CN107723604A - A kind of economical 690MPa levels dual phase steel and preparation method thereof - Google Patents
A kind of economical 690MPa levels dual phase steel and preparation method thereof Download PDFInfo
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- CN107723604A CN107723604A CN201711226908.4A CN201711226908A CN107723604A CN 107723604 A CN107723604 A CN 107723604A CN 201711226908 A CN201711226908 A CN 201711226908A CN 107723604 A CN107723604 A CN 107723604A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
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- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
The invention discloses a kind of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel and preparation method thereof, belongs to Ferrous Metallurgy and hot-rolling plate band production technical field.A kind of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel, by weight percentage, its chemical composition are C:0.08%~0.12%, Si≤0.15%, Mn:1.70%~1.95%, Nb:0.045%~0.055%, P≤0.02%, S:≤ 0.003%, Als:0.015%~0.050%, Ti:0.08~0.12, remaining is Fe and inevitable impurity.The present invention passes through chemical composition ranges reasonable in design, coordinate required rolling mill practice simultaneously, it is equipped with rational quick cooldown rate and coiling temperature section, obtain the microstructure of ferrite and bainite composition, preparing gained dual phase steel has the advantages that intensity is high, elongation percentage is high, forming property is good, and its cost is cheap, be worthy to be popularized utilization.
Description
Technical field
The invention belongs to Ferrous Metallurgy and hot-rolling plate band production technical field, and in particular to a kind of economical 690MPa levels
Hot-rolled ferrite-bainite dual-phase steel and preparation method thereof.
Background technology
For automotive light weight technology, reduce oil consumption and improvement vehicle security etc., in recent years the research and development plan of many new steel grades
It is concentrated mainly on AHSS (Advanced High Strength Steel, letter of the exploitation with favorable forming property
Claim AHSS).The species of AHSS steel is a lot, such as ferrite/martensite two-phase (Ferrite/Martensite Dual Phase, letter
Claim FMDP) steel, ferrite/bainite two-phase (Ferrite/Bainite Dual Phase, abbreviation FBDP) steel, phase-change induced modeling
Property (Transformation Induced Plasticity, abbreviation TRIP) steel, twin crystal inducing plasticity (Twinning
Induced Plasicity, abbreviation TWIP) steel, complex phase (Complex Phase, abbreviation CP) steel, martensite (Martensite,
Abbreviation M) steel, quenching partition (Quenching and Paritioning, abbreviation Q&P) steel and hot forming (Hot Formed, letter
Claim HF) steel etc..
FBDP steel is also referred to as stretch flange formability (Stretch-Flangeable, abbreviation SF) steel or high reaming (High Hole-
Expansion, abbreviation HHE) steel, when bainite content is 10%~20%, it has very good forming property, especially
It is Extending flange Perfor.Relative to HSLA (Aldecor, High Strength Low Alloy Steel) and FMDP
Steel, the major advantage of FBDP steel are to improve sheared edge ductility, take into account the contradiction and balance of intensity and extensibility, and it is welded
Connect, fatigue and reaming it is functional, have general material it is incomparable the advantages of;FBDP steel heat affected area after Flash Butt Welding
Hardness be higher than parent metal, be not in ruckbildung during with post-processing, while the steel plate has good slight-fatigability
It can coordinate, compared with the HSLA steel of equality strength rank, FBDP steel strain hardening exponent (n values) and breaking elongation are higher, therefore
FBDP steel is higher similar to requirements such as automobile chassises more suitable for punching press, and the part that extension property is good.
In the 1990s, the U.S., Japan etc. develop the hot rolling FB steel of the high reaming performance of 440~780MPa levels in succession
Plate, its hole expansibility are 70%~131%, are mainly used in formability, the especially good automobile chassis of flange performance requirement, car
The parts such as wheel, because it contains more expensive alloying elements Cr, Nb, Ti, V and Mo etc., although can under conditions of cooling rate is relatively low
To obtain ferrite/bainite duplex structure, but its cost is higher.
The quick renewal of progress and rolling equipment recently as technology, material upgrading speed are also adding
It hurry up, meanwhile, energy crisis exacerbation and policy requirements energy-saving and emission-reduction and the requirement of automotive light weight technology are constantly deepened, Eco-power high-strength
Steel cry more and more higher.Therefore, currently it is badly in need of the dual phase steel of ferrite and bainite that a kind of cheap and can of cost ensures excellent properties,
To meet the development topic that high-performance is economical, energy-saving.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of economical 690MPa levels hot-rolled ferrite-bainite two-phase
Steel and preparation method thereof, the dual phase steel have intensity height, elongation percentage without expensive alloying elements such as Cr, Nb, Ti, V and Mo
High, the advantages that forming property is good.
Technical scheme is to provide a kind of economical 690MPa levels hot rolling iron used by the present invention solves above-mentioned technical problem
Ferritic bainite dual-phase steel, by weight percentage, its chemical composition is:C:0.08%~0.12%, Si≤0.15%, Mn:
1.70%~1.95%, Nb:0.045%~0.055%, P≤0.02%, S:≤ 0.003%, Als:0.015%~
0.050%, Ti:0.08~0.12, remaining is Fe and inevitable impurity.
Wherein, it is described economical in economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
The microstructure of 690MPa level hot-rolled ferrite-bainite dual-phase steels is made up of ferrite and bainite;Wherein, the matter of bainite
It is 10~40% to measure content.
Wherein, it is described ferritic flat in economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
Equal crystallite dimension≤10 μm;The mean grain size of the bainite is 12~12.5 μm.
Wherein, it is described economical in economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
The yield strength of 690MPa level hot-rolled ferrite-bainite dual-phase steels is 600~750MPa, and tensile strength is >=690MPa, is extended
Rate is >=18%.
Present invention also offers the preparation side of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
Method, this method comprise the following steps:
Chain-wales are mended hello Al lines → LF refining and added after desulfurizing iron → converter smelting top-bottom blowing → deoxidation, alloying → stove
Heat → continuous casting → heating of plate blank → high-pressure water descaling → roughing → Coil Box batches → finish rolling → section cooling → and batches → pack
Storage.
Wherein, it is described in the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
The tapping temperature of heating of plate blank is 1200~1240 DEG C.
Wherein, it is described in the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
Roughing uses 5 passages, every time deflection >=20% in roughing.
Wherein, it is described in the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
Workpiece thickness is 32~45mm in roughing.
Wherein, it is described in the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
Start rolling temperature Wei≤1030 DEG C in finish rolling.
Preferably, in the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above, institute
It is 950~1030 DEG C to state start rolling temperature in finish rolling.
Wherein, it is described in the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
Finishing temperature is 850~890 DEG C in finish rolling.
Wherein, it is described in the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
Rolling thickness is 2.5~6.0mm in finish rolling.
Wherein, it is described in the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above
Section cooling is using double section cooling techniques;The operation of double section cooling techniques is:It is first cold with 30~60 DEG C/s cooling velocity
But to 600~640 DEG C, 5~8s is incubated, then 520~550 DEG C are cooled to 10~30 DEG C/s cooling velocity.
Wherein, in the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described above, warp is worked as
Section cooling is batched to 520~550 DEG C.
The beneficial effects of the invention are as follows:
The present invention uses C-Mn-Nb-Ti composition design, wherein low C content can ensure that material has good shaping
Performance;Appropriate Mn contents can provide a part of solid solution strengthening effect;Nb addition can effective crystal grain thinning, Ti enhancing steel
Intensity;By chemical composition ranges reasonable in design, while coordinate required rolling mill practice, be equipped with rational quick cooling
Speed and coiling temperature section, the final microstructure for obtaining ferrite and bainite composition, prepare the economical 690MPa of gained
Agent dual phase steel of ferrite and bainite has the advantages that intensity is high, elongation percentage is high, forming property is good, and its cost is cheap, is worth pushing away
It is wide to use.
Embodiment
Specifically, a kind of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel, by weight percentage, its chemistry
Composition is:C:0.08%~0.12%, Si≤0.15%, Mn:1.70%~1.95%, Nb:0.045%~0.055%, P≤
0.02%, S:≤ 0.003%, Als:0.015%~0.050%, Ti:0.08~0.12, remaining be Fe and inevitably it is miscellaneous
Matter.
In composition design, the present invention uses C-Mn-Nb-Ti composition design, wherein low C content can ensure material
There is good forming property;Appropriate Mn contents can provide a part of solid solution strengthening effect;Nb addition can be refined effectively
Crystal grain, Ti coordinate required rolling mill practice, the final microstructure for obtaining ferrite and bainite composition, are prepared simultaneously
Economical 690 grades of dual phase steel of ferrite and bainite of intensity, plasticity and reaming excellent performance.
The valuable microalloy element such as Mo, Cr, Ni is not added in dual phase steel provided by the present invention, cost is cheap, and its is microcosmic
Tissue is made up of ferrite and bainite, wherein, the mass content of bainite is 10~40%, the average grain size of bainite
For 12~12.5 μm, surplus is ferrite, ferritic average grain size≤10 μm, and the present invention dual phase steel possess it is excellent
Different mechanical property, yield strength are 600~750MPa, and tensile strength is >=690MPa, and elongation percentage is >=18%.
, can be simultaneous in order to dual phase steel due to not adding the valuable microalloy element such as Mo, Cr, Ni in dual phase steel of the present invention
Mechanical property cheap and excellent Gu Chengben, when by ingenious rational composition design, it is also necessary to coordinate provided by the present invention
The preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel, this method comprise the following steps:
Chain-wales are mended hello Al lines → LF refining and added after desulfurizing iron → converter smelting top-bottom blowing → deoxidation, alloying → stove
Heat → continuous casting → heating of plate blank → high-pressure water descaling → roughing → Coil Box batches → finish rolling → section cooling → and batches → pack
Storage.
The tapping temperature of heating of plate blank is 1200~1240 DEG C in the above method, has both ensured that slab was fully heated, alloy is first
Plain fully solid solution, the abnormal growth of austenite crystal is prevented again;Roughing uses 5 passages, and every time deflection is necessary >=and 20%, protect
Austenite recrystallization is demonstrate,proved, fining austenite grains, can obtain the middle base that thickness is 32~45mm;Entry temperature at finishing is not wanted
Ask (general start rolling temperature Wei≤1030 DEG C, preferably 950~1030 DEG C), finishing temperature scope is 850~890 DEG C;After finish rolling
Section cooling be cooled to 600~640 DEG C using double section cooling techniques, the fast quickly cooling of leading portion with 30~60 DEG C/s cooling velocity,
5~8s is incubated, 520~550 DEG C is cooled to 10~30 DEG C/s cooling velocity, then batches.
FB dual phase steels are produced using present component, due to not adding the valuable microalloy element such as Mo, Cr, Ni, its CCT is bent
In line P and B transition curves some overlap, while bainite transformation has the spy of the two for diffusion with the phase transformation that meets of shear
Sign, this requires that there is big cooldown rate early stage in section cooling, meanwhile, it is incubated when being cooled to 600~640 DEG C, promotes C
Further diffusion, subsequently continue to be quickly cooled to the curling of bainite transformation section, obtain ferrite and add bainite structure.
The high intensity of dual phase steel of the present invention is from four aspects:When solution strengthening, second, tiny ferrite crystal grain, third,
Ferrite-bainite build up, fourth, Ti Second Phase Precipitation is strengthened.Simple solution strengthening and refined crystalline strengthening can not reach
690MPa intensity ranks, so the present invention adds appropriate Ti, reach precipitation strength using its Second Phase Precipitation, reach
690MPa ranks;The size of ferrite crystal grain must be controlled at≤10 μm simultaneously, and this just needs steel plate necessary after finish to gauge terminates
Fast quickly cooling, while 5s is incubated at 600~640 DEG C, 450~500 DEG C are subsequently quickly cooled to again and is batched, and this can both ensure
To tiny ferrite, while bainite can be also obtained, reach reinforcing and require.
The present invention is described in further detail below by embodiment, but therefore not limited the scope of the present invention
Among described scope of embodiments.
Embodiment 1
The present embodiment uses four experimental groups, the economical 690MPa levels hot-rolled ferrite-bainite two-phase of experimental group 1~4
The chemical composition of steel is shown in Table 1;
The chemical composition of the dual phase steel of 1 embodiment of table 1
The technological process of production of the present embodiment is:Desulfurizing iron → converter smelting top-bottom blowing → deoxidation, alloying → stove
Afterwards chain-wales mend feed Al lines → LF refining heating → continuous casting → heating of plate blank → high-pressure water descaling → roughing → Coil Box batch →
→ packaging and storage is batched in finish rolling → section cooling →.
Economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel, after conventional converter smelting, continuous casting, gained slab
Chemical composition it is as shown in table 1;
Slab obtained by continuous casting is heated to 1200~1240 DEG C (i.e. tapping temperature in table 2) insulation roughing, 200~250mm
Thick slab pass through 5 passage roughing, and every time deflection is necessary >=and 20%, workpiece thickness difference different according to finished product thickness
(ensureing deflection, interior variation can required);
Steel billet after roughing then carries out Coil Box and batched, and the Coil Box can be mandrelless transform Coil Box;
Base exchanges end to end among being realized in Coil Box, to ensure that the elongated temperature of steel billet is uniform;Secondary oxidation iron sheet is removed to protect simultaneously
It is bright and clean to demonstrate,prove steel billet plate face;
Middle base carries out displacement uncoiling after being batched through Coil Box, and finish rolling, entry temperature at finishing are carried out into finish rolling area
(i.e. start rolling temperature in table 2) is not higher than 1030 DEG C, and finishing temperature scope is 850~890 DEG C, using double section boshers after finish rolling
Skill, the fast quickly cooling of leading portion are cooled to 640 DEG C with 30~60 DEG C/s, are incubated 5s, then be cooled to 500 with 10~30 DEG C/s cooling velocity
~550 DEG C are batched;
After batching, packaging and storage, economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel is produced;
Hot rolling technology controlling value is shown in Table 2 in the present embodiment;
The hot rolling technology controlling value of the embodiment 1 of table 2
The economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel of the above-mentioned gained of experimental group 1~4, is carried out by national standard
Determine its yield strength, tensile strength and elongation percentage;Cold bending experiment is mouldability confirmatory experiment, is not ftractureed after clod wash as closing
Lattice;Each experimental group Mechanical Properties of Dual Phase Steels is shown in Table 3.
The mechanical property of 3 embodiment of table, 1 each experimental group dual phase steel
From the present embodiment, the chemical composition of the present invention by controlling steel and preparation method thereof, obtained a kind of intensity,
The economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel of plasticity and reaming excellent performance;The present invention uses C-Mn-Nb-Ti
Composition design, do not add the expensive alloying elements such as Cr, Nb, Ti, V and Mo, significantly reduce the cost of alloy of steel, from material
Aspect realizes economical.
Claims (9)
1. economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel, it is characterised in that:By weight percentage, its chemistry into
It is divided into:C:0.08%~0.12%, Si≤0.15%, Mn:1.70%~1.95%, Nb:0.045%~0.055%, P≤
0.02%, S:≤ 0.003%, Als:0.015%~0.050%, Ti:0.08~0.12, remaining be Fe and inevitably it is miscellaneous
Matter.
2. economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel according to claim 1, it is characterised in that:It is described
The microstructure of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel is made up of ferrite and bainite;Wherein, bayesian
The mass content of body is 10~40%.
3. economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel according to claim 2, it is characterised in that:It is described
Ferritic average grain size≤10 μm;The mean grain size of the bainite is 12~12.5 μm.
4. economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel according to claim 1, it is characterised in that:It is described
The yield strength of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel is 600~750MPa, tensile strength for >=
690MPa, elongation percentage are >=18%.
5. the preparation method of the economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel described in any one of Claims 1 to 4,
It is characterized in that:Comprise the following steps:
After desulfurizing iron → converter smelting top-bottom blowing → deoxidation, alloying → stove chain-wales mend feed the heating of Al lines → LF refining →
Continuous casting → heating of plate blank → high-pressure water descaling → roughing → Coil Box batches → finish rolling → section cooling → and batches → packaging and storage.
6. the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel according to claim 5, it is special
Sign is:The tapping temperature of the heating of plate blank is 1200~1240 DEG C.
7. the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel according to claim 5, it is special
Sign is:Roughing uses 5 passages, every time deflection >=20% in the roughing;In the roughing workpiece thickness be 32~
45mm。
8. the preparation method of economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel according to claim 5, it is special
Sign is:Finishing temperature is 850~890 DEG C in the finish rolling;Rolling thickness is 2.5~6.0mm in the finish rolling.
9. the preparation of the economical 690MPa levels hot-rolled ferrite-bainite dual-phase steel according to any one of claim 5~8
Method, it is characterised in that:The section cooling is using double section cooling techniques;The operation of double section cooling techniques is:First with 30
~60 DEG C/s cooling velocity is cooled to 600~640 DEG C, is incubated 5~8s, then be cooled to 10~30 DEG C/s cooling velocity
520~550 DEG C.
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CN110257725A (en) * | 2019-07-30 | 2019-09-20 | 马鞍山钢铁股份有限公司 | A kind of high-strength dual phase sheet steel of 980MPa grades of hot rolling and preparation method thereof |
CN112718859A (en) * | 2021-01-22 | 2021-04-30 | 山西太钢不锈钢股份有限公司 | Hot continuous rolling method for super duplex stainless steel coiled plate |
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CN110257725A (en) * | 2019-07-30 | 2019-09-20 | 马鞍山钢铁股份有限公司 | A kind of high-strength dual phase sheet steel of 980MPa grades of hot rolling and preparation method thereof |
CN112718859A (en) * | 2021-01-22 | 2021-04-30 | 山西太钢不锈钢股份有限公司 | Hot continuous rolling method for super duplex stainless steel coiled plate |
CN113025896A (en) * | 2021-02-24 | 2021-06-25 | 张家港荣盛特钢有限公司 | Bainite type 700 MPa-grade hot-rolled high-strength coiled screw and production method thereof |
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