Magnetic-coagulation precipitates method for purifying water and device
Technical field
The present invention relates to water purification technology field, espespecially a kind of magnetic-coagulation precipitation method for purifying water and device.
Background technology
Often containing the material such as suspension, colloid in waste water, to be up to state standards, professional standard or provincial standard, need by
The slightly solubility material such as suspension, colloid in waste water is separated, so as to reach the purification of water quality.
Coagulating sedimentation is conventional solid-liquid separation technique, into water add flocculant, flocculation aid by the suspension in waste water,
Coacervation of colloid precipitates into the larger flco of particle diameter, flco in sedimentation basin, so as to reach the purpose of purification of water quality.
It is the shortcomings that coagulating sedimentation at present:1st, flocculant chemical feeding quantity is big, and operating cost is high;2nd, floc settling velocity is slow, accounts for
Ground area is big.
The content of the invention
It is an object of the invention to provide a kind of magnetic-coagulation precipitation method for purifying water and device, its technical process is to thin
Bacterium, virus, oil and a variety of fine particles have good suction-operated, will than traditional handicraft to the removal effect of the pollutant
It is good, simultaneously because the performance of its high speed pellets, makes it compared with traditional handicraft, have that speed is fast, efficiency high, purifier take up an area
Area is small, investment is small, advantages of simple structure and simple.
To achieve these goals, technical solution of the invention is:A kind of magnetic-coagulation precipitates method for purifying water, its
Comprise the following steps:
(1) dosing coagulant into coagulation reaction tank, the waste water in coagulation reaction tank is made fully to be reacted with coagulant;
(2) mixed liquor for the abundant reaction that step (1) obtains is entered magnetic-coagulation reaction tank, backward magnetic-coagulation reaction tank
Magnetic is inside added, waste water is fully reacted with magnetic;
(3) the magnetic mixed liquor for the abundant reaction that step (2) obtains is entered flocculation tank, backward flocculation tank in
Flocculation aid is added, it is combined into one with waste water flocculating;
(4) mixed liquor after the completion of step (3) coagulating is precipitated into sedimentation basin, water up to standard after precipitation
Outer row or advanced treating, sediment is reclaimed, emission treatment.
Magnetic-coagulation of the present invention precipitates method for purifying water, wherein dosing coagulant in every liter of waste water in the step (1)
Measure as 25-100 milligrams, the sufficient reaction time of waste water and the coagulant is 15-30 minutes.
Magnetic-coagulation of the present invention precipitates method for purifying water, wherein the magnetic amount added in the step (2) in every liter of waste water
For 25-50 milligrams, the sufficient reaction time of waste water and the magnetic is 5-10 minutes.
Magnetic-coagulation of the present invention precipitates method for purifying water, wherein adding flocculation aid in every liter of waste water in the step (3)
Measure as 2-5 milligrams, the sufficient reaction time of waste water and the flocculation aid is 15-30 minutes.
Magnetic-coagulation of the present invention precipitates method for purifying water, wherein the sediment in the step (4) is evacuated to by sludge pump
Magnetic powder recovering device and magnetic throwing device recycling, the sludge in sediment are evacuated to sludge treating system through sludge pump and entered
Row processing.
A kind of magnetic-coagulation precipitates quality purifying device for water, including be sequentially connected coagulation reaction tank, magnetic-coagulation reaction tank,
Flocculation tank and sedimentation basin, pass through respectively between the coagulation reaction tank, magnetic-coagulation reaction tank, flocculation tank and sedimentation basin
The through hole that is set on adjacent wall and connect, the coagulation reaction tank is connected by the first pipeline with coagulant dosage device, described
Coagulation reaction tank is connected by the second pipeline with waste water, and the magnetic-coagulation reaction tank is connected by the 3rd pipeline and magnetic throwing device
Logical, the flocculation tank is connected by the 4th pipeline with flocculation aid throwing device, and the top of the sedimentation basin is with being used for outer row
The 5th pipeline connection, the bottom of the sedimentation basin passes through the 6th pipeline and recycling mechanism connection.
Magnetic-coagulation of the present invention precipitates quality purifying device for water, wherein the recycling mechanism includes connecting with the 6th pipeline
Logical sludge pump, the sludge pump are connected by the 7th pipeline with magnetic powder recovering device, and the magnetic powder recovering device passes through the 8th
Pipeline connects with sludge treating system.
Magnetic-coagulation of the present invention precipitates quality purifying device for water, wherein the magnetic powder recovering device passes through the 9th pipeline and the magnetic
Powder throwing device connects.
Magnetic-coagulation of the present invention precipitates quality purifying device for water, wherein the coagulation reaction tank, magnetic-coagulation reaction tank and flocculation are anti-
The first mixer, the second mixer and the 3rd mixer are separately installed with Ying Chi.
Magnetic-coagulation of the present invention precipitates quality purifying device for water, wherein the sedimentation basin is fixed on the ground by support.
After such scheme, magnetic-coagulation precipitation method for purifying water and device of the present invention have the advantages that:
1st, magnetic-coagulation precipitation method for purifying water of the present invention utilizes the mechanism of action of magnetic flocculation:The formation of Magnetic composite flocs with not
The forming process of Magnetic composite flocs is the same, is all completed in the presence of coagulant, and the test result of the current potential of magnetic is shown,
Magnetic surface is in elecrtonegativity (=- 10.5mv), it is possible thereby to infer, the formation experience of the floc sedimentation containing magnetic is as follows:Coagulant water first
Cation caused by solution is gathered in around negatively charged colloidal solid and magnetic powder particle due to absorption charge neutrality effect;Then
Due to the disappearance of electrostatic repulsion, grown up between colloidal solid and magnetic powder particle and by Van der Waals force between their own:
Further agglomerate is flocculated into big floc sedimentation finally by the bridging action of flocculant and precipitated, it can be seen that, there is magnetic participation
The flocculation reaction that is participated in no magnetic of magnetic flocculation reaction there is no an essential distinction, magnetic and other trickle suspended particulates one
Sample, the mechanism of action of coagulant equally work to it, and existing coagulation theory equally has directive significance to magnetic flocculation reaction,
All enhanced coagulation measures will all promote the progress of magnetic flocculation reaction, when sewage enters coagulation reaction tank, be firstly added flocculation
Agent, the coagulation of materials such as suspension in sewage, colloid are made to add small flco phase inter coagulation, absorption after flocculation aid, magnetic into small flco
Flco close, that particle diameter is big is formed, sedimentation basin is entered after the completion of coagulating, flco carries out gravitational settling, wadding in sedimentation basin
Body is deposited in the bucket at sedimentation basin bottom, is discharged by sludge pump, and so as to which water quality is purified, the sludge of discharge returns into magnetic
Receiving apparatus, magnetic throwing device is discharged into after magnetic recovery, sludge is discharged into sludge treating system, so as to reach magnetic recovery, reduces
Operating cost;
2nd, magnetic-coagulation of the present invention precipitation quality purifying device for water is simple in construction, operate with speed is fast, efficiency high, occupation of land
The advantages that area is small, investment is small.
Brief description of the drawings
Fig. 1 is the structural representation of magnetic-coagulation precipitation quality purifying device for water of the present invention.
Below in conjunction with the accompanying drawings, by embodiment, the present invention is described further;
Embodiment
As shown in figure 1, magnetic-coagulation precipitation quality purifying device for water of the present invention, including the coagulating being sequentially connected from left to right
Between pond 1, magnetic-coagulation reaction tank 2, flocculation tank 3 and sedimentation basin 14, wherein coagulation reaction tank 1 and magnetic-coagulation reaction tank 2, magnetic
Between coagulation reaction tank 2 and flocculation tank 3, between flocculation tank 3 and sedimentation basin 14 respectively by being set on adjacent wall
Through hole and connect (not shown).The upper end of coagulation reaction tank 1 is connected by the first pipeline 4 with coagulant dosage device 5, is mixed
The bottom of solidifying reaction tank 1 is connected by the second pipeline 6 with waste water 23, and the upper end of magnetic-coagulation reaction tank 2 passes through the 3rd pipeline 7 and magnetic
Powder throwing device 8 is connected, and the upper end of flocculation tank 3 is connected by the 4th pipeline 9 with flocculation aid throwing device 10, and coagulation
Be separately installed with reaction tank 1, magnetic-coagulation reaction tank 2 and flocculation tank 3 by motor control the first mixer 11, second stir
The mixer 13 of machine 12 and the 3rd is mixed, the first mixer 11, the second mixer 12 and the 3rd mixer 13 are respectively to coagulation reaction tank
1st, the mixing liquid in magnetic-coagulation reaction tank 2 and flocculation tank 3 is stirred, and makes to react abundant in each pond respectively.Sedimentation basin
14 are fixed on the ground by support 24, and the top of sedimentation basin 14 connects with the 5th pipeline 15 for outer row, the 5th pipeline 15
Advanced treating will be arranged or carried out outside water quality up to standard after purification.The bottom of sedimentation basin 14 passes through the 6th pipeline 16 and recycling machine
Structure connects.Recycling mechanism includes the sludge pump 17 connected with the 6th pipeline 16, and sludge pump 17 passes through the 7th pipeline 18 and magnetic
Powder reclaiming device 19 is connected, and magnetic powder recovering device 19 is connected by the 8th pipeline 20 with sludge treating system 21.Magnetic recovery dress
19 are put to connect with magnetic throwing device 8 by the 9th pipeline 22.
Purification of water quality is precipitated by above-mentioned magnetic-coagulation, magnetic-coagulation precipitation method for purifying water of the present invention comprises the following steps:
(1) dosing coagulant into coagulation reaction tank 1, thrown by the amount of dosing coagulant in every liter of waste water for 25-100 milligrams
Add, the waste water in coagulation reaction tank 1 is fully reacted with coagulant, sufficient reaction time is 15-30 minutes;
(2) gate between coagulation reaction tank 1 and magnetic-coagulation reaction tank 2 is opened, makes the abundant reaction that step (1) obtains
Mixed liquor enters magnetic-coagulation reaction tank 2, backward magnetic-coagulation reaction tank 2 in add magnetic, by the magnetic added in every liter of waste water
Measure and added for 25-50 milligrams, waste water is fully reacted with magnetic, sufficient reaction time is 5-10 minutes;
(3) gate between magnetic-coagulation reaction tank 2 and flocculation tank 3 is opened, makes the abundant reaction that step (2) obtains
Magnetic mixed liquor enter flocculation tank 3 in, backward flocculation tank 3 in add flocculation aid, by added in every liter of waste water help it is solidifying
The amount of agent is that 2-5 milligrams add, and the sufficient reaction time of waste water and the flocculation aid is 15-30 minutes, makes itself and waste water flocculating
It is combined into one;
(4) mixed liquor in the step (3) after the completion of coagulating is precipitated into sedimentation basin, up to standard after precipitation
Row or advanced treating outside water, sediment is extracted into magnetic powder recovering device 19 by sludge pump 17 and carries out recycling, and finally send
It is continuing with magnetic throwing device 8, the sludge in sediment is pumped at sludge treating system 21 through sludge pump 17
Reason.
Magnetic-coagulation precipitation method for purifying water of the present invention utilizes the mechanism of action of magnetic flocculation:The formation of Magnetic composite flocs is with being free of
The forming process of magnetic flco is the same, is all completed in the presence of coagulant, the test result of the current potential of magnetic is shown, magnetic
Powder surface is in elecrtonegativity (=- 10.5mv), it is possible thereby to infer, the formation experience of the floc sedimentation containing magnetic is as follows:Coagulant hydrolyzes first
Caused cation is gathered in around negatively charged colloidal solid and magnetic powder particle due to absorption charge neutrality effect;Then by
In the disappearance of electrostatic repulsion, grown up between colloidal solid and magnetic powder particle and by Van der Waals force between their own:Most
Further agglomerate is flocculated afterwards by the bridging action of flocculant into big floc sedimentation to precipitate, it can be seen that, have what magnetic participated in
Magnetic flocculation, which reacts the flocculation reaction participated in no magnetic, does not have an essential distinction, magnetic with as the trickle suspended particulates of others,
The mechanism of action of coagulant equally works to it, and existing coagulation theory equally has directive significance, institute to magnetic flocculation reaction
Some enhanced coagulation measures will all promote the progress of magnetic flocculation reaction, when sewage enters coagulation reaction tank 1, be firstly added flocculation
Agent, the coagulation of materials such as suspension in sewage, colloid are made to add small flco phase inter coagulation, absorption after flocculation aid, magnetic into small flco
Flco close, that particle diameter is big is formed, sedimentation basin 14 is entered after the completion of coagulating, flco carries out gravity in sedimentation basin 14 and sunk
Drop, flco are deposited in the bucket at the bottom of sedimentation basin 14, discharged by sludge pump 17, so as to which water quality is purified, the sludge of discharge
Into magnetic powder recovering device 19, it is discharged into magnetic throwing device 8 and is continuing with after magnetic recovery, sludge is discharged into sludge treating system
21, so as to reach magnetic recovery, reduce operating cost;Magnetic-coagulation precipitation quality purifying device for water of the present invention is simple in construction, operates
To have the advantages that fast speed, efficiency high, floor space is small, investment is small.
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the scope of the present invention
It is defined, on the premise of design spirit of the present invention is not departed from, technology of this area ordinary skill technical staff to the present invention
The various modifications and improvement that scheme is made, it all should fall into the protection domain of claims of the present invention determination.