CN107754199A - A kind of compound type aerosol extinguishing agent - Google Patents

A kind of compound type aerosol extinguishing agent Download PDF

Info

Publication number
CN107754199A
CN107754199A CN201711104817.3A CN201711104817A CN107754199A CN 107754199 A CN107754199 A CN 107754199A CN 201711104817 A CN201711104817 A CN 201711104817A CN 107754199 A CN107754199 A CN 107754199A
Authority
CN
China
Prior art keywords
parts
compound type
type aerosol
aerosol extinguishing
extinguishing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711104817.3A
Other languages
Chinese (zh)
Inventor
卢思迪
王伟
鲁怀宁
左振
王哲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BENGBU LONGTAI FIRE-FIGHTING Co Ltd
Original Assignee
BENGBU LONGTAI FIRE-FIGHTING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BENGBU LONGTAI FIRE-FIGHTING Co Ltd filed Critical BENGBU LONGTAI FIRE-FIGHTING Co Ltd
Priority to CN201711104817.3A priority Critical patent/CN107754199A/en
Publication of CN107754199A publication Critical patent/CN107754199A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/06Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0007Solid extinguishing substances

Abstract

The invention discloses a kind of compound type aerosol extinguishing agent, its raw material includes by weight:40 50 parts of modified aluminas, 20 25 parts of ammonium nitrate, 15 20 parts of trimerization chloramines, 12 14 parts of potassium picrate, 13 parts of Silk Powder, 24 parts of phenolic resin, 23 parts of polyvinyl alcohol, 23 parts of potassium dihydrogen phosphate, 23 parts of stearic acid, 12 parts of conditioning agent.The aerosol extinguishing agent of the present invention has preferable fire extinguishing effectiveness, combustion stability and stability.

Description

A kind of compound type aerosol extinguishing agent
Technical field
The present invention relates to extinguishing chemical, more particularly to a kind of compound type aerosol extinguishing agent.
Background technology
Aerosol type extinguishing chemical is a kind of extinguishing chemical developed recently in fire extinguishing field, and it passes through flame combustion extinguishing chemical In fuel and form aerosol product, so as to reach fire extinguishing purpose.The prior art such as CN1166996A patents of Russia, its Aerosol fire-extinguishing agent prescription is the dicyandiamide of 62-72% potassium nitrate, 8-12% phenolic resin and surplus, due to wherein containing band cyanogen The compound dicyandiamide of base, can produce the noxious material of cyanate, human body and surrounding environment are damaged in combustion.
In addition, existing aerosol type extinguishing chemical fire-fighting efficiency is relatively low, and there is a possibility that to be detonated, security Difference, as also disclosed that a kind of aerosol extinguishing agent in patent application CN9310587.6, it is mainly by oxidant such as potassium nitrate and nitre Sour ammonium, incendiary agent, curing molding agent etc. form, and it is that fire-fighting efficiency is relatively low, fire extinguishing is fast that this extinguishing chemical, which has a subject matter, Spend it is unhappy, wherein toxicity problem be present during production and use in the additives such as the potassium ferricyanide that use.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of compound type aerosol extinguishing agent, the present invention Aerosol extinguishing agent there is preferable fire extinguishing effectiveness, combustion stability and stability.
A kind of compound type aerosol extinguishing agent proposed by the present invention, its raw material include by weight:Modified aluminas 40-50 It is part, ammonium nitrate 20-25 parts, trimerization chloramines 15-20 parts, potassium picrate 12-14 parts, Silk Powder 1-3 parts, phenolic resin 2-4 parts, poly- Vinyl alcohol 2-3 parts, potassium dihydrogen phosphate 2-3 parts, stearic acid 2-3 parts, conditioning agent 1-2 parts.
Preferably, its raw material includes by weight:Modified aluminas 42-48 parts, ammonium nitrate 21-24 parts, trimerization chloramines 16- 19 parts, potassium picrate 12.5-13.5 parts, Silk Powder 1.5-2.5 parts, phenolic resin 2.5-3.5 parts, polyvinyl alcohol 2.2-2.8 parts, Potassium dihydrogen phosphate 2.2-2.8 parts, stearic acid 2.1-2.7 parts, conditioning agent 1.2-1.8 parts.
Preferably, the weight ratio of the stearic acid and conditioning agent is 2.5-2.6:1.5-1.7.
Preferably, the preparation method of the modified aluminas is:Aluminum oxide and montmorillonite are mixed, grind 10-20min, Methyl-silicone oil is added, 40-50 DEG C, insulated and stirred 50-60min is warming up to, vacuum drying, crosses 400-500 mesh sieves, produce modified oxygen Change aluminium.
Preferably, the conditioning agent includes aluminium carbonate, magnesium carbonate and carbon dust.
Preferably, the aluminum oxide, montmorillonite, the weight ratio of methyl-silicone oil are 1:0.2-0.5:2-3.
Preferably, the aluminium carbonate, magnesium carbonate, the weight ratio of carbon dust are 1-2:1-3:1-3.
The preparation technology of the compound type aerosol extinguishing agent of the present invention can be made according to the conventional fabrication process in place field, Each raw material is mixed according to the parts by weight and is molded.
The present invention aerosol extinguishing agent in using modified aluminas and ammonium nitrate as oxidant, wherein, with montmorillonite with Methyl-silicone oil is modified to aluminum oxide, and both, which coordinate, is collectively forming the hydrophobic field of superposition, and collaboration keeps the hydrophobic protection against the tide of aluminum oxide Property, the defects of making up the aluminum oxide easy moisture absorption, modified aluminum oxide and ammonium nitrate interworking have that oxygen content is high, is not easy the moisture absorption, production The characteristics of thing is nontoxic, while make obtained aerosol extinguishing agent that there is relatively low friction sensitivity and impact sensitivity;With trimerization chloramines With potassium picrate as fuel agent, wherein, potassium picrate has preferable heat endurance, compatibility and stability, and it is fast to burn Speed residual is few, adds Silk Powder, and its potassium element contained can play fire extinguishing function, add Silk Powder, can be to picric acid Potassium is modified, and reduces the ignition temperature of potassium picrate, after trimerization chloramines interworking, can significantly improve aerosol extinguishing agent Fire extinguishing effect;Phenolic resin, polyvinyl alcohol, potassium dihydrogen phosphate, stearic acid are added, with ammonium nitrate mating reaction, is further reduced Ignition temperature, improve combustion stability, fire extinguishing effectiveness and the stability of aerosol extinguishing agent.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of compound type aerosol extinguishing agent, its raw material include by weight:40 parts of modified aluminas, 25 parts of ammonium nitrate, It is 15 parts of trimerization chloramines, 14 parts of potassium picrate, 1 part of Silk Powder, 4 parts of phenolic resin, 2 parts of polyvinyl alcohol, 3 parts of potassium dihydrogen phosphate, hard 2 parts of resin acid, 2 parts of conditioning agent.
Embodiment 2
A kind of compound type aerosol extinguishing agent, its raw material include by weight:50 parts of modified aluminas, 20 parts of ammonium nitrate, It is 20 parts of trimerization chloramines, 12 parts of potassium picrate, 3 parts of Silk Powder, 2 parts of phenolic resin, 3 parts of polyvinyl alcohol, 2 parts of potassium dihydrogen phosphate, hard 3 parts of resin acid, 1 part of conditioning agent;
Wherein, the preparation method of the modified aluminas is:Aluminum oxide and montmorillonite are mixed, grind 10min, adds first Base silicone oil, 50 DEG C, insulated and stirred 50min are warming up to, vacuum drying, 500 mesh sieves is crossed, produces modified aluminas.
Embodiment 3
A kind of compound type aerosol extinguishing agent, its raw material include by weight:45 parts of modified aluminas, 23 parts of ammonium nitrate, 17 parts of trimerization chloramines, 13 parts of potassium picrate, 2 parts of Silk Powder, 3 parts of phenolic resin, 2.5 parts of polyvinyl alcohol, potassium dihydrogen phosphate 2.5 Part, 2.5 parts of stearic acid, 1.5 parts of conditioning agent;
Wherein, the preparation method of the modified aluminas is:Aluminum oxide and montmorillonite are mixed, grind 20min, adds first Base silicone oil, 40 DEG C, insulated and stirred 60min are warming up to, vacuum drying, 400 mesh sieves is crossed, produces modified aluminas;
The conditioning agent includes aluminium carbonate, magnesium carbonate and carbon dust.
Embodiment 4
A kind of compound type aerosol extinguishing agent, its raw material include by weight:42 parts of modified aluminas, 24 parts of ammonium nitrate, 16 parts of trimerization chloramines, 13.5 parts of potassium picrate, 1.5 parts of Silk Powder, 3.5 parts of phenolic resin, 2.2 parts of polyvinyl alcohol, biphosphate 2.8 parts of potassium, 2.1 parts of stearic acid, 1.8 parts of conditioning agent;
Wherein, the preparation method of the modified aluminas is:Aluminum oxide and montmorillonite are mixed, grind 15min, adds first Base silicone oil, 45 DEG C, insulated and stirred 55min are warming up to, vacuum drying, 400 mesh sieves is crossed, produces modified aluminas;
The conditioning agent includes aluminium carbonate, magnesium carbonate and carbon dust;
The aluminum oxide, montmorillonite, the weight ratio of methyl-silicone oil are 1:0.2:3;
The aluminium carbonate, magnesium carbonate, the weight ratio of carbon dust are 1:3:1.
Embodiment 5
A kind of compound type aerosol extinguishing agent, its raw material include by weight:48 parts of modified aluminas, 21 parts of ammonium nitrate, 19 parts of trimerization chloramines, 12.5 parts of potassium picrate, 2.5 parts of Silk Powder, 2.5 parts of phenolic resin, 2.8 parts of polyvinyl alcohol, biphosphate 2.2 parts of potassium, 2.7 parts of stearic acid, 1.2 parts of conditioning agent;
Wherein, the preparation method of the modified aluminas is:Aluminum oxide and montmorillonite are mixed, grind 13min, adds first Base silicone oil, 47 DEG C, insulated and stirred 52min are warming up to, vacuum drying, 500 mesh sieves is crossed, produces modified aluminas;
The conditioning agent includes aluminium carbonate, magnesium carbonate and carbon dust;
The aluminum oxide, montmorillonite, the weight ratio of methyl-silicone oil are 1:0.5:2;
The aluminium carbonate, magnesium carbonate, the weight ratio of carbon dust are 2:1:3.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (7)

1. a kind of compound type aerosol extinguishing agent, it is characterised in that its raw material includes by weight:Modified aluminas 40-50 parts, Ammonium nitrate 20-25 parts, trimerization chloramines 15-20 parts, potassium picrate 12-14 parts, Silk Powder 1-3 parts, phenolic resin 2-4 parts, poly- second Enol 2-3 parts, potassium dihydrogen phosphate 2-3 parts, stearic acid 2-3 parts, conditioning agent 1-2 parts.
2. compound type aerosol extinguishing agent according to claim 1, it is characterised in that its raw material includes by weight:It is modified Aluminum oxide 42-48 parts, ammonium nitrate 21-24 parts, trimerization chloramines 16-19 parts, potassium picrate 12.5-13.5 parts, Silk Powder 1.5-2.5 Part, phenolic resin 2.5-3.5 parts, polyvinyl alcohol 2.2-2.8 parts, potassium dihydrogen phosphate 2.2-2.8 parts, stearic acid 2.1-2.7 parts, tune Save agent 1.2-1.8 parts.
3. compound type aerosol extinguishing agent according to claim 1 or claim 2, it is characterised in that the stearic acid and conditioning agent Weight ratio is 2.5-2.6:1.5-1.7.
4. according to any one of the claim 1-3 compound type aerosol extinguishing agents, it is characterised in that the modified aluminas Preparation method is:Aluminum oxide and montmorillonite are mixed, grind 10-20min, adds methyl-silicone oil, is warming up to 40-50 DEG C, insulation 50-60min is stirred, vacuum drying, 400-500 mesh sieves is crossed, produces modified aluminas.
5. according to any one of the claim 1-4 compound type aerosol extinguishing agents, it is characterised in that the conditioning agent includes carbon Sour aluminium, magnesium carbonate and carbon dust.
6. compound type aerosol extinguishing agent according to claim 4, it is characterised in that the aluminum oxide, montmorillonite, methyl silicon The weight ratio of oil is 1:0.2-0.5:2-3.
7. compound type aerosol extinguishing agent according to claim 5, it is characterised in that the aluminium carbonate, magnesium carbonate, carbon dust Weight ratio is 1-2:1-3:1-3.
CN201711104817.3A 2017-11-10 2017-11-10 A kind of compound type aerosol extinguishing agent Withdrawn CN107754199A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711104817.3A CN107754199A (en) 2017-11-10 2017-11-10 A kind of compound type aerosol extinguishing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711104817.3A CN107754199A (en) 2017-11-10 2017-11-10 A kind of compound type aerosol extinguishing agent

Publications (1)

Publication Number Publication Date
CN107754199A true CN107754199A (en) 2018-03-06

Family

ID=61273419

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711104817.3A Withdrawn CN107754199A (en) 2017-11-10 2017-11-10 A kind of compound type aerosol extinguishing agent

Country Status (1)

Country Link
CN (1) CN107754199A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114984504A (en) * 2022-07-13 2022-09-02 湖南中科智网电力科技有限公司 Aerosol extinguishing agent for power distribution cabinet and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1078161A (en) * 1992-01-30 1993-11-10 柳别尔崔科学生产协会(联盟) Fire-extinguishing composite
CN101554520A (en) * 2009-05-26 2009-10-14 胡永华 Steam hot aerosol fire-extinguishing composite and application method and fire extinguishing device thereof
CN101376049B (en) * 2008-09-26 2011-07-27 陕西坚瑞消防股份有限公司 Extinguishment combination with hot gas sol
CN105169614A (en) * 2015-09-06 2015-12-23 苏州久港消防设备有限公司 Aerosol extinguishant for handheld fire extinguisher and preparation method of aerosol extinguishant
CN105999606A (en) * 2016-06-12 2016-10-12 杨根喜 Ammonium phosphate high-effect superfine dry powder extinguishing agent and production method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1078161A (en) * 1992-01-30 1993-11-10 柳别尔崔科学生产协会(联盟) Fire-extinguishing composite
CN101376049B (en) * 2008-09-26 2011-07-27 陕西坚瑞消防股份有限公司 Extinguishment combination with hot gas sol
CN101554520A (en) * 2009-05-26 2009-10-14 胡永华 Steam hot aerosol fire-extinguishing composite and application method and fire extinguishing device thereof
CN105169614A (en) * 2015-09-06 2015-12-23 苏州久港消防设备有限公司 Aerosol extinguishant for handheld fire extinguisher and preparation method of aerosol extinguishant
CN105999606A (en) * 2016-06-12 2016-10-12 杨根喜 Ammonium phosphate high-effect superfine dry powder extinguishing agent and production method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114984504A (en) * 2022-07-13 2022-09-02 湖南中科智网电力科技有限公司 Aerosol extinguishing agent for power distribution cabinet and preparation method thereof

Similar Documents

Publication Publication Date Title
CN106397075B (en) A kind of firecrackers safety firing cable composition
CN104307132B (en) A kind of preparation method of ABC powder extinguishing agent
MY161434A (en) Ferrocene-based fire extinguishing composition
CN101921159B (en) Sulfur-free and pearlite-free firecracker reagent and preparation method thereof
CN101279867A (en) Non-sulphur firecracker components and preparation thereof
CN107035398B (en) A kind of compound retardant of physical-chemical and its preparation and application for preventing and treating low order coal spontaneous combustion
CA2772641A1 (en) A novel aging-resistant aerosol generating agent and preparing method thereof
KR101209706B1 (en) Fire extinguishing agent composition for solid-aerosol automatic extinguisher and manufacturing method thereof
CN104311374A (en) Novel sensitization bubble carrier colloidal emulsion explosive and preparation method thereof
CN102249824A (en) Formula of gunpowder for timing firing cable of display shell
MX340968B (en) Fire extinguishing composition producing fire extinguishing substance by high temperature sublimation.
CN106800633A (en) High fire-retardance sealing agent of single component polyurethane foam of oxygen index (OI) >=32 and preparation method thereof
CN107754199A (en) A kind of compound type aerosol extinguishing agent
CN104511127A (en) Class D fire extinguishing agent and preparation method thereof
CN102775814B (en) Method for preparing micro-encapsulation red phosphorus
CN105198680A (en) Sulfur-free composite material composition for preparing firecrackers
CN104892333A (en) High temperature sensitization method for preparing coal mine emulsion explosive
US10065897B2 (en) Pyrotechnics containing oleoresin
CN108124864A (en) A kind of stable type compound sodium nitrophenolate and preparation method thereof
WO2018172835A1 (en) Fire-resistant and fireproof composition, method of manufacture and use of the same for limiting the spread of fire and for increasing of fire resistance of an organic material
CN103880572B (en) Fireworks and firecrackers pyrotechnic composition composition
CN110448850B (en) Low-temperature concentrated fire extinguishing agent and preparation method and application method thereof
CN109081764A (en) A kind of novel quick-fried loud fireworks medicament
CN112521916A (en) Chemical compound type coolant for aerosol fire extinguishing product and preparation method thereof
CN108003832B (en) Environment-friendly binder and preparation method and application thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20180306

WW01 Invention patent application withdrawn after publication