CN107653084A - The liquid detergent of the aliphatic acid of the production containing useful swill oil - Google Patents

The liquid detergent of the aliphatic acid of the production containing useful swill oil Download PDF

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Publication number
CN107653084A
CN107653084A CN201711097541.0A CN201711097541A CN107653084A CN 107653084 A CN107653084 A CN 107653084A CN 201711097541 A CN201711097541 A CN 201711097541A CN 107653084 A CN107653084 A CN 107653084A
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CN
China
Prior art keywords
parts
concentration
liquid detergent
acid
containing useful
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711097541.0A
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Chinese (zh)
Inventor
杨宝玉
杨解定
张永恒
王粉妮
阴国富
杨宝新
王健
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Individual
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Individual
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Priority to CN201711097541.0A priority Critical patent/CN107653084A/en
Publication of CN107653084A publication Critical patent/CN107653084A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The liquid detergent of the aliphatic acid of the production containing useful swill oil, by mass percentage, including following components:Refined fat acid;Deionized water;The sulfonic acid of concentration 96%;The HES of concentration 30%;The 6501 of concentration 90%;Preservative;Thickener;Edible salt;Essence;The caustic soda of concentration 30%;With the characteristics of not stratified, no suspended substance or precipitation, stability is good.

Description

The liquid detergent of the aliphatic acid of the production containing useful swill oil
Technical field
The invention belongs to liquid detergent technical field, and in particular to the liquid detergent of the aliphatic acid of the production containing useful swill oil.
Background technology
Traditional liquid detergent essence collocation method contains phosphate, hinders hand during cleaning, pollutes environment, phosphorous liquid detergent is with phosphoric acid For salt as main auxiliary agent, phosphate is a kind of high-efficiency builder for detergent, while is also the growth regulator of algae, the phosphorus content rise in water, Water quality tends to eutrophication, can cause various algae.Phenomena such as pasture and water largely grow, and water hypoxia can make fish death.At present, Having 30-40% water body in the world, there is eutrophication to some extent.Statistics is asked according to relevant portion, at present China's articles for washing Only the annual consumption of liquid detergent one is just at 3,000,000 tons or so.If 15% meter will be connect into phosphatic average content in washing powder Calculate, just have more than 500,000 tons of phosphorus-containing compounds every year and be discharged into surface water, and 1 gram of phosphorus can make 100 grams of algal grown, environmental protection Scientific research department asks that survey data is shown, because phosphorous excessive, China lake and urban water system are nearly all in eutrophic state, water quality Severe exacerbation, many places can not be drunk at all.
Only several non-phosphate liquid laundry detergents, its price are significantly larger than phosphorous liquid detergent in the market.Buy without phosphorus Liquid detergent needs pay this extra 30%-50% expense, and the general public and the effect for not knowing about without phosphorus certainly clothing powder, therefore big Push and extensively acquire a certain degree of difficulty.
In addition, powdered active matter foam is few, secondary foaming is poor, foam is few.
As the miscellaneous dining establishment such as the fast development of social economy, hotel expands day by day, quantity is rapidly Increase, waste water yield also increase therewith, and containing more floating object, suspension in most of oil-polluted waters, some is even Also containing impurity such as substantial amounts of silt, remaining foods, waste water is directly discharged into sewer, not only pollutes surrounding environment, and In the winter time because grease solidification often results in sewer blockage, sewage overflows, not only pollutes production, living environment, and Add unnecessary dredging to pay wages, the pollutant in its waste water includes COD COD, BOD, SS animals and plants and detergent Deng.Particularly vegetable and animals oils bring puzzlement to be come into the market with " waste oil " without thread in society and seriously endanger people to sewage disposal Physical and mental health, cause the secondary pollution of catering trade.
If swill oil can be used to manufacture liquid detergent, swill oil can be made to become Fei Weibao, waste resource is realized and recycle, Reach the purpose of clean manufacturing and recycling economy.
The content of the invention
To overcome above-mentioned the deficiencies in the prior art, it is an object of the invention to provide the aliphatic acid produced containing useful swill oil Liquid detergent, there is not stratified, no suspended substance or precipitation, the characteristics of stability is good.
To achieve the above object, the technical solution adopted by the present invention is:1st, the aliphatic acid of the production containing useful swill oil is washed Clean essence, by mass percentage, including following components:
Refined fat acid 4%;
Deionized water 73.7%;
The sulfonic acid 7% of concentration 96%;
The HES 4.8% of concentration 30%;
The 6501 2% of concentration 90%;
Preservative 0.1%;
Thickener 2%;
Edible salt 1.5%;
Essence 0.1%;
The caustic soda 4.8% of concentration 30%.
The liquid detergent of the aliphatic acid of the production containing useful swill oil, by mass fraction, including following components:
Refined fat acid 2-6 parts;
Deionized water 70-80 parts;
Sulfonic acid 4-11 parts of concentration 96%;
HES 2-8 parts of concentration 30%;
6501 1-3 parts of concentration 90%;
Preservative 0.05-0.15 parts;
Thickener 1.5-2 parts;
Edible salt 1-2 parts;
Essence 0.05-0.15 parts;
Caustic soda 2-8 parts of concentration 30%.
The beneficial effects of the invention are as follows:
Through examining, liquid detergent of the invention is not stratified, no suspended substance(Add except the product of even suspension grain fraction)Or Precipitation;Uniform liquid without mechanical admixture;Without other peculiar smell;Active matter content >=27%;Total phosphorus pentoxide≤0.4%;PH value (25 DEG C, 1% solution)For 6.8;Stability is heat-resisting:40 ± 1 DEG C holding 24h, after recovering to room temperature with no significant difference before experiment; Stability resists cold:- 5 DEG C~-10 DEG C holding 24h, after recovering to room temperature compared with before experiment, without obvious Traits change.
Embodiment
The present invention is described in further detail with reference to embodiment.
Embodiment 1:
The liquid detergent of the aliphatic acid of the production containing useful swill oil, by mass percentage, including following components:
Refined fat acid 4%;
Deionized water 73.7%;
The sulfonic acid 7% of concentration 96%;
The HES 4.8% of concentration 30%;
The 6501 2% of concentration 90%;
Preservative 0.1%;
Thickener 2%;
Edible salt 1.5%;
Essence 0.1%;
The caustic soda 4.8% of concentration 30%.
Through examining, the liquid detergent of the present embodiment is not stratified, no suspended substance(The product for adding even suspension grain fraction removes Outside)Or precipitation;Uniform liquid without mechanical admixture;Without other peculiar smell;Active matter content >=27%;Total phosphorus pentoxide≤0.4%; PH value(25 DEG C, 1% solution)For 6.8;Stability is heat-resisting:40 ± 1 DEG C of holding 24h are obvious poor with nothing before experiment after recovering to room temperature It is different;Stability resists cold:- 5 DEG C~-10 DEG C holding 24h, after recovering to room temperature compared with before experiment, without obvious Traits change.
Embodiment 2:
The liquid detergent of the aliphatic acid of the production containing useful swill oil, by mass fraction, including following components, 2 parts of refined fat acid;
70 parts of deionized water;
4 parts of the sulfonic acid of concentration 96%;
2 parts of the HES of concentration 30%;
6,501 1 parts of concentration 90%;
0.05 part of preservative;
1.5 parts of thickener;
1 part of edible salt;
0.05 part of essence;
2 parts of the caustic soda of concentration 30%.
Through examining, the liquid detergent of the present embodiment is not stratified, no suspended substance(The product for adding even suspension grain fraction removes Outside)Or precipitation;Uniform liquid without mechanical admixture;Without other peculiar smell;Active matter content >=27%;Total phosphorus pentoxide≤0.4%; PH value(25 DEG C, 1% solution)For 6.8;Stability is heat-resisting:40 ± 1 DEG C of holding 24h are obvious poor with nothing before experiment after recovering to room temperature It is different;Stability resists cold:- 5 DEG C~-10 DEG C holding 24h, after recovering to room temperature compared with before experiment, without obvious Traits change.
Embodiment 3:
The liquid detergent of the aliphatic acid of the production containing useful swill oil, by mass fraction, including following components:
4 parts of refined fat acid;
73.7 parts of deionized water;
7 parts of the sulfonic acid of concentration 96%;
4.8 parts of the HES of concentration 30%;
6,501 2 parts of concentration 90%;
0.1 part of preservative;
2 parts of thickener;
1.5 parts of edible salt;
0.1 part of essence;
4.8 parts of the caustic soda of concentration 30%.
Through examining, the liquid detergent of the present embodiment is not stratified, no suspended substance(The product for adding even suspension grain fraction removes Outside)Or precipitation;Uniform liquid without mechanical admixture;Without other peculiar smell;Active matter content >=27%;Total phosphorus pentoxide≤0.4%; PH value(25 DEG C, 1% solution)For 6.8;Stability is heat-resisting:40 ± 1 DEG C of holding 24h are obvious poor with nothing before experiment after recovering to room temperature It is different;Stability resists cold:- 5 DEG C~-10 DEG C holding 24h, after recovering to room temperature compared with before experiment, without obvious Traits change.
Embodiment 4:
The liquid detergent of the aliphatic acid of the production containing useful swill oil, by mass fraction,
6 parts of refined fat acid;
80 parts of deionized water;
11 parts of the sulfonic acid of concentration 96%;
HES8 parts of concentration 30%;
6,501 3 parts of concentration 90%;
0.15 part of preservative;
2.5 parts of thickener;
2 parts of edible salt;
0.15 part of essence;
8 parts of the caustic soda of concentration 30%.
Through examining, the liquid detergent of the present embodiment is not stratified, no suspended substance(The product for adding even suspension grain fraction removes Outside)Or precipitation;Uniform liquid without mechanical admixture;Without other peculiar smell;Active matter content >=27%;Total phosphorus pentoxide≤0.4%; PH value(25 DEG C, 1% solution)For 6.8;Stability is heat-resisting:40 ± 1 DEG C of holding 24h are obvious poor with nothing before experiment after recovering to room temperature It is different;Stability resists cold:- 5 DEG C~-10 DEG C holding 24h, after recovering to room temperature compared with before experiment, without obvious Traits change.

Claims (5)

1. the liquid detergent of the aliphatic acid of the production containing useful swill oil, by mass percentage, including following components:
Refined fat acid 4%;
Deionized water 73.7%;
The sulfonic acid 7% of concentration 96%;
The HES 4.8% of concentration 30%;
The 6501 2% of concentration 90%;
Preservative 0.1%;
Thickener 2%;
Edible salt 1.5%;
Essence 0.1%;
The caustic soda 4.8% of concentration 30%.
2. the liquid detergent of the aliphatic acid of the production containing useful swill oil, by mass fraction, including following components:
Refined fat acid 2-6 parts;
Deionized water 70-80 parts;
Sulfonic acid 4-11 parts of concentration 96%;
HES 2-8 parts of concentration 30%;
6501 1-3 parts of concentration 90%;
Preservative 0.05-0.15 parts;
Thickener 1.5-2 parts;
Edible salt 1-2 parts;
Essence 0.05-0.15 parts;
Caustic soda 2-8 parts of concentration 30%.
3. the liquid detergent of the aliphatic acid of the production according to claim 2 containing useful swill oil, by mass fraction, its feature exists In the liquid detergent of the aliphatic acid of the production containing useful swill oil, by mass fraction, including following components:
2 parts of refined fat acid;
70 parts of deionized water;
4 parts of the sulfonic acid of concentration 96%;
2 parts of the HES of concentration 30%;
6,501 1 parts of concentration 90%;
0.05 part of preservative;
1.5 parts of thickener;
1 part of edible salt;
0.05 part of essence;
2 parts of the caustic soda of concentration 30%.
4. the liquid detergent of the aliphatic acid of the production according to claim 2 containing useful swill oil, by mass fraction, its feature exists In,
4 parts of refined fat acid;
73.7 parts of deionized water;
7 parts of the sulfonic acid of concentration 96%;
4.8 parts of the HES of concentration 30%;
6,501 2 parts of concentration 90%;
0.1 part of preservative;
2 parts of thickener;
1.5 parts of edible salt;
0.1 part of essence;
4.8 parts of the caustic soda of concentration 30%.
5. the liquid detergent of the aliphatic acid of the production according to claim 2 containing useful swill oil, by mass fraction, its feature exists In,
6 parts of refined fat acid;
80 parts of deionized water;
11 parts of the sulfonic acid of concentration 96%;
HES8 parts of concentration 30%;
6,501 3 parts of concentration 90%;
0.15 part of preservative;
2.5 parts of thickener;
2 parts of edible salt;
0.15 part of essence;
8 parts of the caustic soda of concentration 30%.
CN201711097541.0A 2017-11-09 2017-11-09 The liquid detergent of the aliphatic acid of the production containing useful swill oil Pending CN107653084A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711097541.0A CN107653084A (en) 2017-11-09 2017-11-09 The liquid detergent of the aliphatic acid of the production containing useful swill oil

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Application Number Priority Date Filing Date Title
CN201711097541.0A CN107653084A (en) 2017-11-09 2017-11-09 The liquid detergent of the aliphatic acid of the production containing useful swill oil

Publications (1)

Publication Number Publication Date
CN107653084A true CN107653084A (en) 2018-02-02

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112195070A (en) * 2020-11-23 2021-01-08 上海变宝科技有限公司 Kitchen swill oil soap powder and manufacturing method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445771A (en) * 2008-12-20 2009-06-03 汕头市大千高新科技研究中心有限公司 Fancy soap applicable for face-cleaning and bath
CN102796632A (en) * 2012-07-27 2012-11-28 启东润泽机床附件有限公司 High-efficient deoiling detergent
CN103484264A (en) * 2013-09-25 2014-01-01 周元材 High concentrated paste-shaped detergent
CN103497849A (en) * 2013-10-23 2014-01-08 杨解定 Detergent containing fatty acid
CN103525595A (en) * 2013-10-23 2014-01-22 杨解定 Fatty acid-containing soap powder

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101445771A (en) * 2008-12-20 2009-06-03 汕头市大千高新科技研究中心有限公司 Fancy soap applicable for face-cleaning and bath
CN102796632A (en) * 2012-07-27 2012-11-28 启东润泽机床附件有限公司 High-efficient deoiling detergent
CN103484264A (en) * 2013-09-25 2014-01-01 周元材 High concentrated paste-shaped detergent
CN103497849A (en) * 2013-10-23 2014-01-08 杨解定 Detergent containing fatty acid
CN103525595A (en) * 2013-10-23 2014-01-22 杨解定 Fatty acid-containing soap powder

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112195070A (en) * 2020-11-23 2021-01-08 上海变宝科技有限公司 Kitchen swill oil soap powder and manufacturing method thereof

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Application publication date: 20180202

RJ01 Rejection of invention patent application after publication