CN107638801A - The low emission technique and complexes of pollutant in garbage power generation boiler flue gas - Google Patents

The low emission technique and complexes of pollutant in garbage power generation boiler flue gas Download PDF

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Publication number
CN107638801A
CN107638801A CN201711033296.7A CN201711033296A CN107638801A CN 107638801 A CN107638801 A CN 107638801A CN 201711033296 A CN201711033296 A CN 201711033296A CN 107638801 A CN107638801 A CN 107638801A
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China
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gas
adsorption tanks
flue gas
tank
power generation
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CN201711033296.7A
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Chinese (zh)
Inventor
刘怀平
程晓辉
李玉洋
王磊济
程婷婷
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Jiangsu Zhongke Energy Saving & Environmental Protection Technology Co Ltd
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Jiangsu Zhongke Energy Saving & Environmental Protection Technology Co Ltd
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Priority to CN201711033296.7A priority Critical patent/CN107638801A/en
Publication of CN107638801A publication Critical patent/CN107638801A/en
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Abstract

The invention discloses a kind of garbage power generation boiler flue gas multiple pollutant minimum discharge technique and complexes,Wherein SDA reactors,Sack cleaner,First adsorption tanks,Regenerating tank and gas-liquid separator are sequentially connected,Gas-liquid separator connects respectively neutralizes case and oxidation Decomposition tower,Oxidation Decomposition tower connects the second adsorption tanks,Flue gas enters SDA reactors,Dry method is sprayed,Sack cleaner absorbs substantial amounts of acid,Adsorb the dust in flue gas,Resulting gas enters the first adsorption tanks,Regenerating tank continues to absorb the heavy metal in flue gas,Bioxin and oxidation of NOx,Absorption and regeneration alternate run,Regenerate obtained gas and go out gas and liquid into gas-liquid separator separates,Obtained liquid, which flows into, to be neutralized case and is reacted with the soda or ammoniacal liquor for neutralizing case,Gas enters the absorption of the second adsorption tanks after entering the oxidation of oxidation Decomposition tower,The neat stress for adsorbing to obtain through two-stage is discharged,The gas of second level absorption regeneration turns also to gas-liquid separator and enters secondary oxidation and absorption,Until reaching discharge standard,Meet minimum discharge requirement.

Description

The low emission technique and complexes of pollutant in garbage power generation boiler flue gas
Technical field
The present invention relates to pollutant absorption techniques field, is polluted in particular to a kind of garbage power generation boiler flue gas more Thing minimum discharge technique and complexes.
Background technology
In recent years, the urbanization process in China is accelerated, and city numbers and scale constantly expand, but due to environmental protection basis Build serious hysteresis so that pollution getting worse of the municipal refuse to urban ecological environment.Expect the production of the year two thousand twenty municipal refuse Raw amount will be up to 3.23 hundred million tons, and rubbish processing to be harmless is extremely urgent.The mode that waste incineration is handled in city is mainly at burning Manage, contain CO in tail gas caused by waste incineration2、SO2、NOXDeng, in addition, it can also produce some toxic gases, including Grain thing, bioxin etc..
Garbage power plant smoke temperature is relatively low, complicated component, and difficulty of governance is big, especially the removing of nitrogen oxides, bioxin, Always difficult point, the garbage-incineration smoke purifying handling process that Chinese Ministry of Environmental Protection is recommended at present are:SNCR+ semidry methods+activated carbon+dry method + sack cleaner.By this process combination, discharging standards GB18485-2014 can be reached, but be extremely difficult to European Union Discharge standard 2000/76/EC, the minimum discharge better than European Union Emission standard 2000/76/EC far can not then reach.
The content of the invention
It is contemplated that solves above-mentioned technical problem to a certain extent.
In view of this, the invention provides one kind, this can remove particulate matter, bioxin in flue gas, again to greatest extent Metal and sour gas, meet minimum discharge requirement.
In order to solve the above-mentioned technical problem, the invention provides a kind of garbage power generation boiler flue gas multiple pollutant minimum discharge Technique and complexes, SDA reactors, sack cleaner, the first adsorption tanks, regenerating tank, the first slack tank and gas-liquid separator, Oxidation Decomposition tower, the second adsorption tanks and the second slack tank pass sequentially through pipeline communication, after the separation of the gas-liquid separator Liquid outlet connection neutralizes case, and ozone generator is also connected between the oxidation Decomposition tower and the gas-liquid separator.Further, First adsorption tanks, regenerating tank, the first slack tank, the outlet of the second adsorption tanks and the second slack tank, entrance are set respectively to be cut Only valve, adsorption tanks are in parallel with regenerating tank and/or are arranged in series, alternate run.
Further, first adsorption tanks, regenerating tank, the first slack tank, the second adsorption tanks and the second slack tank adsorption material Expect that there is absorption and oxidative function for polyfunctional group NACF, this NACF.
Further, first adsorption tanks, regenerating tank, the first slack tank, the second adsorption tanks and the connection of the second slack tank are steamed Steam pipe road.
Further, heat exchanger is set between the neutralization case and gas-liquid separator.
Further, the neutralization case connection wastewater treatment equipment.
Further, the equipment for neutralizing case connection soda, ammoniacal liquor or other alkali lye.
Further, first adsorption tanks, regenerating tank, the first slack tank, the second adsorption tanks and the connection of the second slack tank Neat stress pipeline.
The low emission technique of pollutant in a kind of garbage power generation boiler flue gas, based on any one described in claim 1 ~ 7 The low emission device of pollutant is completed in kind garbage power generation boiler flue gas, it is characterised in that as follows including step:
S1:Absorption process, flue gas absorbs substantial amounts of acid by semidry method reactor, by the flue gas of gained and Ca (OH)2Powder, activity Powdered carbon sprays into flue, is passed into sack cleaner dedusting, and the flue gas after dedusting is passed through the suction of polyfunctional group carbon fiber adsorption and catalytic combustion tank Receive heavy metal, bioxin and oxidation of NOx, adsorption tanks absorption regenerates afterwards to a certain extent, and adsorption tanks switch to regenerating tank, absorption and Regenerate alternate run;
S2:Separation process, the gas-liquid mixture of step S1 regeneration gained are passed through gas-liquid separator separates and go out gas and liquid, separate Liquid flow into and neutralize case, and flow into wastewater treatment dress with being added to after the soda neutralized in case, ammoniacal liquor or other alkaline reactions Put;
S3:Oxidizing process is forced, the gas that gas-liquid separation obtains in step S2 sprays into ozone, oxidation Decomposition tower is passed through, in ozone With by the NOX oxidation in gas be NO in the presence of catalyst2, the gas of gained is passed through second level adsorption tanks and absorbs NO2, only Flue gas discharge after change, the operation of second level adsorption tanks switch to regeneration afterwards to a certain extent, and the gas-liquid mixture of regeneration repeats S2 And S3.
Further, lead into first adsorption tanks, regenerating tank, the first slack tank, the second adsorption tanks and the second slack tank Enter steam, adsorption tanks operation to a certain extent when switch to regenerating tank, to tank in add steam, steam is by the absorption of activated carbon Material parsing regeneration, the adsorption capacity of activity recovery charcoal.Adsorption tanks, regenerating tank, slack tank are standby each other, alternate run.
Further, catalyst is set in the oxidation Decomposition tower, and flue gas input ozone will under ozone and catalyst action NOX oxidation is NO2.
The technical effects of the invention are that:The complexes of pollutant, its feature exist in a kind of garbage power generation boiler flue gas In, SDA reactors, sack cleaner, the first adsorption tanks, regenerating tank, the first slack tank and gas-liquid separator, oxidation Decomposition tower, Second adsorption tanks and the second slack tank pass sequentially through pipeline communication, and the liquid outlet connection after the separation of gas-liquid separator neutralizes Case, ozone generator is also connected between oxidation Decomposition tower and gas-liquid separator, device design science, characteristics of compact layout can be long-term Stable operation, there is very strong practicality and widely property on probation.
The low emission technique of pollutant in a kind of garbage power generation boiler flue gas, flue gas enters SDA reactors, dry method is sprayed, Sack cleaner absorbs the dust in substantial amounts of acid gas, bioxin, absorption flue gas, resulting gas enter the first adsorption tanks, Regenerating tank absorb flue gas in heavy metal, bioxin and oxidation of NOx, obtained gas enter gas-liquid separator separates go out gas with Liquid, obtained liquid, which flows into, neutralizes case and the alkaline reaction with neutralizing case, after obtained gas enters the oxidation of oxidation Decomposition tower Adsorbed into the second adsorption tanks, resulting neat stress is discharged, second level regeneration gas returns to gas-liquid separator and is again introduced into Secondary oxidation and absorption, the pollutant in flue gas can be removed to greatest extent, the efficiency high of desulfurization and dedusting, can reach low row The requirement put.
Brief description of the drawings
Fig. 1 is a kind of garbage power generation boiler flue gas multiple pollutant minimum discharge technique and complexes according to the present invention Structural representation.
Wherein, 1- SDA reactors;2- sack cleaners;The adsorption tanks of 3- first;4- regenerating tanks;The slack tanks of 5- first;6- Second adsorption tanks;The slack tanks of 7- second;8- oxidation Decomposition towers;9- gas-liquid separators;In 10- and case;11- heat exchangers;12- waste water Processing unit;13- stop valves;14- neat stress pipelines;15- generates alkali lye equipment;16- jet chimneys;17- ozone generators.
Embodiment
The invention will be further described with specific embodiment below in conjunction with the accompanying drawings, so that those skilled in the art can be with It is better understood from the present invention and can be practiced, but illustrated embodiment is not as a limitation of the invention.
As shown in figure 1, in a kind of garbage power generation boiler flue gas pollutant complexes, SDA reactors 1, bag-type dust Device 2, the first adsorption tanks 3, regenerating tank 4, the first slack tank 5 and gas-liquid separator 9, oxidation Decomposition tower 8, the second adsorption tanks 6 and Second slack tank 7 passes sequentially through pipeline communication, and the liquid outlet connection after the separation of gas-liquid separator 9 neutralizes case 10, oxidation point Ozone generator 17 is also connected between solution tower 8 and gas-liquid separator 9.
According to a particular embodiment of the invention, after semi-dry desulphurization, white lime and active powdered carbon are sprayed into by injection apparatus In the flue for connecting SDA adsorption towers and sack cleaner.
According to a particular embodiment of the invention, sack cleaner sets ash-discharging device, and the dust sucked is drawn off.
First adsorption tanks 3, regenerating tank 4, the first slack tank 5, the outlet of the second adsorption tanks 6 and the second slack tank 7, entrance point Not She Zhi stop valve 13, the first adsorption tanks 3, regenerating tank 4, the first slack tank 5, the second adsorption tanks 6 and the second slack tank 7 connect logical Enter jet chimney 16, neutralize and heat exchanger 11 is set between case 10 and gas-liquid separator 9, neutralize case 10 and connect wastewater treatment equipment 12, neutralize the equipment 15 of the connection generation alkali lye of case 10, the top of the first adsorption tanks 3, the top of regenerating tank 4, the top of the first slack tank 5, The top of second adsorption tanks 6 and the top of the second slack tank 7 connection neat stress pipeline 14.
According to a particular embodiment of the invention, it is acidic liquid to neutralize in case, and soda, ammoniacal liquor or other alkali lye, which flow into, to be neutralized Neutralization reaction occurs in case, recovering liquid temperature is high, and the temperature for neutralizing influent in case is reduced by heat exchanger.
As shown in figure 1, in a kind of garbage power generation boiler flue gas pollutant low emission technique;
S1:Absorption process, flue gas absorbs substantial amounts of acid by semidry method reactor, by the flue gas of gained and Ca (OH)2Powder, activity Powdered carbon sprays into flue, is passed into sack cleaner dedusting, and the flue gas after dedusting is passed through the suction of polyfunctional group carbon fiber adsorption and catalytic combustion tank Receive heavy metal, bioxin and oxidation of NOx, adsorption tanks absorption regenerates afterwards to a certain extent, and adsorption tanks switch to regenerating tank, absorption and Regenerate alternate run.
S2:Separation process, the gas-liquid mixture of step S1 regeneration gained are passed through gas-liquid separator separates and go out gas and liquid, The liquid of separation, which flows into, neutralizes case, and with being flowed into after being added to the soda neutralized in case, ammoniacal liquor or other alkaline reactions at waste water Manage device.
S3:Oxidizing process is forced, the gas that gas-liquid separation obtains in step S2 sprays into ozone, is passed through oxidation Decomposition tower, By the NOX oxidation in gas it is NO in the presence of ozone and catalyst2, the gas of gained is passed through second level adsorption tanks and absorbed NO2, after purification flue gas discharge, the second level adsorption tanks operation switch to regeneration, the gas-liquid mixture of regeneration afterwards to a certain extent Repeat S2 and S3.
Steam is passed through in first adsorption tanks, regenerating tank, the first slack tank, the second adsorption tanks and the second slack tank, steam will The material heating desorption of the absorption of activated carbon, the adsorption capacity of activity recovery charcoal.Adsorption tanks, regenerating tank, slack tank alternate run, It is standby each other.
Catalyst is set in oxidation Decomposition tower, flue gas input ozone, is by NOX oxidation under ozone and catalyst action NO2。
Embodiment described above is only to absolutely prove preferred embodiment that is of the invention and being lifted, protection model of the invention Enclose not limited to this.The equivalent substitute or conversion that those skilled in the art are made on the basis of the present invention, in the present invention Protection domain within.Protection scope of the present invention is defined by claims.

Claims (10)

  1. A kind of 1. complexes of pollutant in garbage power generation boiler flue gas, it is characterised in that SDA reactors, sack cleaner, First adsorption tanks, regenerating tank, the first slack tank and gas-liquid separator, oxidation Decomposition tower, the second adsorption tanks and the second slack tank Pass sequentially through pipeline communication, the connection of liquid outlet after the separation of the gas-liquid separator neutralizes case, the oxidation Decomposition tower and Ozone generator is also connected between the gas-liquid separator.
  2. 2. the complexes of pollutant in garbage power generation boiler flue gas according to claim 1, it is characterised in that described One adsorption tanks, regenerating tank, the first slack tank, the outlet of the second adsorption tanks and the second slack tank, entrance set stop valve respectively, inhale Attached tank is in parallel with regenerating tank and/or is arranged in series, alternate run;First adsorption tanks, regenerating tank, the first slack tank, second Adsorption tanks and the second slack tank sorbing material are polyfunctional group NACF.
  3. 3. the complexes of pollutant in garbage power generation boiler flue gas according to claim 1, it is characterised in that described One adsorption tanks, regenerating tank, the first slack tank, the second adsorption tanks and the second slack tank connection jet chimney.
  4. 4. the complexes of pollutant in garbage power generation boiler flue gas according to claim 1, it is characterised in that in described Heat exchanger is set between case and gas-liquid separator.
  5. 5. the low emission device of pollutant in garbage power generation boiler flue gas according to claim 1, it is characterised in that described Neutralize case connection wastewater treatment equipment.
  6. 6. the complexes of pollutant in garbage power generation boiler flue gas according to claim 1, it is characterised in that in described The equipment that soda, ammoniacal liquor or other alkali lye are connected with case.
  7. 7. the complexes of pollutant in garbage power generation boiler flue gas according to claim 1, it is characterised in that described One adsorption tanks, regenerating tank, the first slack tank, the second adsorption tanks and the second slack tank connection neat stress pipeline.
  8. A kind of 8. low emission technique of pollutant in garbage power generation boiler flue gas, based on any one described in claim 1 ~ 7 The low emission device of pollutant is completed in garbage power generation boiler flue gas, it is characterised in that as follows including step:
    S1:Absorption process, flue gas absorbs substantial amounts of acid by SDA reactors, by the flue gas of gained and Ca (OH)2Powder, active powdered carbon Flue is sprayed into, is passed into sack cleaner dedusting, the flue gas after dedusting is passed through polyfunctional group carbon fiber adsorption and catalytic combustion tank and absorbs weight Metal, bioxin and oxidation of NOx, adsorption tanks absorption regenerate afterwards to a certain extent, and adsorption tanks switch to regenerating tank, absorption and regeneration Alternate run;
    S2:Separation process, the gas-liquid mixture of step S1 regeneration gained are passed through gas-liquid separator separates and go out gas and liquid, separate Liquid flow into neutralize case, and with neutralize case in soda or ammoniacal liquor reaction after flow into wastewater treatment equipment;
    S3:Oxidizing process is forced, the gas that gas-liquid separation obtains in step S2 sprays into ozone, oxidation Decomposition tower is passed through, in ozone With by the NOX oxidation in gas be NO in the presence of catalyst2, the gas of gained is passed through second level adsorption tanks and absorbs NO2, only Flue gas discharge after change, the operation of second level adsorption tanks switch to regeneration afterwards to a certain extent, and the gas-liquid mixture of regeneration repeats S2 And S3.
  9. 9. the low emission technique of pollutant in garbage power generation boiler flue gas according to claim 8, it is characterised in that to institute State and steam is passed through in the first adsorption tanks, regenerating tank, the first slack tank, the second adsorption tanks and the second slack tank, steam is by activated carbon Absorption material heating desorption, the adsorption capacity of activity recovery charcoal, adsorption tanks, regenerating tank, slack tank alternate run are standby each other With.
  10. 10. the low emission technique of pollutant in garbage power generation boiler flue gas according to claim 8, it is characterised in that institute State and catalyst is set in oxidation Decomposition tower, flue gas input ozone, by NO under ozone and catalyst actionxIt is oxidized to NO2
CN201711033296.7A 2017-10-30 2017-10-30 The low emission technique and complexes of pollutant in garbage power generation boiler flue gas Pending CN107638801A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110404343A (en) * 2019-08-30 2019-11-05 华能国际电力股份有限公司 Coal-fired flue gas SO3Aerosol removal system and method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000015058A (en) * 1998-07-02 2000-01-18 Sumitomo Heavy Ind Ltd Treatment apparatus and method for incinerator exhaust gas
CN102895857A (en) * 2012-10-31 2013-01-30 北京国电清新环保技术股份有限公司 Comprehensive waste incineration flue gas purification system and purification method thereof
CN102989302A (en) * 2012-09-12 2013-03-27 河南绿典环保节能科技有限公司 Smoke wet oxidation denitration method
CN205252843U (en) * 2015-12-10 2016-05-25 徐州工程学院 Tail gas denitration absorbing device
CN205988655U (en) * 2015-09-30 2017-03-01 中国石油化工股份有限公司 A kind of caprolactam exhaust gas processing device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000015058A (en) * 1998-07-02 2000-01-18 Sumitomo Heavy Ind Ltd Treatment apparatus and method for incinerator exhaust gas
CN102989302A (en) * 2012-09-12 2013-03-27 河南绿典环保节能科技有限公司 Smoke wet oxidation denitration method
CN102895857A (en) * 2012-10-31 2013-01-30 北京国电清新环保技术股份有限公司 Comprehensive waste incineration flue gas purification system and purification method thereof
CN205988655U (en) * 2015-09-30 2017-03-01 中国石油化工股份有限公司 A kind of caprolactam exhaust gas processing device
CN205252843U (en) * 2015-12-10 2016-05-25 徐州工程学院 Tail gas denitration absorbing device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110404343A (en) * 2019-08-30 2019-11-05 华能国际电力股份有限公司 Coal-fired flue gas SO3Aerosol removal system and method

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