CN107868028A - A kind of method that zeaxanthin acid dipalmitate is extracted in the raw material from liquid medlar - Google Patents
A kind of method that zeaxanthin acid dipalmitate is extracted in the raw material from liquid medlar Download PDFInfo
- Publication number
- CN107868028A CN107868028A CN201711074611.0A CN201711074611A CN107868028A CN 107868028 A CN107868028 A CN 107868028A CN 201711074611 A CN201711074611 A CN 201711074611A CN 107868028 A CN107868028 A CN 107868028A
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- China
- Prior art keywords
- matrimony vine
- zeaxanthin
- extract
- acid dipalmitate
- concentrate
- Prior art date
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- 229960002477 riboflavin Drugs 0.000 description 1
- 235000005493 rutin Nutrition 0.000 description 1
- IKGXIBQEEMLURG-BKUODXTLSA-N rutin Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@@H]1OC[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](OC=2C(C3=C(O)C=C(O)C=C3OC=2C=2C=C(O)C(O)=CC=2)=O)O1 IKGXIBQEEMLURG-BKUODXTLSA-N 0.000 description 1
- 229960004555 rutoside Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000000194 supercritical-fluid extraction Methods 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XACHQDDXHDTRLX-HZXCUAKRSA-N zeaxanthin dipalmitate Chemical compound CC1(C)CC(OC(=O)CCCCCCCCCCCCCCC)CC(C)=C1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CC(OC(=O)CCCCCCCCCCCCCCC)CC1(C)C XACHQDDXHDTRLX-HZXCUAKRSA-N 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/105—Plant extracts, their artificial duplicates or their derivatives
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/10—Animal feeding-stuffs obtained by microbiological or biochemical processes
- A23K10/12—Animal feeding-stuffs obtained by microbiological or biochemical processes by fermentation of natural products, e.g. of vegetable material, animal waste material or biomass
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- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/02—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation containing fruit or vegetable juices
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/38—Other non-alcoholic beverages
- A23L2/382—Other non-alcoholic beverages fermented
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/30—Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/125—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives containing carbohydrate syrups; containing sugars; containing sugar alcohols; containing starch hydrolysates
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/20—Reducing nutritive value; Dietetic products with reduced nutritive value
- A23L33/21—Addition of substantially indigestible substances, e.g. dietary fibres
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
- C07C403/24—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by six-membered non-aromatic rings, e.g. beta-carotene
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- C07C2601/00—Systems containing only non-condensed rings
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Abstract
The invention discloses a kind of method that zeaxanthin acid dipalmitate is extracted in raw material from liquid medlar, it is beaten to obtain matrimony vine pulp, enzymolysis, fluid extraction, vacuum desolvation with fresh fructus lycii, rehydration matrimony vine and obtains zeaxanthin acid dipalmitate extract, then manufactures the zeaxanthin acid dipalmitate micro-capsule powder of different content；The present invention respectively obtains matrimony vine dietary fiber and matrimony vine albumen and matrimony vine syrup from the residue of extraction zeaxanthin acid dipalmitate, and extraction has obtained other matrimony vine functional components such as matrimony vine flavones, polysaccharide, alkaloid；Present invention reduces the extraction cost of matrimony vine functional materials, improves the raw material availability of matrimony vine, raw material is accomplished to eat the dry added value for bleeding, improving raw material.
Description
Technical field：
The invention belongs to field of biological extraction, concretely relates to one kind and extracts zeaxanthin from liquid medlar raw material
The method of acid dipalmitate.
Technical background：
In matrimony vine containing abundant carotenoid, matrimony vine flavones, LBP-X, glycine betaine, monosaccharide and disaccharide, riboflavin,
Taurine, unrighted acid, and 18 kinds of amino acid and 19 kinds of essential trace elements.Carotenoid includes luteole
And its esters, physalin, kryptoxanthin, beta carotene, wherein the zeaxanthin with improving eyesight function be in all fruit most
Gao Zhe.
Deep-processing and colligating-using on matrimony vine, it has been disclosed that technology have《Supercritical Chinese wolfberry fruit dregs extract and its life
Production method》(CN 100400133C), its technical scheme use supercritical extraction technique, and the main component of extract is matrimony vine seed
The aliphatic acid such as oil, oleic acid and linoleic acid account for more than the 90% of extract, and zeaxanthin only contains 0.6%~0.7%, extraction cost
Height, it is less efficient.Authorized announcement date is that 2016.03.16 patents of invention " extract the side of zeaxanthin from matrimony vine, matrimony vine waste residue
Matrimony vine or Chinese wolfberry fruit dregs are separated into matrimony vine seed and matrimony vine pulp by method " (CN103130698B) patent of invention, the technical scheme, point
High concentration zeaxanthin extract and the matrimony vine seed of high-purity Cui Qu not can be obtained, this method is extracted with solid material,
Fresh fruit needs drying to extract, and increases extraction cost.There is presently no find directly using fresh fructus lycii or wolfberry juice, wolfberry fruit syrup as
Raw material carries out integrating extraction zeaxanthin acid dipalmitate and zeaxanthin, flavones, polysaccharide, the report of glycine betaine, also has not seen
The report of dietary fiber and matrimony vine protein is separated from matrimony vine, also has not seen the report that matrimony vine syrup is made using matrimony vine, more
Have not seen the report for being processed with matrimony vine and remaining carbohydrate and carrying out fodder yeast culture.Existing extracting method production cost is higher, matrimony vine
The comprehensive utilization ratio of raw material is relatively low.
The content of the invention：
The present invention provides a kind of method that zeaxanthin acid dipalmitate is extracted in raw material from liquid medlar, solves existing skill
Art extraction cost is high, the low technical problem of efficiency, improves the extraction process of zeaxanthin acid dipalmitate, solves with fresh fructus lycii
Or the technical problem extracted with liquid material, improve the comprehensive utilization ratio of matrimony vine.
To achieve the above object, the present invention provide one kind from liquid medlar raw material extract zeaxanthin acid dipalmitate with
And zeaxanthin, flavones, polysaccharide, dietary fiber, glycine betaine, the extracting method of matrimony vine syrup, and matrimony vine starch-based product and matrimony vine
Eyesight beverage and matrimony vine medlar oil, the preparation method of matrimony vine ball.
The step of zeaxanthin acid dipalmitate is extracted from liquid medlar raw material is as follows：
1) matrimony vine pretreatment of raw material obtains wolfberry fruit syrup, pectase is then added in obtained wolfberry fruit syrup, cellulase is carried out
Enzymolysis；
Further, the matrimony vine pretreatment of raw material refers to dry wolfberry rehydration, matrimony vine slag rehydration, and mashing remove seed obtains matrimony vine
Slurry；
Further, the matrimony vine pretreatment of raw material refers to fresh fructus lycii cleaning, mashing remove seed, is concentrated to give wolfberry fruit syrup；
Further, the matrimony vine pretreatment of raw material refers to that fresh fructus lycii, rehydration matrimony vine, rehydration matrimony vine slag mashing remove seed obtain Chinese holly
Fructus lycii is starched, and the Wolfberry powder of raw material weight 0-100% is added in matrimony vine pulp, stir to obtain wolfberry fruit syrup；
Further, added Wolfberry powder is broken wall wolfberry fruit powder of the granularity more than 300 mesh；
Further, the matrimony vine pretreatment of raw material refers to that fresh fructus lycii and a certain proportion of dry wolfberry are beaten to obtain matrimony vine together
Slurry；
Further, the matrimony vine pretreatment of raw material refers to that Wolfberry powder dissolves to obtain wolfberry fruit syrup.
2) wolfberry fruit syrup after enzymolysis is added into extracting system, adds extractant, closed extraction, extracting pressure is maintained at
0.1-10Mpa, the settable backflow spray of extracting system, may also set up stirring；Extractant is reclaimed into parsing when reaching balance
Tank, decompression separate out extract, reclaim extractant, collect zeaxanthin acid dipalmitate extract, complete by some grades of extractions
Wolfberry fruit syrup into extraction is then released from extractor bottom.
Also multi-stage counter current extraction can be carried out, the matrimony vine pulp after enzymolysis is added to first extraction of multi-stage counter current extraction system
Take in tank, add the extractant from next stage (fresh extractant), carry out closed extraction, can be stirred during extraction, also may be used
Backflow, extracting pressure are maintained at 0.1-10Mpa, and reclaiming extractant into parsing tank, decompression when reaching balance analyses extract
Go out, reclaim extractant, collect zeaxanthin acid dipalmitate extract, pulp then enters next stage extractor, and addition comes from down
The extractant of one-level (fresh extractant) is extracted, and reclaims the extractant containing extract into temporary storage tank when reaching balance,
It is passed through the first extractor to be extracted, pulp then enters third level extractor.So by some grades of extractions, the Chinese holly extracted is completed
Qi slurry is then released from afterbody extractor bottom；The flow direction of wolfberry fruit syrup and the flow direction of extractant on the contrary, from enter extracting system to
Extracting system is discharged, the content of zeaxanthin acid dipalmitate gradually reduces, until being zero after some grades of extractions；Extractant is then
On the contrary, the content of zeaxanthin acid dipalmitate therein is stepped up after some grades of extractions, until after first order extraction
Reach highest and decompress precipitation.
Further, extracting pressure is maintained at 0.4-0.5Mpa.
Further, the extractant is subcritical fluids, is propane, butane, iso-butane (R600a), 1,1,1,2- tetra-
One kind in fluoroethane (R134a), dimethyl ether (DME), liquefied petroleum gas (LPG), carbon dioxide and sulfur hexafluoride.
Further, extractant recovery is reclaimed by compressor.
Further, the ethanol of raw material weight 0-10% is added when adding fresh extractant.
3) the zeaxanthin acid dipalmitate extract being collected into carries out vacuum desolvation, until extractant remains in extract
Amount is less than 8ppm, collects zeaxanthin acid dipalmitate extract；
4) the zeaxanthin acid dipalmitate that the zeaxanthin acid dipalmitate extract obtained is fabricated to different content is micro-
Capsule powder；
A kind of method for extracting zeaxanthin in matrimony vine, zeaxanthin acid dipalmitate extract carry out saponification, separation, knot
Crystalline substance, sterling zeaxanthin is dried to obtain, obtained sterling zeaxanthin is fabricated to the micro-capsule powder of different zeaxanthins.
The compositions such as rutin and chlorogenic acid are mainly contained in matrimony vine flavones, it is yellow that one kind extracts matrimony vine from liquid medlar raw material
The method of ketone, is comprised the steps of：
1) after the extraction being collected into the method for zeaxanthin acid dipalmitate is extracted in the above-mentioned raw material from liquid medlar
Wolfberry fruit syrup vacuum desolvation, until extractant residual quantity is less than 8ppm, collection wolfberry fruit syrup is standby.
2) filter, obtain matrimony vine screenings and clear liquid, clear liquid concentration, obtain concentrate；This concentrate can be used as matrimony vine syrup.
3) alcohol is added in concentrate, adjustment alcohol content reaches more than 80%, stands, isolate sediment and clear liquid；
4) further concentration can obtain second of matrimony vine syrup after clear liquid recovered alcohol；With non-pole after clear liquid recovered alcohol
Property and the further separating-purifying of low pole macroreticular resin obtain matrimony vine flavones and remaining raffinate；Raffinate is further concentrated to give the 3rd
Kind matrimony vine syrup.
A kind of matrimony vine dietary fiber, utilize the method and step 1 that flavones is extracted from liquid medlar raw material) obtained wolfberry fruit syrup
Slag forms through drying, crushing.
A kind of preparation method of LBP-X, is comprised the steps of：
1) method and step 2 of flavones is extracted in matrimony vine) obtained sediment adds appropriate water to dissolve, and reach concentration
10%；
2) 20% chloroform and 4% n-butanol is added in above-mentioned solution, acutely concussion 30 minutes, centrifuged, returned
Accept the chloroform of layer, pour out supernatant, reclaim n-butanol, by the albuminate washing in middle level it is dry matrimony vine albumen；Return
Receive the supernatant after n-butanol and repeat above-mentioned technique, until occurring without albuminate, obtain supernatant；
3) vacuum freeze drying obtains LBP-X after the supernatant concentration obtained.
A kind of extracting method of medlar biological alkali, with the method and step 4 that flavones is extracted in matrimony vine) obtained raffinate is through macropore
Resin or ion-exchange treatment, obtain permeate and eluent, eluent again through desalination, concentration, separate out crystallization, dry that matrimony vine gives birth to
Alkaloids；Permeate is concentrated to obtain the 4th kind of matrimony vine syrup.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：
Wolfberry juice or fermentation wolfberry juice 5-50%, white granulated sugar 5-10%, taurine 0.01-1%, cassia seed extract
0.1-5%, chrysanthemum extract 0.1-5%, blueberry juice 1-5%, grape seed extract 0.1-5%, vitamin C 0.01-
1%th, oligosaccharide 0.1-1%, lutein 0.001-0.1%, arabinose are some, zeaxanthin acid dipalmitate micro-capsule or jade
Cream-coloured matter micro-capsule is some, acid, stabilizer, emulsifying agent are some, and remaining is water.Further, the addition of the arabinose
Amount is 3-the 5% of white granulated sugar；Further, the content ratio of the zeaxanthin and lutein is 1:5.
A kind of matrimony vine starch-based product, containing matrimony vine 4-10%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin
Or two kinds, its addition with control the content (mass percent) of the zeaxanthin in the matrimony vine starch-based product 0-
0.1%.Further, the matrimony vine starch-based product includes matrimony vine bean vermicelli, matrimony vine vermicelli, matrimony vine ground rice, matrimony vine rice noodles；Further
Ground, the matrimony vine refer to wolfberry fruit powder, Lycium chinense juice, concentrated medlar juice.
A kind of medlar oil, matrimony vine ball, the matrimony vine that will be collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Slurry filtering, matrimony vine screenings and clear liquid are obtained, clear liquid concentration, obtains concentrate, medlar oil or matrimony vine ball is further made in concentrate；Or
The auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, medlar oil or matrimony vine is further made
Ball.
Another medlar oil, matrimony vine ball, preparation method are：
1) wolfberry fruit syrup being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine is filtered, obtains matrimony vine screenings
And clear liquid, clear liquid concentration, obtain concentrate；
2) the zeaxanthin acid dipalmitate being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine is carried
Take thing or zeaxanthin acid dipalmitate micro-capsule powder that emulsion is made；
3) auxiliary materials such as other Chinese medicine extracts, honey are added in the concentrate of step 1), continue to concentrate after mixing, are concentrated
Addition step 2) obtains zeaxanthin acid dipalmitate after end or medlar oil or matrimony vine is further made in zeaxanthin emulsion
Ball.
A kind of matrimony vine feeds yeast, is followed by with the permeate obtained in the extracting method of medlar biological alkali by composition adjustment
Primary yeast seed liquor progress fermentating breeding, collection cell, drying form.
The present invention obtains following beneficial effect：
1. for the present invention with wolfberry fruit syrup made from medlar fresh fruit or dried fruit of lycium barbarum, matrimony vine slag rehydration, concentrated medlar juice is raw material,
Zeaxanthin acid dipalmitate and its zeaxanthin are extracted from liquid material, raw material use range is expanded, reduces extraction
Cost.
2. fresh fructus lycii of the present invention and dry wolfberry are used in combination, the solid content of slurries is improved, eliminates the work of concentration
Skill, realizes energy-saving, reduces production cost.
3. the present invention respectively obtains matrimony vine dietary fiber and matrimony vine from the residue of extraction zeaxanthin acid dipalmitate
Albumen and matrimony vine syrup, extraction have obtained other matrimony vine functional components such as matrimony vine flavones, polysaccharide, alkaloid, have improved matrimony vine
Utilization rate, raw material is accomplished to eat dry bleed.
4. fresh fructus lycii, rehydration matrimony vine, rehydration matrimony vine slag mashing remove seed obtain matrimony vine pulp, it is complete that matrimony vine is added in matrimony vine pulp
The pretreating scheme of the matrimony vine raw material of powder, the purpose of wolfberry juice concentration was both reached, and had realized energy-saving, and contained extract again
A certain amount of aliphatic acid, it is more convenient the collection of extract zeaxanthin acid dipalmitate.
5. extractant of the present invention uses subcritical fluids, extraction efficiency is high, and extractant recovery is carried out by compressor, together
Prior art is compared to saving energy consumption.
6. the deep processings such as matrimony vine starch-based product, wolfberry bright eye beverage, medlar oil, matrimony vine ball are obtained using wolfberry fruit extract
Product.
7. the different phase of extraction has obtained four kinds of matrimony vine syrup containing difference in functionality material.
Specific embodiment
Embodiment 1
The step of zeaxanthin acid dipalmitate is extracted from liquid medlar raw material is as follows：
1) dry wolfberry or matrimony vine slag add 5 times of water progress rehydration mashing, remove matrimony vine seed and obtain matrimony vine pulp, add in slurry
Pectase, cellulase is added to be digested, it is then high-pressure homogeneous.
2) wolfberry fruit syrup after enzymolysis is added into extracting system, adds extractant, closed extraction, extracting pressure is maintained at
0.4-0.5Mpa, the settable backflow spray of extracting system, may also set up stirring；Extractant is reclaimed into parsing when reaching balance
Tank, decompression separate out extract, reclaim extractant, collect zeaxanthin acid dipalmitate extract, complete by some grades of extractions
Wolfberry fruit syrup into extraction is then released from extractor bottom.Extractant used is propane, butane, iso-butane (R600a), 1,1,1,2- tetra-
One kind in fluoroethane (R134a), dimethyl ether (DME), liquefied petroleum gas (LPG), carbon dioxide and sulfur hexafluoride, the present embodiment
Use butane as extractant.Extractant recovery is reclaimed by compressor.For the ease of the collection of extract, adding
The ethanol of raw material weight 0% is added during fresh extractant.
3) the zeaxanthin acid dipalmitate extract being collected into carries out vacuum desolvation, until extractant remains in extract
Amount is less than 8ppm, collects zeaxanthin acid dipalmitate extract.
4) the zeaxanthin acid dipalmitate extract dissolving obtained, emulsification, selects foodstuff glue to pass through spraying as wall material
Dry the zeaxanthin acid dipalmitate micro-capsule powder for being fabricated to different content.
By above gained zeaxanthin acid dipalmitate extract carry out saponification, separation, crystallize, be dried to obtain sterling jade
Cream-coloured matter, obtained sterling zeaxanthin dissolving, emulsification, carries out spray drying as wall material using cellulose or foodstuff glue and is fabricated to
The micro-capsule powder of different zeaxanthins.
Extract what is released in the step 2) of zeaxanthin acid dipalmitate from extractor bottom in the above-mentioned raw material from liquid medlar
Wolfberry fruit syrup is filtered, and obtains matrimony vine screenings and clear liquid, and matrimony vine screenings obtains matrimony vine dietary fiber by drying, crushing；Clear liquid is dense
Contracting, obtains matrimony vine syrup；Add alcohol in concentrate, adjustment alcohol content reaches more than 80%, stands, and isolates sediment and clear
Liquid；Further concentration can obtain second of matrimony vine syrup after clear liquid recovered alcohol；With nonpolar and weak after clear liquid recovered alcohol
The polar macroporous further separating-purifying of resin obtains matrimony vine flavones and remaining raffinate；Remaining raffinate is further concentrated to give the 3rd
Kind matrimony vine syrup；Remaining raffinate obtains permeate and eluent, eluent is again through de- through macroreticular resin or ion-exchange treatment
Salt, concentration, separate out crystallization, dry medlar biological alkali, permeate it is concentrated the 4th kind of matrimony vine syrup.
The above-mentioned sediment isolated adds appropriate water to dissolve, and concentration is reached 10%, adds 20% chloroform
N-butanol with 4%, acutely concussion 30 minutes, centrifugation, reclaims the chloroform of lower floor, pours out supernatant, reclaim n-butanol, will
Dry the matrimony vine albumen of albuminate washing in middle level；Supernatant after recovery n-butanol repeats above-mentioned technique, until nothing
Albuminate occurs, and obtains supernatant；Vacuum freeze drying obtains LBP-X after obtained supernatant concentration.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Chinese holly
Qi juice 5%, white granulated sugar 10%, taurine 0.1%, cassia seed extract 0.1%, chrysanthemum extract 0.5%, blueberry juice 1.5%,
Grape seed extract 0.15%, vitamin C 0.01%, oligosaccharide 0.11%, lutein 0.0008%, arabinose 0.15%,
Extract obtained zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule is some, make zeaxanthin and lutein in beverage
Content ratio is 1:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Hair
Ferment wolfberry juice 5%, white granulated sugar 10%, taurine 0.1%, cassia seed extract 0.1%, chrysanthemum extract 0.5%, blueberry juice
1.5%th, grape seed extract 0.15%, vitamin C 0.01%, oligosaccharide 0.11%, lutein 0.0005%, arabinose
0.15%th, zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule are some, make containing for zeaxanthin and lutein in beverage
It is 1 to measure ratio:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of matrimony vine bean vermicelli, containing matrimony vine (butt) 8%, containing in the zeaxanthin acid dipalmitate extracted or zeaxanthin
One or two, its addition to control the content of the zeaxanthin in matrimony vine bean vermicelli (mass percent) 0.0006%,
Matrimony vine is ground into wolfberry fruit powders more than 300 mesh, wolfberry fruit powder and zeaxanthin acid dipalmitate are added in starch, mixing, is added
Water beat paste, adjust powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, drying form matrimony vine bean vermicelli.
A kind of matrimony vine vermicelli, containing matrimony vine (butt) 6%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition is to control the content of the zeaxanthin in matrimony vine vermicelli (mass percent) to soak matrimony vine 0.0008%
Bubble mashing homogeneous adds wolfberry fruit syrup and zeaxanthin acid dipalmitate in starch, mixing, added into wolfberry fruit syrups more than 300 mesh
Water beat paste, adjust powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, drying form matrimony vine vermicelli.
A kind of matrimony vine ground rice, containing matrimony vine (butt) 4%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition 0.0005%, rice, washes rice, bubble with the content (mass percent) of the zeaxanthin in matrimony vine ground rice
Rice plus starch add wolfberry juice, add zeaxanthin acid dipalmitate, are milled, evaporate self heating, wire squeeze, filoselle and make thinner, be aging, multiple
Steaming, cooling, loose wire, drying form matrimony vine ground rice.
A kind of matrimony vine rice noodles, containing matrimony vine (butt) 10%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin
Or two kinds, its addition is to control the content of the zeaxanthin in matrimony vine rice noodles (mass percent) 0.0008%, rice warp
The processes such as everfermentation, addition matrimony vine defibrination, clear filter, steaming, extruding, cooking form matrimony vine rice noodles.
A kind of medlar oil, matrimony vine ball, the matrimony vine that will be collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Slurry filtering, matrimony vine screenings and clear liquid are obtained, clear liquid concentration, obtains concentrate, medlar oil or matrimony vine ball is further made in concentrate；Or
The auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, medlar oil or matrimony vine is further made
Ball；Or added in concentrate by the double palm fibres of the zeaxanthin being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of glycerin monostearate extract or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, further make
Into medlar oil, matrimony vine ball；Or the auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, concentrate
Add after end and carried by the zeaxanthin acid dipalmitate being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of taking thing or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, be further made medlar oil,
Matrimony vine ball.
A kind of matrimony vine feeds yeast, is followed by with the permeate obtained in the extracting method of medlar biological alkali by composition adjustment
Primary yeast seed liquor progress fermentating breeding, collection cell, drying form.
The present embodiment is only to illustrate technical solution of the present invention, and the embodiment of other combinations in such as each data area is herein
Just do not enumerate, but belong to the scope of the present invention.
Embodiment 2
The step of zeaxanthin acid dipalmitate is extracted from liquid medlar raw material is as follows：
2) dry wolfberry or matrimony vine slag add 3.5 times of water and carry out rehydration mashing, remove matrimony vine seed and obtain matrimony vine pulp, in slurry
Addition pectase, cellulase are digested, then high-pressure homogeneous.
2) the matrimony vine pulp after enzymolysis is added in first extractor of multi-stage counter current extraction system, added from next
The extractant of level (fresh extractant), opens backflow and stirring carries out closed extraction, and extracting pressure is maintained at 0.4-0.5Mpa,
Reclaiming extractant into parsing tank, decompression when reaching balance separates out extract, reclaims extractant, collects the double palms of zeaxanthin
Acid esters extract, pulp then enter next stage extractor, add the extractant from next stage (fresh extractant) and are extracted,
The extractant containing extract is reclaimed into temporary storage tank when reaching balance, the first extractor is passed through and is extracted, pulp then enters
Third level extractor.So by some grades of extractions, the wolfberry fruit syrup for completing extraction is then released from afterbody extractor bottom；Matrimony vine
The flow direction of slurry and the flow direction of extractant on the contrary, from enter extracting system to discharge extracting system, zeaxanthin acid dipalmitate
Content gradually reduces, until being zero after some grades of extractions；Extractant then on the contrary, by some grades extraction after maize therein
The content of matter acid dipalmitate is stepped up, until reaching highest after first order extraction and decompressing precipitation.Extractant enters extraction
Pressure is maintained at 0.4-0.5Mpa when the conveying and extraction of tank.Extractant used is propane, butane, iso-butane (R600a), 1,
One kind in 1,1,2- HFC-134a (R134a), dimethyl ether (DME), liquefied petroleum gas (LPG), carbon dioxide and sulfur hexafluoride,
The present embodiment is using liquefied petroleum gas (LPG) alkane as extractant.Extractant recovery is reclaimed by compressor.In order to just
In the collection of extract, the ethanol of addition raw material weight 5% when adding fresh extractant.
3) the zeaxanthin acid dipalmitate extract being collected into carries out vacuum desolvation, until extractant remains in extract
Amount is less than 8ppm, collects zeaxanthin acid dipalmitate extract.
4) the zeaxanthin acid dipalmitate extract dissolving obtained, emulsification, selects foodstuff glue to pass through spraying as wall material
Dry the zeaxanthin acid dipalmitate micro-capsule powder for being fabricated to different content.
By above gained zeaxanthin acid dipalmitate extract carry out saponification, separation, crystallize, be dried to obtain sterling jade
Cream-coloured matter, obtained sterling zeaxanthin dissolving, emulsification, carries out spray drying as wall material using cellulose or foodstuff glue and is fabricated to
The micro-capsule powder of different zeaxanthins.
Extracted in the above-mentioned raw material from liquid medlar in the step 2) of zeaxanthin acid dipalmitate from afterbody extractor
The wolfberry fruit syrup of bottom releasing is filtered, and obtains matrimony vine screenings and clear liquid, and matrimony vine screenings obtains matrimony vine meals fibre by drying, crushing
Dimension；Clear liquid concentrates, and obtains matrimony vine syrup；Alcohol is added in concentrate, adjustment alcohol content reaches more than 80%, stands, isolate
Sediment and clear liquid；Further concentration can obtain second of matrimony vine syrup after clear liquid recovered alcohol；Used after clear liquid recovered alcohol
The nonpolar and further separating-purifying of low pole macroreticular resin obtains matrimony vine flavones and remaining raffinate；Remaining raffinate is further dense
Contracting obtains the third matrimony vine syrup；Remaining raffinate obtains permeate and eluent, eluted through macroreticular resin or ion-exchange treatment
Liquid again through desalination, concentration, separate out crystallization, dry medlar biological alkali, permeate it is concentrated the 4th kind of matrimony vine syrup.
The above-mentioned sediment isolated adds appropriate water to dissolve, and concentration is reached 10%, adds 20% chloroform
N-butanol with 4%, acutely concussion 30 minutes, centrifugation, reclaims the chloroform of lower floor, pours out supernatant, reclaim n-butanol, will
Dry the matrimony vine albumen of albuminate washing in middle level；Supernatant after recovery n-butanol repeats above-mentioned technique, until nothing
Albuminate occurs, and obtains supernatant；Vacuum freeze drying obtains LBP-X after obtained supernatant concentration.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Chinese holly
Qi juice 5%, white granulated sugar 10%, taurine 0.1%, cassia seed extract 0.1%, chrysanthemum extract 0.5%, blueberry juice 1.5%,
Grape seed extract 0.15%, vitamin C 0.01%, oligosaccharide 0.11%, lutein 0.0008%, arabinose 0.15%,
Extract obtained zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule is some, make zeaxanthin and lutein in beverage
Content ratio is 1:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Hair
Ferment wolfberry juice 5%, white granulated sugar 10%, taurine 0.1%, cassia seed extract 0.1%, chrysanthemum extract 0.5%, blueberry juice
1.5%th, grape seed extract 0.15%, vitamin C 0.01%, oligosaccharide 0.11%, lutein 0.0005%, arabinose
0.15%th, zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule are some, make containing for zeaxanthin and lutein in beverage
It is 1 to measure ratio:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of matrimony vine bean vermicelli, containing matrimony vine (butt) 8%, containing in the zeaxanthin acid dipalmitate extracted or zeaxanthin
One or two, its addition to control the content of the zeaxanthin in matrimony vine bean vermicelli (mass percent) 0.0006%,
Matrimony vine is ground into wolfberry fruit powders more than 300 mesh, wolfberry fruit powder and zeaxanthin acid dipalmitate are added in starch, mixing, is added
Water beat paste, adjust powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, drying form matrimony vine bean vermicelli.
A kind of matrimony vine vermicelli, containing matrimony vine (butt) 6%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition is to control the content of the zeaxanthin in matrimony vine vermicelli (mass percent) to soak matrimony vine 0.0008%
Bubble mashing homogeneous adds wolfberry fruit syrup and zeaxanthin acid dipalmitate in starch, mixing, added into wolfberry fruit syrups more than 300 mesh
Water beat paste, adjust powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, drying form matrimony vine vermicelli.
A kind of matrimony vine ground rice, containing matrimony vine (butt) 4%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition 0.0005%, rice, washes rice, bubble with the content (mass percent) of the zeaxanthin in matrimony vine ground rice
Rice plus starch add wolfberry juice, add zeaxanthin acid dipalmitate, are milled, evaporate self heating, wire squeeze, filoselle and make thinner, be aging, multiple
Steaming, cooling, loose wire, drying form matrimony vine ground rice.
A kind of matrimony vine rice noodles, containing matrimony vine (butt) 10%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin
Or two kinds, its addition is to control the content of the zeaxanthin in matrimony vine rice noodles (mass percent) 0.0008%, rice warp
The processes such as everfermentation, addition matrimony vine defibrination, clear filter, steaming, extruding, cooking form matrimony vine rice noodles.
A kind of medlar oil, matrimony vine ball, the matrimony vine that will be collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Slurry filtering, matrimony vine screenings and clear liquid are obtained, clear liquid concentration, obtains concentrate, medlar oil or matrimony vine ball is further made in concentrate；Or
The auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, medlar oil or matrimony vine is further made
Ball；Or added in concentrate by the double palm fibres of the zeaxanthin being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of glycerin monostearate extract or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, further make
Into medlar oil, matrimony vine ball；Or the auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, concentrate
Add after end and carried by the zeaxanthin acid dipalmitate being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of taking thing or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, be further made medlar oil,
Matrimony vine ball.
A kind of matrimony vine feeds yeast, is followed by with the permeate obtained in the extracting method of medlar biological alkali by composition adjustment
Primary yeast seed liquor progress fermentating breeding, collection cell, drying form.
The present embodiment is only to illustrate technical solution of the present invention, and the embodiment of other combinations in such as each data area is herein
Just do not enumerate, but belong to the scope of the present invention.
Embodiment 3
The step of zeaxanthin acid dipalmitate is extracted from liquid medlar raw material is as follows：
1) matrimony vine pretreatment of raw material, fresh fructus lycii cleaning mashing remove matrimony vine seed, and the Wolfberry powder for adding 30% dissolves to obtain Chinese holly
Qi is starched, and addition pectase, cellulase are digested.
2) the matrimony vine pulp after enzymolysis is added in first extractor of multi-stage counter current extraction system, added from next
The extractant of level (fresh extractant), opens backflow and stirring carries out closed extraction, and extracting pressure is maintained at 0.4-0.5Mpa,
Reclaiming extractant into parsing tank, decompression when reaching balance separates out extract, reclaims extractant, collects the double palms of zeaxanthin
Acid esters extract, pulp then enter next stage extractor, add the extractant from next stage (fresh extractant) and are extracted,
The extractant containing extract is reclaimed into temporary storage tank when reaching balance, the first extractor is passed through and is extracted, pulp then enters
Third level extractor.So by some grades of extractions, the wolfberry fruit syrup for completing extraction is then released from afterbody extractor bottom；Matrimony vine
The flow direction of slurry and the flow direction of extractant on the contrary, from enter extracting system to discharge extracting system, zeaxanthin acid dipalmitate
Content gradually reduces, until being zero after some grades of extractions；Extractant then on the contrary, by some grades extraction after maize therein
The content of matter acid dipalmitate is stepped up, until reaching highest after first order extraction and decompressing precipitation.Extractant enters extraction
Pressure is maintained at 0.4-0.5Mpa when the conveying and extraction of tank.Extractant used is propane, butane, iso-butane (R600a), 1,
One kind in 1,1,2- HFC-134a (R134a), dimethyl ether (DME), liquefied petroleum gas (LPG), carbon dioxide and sulfur hexafluoride,
The present embodiment is using propane as extractant.Extractant recovery is reclaimed by compressor.For the ease of the receipts of extract
Collection, the ethanol of raw material weight 10% is added when adding fresh extractant.
3) the zeaxanthin acid dipalmitate extract being collected into carries out vacuum desolvation, until extractant remains in extract
Amount is less than 8ppm, collects zeaxanthin acid dipalmitate extract.
4) the zeaxanthin acid dipalmitate extract dissolving obtained, emulsification, selects foodstuff glue to pass through spraying as wall material
Dry the zeaxanthin acid dipalmitate micro-capsule powder for being fabricated to different content.
By above gained zeaxanthin acid dipalmitate extract carry out saponification, separation, crystallize, be dried to obtain sterling jade
Cream-coloured matter, obtained sterling zeaxanthin dissolving, emulsification, carries out spray drying as wall material using cellulose or foodstuff glue and is fabricated to
The micro-capsule powder of different zeaxanthins.
Extracted in the above-mentioned raw material from liquid medlar in the step 2) of zeaxanthin acid dipalmitate from afterbody extractor
The wolfberry fruit syrup of bottom releasing is filtered, and obtains matrimony vine screenings and clear liquid, and matrimony vine screenings obtains matrimony vine meals fibre by drying, crushing
Dimension；Clear liquid concentrates, and obtains matrimony vine syrup；Alcohol is added in concentrate, adjustment alcohol content reaches more than 80%, stands, isolate
Sediment and clear liquid；Further concentration can obtain second of matrimony vine syrup after clear liquid recovered alcohol；Used after clear liquid recovered alcohol
The nonpolar and further separating-purifying of low pole macroreticular resin obtains matrimony vine flavones and remaining raffinate；Remaining raffinate is further dense
Contracting obtains the third matrimony vine syrup；Remaining raffinate obtains permeate and eluent, eluted through macroreticular resin or ion-exchange treatment
Liquid again through desalination, concentration, separate out crystallization, dry medlar biological alkali, permeate it is concentrated the 4th kind of matrimony vine syrup.
The above-mentioned sediment isolated adds appropriate water to dissolve, and concentration is reached 10%, adds 20% chloroform
N-butanol with 4%, acutely concussion 30 minutes, centrifugation, reclaims the chloroform of lower floor, pours out supernatant, reclaim n-butanol, will
Dry the matrimony vine albumen of albuminate washing in middle level；Supernatant after recovery n-butanol repeats above-mentioned technique, until nothing
Albuminate occurs, and obtains supernatant；Vacuum freeze drying obtains LBP-X after obtained supernatant concentration.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Chinese holly
Qi juice 10%, white granulated sugar 8%, taurine 0.1%, cassia seed extract 0.2%, chrysanthemum extract 0.5%, blueberry juice 0.5%,
Grape seed extract 0.15%, vitamin C 0.01%, oligosaccharide 0.11%, lutein 0.0009%, arabinose 0.15%,
Extract obtained zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule is some, make zeaxanthin and lutein in beverage
Content ratio is 1:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Hair
Ferment wolfberry juice 10%, white granulated sugar 10%, taurine 0.15%, cassia seed extract 0.21%, chrysanthemum extract 0.5%, blueberry
Juice 0.5%, grape seed extract 0.45%, vitamin C 0.02%, oligosaccharide 0.11%, lutein 0.0006%, arabinose
0.15%th, zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule are some, make containing for zeaxanthin and lutein in beverage
It is 1 to measure ratio:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of matrimony vine bean vermicelli, containing matrimony vine (butt) 8%, containing in the zeaxanthin acid dipalmitate extracted or zeaxanthin
One or two, its addition to control the content of the zeaxanthin in matrimony vine bean vermicelli (mass percent) 0.0001%,
Matrimony vine is ground into wolfberry fruit powders more than 300 mesh, wolfberry fruit powder and zeaxanthin acid dipalmitate are added in starch, mixing, is added
Water beat paste, adjust powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, drying form matrimony vine bean vermicelli.
A kind of matrimony vine vermicelli, containing matrimony vine (butt) 6%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition is to control the content of the zeaxanthin in matrimony vine vermicelli (mass percent) to soak matrimony vine 0.0008%
Bubble mashing homogeneous adds wolfberry fruit syrup and zeaxanthin acid dipalmitate in starch, mixing, added into wolfberry fruit syrups more than 300 mesh
Water beat paste, adjust powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, drying form matrimony vine vermicelli.
A kind of matrimony vine ground rice, containing matrimony vine (butt) 5%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition 0.0006%, rice, washes rice, bubble with the content (mass percent) of the zeaxanthin in matrimony vine ground rice
Rice plus starch add wolfberry juice, add zeaxanthin acid dipalmitate, are milled, evaporate self heating, wire squeeze, filoselle and make thinner, be aging, multiple
Steaming, cooling, loose wire, drying form matrimony vine ground rice.
A kind of matrimony vine rice noodles, containing matrimony vine (butt) 10%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin
Or two kinds, its addition is to control the content of the zeaxanthin in matrimony vine rice noodles (mass percent) 0.0008%, rice warp
The processes such as everfermentation, addition matrimony vine defibrination, clear filter, steaming, extruding, cooking form matrimony vine rice noodles.
A kind of medlar oil, matrimony vine ball, the matrimony vine that will be collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Slurry filtering, matrimony vine screenings and clear liquid are obtained, clear liquid concentration, obtains concentrate, medlar oil or matrimony vine ball is further made in concentrate；Or
The auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, medlar oil or matrimony vine is further made
Ball；Or added in concentrate by the double palm fibres of the zeaxanthin being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of glycerin monostearate extract or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, further make
Into medlar oil, matrimony vine ball；Or the auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, concentrate
Add after end and carried by the zeaxanthin acid dipalmitate being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of taking thing or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, be further made medlar oil,
Matrimony vine ball.
A kind of matrimony vine feeds yeast, is followed by with the permeate obtained in the extracting method of medlar biological alkali by composition adjustment
Primary yeast seed liquor progress fermentating breeding, collection cell, drying form.
The present embodiment is only to illustrate technical solution of the present invention, and the embodiment of other combinations in such as each data area is herein
Just do not enumerate, but belong to the scope of the present invention.
Embodiment 4
The step of zeaxanthin acid dipalmitate is extracted from liquid medlar raw material is as follows：
1) matrimony vine pretreatment of raw material, fresh fructus lycii, 1:3 rehydration matrimony vines, 1:2 rehydration matrimony vine slags are beaten remove seed, obtain matrimony vine pulp,
The Wolfberry powder of raw material weight (butt) 10% is added, stirring and dissolving obtains wolfberry fruit syrup, and addition pectase, cellulase carry out enzyme
Solution, then high-pressure homogeneous, Wolfberry powder used is broken wall wolfberry fruit powder of the granularity more than 300 mesh.
2) the matrimony vine pulp after enzymolysis is added in first extractor of multi-stage counter current extraction system, added from next
The extractant of level (fresh extractant), opens backflow and stirring carries out closed extraction, and extracting pressure is maintained at 0.4-0.5Mpa,
Reclaiming extractant into parsing tank, decompression when reaching balance separates out extract, reclaims extractant, collects the double palms of zeaxanthin
Acid esters extract, pulp then enter next stage extractor, add the extractant from next stage (fresh extractant) and are extracted,
The extractant containing extract is reclaimed into temporary storage tank when reaching balance, the first extractor is passed through and is extracted, pulp then enters
Third level extractor.So by some grades of extractions, the wolfberry fruit syrup for completing extraction is then released from afterbody extractor bottom；Matrimony vine
The flow direction of slurry and the flow direction of extractant on the contrary, from enter extracting system to discharge extracting system, zeaxanthin acid dipalmitate
Content gradually reduces, until being zero after some grades of extractions；Extractant then on the contrary, by some grades extraction after maize therein
The content of matter acid dipalmitate is stepped up, until reaching highest after first order extraction and decompressing precipitation.Extractant enters extraction
Pressure is maintained at 0.4-0.5Mpa when the conveying and extraction of tank.Extractant used is propane, butane, iso-butane (R600a), 1,
One kind in 1,1,2- HFC-134a (R134a), dimethyl ether (DME), liquefied petroleum gas (LPG), carbon dioxide and sulfur hexafluoride,
The present embodiment is used as extractant using HFA 134a (R134a).Extractant recovery is reclaimed by compressor.
For the ease of the collection of extract, the ethanol of addition raw material weight 5% when adding fresh extractant.
3) the zeaxanthin acid dipalmitate extract being collected into carries out vacuum desolvation, until extractant remains in extract
Amount is less than 8ppm, collects zeaxanthin acid dipalmitate extract.
4) the zeaxanthin acid dipalmitate extract dissolving obtained, emulsification, selects foodstuff glue to pass through spraying as wall material
Dry the zeaxanthin acid dipalmitate micro-capsule powder for being fabricated to different content.
By above gained zeaxanthin acid dipalmitate extract carry out saponification, separation, crystallize, be dried to obtain sterling jade
Cream-coloured matter, obtained sterling zeaxanthin dissolving, emulsification, carries out spray drying as wall material using cellulose or foodstuff glue and is fabricated to
The micro-capsule powder of different zeaxanthins.
Extracted in the above-mentioned raw material from liquid medlar in the step 2) of zeaxanthin acid dipalmitate from afterbody extractor
The wolfberry fruit syrup of bottom releasing is filtered, and obtains matrimony vine screenings and clear liquid, and matrimony vine screenings obtains matrimony vine meals fibre by drying, crushing
Dimension；Clear liquid concentrates, and obtains matrimony vine syrup；Alcohol is added in concentrate, adjustment alcohol content reaches more than 80%, stands, isolate
Sediment and clear liquid；Further concentration can obtain second of matrimony vine syrup after clear liquid recovered alcohol；Used after clear liquid recovered alcohol
The nonpolar and further separating-purifying of low pole macroreticular resin obtains matrimony vine flavones and remaining raffinate；Remaining raffinate is further dense
Contracting obtains the third matrimony vine syrup；Remaining raffinate obtains permeate and eluent, eluted through macroreticular resin or ion-exchange treatment
Liquid again through desalination, concentration, separate out crystallization, dry medlar biological alkali, permeate it is concentrated the 4th kind of matrimony vine syrup.
The above-mentioned sediment isolated adds appropriate water to dissolve, and concentration is reached 10%, adds 20% chloroform
N-butanol with 4%, acutely concussion 30 minutes, centrifugation, reclaims the chloroform of lower floor, pours out supernatant, reclaim n-butanol, will
Dry the matrimony vine albumen of albuminate washing in middle level；Supernatant after recovery n-butanol repeats above-mentioned technique, until nothing
Albuminate occurs, and obtains supernatant；Vacuum freeze drying obtains LBP-X after obtained supernatant concentration.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Chinese holly
Qi juice 20%, white granulated sugar 7%, taurine 0.15%, cassia seed extract 0.3%, chrysanthemum extract 0.25%, blueberry juice
1.5%th, grape seed extract 0.25%, vitamin C 0.01%, oligosaccharide 0.11%, lutein 0.005%, arabinose
0.15%th, the obtained zeaxanthin acid dipalmitate micro-capsule of extraction or zeaxanthin micro-capsule are some, make in beverage zeaxanthin and
The content ratio of lutein is 1:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Hair
Ferment wolfberry juice 25%, white granulated sugar 8%, taurine 0.21%, cassia seed extract 0.31%, chrysanthemum extract 0.45%, blueberry
Juice 1.25%, grape seed extract 0.25%, vitamin C 0.01%, oligosaccharide 0.11%, lutein 0.0005%, Arab
Sugar 0.15%, zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule are some, make zeaxanthin and lutein in beverage
Content ratio is 1:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of matrimony vine bean vermicelli, containing matrimony vine (butt) 10%, containing the zeaxanthin acid dipalmitate extracted or zeaxanthin
One or both of, its addition is to control the content of the zeaxanthin in matrimony vine bean vermicelli (mass percent) to exist
0.0009%, matrimony vine is ground into wolfberry fruit powders more than 300 mesh, wolfberry fruit powder and the double palmitic acids of zeaxanthin are added in starch
Ester, mixing, add water beat paste, tune powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, dry form matrimony vine bean vermicelli.
A kind of matrimony vine vermicelli, containing matrimony vine (butt) 6%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition is to control the content of the zeaxanthin in matrimony vine vermicelli (mass percent) to soak matrimony vine 0.0008%
Bubble mashing homogeneous adds wolfberry fruit syrup and zeaxanthin acid dipalmitate in starch, mixing, added into wolfberry fruit syrups more than 300 mesh
Water beat paste, adjust powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, drying form matrimony vine vermicelli.
A kind of matrimony vine ground rice, containing matrimony vine (butt) 5%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition 0.0005%, rice, washes rice, bubble with the content (mass percent) of the zeaxanthin in matrimony vine ground rice
Rice plus starch add wolfberry juice, add zeaxanthin acid dipalmitate, are milled, evaporate self heating, wire squeeze, filoselle and make thinner, be aging, multiple
Steaming, cooling, loose wire, drying form matrimony vine ground rice.
A kind of matrimony vine rice noodles, containing matrimony vine (butt) 5%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition is to control the content of the zeaxanthin in matrimony vine rice noodles (mass percent) 0.004%, and rice is by hair
The processes such as ferment, addition matrimony vine defibrination, clear filter, steaming, extruding, cooking form matrimony vine rice noodles.
A kind of medlar oil, matrimony vine ball, the matrimony vine that will be collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Slurry filtering, matrimony vine screenings and clear liquid are obtained, clear liquid concentration, obtains concentrate, medlar oil or matrimony vine ball is further made in concentrate；Or
The auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, medlar oil or matrimony vine is further made
Ball；Or added in concentrate by the double palm fibres of the zeaxanthin being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of glycerin monostearate extract or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, further make
Into medlar oil, matrimony vine ball；Or the auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, concentrate
Add after end and carried by the zeaxanthin acid dipalmitate being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of taking thing or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, be further made medlar oil,
Matrimony vine ball.
A kind of matrimony vine feeds yeast, is followed by with the permeate obtained in the extracting method of medlar biological alkali by composition adjustment
Primary yeast seed liquor progress fermentating breeding, collection cell, drying form.
The present embodiment is only to illustrate technical solution of the present invention, and the embodiment of other combinations in such as each data area is herein
Just do not enumerate, but belong to the scope of the present invention.
Embodiment 5
The step of zeaxanthin acid dipalmitate is extracted from liquid medlar raw material is as follows：
1) matrimony vine pretreatment of raw material, fresh fructus lycii and dry wolfberry press 1:1 ratio is beaten to obtain wolfberry fruit syrup together, in above-mentioned matrimony vine
Addition pectase, cellulase are digested in slurry, then high-pressure homogeneous.
2) the matrimony vine pulp after enzymolysis is added in first extractor of multi-stage counter current extraction system, added from next
The extractant of level (fresh extractant), opens backflow and stirring carries out closed extraction, and extracting pressure is maintained at 8-9Mpa, reached
Reclaiming extractant into parsing tank, decompression during balance separates out extract, reclaims extractant, collects zeaxanthin acid dipalmitate
Extract, pulp then enter next stage extractor, add the extractant from next stage (fresh extractant) and are extracted, are reached
The extractant containing extract is reclaimed into temporary storage tank during balance, the first extractor is passed through and is extracted, pulp then enters the 3rd
Level extractor.So by some grades of extractions, the wolfberry fruit syrup for completing extraction is then released from afterbody extractor bottom；Wolfberry fruit syrup
Flow direction and the flow direction of extractant are on the contrary, from extracting system is entered to discharge extracting system, the content of zeaxanthin acid dipalmitate
Gradually reduce, until being zero after some grades of extractions；Extractant is then on the contrary, zeaxanthin therein is double after some grades of extractions
The content of palmitate is stepped up, until reaching highest after first order extraction and decompressing precipitation.Extractant enters extractor
Pressure is maintained at 8-9Mpa when conveying and extraction.Extractant used is propane, butane, iso-butane (R600a), 1,1,1,2- tetrafluoro
One kind in ethane (R134a), dimethyl ether (DME), liquefied petroleum gas (LPG), carbon dioxide and sulfur hexafluoride, the present embodiment are adopted
Extractant is used as by the use of carbon dioxide.Extractant recovery is reclaimed by compressor.For the ease of the collection of extract, adding
The ethanol of raw material weight 7% is added when entering fresh extractant.
3) the zeaxanthin acid dipalmitate extract being collected into carries out vacuum desolvation, until extractant remains in extract
Amount is less than 8ppm, collects zeaxanthin acid dipalmitate extract.
4) the zeaxanthin acid dipalmitate extract dissolving obtained, emulsification, selects foodstuff glue to pass through spraying as wall material
Dry the zeaxanthin acid dipalmitate micro-capsule powder for being fabricated to different content.
By above gained zeaxanthin acid dipalmitate extract carry out saponification, separation, crystallize, be dried to obtain sterling jade
Cream-coloured matter, obtained sterling zeaxanthin dissolving, emulsification, carries out spray drying as wall material using cellulose or foodstuff glue and is fabricated to
The micro-capsule powder of different zeaxanthins.
Extracted in the above-mentioned raw material from liquid medlar in the step 2) of zeaxanthin acid dipalmitate from afterbody extractor
The wolfberry fruit syrup of bottom releasing is filtered, and obtains matrimony vine screenings and clear liquid, and matrimony vine screenings obtains matrimony vine meals fibre by drying, crushing
Dimension；Clear liquid concentrates, and obtains matrimony vine syrup；Alcohol is added in concentrate, adjustment alcohol content reaches more than 80%, stands, isolate
Sediment and clear liquid；Further concentration can obtain second of matrimony vine syrup after clear liquid recovered alcohol；Used after clear liquid recovered alcohol
The nonpolar and further separating-purifying of low pole macroreticular resin obtains matrimony vine flavones and remaining raffinate；Remaining raffinate is further dense
Contracting obtains the third matrimony vine syrup；Remaining raffinate obtains permeate and eluent, eluted through macroreticular resin or ion-exchange treatment
Liquid again through desalination, concentration, separate out crystallization, dry medlar biological alkali, permeate it is concentrated the 4th kind of matrimony vine syrup.
The above-mentioned sediment isolated adds appropriate water to dissolve, and concentration is reached 10%, adds 20% chloroform
N-butanol with 4%, acutely concussion 30 minutes, centrifugation, reclaims the chloroform of lower floor, pours out supernatant, reclaim n-butanol, will
Dry the matrimony vine albumen of albuminate washing in middle level；Supernatant after recovery n-butanol repeats above-mentioned technique, until nothing
Albuminate occurs, and obtains supernatant；Vacuum freeze drying obtains LBP-X after obtained supernatant concentration.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Chinese holly
Qi juice 50%, white granulated sugar 2%, taurine 0.1%, cassia seed extract 0.1%, chrysanthemum extract 0.5%, blueberry juice 1.5%,
Grape seed extract 0.15%, vitamin C 0.01%, oligosaccharide 0.11%, lutein 0.005%, arabinose 0.15%, carry
The zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule obtained is some, makes containing for zeaxanthin and lutein in beverage
It is 1 to measure ratio:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Hair
Ferment wolfberry juice 50%, white granulated sugar 5%, taurine 0.21%, cassia seed extract 0.3%, chrysanthemum extract 0.25%, blueberry juice
0.5%th, grape seed extract 0.85%, vitamin C 0.01%, oligosaccharide 0.21%, lutein 0.005%, arabinose
0.15%th, zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule are some, make containing for zeaxanthin and lutein in beverage
It is 1 to measure ratio:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of matrimony vine bean vermicelli, containing matrimony vine (butt) 10%, containing the zeaxanthin acid dipalmitate extracted or zeaxanthin
One or both of, its addition is to control the content of the zeaxanthin in matrimony vine bean vermicelli (mass percent) to exist
0.0009%, matrimony vine is ground into wolfberry fruit powders more than 300 mesh, wolfberry fruit powder and the double palmitic acids of zeaxanthin are added in starch
Ester, mixing, add water beat paste, tune powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, dry form matrimony vine bean vermicelli.
A kind of matrimony vine vermicelli, containing matrimony vine (butt) 6%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition is to control the content of the zeaxanthin in matrimony vine vermicelli (mass percent) to soak matrimony vine 0.0008%
Bubble mashing homogeneous adds wolfberry fruit syrup and zeaxanthin acid dipalmitate in starch, mixing, added into wolfberry fruit syrups more than 300 mesh
Water beat paste, adjust powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, drying form matrimony vine vermicelli.
A kind of matrimony vine ground rice, containing matrimony vine (butt) 4%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition 0.0005%, rice, washes rice, bubble with the content (mass percent) of the zeaxanthin in matrimony vine ground rice
Rice plus starch add wolfberry juice, add zeaxanthin acid dipalmitate, are milled, evaporate self heating, wire squeeze, filoselle and make thinner, be aging, multiple
Steaming, cooling, loose wire, drying form matrimony vine ground rice.
A kind of matrimony vine rice noodles, containing matrimony vine (butt) 3%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, to control the content of the zeaxanthin in matrimony vine rice noodles (mass percent) 0.0004%, rice passes through its addition
The processes such as fermentation, addition matrimony vine defibrination, clear filter, steaming, extruding, cooking form matrimony vine rice noodles.
A kind of medlar oil, matrimony vine ball, the matrimony vine that will be collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Slurry filtering, matrimony vine screenings and clear liquid are obtained, clear liquid concentration, obtains concentrate, medlar oil or matrimony vine ball is further made in concentrate；Or
The auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, medlar oil or matrimony vine is further made
Ball；Or added in concentrate by the double palm fibres of the zeaxanthin being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of glycerin monostearate extract or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, further make
Into medlar oil, matrimony vine ball；Or the auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, concentrate
Add after end and carried by the zeaxanthin acid dipalmitate being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of taking thing or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, be further made medlar oil,
Matrimony vine ball.
A kind of matrimony vine feeds yeast, is followed by with the permeate obtained in the extracting method of medlar biological alkali by composition adjustment
Primary yeast seed liquor progress fermentating breeding, collection cell, drying form.
Embodiment 6
The step of zeaxanthin acid dipalmitate is extracted from liquid medlar raw material is as follows：
1) Wolfberry powder dissolves to obtain wolfberry fruit syrup, and addition pectase, cellulase are digested.
2) the matrimony vine pulp after enzymolysis is added in first extractor of multi-stage counter current extraction system, added from next
The extractant of level (fresh extractant), opens backflow and stirring carries out closed extraction, and extracting pressure is maintained at 0.4-0.5Mpa,
Reclaiming extractant into parsing tank, decompression when reaching balance separates out extract, reclaims extractant, collects the double palms of zeaxanthin
Acid esters extract, pulp then enter next stage extractor, add the extractant from next stage (fresh extractant) and are extracted,
The extractant containing extract is reclaimed into temporary storage tank when reaching balance, the first extractor is passed through and is extracted, pulp then enters
Third level extractor.So by some grades of extractions, the wolfberry fruit syrup for completing extraction is then released from afterbody extractor bottom；Matrimony vine
The flow direction of slurry and the flow direction of extractant on the contrary, from enter extracting system to discharge extracting system, zeaxanthin acid dipalmitate
Content gradually reduces, until being zero after some grades of extractions；Extractant then on the contrary, by some grades extraction after maize therein
The content of matter acid dipalmitate is stepped up, until reaching highest after first order extraction and decompressing precipitation.Extractant enters extraction
Pressure is maintained at 0.4-0.5Mpa when the conveying and extraction of tank.Extractant used is propane, butane, iso-butane (R600a), 1,
One kind in 1,1,2- HFC-134a (R134a), dimethyl ether (DME), liquefied petroleum gas (LPG), carbon dioxide and sulfur hexafluoride,
The present embodiment is using sulfur hexafluoride as extractant.Extractant recovery is reclaimed by compressor.For the ease of extract
Collection, when adding fresh extractant add raw material weight 10% ethanol.
3) the zeaxanthin acid dipalmitate extract being collected into carries out vacuum desolvation, until extractant remains in extract
Amount is less than 8ppm, collects zeaxanthin acid dipalmitate extract.
4) the zeaxanthin acid dipalmitate extract dissolving obtained, emulsification, selects foodstuff glue to pass through spraying as wall material
Dry the zeaxanthin acid dipalmitate micro-capsule powder for being fabricated to different content.
By above gained zeaxanthin acid dipalmitate extract carry out saponification, separation, crystallize, be dried to obtain sterling jade
Cream-coloured matter, obtained sterling zeaxanthin dissolving, emulsification, carries out spray drying as wall material using cellulose or foodstuff glue and is fabricated to
The micro-capsule powder of different zeaxanthins.
Extracted in the above-mentioned raw material from liquid medlar in the step 2) of zeaxanthin acid dipalmitate from afterbody extractor
The wolfberry fruit syrup of bottom releasing is filtered, and obtains matrimony vine screenings and clear liquid, and matrimony vine screenings obtains matrimony vine meals fibre by drying, crushing
Dimension；Clear liquid concentrates, and obtains matrimony vine syrup；Alcohol is added in concentrate, adjustment alcohol content reaches more than 80%, stands, isolate
Sediment and clear liquid；Further concentration can obtain second of matrimony vine syrup after clear liquid recovered alcohol；Used after clear liquid recovered alcohol
The nonpolar and further separating-purifying of low pole macroreticular resin obtains matrimony vine flavones and remaining raffinate；Remaining raffinate is further dense
Contracting obtains the third matrimony vine syrup；Remaining raffinate obtains permeate and eluent, eluted through macroreticular resin or ion-exchange treatment
Liquid again through desalination, concentration, separate out crystallization, dry medlar biological alkali, permeate it is concentrated the 4th kind of matrimony vine syrup.
The above-mentioned sediment isolated adds appropriate water to dissolve, and concentration is reached 10%, adds 20% chloroform
N-butanol with 4%, acutely concussion 30 minutes, centrifugation, reclaims the chloroform of lower floor, pours out supernatant, reclaim n-butanol, will
Dry the matrimony vine albumen of albuminate washing in middle level；Supernatant after recovery n-butanol repeats above-mentioned technique, until nothing
Albuminate occurs, and obtains supernatant；Vacuum freeze drying obtains LBP-X after obtained supernatant concentration.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Chinese holly
Qi juice 10%, white granulated sugar 8%, taurine 0.1%, cassia seed extract 0.2%, chrysanthemum extract 0.5%, blueberry juice 0.5%,
Grape seed extract 0.15%, vitamin C 0.01%, oligosaccharide 0.11%, lutein 0.0009%, arabinose 0.15%,
Extract obtained zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule is some, make zeaxanthin and lutein in beverage
Content ratio is 1:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：Hair
Ferment wolfberry juice 10%, white granulated sugar 10%, taurine 0.15%, cassia seed extract 0.21%, chrysanthemum extract 0.5%, blueberry
Juice 0.5%, grape seed extract 0.45%, vitamin C 0.02%, oligosaccharide 0.11%, lutein 0.0006%, arabinose
0.15%th, zeaxanthin acid dipalmitate micro-capsule or zeaxanthin micro-capsule are some, make containing for zeaxanthin and lutein in beverage
It is 1 to measure ratio:5, acid, stabilizer, emulsifying agent are some, and remaining is water.
A kind of matrimony vine bean vermicelli, containing matrimony vine (butt) 8%, containing in the zeaxanthin acid dipalmitate extracted or zeaxanthin
One or two, its addition to control the content of the zeaxanthin in matrimony vine bean vermicelli (mass percent) 0.0001%,
Matrimony vine is ground into wolfberry fruit powders more than 300 mesh, wolfberry fruit powder and zeaxanthin acid dipalmitate are added in starch, mixing, is added
Water beat paste, adjust powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, drying form matrimony vine bean vermicelli.
A kind of matrimony vine vermicelli, containing matrimony vine (butt) 6%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition is to control the content of the zeaxanthin in matrimony vine vermicelli (mass percent) to soak matrimony vine 0.0008%
Bubble mashing homogeneous adds wolfberry fruit syrup and zeaxanthin acid dipalmitate in starch, mixing, added into wolfberry fruit syrups more than 300 mesh
Water beat paste, adjust powder, vacuum outgas, leak powder, boil powder, cooling, freezing, defrosting, drying form matrimony vine vermicelli.
A kind of matrimony vine ground rice, containing matrimony vine (butt) 5%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin or
Two kinds, its addition 0.0006%, rice, washes rice, bubble with the content (mass percent) of the zeaxanthin in matrimony vine ground rice
Rice plus starch add wolfberry juice, add zeaxanthin acid dipalmitate, are milled, evaporate self heating, wire squeeze, filoselle and make thinner, be aging, multiple
Steaming, cooling, loose wire, drying form matrimony vine ground rice.
A kind of matrimony vine rice noodles, containing matrimony vine (butt) 10%, one kind in acid dipalmitate containing zeaxanthin or zeaxanthin
Or two kinds, its addition is to control the content of the zeaxanthin in matrimony vine rice noodles (mass percent) 0.0008%, rice warp
The processes such as everfermentation, addition matrimony vine defibrination, clear filter, steaming, extruding, cooking form matrimony vine rice noodles.
A kind of medlar oil, matrimony vine ball, the matrimony vine that will be collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Slurry filtering, matrimony vine screenings and clear liquid are obtained, clear liquid concentration, obtains concentrate, medlar oil or matrimony vine ball is further made in concentrate；Or
The auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, medlar oil or matrimony vine is further made
Ball；Or added in concentrate by the double palm fibres of the zeaxanthin being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of glycerin monostearate extract or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, further make
Into medlar oil, matrimony vine ball；Or the auxiliary materials such as other Chinese medicine extracts, honey are added in concentrate, continue to concentrate after mixing, concentrate
Add after end and carried by the zeaxanthin acid dipalmitate being collected into the extracting method of zeaxanthin acid dipalmitate in matrimony vine
Emulsion made of taking thing or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin micro-capsule, be further made medlar oil,
Matrimony vine ball.
A kind of matrimony vine feeds yeast, is followed by with the permeate obtained in the extracting method of medlar biological alkali by composition adjustment
Primary yeast seed liquor progress fermentating breeding, collection cell, drying form.
The present embodiment is only to illustrate technical solution of the present invention, and the embodiment of other combinations in such as each data area is herein
Just do not enumerate, but belong to the scope of the present invention.
The present invention is not limited only to above-described embodiment.
Although specific embodiments of the present invention are described above-described embodiment, those skilled in the art should
This is recognized, on the premise of without departing from the spirit and scope of the present invention, the present invention can be variously changed and be modified, its
As a result all within protection scope of the present invention.
Claims (11)
1. extracting the method for zeaxanthin acid dipalmitate in a kind of raw material from liquid medlar, the described method comprises the following steps：
1) matrimony vine pretreatment of raw material, including dry wolfberry rehydration, matrimony vine slag rehydration, mashing remove seed obtain wolfberry fruit syrup；Fresh fructus lycii cleaning, beat
Slurry remove seed obtains wolfberry fruit syrup；Fresh fructus lycii, rehydration matrimony vine, rehydration matrimony vine slag mashing remove seed obtain matrimony vine pulp, are added in matrimony vine pulp
The Wolfberry powder of raw material weight 0-100%, stir to obtain wolfberry fruit syrup；Fresh fructus lycii and a certain proportion of dry wolfberry are beaten together
Obtain wolfberry fruit syrup；Wolfberry powder dissolves to obtain wolfberry fruit syrup；Then pectase is added in obtained wolfberry fruit syrup, cellulase carries out enzyme
Solution；
2) wolfberry fruit syrup after enzymolysis is added into extracting system, adds extractant, carry out closed extraction, extracting pressure is maintained at
0.1-10Mpa, reclaiming extractant into parsing tank, decompression when reaching balance separates out extract, reclaims extractant, collects beautiful
Cream-coloured matter acid dipalmitate extract, by some grades of extractions, the wolfberry fruit syrup for completing extraction is then released from extractor bottom；The extraction
Taking agent recovery is reclaimed by compressor；The extractant is propane, butane, iso-butane (R600a), 1,1,1,2- tetrafluoro
One kind in ethane (R134a), dimethyl ether (DME), liquefied petroleum gas (LPG), carbon dioxide and sulfur hexafluoride；
3) the zeaxanthin acid dipalmitate extract being collected into carries out vacuum desolvation, until extract extractant residual quantity is less than
8ppm, collection obtain zeaxanthin acid dipalmitate extract；
4) the zeaxanthin acid dipalmitate extract obtained is fabricated to the zeaxanthin acid dipalmitate microcapsule powder of different content
End.
2. the method for zeaxanthin is extracted in a kind of raw material from liquid medlar, it is characterised in that the maize described in claim 1
Matter acid dipalmitate extract carries out saponification, separation, crystallizes, is dried to obtain sterling zeaxanthin；Sterling zeaxanthin is further
It is fabricated to the micro-capsule powder of different zeaxanthins.
3. extracting the method for flavones in a kind of raw material from liquid medlar, comprise the steps of：
1) wolfberry fruit syrup that claim 1 step 2) is completed to extraction from the releasing of afterbody extractor bottom passes through vacuum desolvation, directly
It is less than 8ppm to extractant residual quantity, it is standby collects wolfberry fruit syrup；
2) wolfberry fruit syrup collected is filtered, and is obtained matrimony vine screenings and clear liquid, clear liquid concentration, is obtained concentrate；
3) alcohol is added in concentrate, adjustment alcohol content reaches more than 80%, stands, isolate sediment and clear liquid；
4) further separating-purifying obtains matrimony vine flavones and remaining raffinate after clear liquid recovered alcohol.
4. a kind of matrimony vine dietary fiber, it is characterised in that formed using the matrimony vine screenings described in claim 3 through drying, crushing.
5. extracting the method for polysaccharide in a kind of raw material from liquid medlar, comprise the steps of：
1) add appropriate water to dissolve the sediment described in claim 3, concentration is reached 10%；
2) 20% chloroform and 4% n-butanol is added in above-mentioned solution, acutely concussion 30 minutes, centrifugation, under recovery
The chloroform of layer, supernatant is poured out, reclaim n-butanol, collect the albuminate in middle level；Reclaim the supernatant weight after n-butanol
Above-mentioned technique is carried out again, until occurring without albuminate, obtains supernatant；
3) vacuum freeze drying obtains LBP-X after the supernatant concentration obtained.
6. a kind of matrimony vine albumen, it is characterised in that the medial degeneration albumen that claim 5 is collected is subjected to washing and is drying to obtain Chinese holly
Qi albumen.
7. the method for alkaloid is extracted in a kind of raw material from liquid medlar, it is characterised in that obtained with claim 3 step 4)
Raffinate obtains permeate and eluent through ion exchange or macroporous resin treatment, eluent again through desalination, concentration, separate out crystallization, dry
It is dry to obtain medlar biological alkali.
8. a kind of matrimony vine syrup, it is characterised in that the matrimony vine syrup is the concentrate described in claim 3 step 2)；The Chinese holly
Concentrate and form after the clear liquid recovered alcohol that Qi syrup obtains for claim 3 step 3)；The matrimony vine syrup is with claim 3
Raffinate that step 4) obtains is concentrated to be formed；The matrimony vine syrup, which is that the permeate obtained with claim 7 is concentrated, to be formed.
9. a kind of eyesight improving matrimony vine beverage containing zeaxanthin, it is characterised in that there is the composition of following percentage by weight：
Wolfberry juice or fermentation wolfberry juice 5-50%, white granulated sugar 5-10%, taurine 0.01-1%, cassia seed extract 0.1-
5%th, chrysanthemum extract 0.1-5%, blueberry juice 0-5%, grape seed extract 0.1-5%, vitamin C 0.01-1%, low
Glycan 0.1-1%, the maize that lutein 0.001-0.01%, arabinose are some, method as claimed in claim 1 obtains
Zeaxanthin micro-capsule that matter acid dipalmitate micro-capsule or claim 2 methods described obtain is some, acid, stabilizer, emulsification
Agent is some, and remaining is water；The addition of the arabinose is 3-the 5% of white granulated sugar；The zeaxanthin and lutein contain
It is 1 to measure ratio:5.
A kind of 10. matrimony vine starch-based product, it is characterised in that contain matrimony vine (butt) 4-10% in matrimony vine starch-based product, will containing right
Seek 1 obtained zeaxanthin acid dipalmitate or one or both of zeaxanthin that claim 2 obtains, its addition with
The content (mass percent) of the zeaxanthin in the matrimony vine starch-based product is controlled 0-0.1%；The matrimony vine starch-based product
Including matrimony vine bean vermicelli, matrimony vine vermicelli, matrimony vine ground rice, matrimony vine rice noodles；The matrimony vine refers to wolfberry fruit powder, Lycium chinense juice, matrimony vine concentration
Juice.
11. a kind of medlar oil, matrimony vine ball, it is characterised in that wolfberry fruit syrup filtering is discharged after claim 1 is extracted, obtains matrimony vine screenings
And clear liquid, clear liquid concentration, concentrate is obtained, medlar oil or matrimony vine ball is further made in concentrate；Or added in concentrate other
The auxiliary materials such as Chinese medicine extract, honey, continue to concentrate after mixing, and medlar oil or matrimony vine ball is further made；Or add in concentrate
Enter the zeaxanthin acid dipalmitate extract being collected into by claim 1 or zeaxanthin acid dipalmitate micro-capsule powder or
Emulsion made of zeaxanthin or its micro-capsule, medlar oil, matrimony vine ball is further made；Or other Chinese medicines are added in concentrate
The auxiliary materials such as extract solution, honey, continue to concentrate after mixing, concentration adds the zeaxanthin by being collected into by claim 1 after terminating
Emulsion made of acid dipalmitate extract or zeaxanthin acid dipalmitate micro-capsule powder or zeaxanthin or its micro-capsule,
Medlar oil, matrimony vine ball is further made.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911217110.2A CN110810680A (en) | 2017-11-05 | 2017-11-05 | Eyesight-improving medlar beverage containing zeaxanthin |
| CN201911217396.4A CN111194921A (en) | 2017-11-05 | 2017-11-05 | Preparation method of Chinese wolfberry fruit paste |
| CN201711074611.0A CN107868028A (en) | 2017-11-05 | 2017-11-05 | A kind of method that zeaxanthin acid dipalmitate is extracted in the raw material from liquid medlar |
| CN201911210590.XA CN110892987A (en) | 2017-11-05 | 2017-11-05 | Preparation method of wolfberry syrup |
| CN201911217107.0A CN110881650A (en) | 2017-11-05 | 2017-11-05 | Chinese wolfberry starch product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711074611.0A CN107868028A (en) | 2017-11-05 | 2017-11-05 | A kind of method that zeaxanthin acid dipalmitate is extracted in the raw material from liquid medlar |
Related Child Applications (4)
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| CN201911217396.4A Division CN111194921A (en) | 2017-11-05 | 2017-11-05 | Preparation method of Chinese wolfberry fruit paste |
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| CN201911217110.2A Pending CN110810680A (en) | 2017-11-05 | 2017-11-05 | Eyesight-improving medlar beverage containing zeaxanthin |
| CN201711074611.0A Pending CN107868028A (en) | 2017-11-05 | 2017-11-05 | A kind of method that zeaxanthin acid dipalmitate is extracted in the raw material from liquid medlar |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110746515A (en) * | 2019-10-28 | 2020-02-04 | 百瑞源枸杞股份有限公司 | Lycium barbarum polysaccharide, lycium barbarum red element and lycium barbarum polypeptide prepared by synchronous separation and preparation method thereof |
| CN111467334A (en) * | 2020-04-20 | 2020-07-31 | 宁夏农林科学院枸杞工程技术研究所 | Method for preparing zeaxanthin dipalmitate high internal phase emulsion by using amyloid fiber-polysaccharide complex |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113332366A (en) * | 2020-03-02 | 2021-09-03 | 张腾龙 | Application of medical composition in preparing medicine for treating xerophthalmia |
| CN116326702A (en) * | 2023-02-23 | 2023-06-27 | 重庆瑞航生物科技有限公司 | Blueberry beverage with eye protection function and preparation method thereof |
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| CN111194921A (en) | 2020-05-26 |
| CN110892987A (en) | 2020-03-20 |
| CN110810680A (en) | 2020-02-21 |
| CN110881650A (en) | 2020-03-17 |
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