CN107856375A - A kind of boiling film for packaging for foodstuff - Google Patents

A kind of boiling film for packaging for foodstuff Download PDF

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Publication number
CN107856375A
CN107856375A CN201711004917.9A CN201711004917A CN107856375A CN 107856375 A CN107856375 A CN 107856375A CN 201711004917 A CN201711004917 A CN 201711004917A CN 107856375 A CN107856375 A CN 107856375A
Authority
CN
China
Prior art keywords
layer
boiling
packaging
film
middle level
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711004917.9A
Other languages
Chinese (zh)
Inventor
华永芬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Pacific New Material Co Ltd
Original Assignee
Wuxi Pacific New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Pacific New Material Co Ltd filed Critical Wuxi Pacific New Material Co Ltd
Priority to CN201711004917.9A priority Critical patent/CN107856375A/en
Publication of CN107856375A publication Critical patent/CN107856375A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/70Food packaging

Landscapes

  • Laminated Bodies (AREA)

Abstract

The invention provides a kind of boiling film for packaging for foodstuff, it holding structure can stablize, be not easily stripped, be separated out without harmful substance in more than 100 DEG C of temperature;It is lamination layer structure, include outer layer, middle level, internal layer successively from top to bottom, the outer layer is the composite bed by enhancement layer and heat-sealing layer stackup, the internal layer is the composite bed by hot sealing layer or/and enhancing layer stackup, it is immiscible between the enhancement layer and hot sealing layer, and be bonded by adhesive, the boiling material that mass percent is 45% ~ 85% is contained in the hot sealing layer of the internal layer.

Description

A kind of boiling film for packaging for foodstuff
Technical field
The present invention relates to co-extrusion technical field of membrane, specially a kind of boiling film for packaging for foodstuff.
Background technology
High temperature resistant boiling film is currently used a kind of packaging material for being used for boiling or cooking food, and it blocks water Oxygen, high temperature resistant boiling, the characteristic of high intensity ensure that nutrition and the health of fast food, extend the shelf-life, and boiling film exists During use, it is desirable to which while killing harmful bacteria in food at high temperature, and can does not destroy the structure of membrane material, will not yet Harmful substance is produced, ensures the safety and sanitation of food;But existing common high temperature resistant boiling film is in 100 DEG C of temperature, although Can holding structure it is complete, but vapor (steam) temperature therefore can cause such boiling film using process often more than 100 DEG C In be easily peeled off, while separate out harmful substance.
The content of the invention
In view of the above-mentioned problems, the invention provides a kind of boiling film for packaging for foodstuff, it can be more than 100 DEG C in temperature When holding structure stablize, be not easily stripped, without harmful substance separate out.
Its technical scheme is so:A kind of boiling film for packaging for foodstuff, it is lamination layer structure, from top to bottom successively Including outer layer, middle level, internal layer, it is characterised in that:The outer layer is by enhancement layer and the composite bed for sealing layer stackup, the internal layer It is immiscible between the enhancement layer and hot sealing layer, and pass through adhesive by hot sealing layer or/and to strengthen the composite bed of layer stackup It is bonded, the boiling material that mass percent is 45% ~ 85% is contained in the hot sealing layer of the internal layer.
It is further characterized by:
The boiling material is medium density polyethylene(MDPE), density range is 0.926g/cm3~0.940g/cm3
The raw material that the middle level uses is nylon(PA)Or ethylene-vinyl alcohol copolymer(EVOH);The side in the middle level is set There is enhancement layer;
The raw material that the enhancement layer uses is nylon(PA);The raw material that the hot sealing layer uses is polyethylene(PE);The poly- second Alkene(PE)With nylon(PA), ethylene-vinyl alcohol copolymer(EVOH)Between it is immiscible, and be bonded by adhesive;
The percetage by weight that the outer layer, middle level, internal layer account for film gross weight is respectively 40% ~ 50%, 15% ~ 20%, 35% ~ 50%;
The thickness of the boiling film is 50 μm ~ 200 μm.
The invention has the advantages that the outer layer of boiling film is the composite bed by enhancement layer and heat-sealing layer stackup, internal layer is By hot sealing layer or/and the composite bed of enhancing layer stackup, it is bonded between enhancement layer and hot sealing layer by adhesive, and in the heat of internal layer Containing the boiling material that mass percent is 45%-85% in sealing, to improve the heat resistance of boiling film and intensity, it can make what is produced Boiling film at 110 DEG C -115 DEG C can holding structure stablize, be not easily stripped, the precipitation without harmful substance.
Brief description of the drawings
Fig. 1 is the structural representation of embodiments of the invention one;
Fig. 2 is the structural representation of embodiments of the invention two;
Fig. 3 is the structural representation of embodiments of the invention three.
Embodiment
In the present invention, the thickness of boiling film is 50 μm ~ 200 μm;Include outer layer 1, middle level 2, internal layer 3 successively from top to bottom, The percetage by weight that outer layer 1, middle level 2, internal layer 3 account for film gross weight is respectively 40% ~ 50%, 15% ~ 20%, 35% ~ 50%, and outer layer 1 is served as reasons The composite bed of enhancement layer and heat-sealing layer stackup, internal layer 3 are the composite bed by hot sealing layer or/and enhancing layer stackup, i.e. internal layer 3 is served as reasons The composite bed of layer stackup is sealed, or internal layer 3 is the composite bed by hot sealing layer and enhancing layer stackup;Between enhancement layer and hot sealing layer It is immiscible, and be bonded by adhesive, containing the boiling material that mass percent is 50%-80% in the hot sealing layer of internal layer 3, that is, exist The polyethylene of internal layer 3(PE)In containing the high temperature resistant boiling material that mass percent is 50%-80%, boiling material is that French TOTAL is public Take charge of the medium density polyethylene of production(MDPE), density range is 0.926g/cm3~0.940g/cm3, the heat-resisting of boiling film can be improved Property and intensity, specifically, the raw material that enhancement layer uses is nylon(PA);The raw material that hot sealing layer uses is polyethylene(PE);Middle level 2 For barrier layer, the raw material used is nylon(PA)Or ethylene-vinyl alcohol copolymer(EVOH);The side in middle level 2 is provided with enhancing Layer;Cost of material utilizes ethylene-vinyl alcohol copolymer to the middle resistance of the high barrier, nylon of oxygen to oxygen than relatively low Every the high temperature resistant boiling characteristic of property, the high intensity of nylon, and boiling material, the boiling film free from extraneous odour that makes to produce, good toughness, Intensity is high, the gas barrier property that blocks water is strong, high temperature resistant boiling, employs the boiling material of French Total companies production, while selects heat resistant type Adhesive, make the boiling film of production at 110 DEG C -115 DEG C can holding structure stablize, be not easily stripped, without harmful substance Separate out.
Embodiment one
As shown in figure 1, high temperature resistant boiling film is 9 layers of lamination layer structure, its thickness is 75 μm, and outer layer 1 is by one layer of nylon(PA)With Two layers of polyethylene(PE)It is laminated, nylon(PA)And with its hithermost layer of polyethylene(PE)Between pass through adhesive (Tie)Bonding;Middle level 2 is nylon(PA);Internal layer 3 is by two layers of polyethylene(PE)It is laminated, and near the poly- second in middle level 2 Alkene(PE)In containing 50% boiling material, the density of boiling material is 0.926g/cm3;It is and logical between middle level 2 and outer layer 1, internal layer 3 Cross adhesive(Tie)Bonding;Specific structure composition is followed successively by from outside to inside:PA-Tie-PE-PE-Tie-PA-Tie-PE-PE.
Embodiment two
As shown in Fig. 2 high temperature resistant boiling film is 9 layers of lamination layer structure, its thickness is 100 μm, and outer layer 1 is by one layer of nylon(PA) And layer of polyethylene(PE)It is laminated, nylon(PA)And polyethylene(PE)Between pass through adhesive(Tie)Bonding;Middle level 2 uses Be ethylene-vinyl alcohol copolymer(EVOH);Internal layer 3 is by one layer of nylon(PA)And two layers of polyethylene(PE)It is laminated, Buddhist nun Dragon(PA)And with its hithermost layer of polyethylene(PE)Between pass through adhesive(Tie)It is bonded, close to middle level 2 in internal layer 3 It is nylon(PA), and near the polyethylene in middle level 2 in internal layer 3(PE)In containing 75% boiling material, the density of boiling material be 0.934g/cm3;And middle level 2 and with layer of polyethylene in its hithermost outer layer 1(PE)Pass through adhesive(Tie)Bonding;Tool The structure composition of body is followed successively by from outside to inside:PA-Tie-PE-Tie-EVOH-PA-Tie-PE-PE.
Embodiment three
As shown in figure 3, high temperature resistant boiling film is 9 layers of lamination layer structure, its thickness is 120 μm, and outer layer 1 is layer of polyethylene(PE) With two layers of nylon(PA)It is laminated, polyethylene(PE)And with its hithermost one layer of nylon(PA)Between pass through adhesive (Tie)Bonding;Middle level 2 is using ethylene-vinyl alcohol copolymer(EVOH);Internal layer 3 is by three-layer polyethylene(PE)Stacking group Into, and near the two layers of polyethylene in middle level 2 in internal layer 3(PE)In be containing 80% boiling material, the density of boiling material 0.940g/cm3;And middle level 2 and with layer of polyethylene in its hithermost internal layer 3(PE)Pass through adhesive(Tie)Bonding;Tool The structure composition of body is followed successively by from outside to inside:PE-Tie-PA-PA-EVOH-Tie-PE-PE-PE.

Claims (6)

1. a kind of boiling film for packaging for foodstuff, it is lamination layer structure, include outer layer, middle level, internal layer successively from top to bottom, It is characterized in that:The outer layer is the composite bed by enhancement layer and heat-sealing layer stackup, and the internal layer is by hot sealing layer or/and enhancing The composite bed of layer stackup, it is immiscible between the enhancement layer and hot sealing layer, and be bonded by adhesive, the heat-sealing of the internal layer Contain the boiling material that mass percent is 45% ~ 85% in layer.
2. a kind of boiling film for packaging for foodstuff according to claim 1, it is characterised in that the boiling material is close in being Spend polyethylene(MDPE), density range is 0.926g/cm3~0.940g/cm3
A kind of 3. boiling film for packaging for foodstuff according to claim 1, it is characterised in that the original that the middle level uses Expect for nylon(PA)Or ethylene-vinyl alcohol copolymer(EVOH);The side in the middle level is provided with enhancement layer.
4. a kind of boiling film for packaging for foodstuff according to claim 1, it is characterised in that what the enhancement layer used Raw material is nylon(PA);The raw material that the hot sealing layer uses is polyethylene(PE);The polyethylene(PE)With nylon(PA), second Alkene-ethenol copolymer(EVOH)Between it is immiscible, and be bonded by adhesive.
5. a kind of boiling film for packaging for foodstuff according to claim 1, it is characterised in that the outer layer, middle level, interior The percetage by weight that layer accounts for film gross weight is respectively 40% ~ 50%, 15% ~ 20%, 35% ~ 50%.
A kind of 6. boiling film for packaging for foodstuff according to claim 1, it is characterised in that the thickness of the boiling film For 50 μm ~ 200 μm.
CN201711004917.9A 2017-10-25 2017-10-25 A kind of boiling film for packaging for foodstuff Pending CN107856375A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711004917.9A CN107856375A (en) 2017-10-25 2017-10-25 A kind of boiling film for packaging for foodstuff

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711004917.9A CN107856375A (en) 2017-10-25 2017-10-25 A kind of boiling film for packaging for foodstuff

Publications (1)

Publication Number Publication Date
CN107856375A true CN107856375A (en) 2018-03-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711004917.9A Pending CN107856375A (en) 2017-10-25 2017-10-25 A kind of boiling film for packaging for foodstuff

Country Status (1)

Country Link
CN (1) CN107856375A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109605891A (en) * 2018-12-29 2019-04-12 无锡市太平洋新材料股份有限公司 A kind of food packaging antifog film

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101525071A (en) * 2009-04-23 2009-09-09 高永明 Seven-layer coextrusion composite high-separation packaging film
CN202053625U (en) * 2011-04-21 2011-11-30 江阴申恒特种新材料有限公司 Multi-layer co-extrusion high-temperature cooking film
CN107283980A (en) * 2017-07-05 2017-10-24 永新股份(黄山)包装有限公司 A kind of digestion resistant polyethylene film and its production technology

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101525071A (en) * 2009-04-23 2009-09-09 高永明 Seven-layer coextrusion composite high-separation packaging film
CN202053625U (en) * 2011-04-21 2011-11-30 江阴申恒特种新材料有限公司 Multi-layer co-extrusion high-temperature cooking film
CN107283980A (en) * 2017-07-05 2017-10-24 永新股份(黄山)包装有限公司 A kind of digestion resistant polyethylene film and its production technology

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109605891A (en) * 2018-12-29 2019-04-12 无锡市太平洋新材料股份有限公司 A kind of food packaging antifog film

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Application publication date: 20180330

RJ01 Rejection of invention patent application after publication