CN107854962A - A kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants - Google Patents

A kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants Download PDF

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Publication number
CN107854962A
CN107854962A CN201711112012.3A CN201711112012A CN107854962A CN 107854962 A CN107854962 A CN 107854962A CN 201711112012 A CN201711112012 A CN 201711112012A CN 107854962 A CN107854962 A CN 107854962A
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CN
China
Prior art keywords
tower body
waste gas
curtain
hollow
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711112012.3A
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Chinese (zh)
Inventor
王慧军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YIXING YEMA ENVIRONMENTAL PROTECTION ENGINEERING Co Ltd
Original Assignee
YIXING YEMA ENVIRONMENTAL PROTECTION ENGINEERING Co Ltd
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Publication date
Application filed by YIXING YEMA ENVIRONMENTAL PROTECTION ENGINEERING Co Ltd filed Critical YIXING YEMA ENVIRONMENTAL PROTECTION ENGINEERING Co Ltd
Priority to CN201711112012.3A priority Critical patent/CN107854962A/en
Publication of CN107854962A publication Critical patent/CN107854962A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1406Multiple stage absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1487Removing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493Selection of liquid materials for use as absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • B01D53/185Liquid distributors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26Drying gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50Combinations of absorbents
    • B01D2252/504Mixtures of two or more absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

Abstract

The invention discloses a kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants, it is characterized in that, including tower body, base and aiutage;The bottom of the tower body is connected with base, and the top of tower body is connected with aiutage;Activated carbon adsorption layer, gas-liquid separation layer and some hollow clapboards are disposed with inside the tower body from top to bottom;There is cavity in the hollow clapboard;Each one end of the hollow clapboard is connected with the side wall of tower body, and the other end is that space is provided between free end, and the side wall of tower body;The neighbouring hollow clapboard and the link position of tower body side wall mutually deviate from;All hollow clapboards will be divided into continuous S-shaped passage inside tower body.The beneficial effect that the present invention is reached:The present apparatus passes through the improvement in structure, enabling according to different exhaust gas constituents and different exhausted air quantities, can efficiently be handled, it is wider suitable for processing various concentrations and the VOCs waste gas of different component, use range.

Description

A kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants
Technical field
The present invention relates to a kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants, belong to VOCs exhaust-gas treatments Purification techniques field.
Background technology
VOCs waste gas purifications industrially, in order to adapt to the rhythm of production of modern industry, collection for waste gas and Processing needs to carry out more more efficient processing comprehensively.But in the prior art, relevant device on the market is mostly with work Property charcoal absorption based on, although possessing, treatment effect is stable, and sorbing material replacing construction length, the adsorption efficiency of organic matter is high, can return Receive the advantages of recycling, but it is just poor on comprehensive, if activated carbon can not be handled, just in the waste gas component of processing Other processing equipment is resulted in the need for, applicable object is relatively simple.
The content of the invention
To solve the deficiencies in the prior art, it is applied to the absorption of VOCs waste gas absorptions it is an object of the invention to provide one kind and sets Standby oil curtain purifying column, it can be adjusted for various tail gas to carry out specific aim processing, it is applied widely, it is more efficient.
In order to realize above-mentioned target, the present invention adopts the following technical scheme that:
A kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants, it is characterized in that, including tower body, base and exhaust Cylinder;The bottom of the tower body is connected with base, and the top of tower body is connected with aiutage;The base is provided with waste gas tower liquid row Mouthful;The lower end of the tower body is provided with exhaust collection mouth and additive import;It is disposed with from top to bottom inside the tower body Activated carbon adsorption layer, gas-liquid separation layer and some hollow clapboards;The gas-liquid separation layer is used to remove the moisture in air-flow;It is described There is cavity in hollow clapboard;Each one end of the hollow clapboard is connected with the side wall of tower body, and the other end is free end, with Space is provided between the side wall of tower body;The neighbouring hollow clapboard and the link position of tower body side wall mutually deviate from;It is all The hollow clapboard will be divided into continuous S-shaped passage inside tower body;The free end of each hollow clapboard is provided with one The oil mixing with water curtain to hang down vertically, and oil mixing with water curtain is connected with the cavity of hollow clapboard;The bottom of each hollow clapboard Portion is provided with profit curtain.
A kind of foregoing oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants, it is characterized in that, each oil The lower end of water curtain is connected with the bottom of the hollow clapboard of underface or tower body.
A kind of foregoing oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants, it is characterized in that, each oil The lower end of cascade is connected with the bottom of the hollow clapboard of underface or tower body.
A kind of foregoing oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants, it is characterized in that, all oil Water mixing curtain is respectively positioned on the center of tower body.
A kind of foregoing oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants, it is characterized in that, the additive Import includes oil filler and tap water inlets;The oil filler is used to add # machinery oil.
A kind of foregoing oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants, it is characterized in that, it is described it is hollow every The junction of plate and profit curtain is dead slot.
A kind of foregoing oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants, it is characterized in that, the base connects It is connected to circulating pump;The circulating pump is connected with the cavity of the superiors' hollow clapboard.
The beneficial effect that the present invention is reached:The present apparatus passes through the improvement in structure, enabling according to different waste gas Composition and different exhausted air quantities, can efficiently it be handled, the VOCs waste gas suitable for handling various concentrations and different component, Use range is wider.
Brief description of the drawings
Fig. 1 is the cross-sectional view of the present apparatus.
The implication of reference in figure:
1- activated carbon adsorption layers, 2- gas-liquid separation layers, 3- profit curtains, 4- profit curtains, 5- tower bodies, 6- exhaust collection mouths, 7- refuel Mouthful, 8- tap water inlets, 9- waste gas towers liquid row's mouth, 10- circulating pumps, 11- aiutages, 12- hollow clapboards, A- airflow directions, PG- Pressure gauge.
Embodiment
The invention will be further described below in conjunction with the accompanying drawings.Following examples are only used for clearly illustrating the present invention Technical scheme, and can not be limited the scope of the invention with this.
The oil curtain purifying column suitable for waste gas absorption adsorption plant involved by this case, in structure, as shown in figure 1, bag Include tower body 5, base and aiutage 11.
The bottom of tower body 5 is connected with base, and the top of tower body 5 is connected with aiutage 11.
The lower end of tower body 5 is provided with exhaust collection mouth 6 and additive import.In the present embodiment, additive import includes adding Hydraulic fluid port 7 and tap water inlets 8, and exhaust collection mouth 6 is arranged on the upper end of additive import.Exhaust collection mouth 6 is in tower body 5 Exit towards under, one cause to greatest extent with additive import enter composition contact.
Activated carbon adsorption layer 1, gas-liquid contact layer and some hollow clapboards 12 are disposed with inside tower body 5 from top to bottom. Internally in structure, one end of each hollow clapboard 12 is connected with the side wall of tower body 5, and the other end is free end, with tower body 5 Side wall between be provided with space.Neighbouring hollow clapboard 12 and the link position of the side wall of tower body 5 mutually deviate from, that is, cause All hollow clapboards 12 will be divided into continuous S-shaped passage inside tower body 5, in order to waste gas, the distance through stream is longer in tower body 5, Time is more long, improves the efficiency for absorbing processing.
Base is connected with circulating pump 10, and circulating pump 10 is connected with the cavity of the superiors hollow clapboard 12.Base is provided with Waste gas tower liquid sewage draining exit, the absorbing liquid flowed down along hollow clapboard 12 can flow to tower bottom after multistage blended absorbent in order, And by being fully absorbed from top to bottom with the VOCs waste gas in waste gas on more than 10 hollow clapboard 12 for being extracted into the superiors of circulating pump Absorption.In use, in the cavity of hollow clapboard 12 by the way that oil-water mixture to be extracted into the superiors so that the dividing plate of lower section is formed Blended absorbent adsorption liquid is covered with profit curtain 3 and profit curtain 4, the efficiency handled so as to the absorption improved to VOCs in waste gas.
The junction of hollow clapboard 12 and oil mixing with water curtain is dead slot, in order to which oil can pass through from cavity, and it is suitable Flow to sharply on lower floor's hollow clapboard 12, in favor of forming oil mixing with water curtain again.
The present apparatus is for paint tail gas, VOCs tail gas absorptions, absorption complete set of equipments, suitable for the organic tail gas of various concentration Absorption processing, compared to active carbon adsorption equipment on the market at present, have treatment effect is stable, sorbing material replacing construction is long, The advantages that organic matter adsorption efficiency is high, recyclable recycling, the scope of application is wider.
Various VOCs gases have certain solubility in certain solvent naphtha liquid, when VOCs gases and oily liq connect When touching, untill amount that the material in VOCs gases is dissolved in solvent naphtha liquid progressively increases to saturation.Absorb the absorption after VOCs Agent can pass through rectifying recovery liquefied petroleum gas product, and absorbent can be recycled after regeneration.
It is different according to discharge operating mode according to VOCs tail gas, the absorption of normal temperature oil can be divided into and low-temperature oil absorbs absorbing process. The present apparatus has same treatment effect to NMHC processing.Operation a period of time can pass through grease trap according to test data Releasing solvent naphtha is recycled or incineration disposal.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, some improvement and deformation can also be made, these are improved and deformation Also it should be regarded as protection scope of the present invention.

Claims (7)

1. a kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants, it is characterized in that, including tower body, base and exhaust Cylinder;The bottom of the tower body is connected with base, and the top of tower body is connected with aiutage;The base is provided with waste gas tower liquid row Mouthful;
The lower end of the tower body is provided with exhaust collection mouth and additive import;It is disposed with from top to bottom inside the tower body Activated carbon adsorption layer, gas-liquid contact layer and some hollow clapboards;The gas-liquid contact layer be used to removing moisture in air-flow and VOCs;There is cavity in the hollow clapboard;Each one end of the hollow clapboard is connected with the side wall of tower body, and the other end is certainly By being provided with space between end, and the side wall of tower body;The neighbouring hollow clapboard and the link position phase of tower body side wall Deviate from;All hollow clapboards will be divided into continuous S-shaped passage inside tower body;
The free end of each hollow clapboard is provided with an oil mixing with water curtain to hang down vertically, and oil mixing with water curtain is with The cavity of dummy receptacle is connected;The bottom of each hollow clapboard is provided with profit curtain.
2. a kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants according to claim 1, it is characterized in that, The lower end of each profit curtain is connected with the hollow clapboard of underface or the bottom of tower body.
3. a kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants according to claim 1, it is characterized in that, The lower end of each profit curtain is connected with the hollow clapboard of underface or the bottom of tower body.
4. a kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants according to claim 3, it is characterized in that, All profit curtains are respectively positioned on the center of tower body.
5. a kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants according to claim 1, it is characterized in that, The additive import includes oil filler and tap water inlets.
6. a kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants according to claim 3, it is characterized in that, The junction of the hollow clapboard and profit curtain is dead slot.
7. a kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants according to claim 6, it is characterized in that, The base is connected with circulating pump;The circulating pump is connected with the cavity of the superiors' hollow clapboard.
CN201711112012.3A 2017-11-13 2017-11-13 A kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants Pending CN107854962A (en)

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CN201711112012.3A CN107854962A (en) 2017-11-13 2017-11-13 A kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants

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Application Number Priority Date Filing Date Title
CN201711112012.3A CN107854962A (en) 2017-11-13 2017-11-13 A kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108854464A (en) * 2018-07-09 2018-11-23 中物院成都科学技术发展中心 A kind of absorbing liquid and its separation and recovery method and device for exhaust-gas treatment
CN112169532A (en) * 2020-08-19 2021-01-05 中国港湾工程有限责任公司 Air compression nitrogen making system
CN112619385A (en) * 2020-11-30 2021-04-09 合肥上华工程设计有限公司 Tail gas deodorization and purification process and device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001198430A (en) * 2000-01-17 2001-07-24 Babcock Hitachi Kk Gas-liquid contact method and gas-liquid contact apparatus
CN101569826A (en) * 2009-06-08 2009-11-04 东莞市科蓝环境保护工程有限公司 Purification method of waste gas with benzene or benzene homolog and purification apparatus thereof
CN204816057U (en) * 2015-07-16 2015-12-02 梁成 Dust removal and desulfurization device water film cleaning channel structure
CN106693650A (en) * 2017-01-10 2017-05-24 合肥图腾龙企业管理事务所(有限合伙) Water curtain check-type super-purification smoke exhaust dedusting and desulfurization system
CN207507213U (en) * 2017-11-13 2018-06-19 宜兴市野马环保工程有限公司 A kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001198430A (en) * 2000-01-17 2001-07-24 Babcock Hitachi Kk Gas-liquid contact method and gas-liquid contact apparatus
CN101569826A (en) * 2009-06-08 2009-11-04 东莞市科蓝环境保护工程有限公司 Purification method of waste gas with benzene or benzene homolog and purification apparatus thereof
CN204816057U (en) * 2015-07-16 2015-12-02 梁成 Dust removal and desulfurization device water film cleaning channel structure
CN106693650A (en) * 2017-01-10 2017-05-24 合肥图腾龙企业管理事务所(有限合伙) Water curtain check-type super-purification smoke exhaust dedusting and desulfurization system
CN207507213U (en) * 2017-11-13 2018-06-19 宜兴市野马环保工程有限公司 A kind of oil curtain purifying column suitable for VOCs waste gas absorption adsorption plants

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108854464A (en) * 2018-07-09 2018-11-23 中物院成都科学技术发展中心 A kind of absorbing liquid and its separation and recovery method and device for exhaust-gas treatment
CN112169532A (en) * 2020-08-19 2021-01-05 中国港湾工程有限责任公司 Air compression nitrogen making system
CN112619385A (en) * 2020-11-30 2021-04-09 合肥上华工程设计有限公司 Tail gas deodorization and purification process and device

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