CN107640829A - A kind of composition for purifying giant salamander water - Google Patents

A kind of composition for purifying giant salamander water Download PDF

Info

Publication number
CN107640829A
CN107640829A CN201710784903.7A CN201710784903A CN107640829A CN 107640829 A CN107640829 A CN 107640829A CN 201710784903 A CN201710784903 A CN 201710784903A CN 107640829 A CN107640829 A CN 107640829A
Authority
CN
China
Prior art keywords
water
parts
composition
giant salamander
modified zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710784903.7A
Other languages
Chinese (zh)
Inventor
陈秀安
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Xiu An Ecological Agriculture Co Ltd
Original Assignee
Anhui Xiu An Ecological Agriculture Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Xiu An Ecological Agriculture Co Ltd filed Critical Anhui Xiu An Ecological Agriculture Co Ltd
Priority to CN201710784903.7A priority Critical patent/CN107640829A/en
Publication of CN107640829A publication Critical patent/CN107640829A/en
Withdrawn legal-status Critical Current

Links

Abstract

The invention discloses a kind of composition for purifying giant salamander water, its raw material includes by weight:10 12 parts of EM bacterium powders, 30 50 parts of adsorbent, 68 parts of complex enzyme, 8 10 parts of calper calcium peroxide, 8 12 parts of calcium dihydrogen phosphate, 8 12 parts of chitosan;Wherein, the raw material of adsorbent includes:Modified zeolite, activated carbon, alum.The present invention can largely adsorb harmful substance and impurity, and concentrated and targetedly decompose removing toxic substances, greatly increase the effect to purify water, the clean-up effect of long period is maintained, and combines improvement microorganisms in water environment, increases water body its purification performance, increase oxygen content of water, improve water body pH, cooperate from many aspects, reach good clean-up effect.

Description

A kind of composition for purifying giant salamander water
Technical field
The present invention relates to water purification technology field, more particularly to a kind of composition for purifying giant salamander water.
Background technology
The clean fearness of giant salamander happiness is dirty, and very strict to local environment water quality requirement, if water quality is bad, the giant salamander is liable to illness. At present, giant salamander breeding water is purified usually through addition adsorbent, but adsorbent can only adsorb harmful substance and impurity, and It can not be decomposed, for a long time using adsorbent so that the effects of purification quality of adsorbent reduces, or even failure.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of composition for purifying giant salamander water, this Invention can largely adsorb harmful substance and impurity, and concentrated and targetedly decompose removing toxic substances, greatly increase the effect to purify water Fruit, the clean-up effect of long period is maintained, and combine improvement microorganisms in water environment, increase water body its purification performance, increase Oxygen content of water, improve water body pH, cooperate from many aspects, reach good clean-up effect.
A kind of composition for purifying giant salamander water proposed by the present invention, its raw material include by weight:EM bacterium powders 10-12 Part, adsorbent 30-50 parts, complex enzyme 6-8 parts, calper calcium peroxide 8-10 parts, calcium dihydrogen phosphate 8-12 parts, chitosan 8-12 parts;
Wherein, the raw material of adsorbent includes:Modified zeolite, activated carbon, alum.
Preferably, in the preparation process of modified zeolite, zeolite is added in the ethoxy solution of silane of γ-aminopropyl three, risen Temperature, with 300-400r/min speed insulated and stirred 8-10h, filters to take filter cake to 70-80 DEG C, washes, is dried to obtain intermediate; Intermediate is added in graphene oxide water solution, 70-80 DEG C is warming up to, insulated and stirred 4-6h, filters to take filter cake, is washed, is done It is dry, it is crushed to 100-120 mesh and obtains modified zeolite.
Preferably, in the preparation process of modified zeolite, the mass fraction of the ethoxy solution of silane of γ-aminopropyl three is 1- 3wt%, its solvent are ethanol and aqueous mixtures, wherein, the volume ratio of second alcohol and water is 1-2:8-9.
Preferably, in the preparation process of modified zeolite, the mass fraction of graphene oxide water solution is 0.5- 0.7wt%.
Preferably, in the preparation process of modified zeolite, the weight ratio of zeolite and the ethoxy silane of γ-aminopropyl three is 10: 0.4-0.6。
Preferably, in the preparation process of modified zeolite, the weight ratio of intermediate and graphene oxide is 10:0.2-0.4.
Preferably, complex enzyme is oxidoreducing enzyme and pectase.
Preferably, modified zeolite, activated carbon, the weight ratio of alum are 5-7:2-3:1-2.
Preferably, the weight of oxidoreducing enzyme and pectase ratio is 1-2:3-5.
Preferably, in the preparation process of the composition of purification giant salamander water, modified zeolite is soaked with water, adds EM Bacterium powder, rotating granulation, dry, then mixed with activated carbon, alum, add complex enzyme, calper calcium peroxide, calcium dihydrogen phosphate, chitosan It is uniformly mixed so as to obtain the composition of purification giant salamander water.
The zeolite that the present invention selects can adsorb ammonia nitrogen and impurity in water, have certain absorption property, but it is adsorbed Performance is simultaneously unstable, and surface grafting processing is carried out to zeolite with the ethoxy silane of γ-aminopropyl three so that zeolite surface grafting is upper A large amount of amino, then be bonded with the hydroxyl on graphene oxide, carboxyl, so as to be grafted graphite oxide in zeolite surface Alkene, so as to considerably increase the absorption property of zeolite;Modified zeolite cooperates with activated carbon, alum, can effectively adsorb water Middle harmful substance and impurity, and modified zeolite is mixed with EM bacterium powders, and a large amount of beneficial bacterias have been adsorbed on zeolite, can be concentrated Decomposition removing toxic substances is carried out to the harmful substance and impurity being adsorbed onto, so as to greatly increase clean-up effect, when extending the purification of the present invention Between;And EM bacterium powders cooperate with oxidoreducing enzyme, pectase, can further promote the decomposition of harmful substance;EM bacteria agent is also The breeding of harmful bacteria can be suppressed, promote the growth of profitable strain, improve microorganisms in water environment, so as to increase water body from Body purifying property;Calper calcium peroxide can increase oxygen content of water, and calcium dihydrogen phosphate can adjust water body pH, make its doll preferably Fish lives;Chitosan and adsorbent cooperate and can further increase the absorption property of the present invention;Pass through above-mentioned each material phase Mutually coordinate so that the present invention can largely adsorb harmful substance and impurity, and concentrated and targetedly decompose removing toxic substances, greatly increase The effect to purify water, the clean-up effect of long period is maintained, and combine improvement microorganisms in water environment, increase water body itself is net Change performance, increase oxygen content of water, improve water body pH, cooperate from many aspects, reach good clean-up effect.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of composition for purifying giant salamander water, its raw material include by weight:11 parts of EM bacterium powders, 40 parts of adsorbent, 7 parts of complex enzyme, 9 parts of calper calcium peroxide, 10 parts of calcium dihydrogen phosphate, 10 parts of chitosan;
Wherein, the raw material of adsorbent includes:Modified zeolite, activated carbon, alum.
Embodiment 2
A kind of composition for purifying giant salamander water, its raw material include by weight:10 parts of EM bacterium powders, 50 parts of adsorbent, 6 parts of complex enzyme, 10 parts of calper calcium peroxide, 8 parts of calcium dihydrogen phosphate, 12 parts of chitosan;
Wherein, the raw material of adsorbent includes:Modified zeolite, activated carbon, alum;
In the preparation process of modified zeolite, it is that the ethoxy silane of 1wt% γ-aminopropyl three is molten that zeolite is added into mass fraction In liquid, 80 DEG C are warming up to, with 300r/min speed insulated and stirred 10h, filters to take filter cake, washes, is dried to obtain intermediate, its In, the weight ratio of zeolite and the ethoxy silane of γ-aminopropyl three is 10:The solvent of the ethoxy solution of silane of 0.4, γ-aminopropyl three is Ethanol and aqueous mixtures, wherein, the volume ratio of second alcohol and water is 1:4;It is that 0.7wt% aoxidizes stone that intermediate is added into mass fraction In black aqueous solution, 70 DEG C are warming up to, insulated and stirred 6h, filters to take filter cake, washed, dry, pulverize to 100 mesh and obtain being modified boiling Stone, wherein, the weight ratio of intermediate and graphene oxide is 10:0.4.
Embodiment 3
A kind of composition for purifying giant salamander water, its raw material include by weight:12 parts of EM bacterium powders, 30 parts of adsorbent, 8 parts of complex enzyme, 8 parts of calper calcium peroxide, 12 parts of calcium dihydrogen phosphate, 8 parts of chitosan;
Wherein, the raw material of adsorbent includes:Modified zeolite, activated carbon, alum, wherein, modified zeolite, activated carbon, alum Weight ratio be 7:2:2;
In the preparation process of modified zeolite, it is that the ethoxy silane of 3wt% γ-aminopropyl three is molten that zeolite is added into mass fraction In liquid, 70 DEG C are warming up to, with 400r/min speed insulated and stirred 8h, filters to take filter cake, washes, is dried to obtain intermediate, its In, the weight ratio of zeolite and the ethoxy silane of γ-aminopropyl three is 10:The solvent of the ethoxy solution of silane of 0.6, γ-aminopropyl three is Ethanol and aqueous mixtures, wherein, the volume ratio of second alcohol and water is 1:9;It is that 0.5wt% aoxidizes stone that intermediate is added into mass fraction In black aqueous solution, 80 DEG C are warming up to, insulated and stirred 4h, filters to take filter cake, washed, dry, pulverize to 120 mesh and obtain being modified boiling Stone, wherein, the weight ratio of intermediate and graphene oxide is 10:0.2;
Complex enzyme is oxidoreducing enzyme and pectase, wherein, the weight ratio of oxidoreducing enzyme and pectase is 2:3.
Embodiment 4
A kind of composition for purifying giant salamander water, its raw material include by weight:10.5 parts of EM bacterium powders, adsorbent 45 Part, 6.5 parts of complex enzyme, 9.5 parts of calper calcium peroxide, 9 parts of calcium dihydrogen phosphate, 11 parts of chitosan;
Wherein, the raw material of adsorbent includes:Modified zeolite, activated carbon, alum, wherein, modified zeolite, activated carbon, alum Weight ratio be 5:3:1;
It is the ethoxy silane of 1.5wt% γ-aminopropyl three by zeolite addition mass fraction in the preparation process of modified zeolite In solution, 78 DEG C are warming up to, with 330r/min speed insulated and stirred 9.5h, filters to take filter cake, washes, is dried to obtain centre Body, wherein, the weight ratio of zeolite and the ethoxy silane of γ-aminopropyl three is 10:The ethoxy solution of silane of 0.45, γ-aminopropyl three Solvent is ethanol and aqueous mixtures, wherein, the volume ratio of second alcohol and water is 1.7:8.3;It is by intermediate addition mass fraction In 0.65wt% graphene oxide water solutions, 72 DEG C are warming up to, insulated and stirred 5.5h, filters to take filter cake, washed, dry, pulverize Modified zeolite is obtained to 100 mesh, wherein, the weight ratio of intermediate and graphene oxide is 10:0.35;
Complex enzyme is oxidoreducing enzyme and pectase, wherein, the weight ratio of oxidoreducing enzyme and pectase is 1:5;
In the preparation process of the composition of purification giant salamander water, modified zeolite is soaked with water, adds EM bacterium powders, rotation Turn to be granulated, dry, then mixed with activated carbon, alum, add complex enzyme, calper calcium peroxide, calcium dihydrogen phosphate, chitosan and be uniformly mixed so as to obtain Purify the composition of giant salamander water.
Embodiment 5
A kind of composition for purifying giant salamander water, its raw material include by weight:11.5 parts of EM bacterium powders, adsorbent 35 Part, 7.5 parts of complex enzyme, 8.5 parts of calper calcium peroxide, 11 parts of calcium dihydrogen phosphate, 9 parts of chitosan;
Wherein, the raw material of adsorbent includes:Modified zeolite, activated carbon, alum, wherein, modified zeolite, activated carbon, alum Weight ratio be 6:2.5:1.5;
It is the ethoxy silane of 2.5wt% γ-aminopropyl three by zeolite addition mass fraction in the preparation process of modified zeolite In solution, 72 DEG C are warming up to, with 370r/min speed insulated and stirred 8.5h, filters to take filter cake, washes, is dried to obtain centre Body, wherein, the weight ratio of zeolite and the ethoxy silane of γ-aminopropyl three is 10:The ethoxy solution of silane of 0.55, γ-aminopropyl three Solvent is ethanol and aqueous mixtures, wherein, the volume ratio of second alcohol and water is 1.3:8.7;It is by intermediate addition mass fraction In 0.55wt% graphene oxide water solutions, 78 DEG C are warming up to, insulated and stirred 4.5h, filters to take filter cake, washed, dry, pulverize Modified zeolite is obtained to 120 mesh, wherein, the weight ratio of intermediate and graphene oxide is 10:0.25;
Complex enzyme is oxidoreducing enzyme and pectase, wherein, the weight ratio of oxidoreducing enzyme and pectase is 1.5:4;
In the preparation process of the composition of purification giant salamander water, modified zeolite is soaked with water, adds EM bacterium powders, rotation Turn to be granulated, dry, then mixed with activated carbon, alum, add complex enzyme, calper calcium peroxide, calcium dihydrogen phosphate, chitosan and be uniformly mixed so as to obtain Purify the composition of giant salamander water.
Test example 1
The water body of the cultivation giant salamander is taken, is divided into 2 parts of weight identical, portion carries out purified treatment using embodiment 5, is designated as Test group;Another carries out purified treatment using alum, is designated as control group, 2 groups of dosages are identical, and water body is examined after 20 days Survey, it is as a result as follows:
Project Test group Control group
Ammonia nitrogen mg/l 0.30 1.25
Cultured water mg/l 0.52 1.38
Hydrogen sulfide mg/l 0.09 0.75
Transparency cm 32 9.2
CODMn mg/l 7.6 15.2
The performance that the present invention purifies water as can be seen from the above table is good.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (10)

1. a kind of composition for purifying giant salamander water, it is characterised in that its raw material includes by weight:EM bacterium powder 10-12 parts, Adsorbent 30-50 parts, complex enzyme 6-8 parts, calper calcium peroxide 8-10 parts, calcium dihydrogen phosphate 8-12 parts, chitosan 8-12 parts;
Wherein, the raw material of adsorbent includes:Modified zeolite, activated carbon, alum.
2. the composition of giant salamander water is purified according to claim 1, it is characterised in that in the preparation process of modified zeolite In, zeolite is added in the ethoxy solution of silane of γ-aminopropyl three, is warming up to 70-80 DEG C, is incubated with 300-400r/min speed 8-10h is stirred, filters to take filter cake, washes, is dried to obtain intermediate;Intermediate is added in graphene oxide water solution, heating To 70-80 DEG C, insulated and stirred 4-6h, filter cake is filtered to take, wash, dry, pulverize to 100-120 mesh and obtain modified zeolite.
3. the composition of giant salamander water is purified according to claim 2, it is characterised in that in the preparation process of modified zeolite In, the mass fraction of the ethoxy solution of silane of γ-aminopropyl three is 1-3wt%, and its solvent is ethanol and aqueous mixtures, wherein, second The volume ratio of alcohol and water is 1-2:8-9.
4. the composition of giant salamander water is purified according to Claims 2 or 3, it is characterised in that in the preparation of modified zeolite During, the mass fraction of graphene oxide water solution is 0.5-0.7wt%.
5. according to the composition of any one of the claim 2-4 purification giant salamander water, it is characterised in that in modified zeolite In preparation process, the weight ratio of zeolite and the ethoxy silane of γ-aminopropyl three is 10:0.4-0.6.
6. according to the composition of any one of the claim 2-5 purification giant salamander water, it is characterised in that in modified zeolite In preparation process, the weight ratio of intermediate and graphene oxide is 10:0.2-0.4.
7. according to the composition of any one of the claim 1-6 purification giant salamander water, it is characterised in that complex enzyme is oxidation Reductase and pectase.
8. according to the composition of any one of the claim 1-7 purification giant salamander water, it is characterised in that modified zeolite, work Property charcoal, the weight ratio of alum are 5-7:2-3:1-2.
9. the composition of giant salamander water is purified according to claim 7, it is characterised in that oxidoreducing enzyme and pectase Weight ratio is 1-2:3-5.
10. according to the composition of any one of the claim 1-9 purification giant salamander water, it is characterised in that in purification doll In the preparation process of the composition of fish water, modified zeolite is soaked with water, add EM bacterium powders, rotating granulation, dry, then with work Property charcoal, alum mix, add complex enzyme, calper calcium peroxide, calcium dihydrogen phosphate, chitosan are uniformly mixed so as to obtain the group of purification giant salamander water Compound.
CN201710784903.7A 2017-09-04 2017-09-04 A kind of composition for purifying giant salamander water Withdrawn CN107640829A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710784903.7A CN107640829A (en) 2017-09-04 2017-09-04 A kind of composition for purifying giant salamander water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710784903.7A CN107640829A (en) 2017-09-04 2017-09-04 A kind of composition for purifying giant salamander water

Publications (1)

Publication Number Publication Date
CN107640829A true CN107640829A (en) 2018-01-30

Family

ID=61111075

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710784903.7A Withdrawn CN107640829A (en) 2017-09-04 2017-09-04 A kind of composition for purifying giant salamander water

Country Status (1)

Country Link
CN (1) CN107640829A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0583658B1 (en) * 1992-08-20 2000-02-23 Biochem Industrial Ltd. A method for improving bottom and water quality in water areas and a set of agents used in the method
CN104671433A (en) * 2015-02-09 2015-06-03 华南理工大学 Compound microbiological oxygenate for removing ammonia nitrogen in aquatic water and preparation method of compound microbiological oxygenate
CN104692542A (en) * 2015-02-09 2015-06-10 华南理工大学 Composite microbial oxygen producer for increasing transparency of aquaculture water and preparation method of composite microbial oxygen producer
CN106362691A (en) * 2016-10-31 2017-02-01 扬州大学 Method for preparing graphene oxide/molecular sieve composite adsorption material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0583658B1 (en) * 1992-08-20 2000-02-23 Biochem Industrial Ltd. A method for improving bottom and water quality in water areas and a set of agents used in the method
CN104671433A (en) * 2015-02-09 2015-06-03 华南理工大学 Compound microbiological oxygenate for removing ammonia nitrogen in aquatic water and preparation method of compound microbiological oxygenate
CN104692542A (en) * 2015-02-09 2015-06-10 华南理工大学 Composite microbial oxygen producer for increasing transparency of aquaculture water and preparation method of composite microbial oxygen producer
CN106362691A (en) * 2016-10-31 2017-02-01 扬州大学 Method for preparing graphene oxide/molecular sieve composite adsorption material

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
付明星: "《淡水养殖动物疾病防治技术》", 30 November 2012, 湖北科学技术出版社 *
冯启明 等: "《非金属矿物加工与开发利用》", 31 December 2010, 地质出版社 *
张光华: "《水处理化学品制备与应用指南》", 31 October 2003, 中国石化出版社 *

Similar Documents

Publication Publication Date Title
Calabi-Floody et al. Smart fertilizers as a strategy for sustainable agriculture
CN102718327B (en) Nano-biological water body remediation agent for aquaculture and preparation method thereof
Cheng et al. Removal of malachite green (MG) from aqueous solutions by native and heat-treated anaerobic granular sludge
Kapoor et al. Fungal biosorption—an alternative treatment option for heavy metal bearing wastewaters: a review
CN103861421B (en) A kind of air purifying preparation
CN102816493B (en) Be rich in the nanometer internal wall environmental protection coating material that silver-colored selenium germanium multielement multifunctinoal health lengthens one's life
CN103936002B (en) A kind of preparation method of water hyacinth biological carbon
CN102268490B (en) Clean technique for co-producing xylose, xylitol and arabinose from agricultural waste and forest waste
CN106422152B (en) Method for removing oxytetracycline in biological medicine waste residues
CN103449680B (en) Method for removing pollutants in sewage
Liu et al. Adsorption of tannin from aqueous solution by deacetylated konjac glucomannan
CN102527347B (en) Magnetic chitosan/cationic surface active agent modified zeolite adsorbent and preparation method and application thereof
CN106116946B (en) Biological organic fertilizer for repairing soil heavy metal and preparation method thereof
CN104803485B (en) A kind of microbial compound enzyme water purification agent granule
CN106492638B (en) A kind of preparation method of nano silver organic frame ultrafiltration membrane and method using its water purification
CN106495874A (en) Combined soil renovation agent and preparation method with compost as raw material
CN103232116B (en) Method for treating heavy-metal wastewater by using biological water purifying agent prepared from cyanobacteria bloom
JP2013539411A (en) Multi-aperture carbon particle air purifier and method for producing the same
CN104230589A (en) Soil improvement biofertilizer and preparation method of soil improvement biofertilizer
CN103205382B (en) Microbial agent for purifying river wastewater and preparation method of microbial agent
CN104209098A (en) Heavy metal adsorbent used in sewage treatment and application of heavy metal adsorbent
CN102344315A (en) Composite microbial seaweed organic liquid fertilizer and preparation method thereof
CN104475038B (en) A kind of automobile environment-friendly type air cleanser and preparation method thereof
CN107282628A (en) A kind of composite modifying agent for repairing farmland pollution soil and preparation method thereof
CN103667392B (en) A kind of preparation method of high purity 95 oligomeric isomaltose

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20180130