional value.
Brief description of the drawings
Fig. 1 is the schematic diagram of the application method of water-based fire retardant glued board environment-friendly type composite flame-retardant agent.
Fig. 2 is the schematic diagram of the fire retardant mechanism of water-based fire retardant glued board environment-friendly type composite flame-retardant agent.
Description of reference numerals
1st, protective layer；2nd, charring layer；3rd, lumber layer；4th, heat source；5th, source of oxygen；
Embodiment
Technical scheme is described in detail with reference to embodiment, but the present invention is not limited to these implementations
Example.
Embodiment 1：A kind of water-based fire retardant glued board is with environment-friendly type composite flame-retardant agent and its preparation and applies (A)
(1) formula of fire retardant
(1) expansion type flame retardant：Material selection phosphorus nitrogen system faintly acid inorganic salts compound GUP01 (supply producers：Lanzhou
Water-based Science and Technology Ltd. of section day), technical grade high-class product, 16 kilograms of dosage；
(2) smoke inhibition fire retardant：Material selection phosphorus nitrogen system alkalescent inorganic salts compound ZRK13 (supply producers：Lanzhou section
Its water-based Science and Technology Ltd.), technical grade high-class product, 2 kilograms of dosage；
(3) anti-dripping melt fire retardant：Material selection boron system inorganic compound BY10 (supply producers：Water-based section of Lanzhou section day
Skill Co., Ltd), technical grade high-class product, 4 kilograms of dosage；
(4) synergistic flame retardant：Material selection nitrogen system Inorganic Ammonium salt compound L S02 (supply producers：Lanzhou section it is water-based
Science and Technology Ltd.), technical grade high-class product, 6 kilograms of dosage；
(5) carbon forming agent：Material selection multicomponent alcoholics compound PV12 (supply producers：The water-based limited public affairs of science and technology of Lanzhou section day
Department), technical grade high-class product, 2 kilograms of dosage；
(6) medicament dispersible carrier：Pure tap water (the H of material selection liquid2O), 80 kilograms of dosage；
(2) preparation method of fire retardant
A, the first step, stock.According to above-mentioned formula and its technical requirements, prepare required a variety of materials in advance.
B, second step, the dosage component of solid during mixed dissolution is formulated.By the material of each solid chemicals component in formula point
It is not added in dissolving tank, adding order is not restricted.Then, then toward addition medicament dispersible carrier in dissolving tank (liquid is pure
Tap water H2O).Medicament solid constituent and medicament dispersible carrier are all added after completion, you can what startup dissolving tank carried stirs
Device is mixed, material in groove is stirred, is disperseed, is dissolved into the mixed solution being completely dissolved.
C, the 3rd step, retardant solution filtering, store, be stand-by.After composite flame-retardant agent completes mixed dissolution, by filtering off
Except insoluble matter impurity, you can it is quantitatively injected, is stored in dedicated chemical pond, it is stand-by.
According to above-mentioned formula and preparation method, you can the water-based fire retardant glued board environment-friendly type composite flame-proof of the present invention is made
Agent (solution).
(3) use of fire retardant and effect
The method soaked using normal temperature and pressure, soaks 24 by wood single-plate in advance prepared composite flame-proof agent solution
Hour, it is ensured that fire retardant does agent drugloading rate >=60 kilogram/m3；Then, wood single-plate is dried into moisture content≤16% naturally；It
Afterwards, according to the mask-making technology of water-based glued board, gluing, assembly, cold pressing, hot pressing, sanding, saw side are carried out to dry fire-retardant veneer
Deng processing, the water-based fire retardant glued board finished product of no aldehyde is made.And to its fire resistance of finished product sampling Detection and main physicochemical property.It is real
Border production application the result shows that, this kind of fire retardant can be compatible with water-based no aldehyde glue, does not influence the production of normal process, cold
Pressure, hot pressing effect are normal.Model testing result shows, product Strength of Plywood detection value for 2.19MPa (standard setting >=
0.7MPa)；Dipping and stripping testing result is qualified, and glue-line does not come unglued (standard setting：Any glue-line strip length ＜ in each side of test specimen
25mm)；Fire resistance oxygen index (OI) detection value is 68.3%.The verification result tested from above application, the fire retardant are used for
Water-based glued board, can produce the water-based fire retardant glued board of superior performance；Fire retardant can be compatible with water-based no aldehyde glue, and fire retardant makes
Do not impacted with to normal production, product has preferable physicochemical property and fire resistance, and application effect is preferable.
Embodiment 2：A kind of water-based fire retardant glued board is with environment-friendly type composite flame-retardant agent and its preparation and applies (B)
(1) formula of fire retardant
(1) expansion type flame retardant：Material selection phosphorus nitrogen system faintly acid inorganic salts compound GUP03 (supply producers：Lanzhou
Water-based Science and Technology Ltd. of section day), technical grade high-class product, 20 kilograms of dosage；
(2) smoke inhibition fire retardant：Material selection phosphorus nitrogen system alkalescent inorganic salts compound ZRK12 (supply producers：Lanzhou section
Its water-based Science and Technology Ltd.), technical grade high-class product, 4 kilograms of dosage；
(3) anti-dripping melt fire retardant：Material selection boron system inorganic compound BY12 (supply producers：Water-based section of Lanzhou section day
Skill Co., Ltd), technical grade high-class product, 6 kilograms of dosage；
(4) synergistic flame retardant：Material selection nitrogen system Inorganic Ammonium salt compound L S03 (supply producers：Lanzhou section it is water-based
Science and Technology Ltd.), technical grade high-class product, 6 kilograms of dosage；
(5) carbon forming agent：Material selection multicomponent alcoholics compound PV10 (supply producers：The water-based limited public affairs of science and technology of Lanzhou section day
Department), technical grade high-class product, 4 kilograms of dosage；
(6) medicament dispersible carrier：The pure tap water (H2O) of material selection liquid, 80 kilograms of dosage；
(2) preparation method of fire retardant
A, the first step, stock.According to above-mentioned formula and its technical requirements, prepare required a variety of materials in advance.
B, second step, the dosage component of solid during mixed dissolution is formulated.By the material of each solid chemicals component in formula point
It is not added in dissolving tank, adding order is not restricted.Then, then toward addition medicament dispersible carrier in dissolving tank (liquid is pure
Tap water H2O).Medicament solid constituent and medicament dispersible carrier are all added after completion, you can what startup dissolving tank carried stirs
Device is mixed, material in groove is stirred, is disperseed, is dissolved into the mixed solution being completely dissolved.
C, the 3rd step, retardant solution filtering, store, be stand-by.After composite flame-retardant agent completes mixed dissolution, by filtering off
Except insoluble matter impurity, you can it is quantitatively injected, is stored in dedicated chemical pond, it is stand-by.
According to above-mentioned formula and preparation method, you can a kind of signified water-based fire retardant glued board environment-friendly type of the present invention is made
Composite flame-retardant agent (solution).
(3) use of fire retardant and effect
The method soaked using normal temperature and pressure, soaks 24 by wood single-plate in advance prepared composite flame-proof agent solution
Hour, it is ensured that fire retardant does agent drugloading rate >=60 kilogram/m3；Then, wood single-plate is dried into moisture content≤16% naturally；It
Afterwards, according to the mask-making technology of water-based glued board, gluing, assembly, cold pressing, hot pressing, sanding, saw side are carried out to dry fire-retardant veneer
Deng processing, the water-based fire retardant glued board finished product of no aldehyde is made.And to its fire resistance of finished product sampling Detection and main physicochemical property.It is real
Border production application the result shows that, this kind of fire retardant can be compatible with water-based no aldehyde glue, does not influence the production of normal process, cold
Pressure, hot pressing effect are normal.Model testing result shows, product Strength of Plywood detection value for 1.35MPa (standard setting >=
0.7MPa)；Dipping and stripping testing result is qualified, and glue-line does not come unglued (standard setting：Any glue-line strip length ＜ in each side of test specimen
25mm)；Fire resistance oxygen index (OI) detection value is 83.7%.The verification result tested from above application, the fire retardant are used for
Water-based glued board, can produce the water-based fire retardant glued board of superior performance；Fire retardant can be compatible with water-based no aldehyde glue, and fire retardant makes
Do not impacted with to normal production, product has preferable physicochemical property and fire resistance, and application effect is preferable.
Claims (9)
1. a kind of water-based fire retardant glued board environment-friendly type composite flame-retardant agent, it is characterised in that by each component system of following weight parts
Into：
16~20 parts of phosphorus nitrogen system faintly acid inorganic salts compound, 2~4 parts of phosphorus nitrogen system alkalescent inorganic salts compound, boron system
4~6 parts of inorganic compound, 5~7 parts of nitrogen system Inorganic Ammonium salt compounds, 2~4 parts of multicomponent alcoholics compound, liquid pure water
70~90 parts.
2. water-based fire retardant glued board environment-friendly type composite flame-retardant agent according to claim 1, it is characterised in that the phosphorus nitrogen
Be faintly acid inorganic salts compound be GUP01, GUP02, GUP03 in one or more.
3. water-based fire retardant glued board environment-friendly type composite flame-retardant agent according to claim 1, it is characterised in that the phosphorus nitrogen
Be alkalescent inorganic salts compound be ZRK12, ZRK13, ZEK14 in one or more.
4. water-based fire retardant glued board environment-friendly type composite flame-retardant agent according to claim 1, it is characterised in that the boron system
One or more in inorganic compound BY10, BY11, BY12.
5. water-based fire retardant glued board environment-friendly type composite flame-retardant agent according to claim 1, it is characterised in that the nitrogen system
One or more in Inorganic Ammonium salt compound L S01, LS02, LS03.
6. water-based fire retardant glued board environment-friendly type composite flame-retardant agent according to claim 1, it is characterised in that described polynary
One or more in alcohol compound PV10, PV11, PV12.
A kind of 7. preparation side of water-based fire retardant glued board environment-friendly type composite flame-retardant agent as described in any one in 1-6 such as claim
Method, it is characterised in that filtered after all the components are uniformly mixed and water-based fire retardant glued board environment-friendly type composite flame-retardant agent is made.
A kind of 8. water-based fire retardant glued board, it is characterised in that the water-based fire retardant gluing described in any one in claim 1-6
Plate is made by the use of environment-friendly type composite flame-retardant agent as fire retardant, and fire retardant drugloading rate is >=60kg/m3。
9. the application of water-based fire retardant glued board environment-friendly type composite flame-retardant agent as described in any one in a kind of 1-6 such as claim,
It is characterized in that, in the preparation of water-based fire retardant glued board, wood single-plate is immersed in the fire retardant fire-retardant veneer is made and
Water-based fire retardant glued board is further prepared, and controls the fire retardant drugloading rate >=60kg/m3。
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710986361.1A CN107901162A (en) | 2017-10-20 | 2017-10-20 | A kind of water-based fire retardant glued board environment-friendly type composite flame-retardant agent, water-based fire retardant glued board, preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710986361.1A CN107901162A (en) | 2017-10-20 | 2017-10-20 | A kind of water-based fire retardant glued board environment-friendly type composite flame-retardant agent, water-based fire retardant glued board, preparation method and application |
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| Publication Number | Publication Date |
|---|---|
| CN107901162A true CN107901162A (en) | 2018-04-13 |
Family
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| CN201710986361.1A Pending CN107901162A (en) | 2017-10-20 | 2017-10-20 | A kind of water-based fire retardant glued board environment-friendly type composite flame-retardant agent, water-based fire retardant glued board, preparation method and application |
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| CN (1) | CN107901162A (en) |
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| CN108656250A (en) * | 2018-05-30 | 2018-10-16 | 德华兔宝宝装饰新材股份有限公司 | A kind of flame-retardant impregnating glued membrane paper face artificial board and its manufacturing method |
| CN108656251A (en) * | 2018-05-30 | 2018-10-16 | 德华兔宝宝装饰新材股份有限公司 | A kind of fire-retardant ecological board and its manufacturing method |
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| CN108656250A (en) * | 2018-05-30 | 2018-10-16 | 德华兔宝宝装饰新材股份有限公司 | A kind of flame-retardant impregnating glued membrane paper face artificial board and its manufacturing method |
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