CN107746265A - A kind of raw material for being used to prepare magnetic induction ceramic package material - Google Patents

A kind of raw material for being used to prepare magnetic induction ceramic package material Download PDF

Info

Publication number
CN107746265A
CN107746265A CN201711005516.5A CN201711005516A CN107746265A CN 107746265 A CN107746265 A CN 107746265A CN 201711005516 A CN201711005516 A CN 201711005516A CN 107746265 A CN107746265 A CN 107746265A
Authority
CN
China
Prior art keywords
mixed
magnetic induction
ceramic package
raw material
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711005516.5A
Other languages
Chinese (zh)
Inventor
王金英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Ruisheng Technology Co Ltd
Original Assignee
Foshan Ruisheng Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Ruisheng Technology Co Ltd filed Critical Foshan Ruisheng Technology Co Ltd
Priority to CN201711005516.5A priority Critical patent/CN107746265A/en
Publication of CN107746265A publication Critical patent/CN107746265A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • C04B35/19—Alkali metal aluminosilicates, e.g. spodumene
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/6261—Milling
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C04B2235/3222—Aluminates other than alumino-silicates, e.g. spinel (MgAl2O4)
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262—Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3817—Carbides
    • C04B2235/3826—Silicon carbides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3852—Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3886—Refractory metal nitrides, e.g. vanadium nitride, tungsten nitride
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/449—Organic acids, e.g. EDTA, citrate, acetate, oxalate
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Abstract

The invention provides a kind of raw material for being used to prepare magnetic induction ceramic package material.It is prepared by following steps：The first step：By potassium albite, vein quartz, spinelle, calcite and not sub- mixed calcining, mixed-powder A is obtained；Second step：Four n-propyl zirconates, γ methacryloxypropyl trimethoxy silanes and ethyl acetate are mixed and dissolved, obtains solution B；3rd step：Mixed-powder A, solution B, carborundum, manganese carbonate, spherical nano TiO 2, alundum (Al2O3), titanium oxide powder, zirconium silicate, glair and Nano titanium nitride are mixed, is put into ball mill and carries out ball milling 23 25 hours, ratio of grinding media to material 1:1；4th step：It is put into baking oven and dries, crosses 100 mesh sieves and produce.There is good heat endurance after the raw material for being used to prepare magnetic induction ceramic package material of the invention are sintered, hardness is high, and sealing effectiveness is good, while the stripping quantity of lead, cadmium is less than national standard many.

Description

A kind of raw material for being used to prepare magnetic induction ceramic package material
Technical field
The present invention relates to packaging material field, and in particular to a kind of former material for being used to prepare magnetic induction ceramic package material Material.
Background technology
With the enhancing of people's living standards continue to improve and environmental consciousness, people increasingly pay close attention to daily living article Influence to health, packaging material are exactly one of which.Packaging material refer to be used for manufacture packing container, packing and decorating, Packages printing, packed and transported etc. meet product packaging requirement used in material, it both include metal, plastics, glass, ceramics, The main packaging materials such as paper, bamboo sheet, wild mushroom class, natural fiber, chemical fibre, composite, again include strapping, decoration, The auxiliary materials such as printing material.Wherein, ceramic package material is due to antibacterial, deodorization and the green work(for being advantageous to health Can, and can be improved and extend in the performance of mechanics, electricity, magnetics, optics, calorifics etc., or even show spy Different performance, therefore, extensive research and application are obtained.Some appearances in the fabrication process be present in traditional ceramic package material The material of radiation is easily caused to human body, containing harmful metal elements such as micro lead, cadmiums, and sealing and heat resistance are bad, Therefore, protection and the mankind of the ceramic package material that research and development heat resistance is good, hardness is high and harmfulness is small for environment are good for Health has important meaning.
The content of the invention
Technical problems to be solved：It is an object of the invention to provide a kind of original for being used to prepare magnetic induction ceramic package material Material, there is good heat endurance after sintered, hardness is high, and sealing effectiveness is good, while the stripping quantity of lead, cadmium is marked less than country Permit more.
Technical scheme：A kind of raw material for being used to prepare magnetic induction ceramic package material, are prepared by following component and step Form：
The first step：Potassium albite 30-50g, vein quartz 10-20g, spinelle 5-10g, calcite 2-4g and not sub- 5-10g are mixed Close, 30-50 minutes are calcined at 1800-2000 DEG C, obtain mixed-powder A；
Second step：By four n-propyl zirconate 5-10g, γ-methacryloxypropyl trimethoxy silane 5-10g and acetic acid Ethyl ester 40-50ml mixes dissolving, obtains solution B；
3rd step：By mixed-powder A, solution B, carborundum 10-30g, manganese carbonate 3-6g, spherical nano TiO 2 2-5g, three Al 2 O 2-5g, titanium oxide powder 2-4g, zirconium silicate 1-3g, glair 1-3g and Nano titanium nitride 1-2g mixing, are put into ball mill Middle progress ball milling 23-25 hours, ratio of grinding media to material 1:1；
4th step：It is put into baking oven and is dried at 80-90 DEG C of temperature, crosses 100 mesh sieves and produce.
It is further preferred that temperature is 1900 DEG C in the first step, calcination time is 35-45 minutes.
It is further preferred that Ball-milling Time is 24 hours in the 3rd step.
It is further preferred that oven temperature is 95 DEG C in the 4th step.
Beneficial effect：The raw material for being used to prepare magnetic induction ceramic package material of the present invention are sintered rear steady with good heat It is qualitative, it is heated to heat exchange in 300 DEG C of inputs, 20 DEG C of water and once, does not occur tire and split, hardness is high, and its hardness maximum is reachable 24.9GPa, while it is only 4.3gmm/ (m that its vapor transmission coefficient is minimum2DKPa), there is good sealing effectiveness, In addition, the stripping quantity of lead, cadmium respectively between 0.010-0.012mg/L and 0.005-0.006mg/L, is permitted less than national standard It is more.
Embodiment
Embodiment 1
A kind of raw material for being used to prepare magnetic induction ceramic package material, are prepared by following component and step：
The first step：Potassium albite 30g, vein quartz 10g, spinelle 5g, calcite 2g and not sub- 5g are mixed, forged at 1800 DEG C Burn 30 minutes, obtain mixed-powder A；
Second step：By four n-propyl zirconate 5g, γ-methacryloxypropyl trimethoxy silane 5g and ethyl acetate 40ml mixes dissolving, obtains solution B；
3rd step：By mixed-powder A, solution B, carborundum 10g, manganese carbonate 3g, spherical nano TiO 2 2g, alundum (Al2O3) 2g, titanium oxide powder 2g, zirconium silicate 1g, glair 1g and Nano titanium nitride 1g mixing, it is put into ball mill and carries out ball milling 23 hours, ball Material is than being 1:1；
4th step：It is put into baking oven and is dried at 80 DEG C of temperature, crosses 100 mesh sieves and produce.
Embodiment 2
A kind of raw material for being used to prepare magnetic induction ceramic package material, are prepared by following component and step：
The first step：Potassium albite 40g, vein quartz 15g, spinelle 7g, calcite 3g and not sub- 7g are mixed, forged at 1900 DEG C Burn 35 minutes, obtain mixed-powder A；
Second step：By four n-propyl zirconate 7g, γ-methacryloxypropyl trimethoxy silane 8g and ethyl acetate 45ml mixes dissolving, obtains solution B；
3rd step：By mixed-powder A, solution B, carborundum 20g, manganese carbonate 4g, spherical nano TiO 2 3g, alundum (Al2O3) 3g, titanium oxide powder 3g, zirconium silicate 2g, glair 2g and Nano titanium nitride 1.5g mixing, it is put into ball mill and carries out ball milling 24 hours, Ratio of grinding media to material is 1:1；
4th step：It is put into baking oven and is dried at 85 DEG C of temperature, crosses 100 mesh sieves and produce.
Embodiment 3
A kind of raw material for being used to prepare magnetic induction ceramic package material, are prepared by following component and step：
The first step：Potassium albite 45g, vein quartz 15g, spinelle 8g, calcite 3g and not sub- 9g are mixed, forged at 1900 DEG C Burn 45 minutes, obtain mixed-powder A；
Second step：By four n-propyl zirconate 9g, γ-methacryloxypropyl trimethoxy silane 9g and ethyl acetate 45ml mixes dissolving, obtains solution B；
3rd step：By mixed-powder A, solution B, carborundum 25g, manganese carbonate 5g, spherical nano TiO 2 4g, alundum (Al2O3) 4g, titanium oxide powder 3g, zirconium silicate 2g, glair 2g and Nano titanium nitride 1.5g mixing, it is put into ball mill and carries out ball milling 24 hours, Ratio of grinding media to material is 1:1；
4th step：It is put into baking oven and is dried at 85 DEG C of temperature, crosses 100 mesh sieves and produce.
Embodiment 4
A kind of raw material for being used to prepare magnetic induction ceramic package material, are prepared by following component and step：
The first step：Potassium albite 50g, vein quartz 20g, spinelle 10g, calcite 4g and not sub- 10g are mixed, at 2000 DEG C Calcining 50 minutes, obtains mixed-powder A；
Second step：By four n-propyl zirconate 10g, γ-methacryloxypropyl trimethoxy silane 10g and ethyl acetate 50ml mixes dissolving, obtains solution B；
3rd step：By mixed-powder A, solution B, carborundum 30g, manganese carbonate 6g, spherical nano TiO 2 5g, alundum (Al2O3) 5g, titanium oxide powder 4g, zirconium silicate 3g, glair 3g and Nano titanium nitride 2g mixing, it is put into ball mill and carries out ball milling 25 hours, ball Material is than being 1:1；
4th step：It is put into baking oven and is dried at 90 DEG C of temperature, crosses 100 mesh sieves and produce.
Comparative example 1
The present embodiment and the difference of embodiment 1 are not containing vein quartz and spinelle.Specifically：
The first step：Potassium albite 30g, calcite 2g are mixed with not sub- 5g, is calcined 30 minutes at 1800 DEG C, obtains mixed-powder A；
Second step：By four n-propyl zirconate 5g, γ-methacryloxypropyl trimethoxy silane 5g and ethyl acetate 40ml mixes dissolving, obtains solution B；
3rd step：By mixed-powder A, solution B, carborundum 10g, manganese carbonate 3g, spherical nano TiO 2 2g, alundum (Al2O3) 2g, titanium oxide powder 2g, zirconium silicate 1g, glair 1g and Nano titanium nitride 1g mixing, it is put into ball mill and carries out ball milling 23 hours, ball Material is than being 1:1；
4th step：It is put into baking oven and is dried at 80 DEG C of temperature, crosses 100 mesh sieves and produce.
Comparative example 2
The difference of the present embodiment and embodiment 1 is not contain calcite and not sub.Specifically：
The first step：Potassium albite 30g, vein quartz 10g and spinelle 5g are mixed, calcines 30 minutes, must mix at 1800 DEG C Powders A；
Second step：By four n-propyl zirconate 5g, γ-methacryloxypropyl trimethoxy silane 5g and ethyl acetate 40ml mixes dissolving, obtains solution B；
3rd step：By mixed-powder A, solution B, carborundum 10g, manganese carbonate 3g, spherical nano TiO 2 2g, alundum (Al2O3) 2g, titanium oxide powder 2g, zirconium silicate 1g, glair 1g and Nano titanium nitride 1g mixing, it is put into ball mill and carries out ball milling 23 hours, ball Material is than being 1:1；
4th step：It is put into baking oven and is dried at 80 DEG C of temperature, crosses 100 mesh sieves and produce.
Comparative example 3
The present embodiment and the difference of embodiment 1 are not containing glair.Specifically：
The first step：Potassium albite 30g, vein quartz 10g, spinelle 5g, calcite 2g and not sub- 5g are mixed, forged at 1800 DEG C Burn 30 minutes, obtain mixed-powder A；
Second step：By four n-propyl zirconate 5g, γ-methacryloxypropyl trimethoxy silane 5g and ethyl acetate 40ml mixes dissolving, obtains solution B；
3rd step：By mixed-powder A, solution B, carborundum 10g, manganese carbonate 3g, spherical nano TiO 2 2g, alundum (Al2O3) 2g, titanium oxide powder 2g, zirconium silicate 1g and Nano titanium nitride 1g mixing, are put into ball mill and carry out ball milling 23 hours, and ratio of grinding media to material is 1:1；
4th step：It is put into baking oven and is dried at 80 DEG C of temperature, crosses 100 mesh sieves and produce.
Table 1 is used for the partial properties index for preparing the raw material of magnetic induction ceramic package material
Its partial properties index is determined after material of the present invention is sintered, see the table below 1, it will be seen that material of the present invention With good heat endurance, it is heated to heat exchange in 300 DEG C of inputs, 20 DEG C of water and once, does not occur tire and split, hardness is high, its hardness Maximum reachable 24.9GPa, while it is only 4.3gmm/ (m that its vapor transmission coefficient is minimum2DKPa), have good Sealing effectiveness, in addition, the stripping quantity of lead, cadmium is respectively between 0.010-0.012mg/L and 0.005-0.006mg/L, less than state Family's standard is many.

Claims (4)

  1. A kind of 1. raw material for being used to prepare magnetic induction ceramic package material, it is characterised in that：Prepared by following component and step Form：
    The first step：Potassium albite 30-50g, vein quartz 10-20g, spinelle 5-10g, calcite 2-4g and not sub- 5-10g are mixed Close, 30-50 minutes are calcined at 1800-2000 DEG C, obtain mixed-powder A；
    Second step：By four n-propyl zirconate 5-10g, γ-methacryloxypropyl trimethoxy silane 5-10g and acetic acid Ethyl ester 40-50ml mixes dissolving, obtains solution B；
    3rd step：By mixed-powder A, solution B, carborundum 10-30g, manganese carbonate 3-6g, spherical nano TiO 2 2-5g, three Al 2 O 2-5g, titanium oxide powder 2-4g, zirconium silicate 1-3g, glair 1-3g and Nano titanium nitride 1-2g mixing, are put into ball mill Middle progress ball milling 23-25 hours, ratio of grinding media to material 1:1；
    4th step：It is put into baking oven and is dried at 80-90 DEG C of temperature, crosses 100 mesh sieves and produce.
  2. A kind of 2. raw material for being used to prepare magnetic induction ceramic package material according to claim 1, it is characterised in that：Institute It is 1900 DEG C to state temperature in the first step, and calcination time is 35-45 minutes.
  3. A kind of 3. raw material for being used to prepare magnetic induction ceramic package material according to claim 1, it is characterised in that：Institute It is 24 hours to state Ball-milling Time in the 3rd step.
  4. A kind of 4. raw material for being used to prepare magnetic induction ceramic package material according to claim 1, it is characterised in that：Institute It is 95 DEG C to state oven temperature in the 4th step.
CN201711005516.5A 2017-10-23 2017-10-23 A kind of raw material for being used to prepare magnetic induction ceramic package material Withdrawn CN107746265A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711005516.5A CN107746265A (en) 2017-10-23 2017-10-23 A kind of raw material for being used to prepare magnetic induction ceramic package material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711005516.5A CN107746265A (en) 2017-10-23 2017-10-23 A kind of raw material for being used to prepare magnetic induction ceramic package material

Publications (1)

Publication Number Publication Date
CN107746265A true CN107746265A (en) 2018-03-02

Family

ID=61254036

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711005516.5A Withdrawn CN107746265A (en) 2017-10-23 2017-10-23 A kind of raw material for being used to prepare magnetic induction ceramic package material

Country Status (1)

Country Link
CN (1) CN107746265A (en)

Similar Documents

Publication Publication Date Title
CN101058476B (en) Antiseep glaze material and glair for Ruyao kiln package container and preparing method thereof
WO2013018728A1 (en) Colored and light-transmitting sintered zirconia compact and use of same
CN107384398A (en) A kind of YAG fluorescent powder and preparation method thereof and YAG fluorescence ceramics prepared therefrom
CN106675273B (en) A kind of multifunctional antibiotic coating and preparation method thereof
CN112778799A (en) Purple ceramic pigment powder particle, preparation method thereof and prepared purple zirconia ceramic
CN106084902B (en) A kind of high infrared radiation powder and preparation method thereof
CN101983949B (en) White opaque glaze for piezoelectric ceramic atomizing sheet and preparation method thereof
CN107746265A (en) A kind of raw material for being used to prepare magnetic induction ceramic package material
CN101857463B (en) Ceramic glaze and preparation method thereof
CN113880593B (en) High-temperature sintered tourmaline type negative ion unglazed ceramic and preparation method thereof
CN111233331A (en) Double-layer pearl reaction glaze and preparation method thereof
CN106242282B (en) A kind of ceramic glaze and preparation method thereof of absorbable electromagnetic radiation
CN104926299B (en) A kind of preparation method of ceramic insertion core
CN108165794A (en) A kind of five titanium intermetallic compound powder batch preparation of three silication
CN104231774B (en) Nanometer internal wall decorative paint
KR101490655B1 (en) Manufacturing Method Of Natural Plant Dyeing Tile
CN106747340A (en) A kind of medical ceramic material and preparation method thereof
CN107573034B (en) Preparation method of lead-free piezoelectric ceramic
CN108484146A (en) A kind of far-infrared ceramic material and preparation method thereof
CN102992807A (en) Method for preparing agate red ceramic glazing material
CN106495654A (en) A kind of magnetic induction ceramic package material and preparation method thereof
CN113999053B (en) Seaweed green ceramic glaze and preparation method thereof
CN104556706A (en) Novel glass ceramic
CN110698180A (en) Preparation method of far infrared ceramic material
CN109880490A (en) A kind of water soluble negative ion conch meal and its manufacture craft

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20180302

WW01 Invention patent application withdrawn after publication