CN107629520A - A kind of coating on metal connecting tube and preparation method thereof - Google Patents

A kind of coating on metal connecting tube and preparation method thereof Download PDF

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Publication number
CN107629520A
CN107629520A CN201710746067.3A CN201710746067A CN107629520A CN 107629520 A CN107629520 A CN 107629520A CN 201710746067 A CN201710746067 A CN 201710746067A CN 107629520 A CN107629520 A CN 107629520A
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CN
China
Prior art keywords
parts
coating
connecting tube
metal connecting
resin
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Pending
Application number
CN201710746067.3A
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Chinese (zh)
Inventor
王诗斌
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Chaohu Pengyuan Metal Pipe Co Ltd
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Chaohu Pengyuan Metal Pipe Co Ltd
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Priority to CN201710746067.3A priority Critical patent/CN107629520A/en
Publication of CN107629520A publication Critical patent/CN107629520A/en
Pending legal-status Critical Current

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Abstract

A kind of coating on metal connecting tube, it is related to tubular object extruding production technical field, it is characterised in that:It is made up of the material of following parts by weight, 15 20 parts of resin, 49 parts of coupling agent, 7 11 parts of modified active powdered carbon, 6 10 parts of defoamer, 13 parts of palm wax emulsion, 13 parts of acrylic acid, 58 parts of dimethylbenzene, 8 12 parts of trimethylolpropane trimethacrylate, 13 parts of zinc dialkyl dithiophosphate, 13 parts of APP, 27 33 parts of clear water.The inventive method is reasonable, easy to operate, corrosion-resistant.

Description

A kind of coating on metal connecting tube and preparation method thereof
Technical field
The present invention relates to tubular object extruding production technical field, and in particular to a kind of coating on metal connecting tube and its Preparation method.
Background technology
Welded still pipe is also referred to as welded tube, be with steel plate or strip welded after cans made of steel pipe, general scale 6 Rice.Welded still pipe simple production process, production efficiency is high, and description is more, and equipment investment is few, but common intensity is less than seamless steel Pipe.
Since the 1930s, with quality strip steel rolling production develop rapidly and weld and inspection technology enters Step, weldquality are constantly lifted, and the description of welded still pipe is increasing, and instead of seamless steel in increasing field Pipe.Welded still pipe is divided into ERW and spiral welded pipe by the form of weld seam.Classify by production method:Technique classification-arc welding Pipe, resistance weld pipe, (high frequency, low frequency) gas welded pipe, the continuous furnace welding of tube.
More small-bore welded tube uses straight weld, and heavy caliber welded tube then more uses spiral welding;It is divided into by steel tube end part shape Circular welded tube and special-shaped (side, square type etc.) welded tube;It is divided into mining fluid conveying welded still pipe, lowpressure stream by material and purposes difference Body conveying galvanized welded pipe, carrier roller of belt conveyer electric welded steel pipe etc..According to the gauge table in existing national standard, by outer The ascending sequence of footpath * wall thickness.
Product standard:
Welded tube common material is:Q235A, Q235C
Q235B、16Mn、20#、Q345、L245、L290、X42、X46、X60、X80、0Cr13、1Cr17、00Cr19Ni11、 1Cr18Ni9,0Cr18Ni11Nb etc..
The blank that welded still pipe uses is steel plate or strip, is divided into the continuous furnace welding of tube, electric welding (resistance because its welding procedure is different Weldering) manage and automatic arc welding pipe.Because the difference of its Type of Welding is divided into two kinds of ERW and spiral welded pipe.Because of its end shape It is divided into circular welded tube and special-shaped (square, flat etc.) welded tube again.Welded tube is divided into following some kinds because its material is different with purposes:
GB/T3091-2008 (low-pressure fluid conveying welded still pipe).Mainly for delivery of water, coal gas, air, oil and take The general lower pressure fluid such as warm heat water or steam and other purposes pipes.Its represent material as:Q235A level steel.
GB/T14291-2006 (mining fluid conveying welded still pipe).It is mainly used in mine pressure wind, draining, axle methane use Straight seam welded steel pipe.It represents material Q235A, level-B steel.
GB/T12770-2002 (the stainless steel welded steel pipe of mechanical structure).It is mainly used in machinery, automobile, bicycle, family Tool, hotel and restaurant decoration and other mechanical parts and structural member.Its represent material 0Cr13,1Cr17,00Cr19Ni11, 1Cr18Ni9,0Cr18Ni11Nb etc..
GB/T12771-1991 (the stainless steel welded steel pipe of fluid conveying).Mainly for delivery of low pressure Korrosionsmedium. Material is represented as 0Cr13,0Cr19Ni9,00Cr19Ni11,00Cr17,0Cr18Ni11Nb, 0017Cr17Ni14Mo2 etc..
Separately have, decoration uses welded stainless steel pipe (GB/T 18705-2002), the stainless steel welded tubing (JG/ of architectural decoration T 3030-1995), and heat exchanger is with welded still pipe (YB4103-2000).
And welded tube is also to be used as connection, although the technique of production is very simple, due to material And the problem of the reason for external environment condition tends to cracking, fracture, paint layer from surface comes off, thus easily cause Damage, reduces service life, brings the loss of many.
The content of the invention
The technical problems to be solved by the invention be to overcome existing technological deficiency provide a kind of method rationally, operation side Just a kind of, corrosion resistant coating on metal connecting tube and preparation method thereof.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of coating on metal connecting tube, it is characterised in that:It is made up of the material of following parts by weight,
Resin 15-20 parts, coupling agent 4-9 parts, modified active powdered carbon 7-11 parts, defoamer 6-10 parts, palm wax emulsion 1-3 Part, acrylic acid 1-3 parts, dimethylbenzene 5-8 parts, trimethylolpropane trimethacrylate 8-12 parts, zinc dialkyl dithiophosphate 1-3 Part, APP 1-3 parts, clear water 27-33 parts;
The resin is E-12 epoxy resin, fluorocarbon resin, long oil alkyd, 191 unsaturated polyester resins, organic One kind in silicones;
The coupling agent is silane resin acceptor kh-550;
The defoamer is one kind in silicone oil, soap salt, higher alcohols, polyether-modified silicon;
The preparation method of the modified active powdered carbon is:Activated carbon is crushed and crosses 300-400 mesh sieves, is added and its weight Identical anion water, 1 hour is stirred, then adds dicyclopentadiene acrylate, mixing 2 is stirred at room temperature Hour, then dry, grind, obtain modified active powdered carbon;
The mass ratio of the dicyclopentadiene acrylate and activated carbon is 1:5;
A kind of preparation method of coating on metal connecting tube is,
I is put into resin, coupling agent, modified active powdered carbon, palm wax emulsion, clear water in reactor, is stirred at 30-35 DEG C Mix 1.5 hours of mixing;
II by defoamer, acrylic acid, dimethylbenzene, trimethylolpropane trimethacrylate, is added in reactor, and heats up To 38-43 DEG C, continue to stir 1.5 hours;
Zinc dialkyl dithiophosphate, APP are continued to be added in reactor by III, are stirred 2 hours i.e. Can;
The speed of the stirring is 2000-2500r/min.
Beneficial effects of the present invention are:Different materials is made by product by a series of mixing, prevented with good The performance of burn into anti-corrosion, and physical and chemical performance is stable, not easy to crack, fracture, by increasing capacitance it is possible to increase the life-span of product.This hair Bright method is reasonable, easy to operate, corrosion-resistant.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, enter below One step illustrates the present invention.
Embodiment 1
A kind of coating on metal connecting tube, it is characterised in that:It is made up of the material of following parts by weight,
15 parts of resin, 4 parts of coupling agent, 7 parts of modified active powdered carbon, 6 parts of defoamer, 1 part of palm wax emulsion, 1 part of acrylic acid, 5 parts of dimethylbenzene, 8 parts of trimethylolpropane trimethacrylate, 1 part of zinc dialkyl dithiophosphate, 1 part of APP, clear water 27 Part;
The resin is E-12 epoxy resin, fluorocarbon resin, long oil alkyd, 191 unsaturated polyester resins, organic One kind in silicones;
The coupling agent is silane resin acceptor kh-550;
The defoamer is one kind in silicone oil, soap salt, higher alcohols, polyether-modified silicon;
The preparation method of the modified active powdered carbon is:Activated carbon is crushed and crosses 300-400 mesh sieves, is added and its weight Identical anion water, 1 hour is stirred, then adds dicyclopentadiene acrylate, mixing 2 is stirred at room temperature Hour, then dry, grind, obtain modified active powdered carbon;
The mass ratio of the dicyclopentadiene acrylate and activated carbon is 1:5;
A kind of preparation method of coating on metal connecting tube is,
I is put into resin, coupling agent, modified active powdered carbon, palm wax emulsion, clear water in reactor, is stirred at 30-35 DEG C Mix 1.5 hours of mixing;
II by defoamer, acrylic acid, dimethylbenzene, trimethylolpropane trimethacrylate, is added in reactor, and heats up To 38-43 DEG C, continue to stir 1.5 hours;
Zinc dialkyl dithiophosphate, APP are continued to be added in reactor by III, are stirred 2 hours i.e. Can;
The speed of the stirring is 2000-2500r/min.
Embodiment 2
A kind of coating on metal connecting tube, it is characterised in that:It is made up of the material of following parts by weight,
20 parts of resin, 9 parts of coupling agent, 11 parts of modified active powdered carbon, 10 parts of defoamer, 3 parts of palm wax emulsion, acrylic acid 3 It is part, 8 parts of dimethylbenzene, 12 parts of trimethylolpropane trimethacrylate, 3 parts of zinc dialkyl dithiophosphate, 3 parts of APP, clear 33 parts of water;
The resin is E-12 epoxy resin, fluorocarbon resin, long oil alkyd, 191 unsaturated polyester resins, organic One kind in silicones;
The coupling agent is silane resin acceptor kh-550;
The defoamer is one kind in silicone oil, soap salt, higher alcohols, polyether-modified silicon;
The preparation method of the modified active powdered carbon is:Activated carbon is crushed and crosses 300-400 mesh sieves, is added and its weight Identical anion water, 1 hour is stirred, then adds dicyclopentadiene acrylate, mixing 2 is stirred at room temperature Hour, then dry, grind, obtain modified active powdered carbon;
The mass ratio of the dicyclopentadiene acrylate and activated carbon is 1:5;
A kind of preparation method of coating on metal connecting tube is,
I is put into resin, coupling agent, modified active powdered carbon, palm wax emulsion, clear water in reactor, is stirred at 30-35 DEG C Mix 1.5 hours of mixing;
II by defoamer, acrylic acid, dimethylbenzene, trimethylolpropane trimethacrylate, is added in reactor, and heats up To 38-43 DEG C, continue to stir 1.5 hours;
Zinc dialkyl dithiophosphate, APP are continued to be added in reactor by III, are stirred 2 hours i.e. Can;
The speed of the stirring is 2000-2500r/min.
Embodiment 3
A kind of coating on metal connecting tube, it is characterised in that:It is made up of the material of following parts by weight,
18 parts of resin, 7 parts of coupling agent, 10 parts of modified active powdered carbon, 8 parts of defoamer, 2 parts of palm wax emulsion, acrylic acid 2 It is part, 6 parts of dimethylbenzene, 10 parts of trimethylolpropane trimethacrylate, 2 parts of zinc dialkyl dithiophosphate, 2 parts of APP, clear 31 parts of water;
The resin is E-12 epoxy resin, fluorocarbon resin, long oil alkyd, 191 unsaturated polyester resins, organic One kind in silicones;
The coupling agent is silane resin acceptor kh-550;
The defoamer is one kind in silicone oil, soap salt, higher alcohols, polyether-modified silicon;
The preparation method of the modified active powdered carbon is:Activated carbon is crushed and crosses 300-400 mesh sieves, is added and its weight Identical anion water, 1 hour is stirred, then adds dicyclopentadiene acrylate, mixing 2 is stirred at room temperature Hour, then dry, grind, obtain modified active powdered carbon;
The mass ratio of the dicyclopentadiene acrylate and activated carbon is 1:5;
A kind of preparation method of coating on metal connecting tube is,
I is put into resin, coupling agent, modified active powdered carbon, palm wax emulsion, clear water in reactor, is stirred at 30-35 DEG C Mix 1.5 hours of mixing;
II by defoamer, acrylic acid, dimethylbenzene, trimethylolpropane trimethacrylate, is added in reactor, and heats up To 38-43 DEG C, continue to stir 1.5 hours;
Zinc dialkyl dithiophosphate, APP are continued to be added in reactor by III, are stirred 2 hours i.e. Can;
The speed of the stirring is 2000-2500r/min.
Comparative example
A kind of coating on metal connecting tube, it is characterised in that:It is made up of the material of following parts by weight,
10 parts of polyvinyl resin, 5 parts of active powdered carbon, 3 parts of defoamer, 1 part of palm wax emulsion, 3 parts of dimethylbenzene, trihydroxy methyl 5 parts of propane triacrylate, 22 parts of clear water;
Above-mentioned material is stirred at room temperature by reactor and is mixed.
By experiment, the performance and effect of measure 1-3 of the embodiment of the present invention and comparative example, such as following table:
Remarks:Performance in table is divided into high, medium and low three levels.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention,
Various changes and modifications of the present invention are possible, and these changes and improvements both fall within scope of the claimed invention It is interior.The scope of the present invention is defined by the appended claims and its equivalents.

Claims (8)

  1. A kind of 1. coating on metal connecting tube, it is characterised in that:It is made up of the material of following parts by weight,
    Resin 15-20 parts, coupling agent 4-9 parts, modified active powdered carbon 7-11 parts, defoamer 6-10 parts, palm wax emulsion 1-3 parts, Acrylic acid 1-3 parts, dimethylbenzene 5-8 parts, trimethylolpropane trimethacrylate 8-12 parts, zinc dialkyl dithiophosphate 1-3 parts, APP 1-3 parts, clear water 27-33 parts.
  2. A kind of 2. coating on metal connecting tube according to claim 1, it is characterised in that:The resin is E-12 One kind in epoxy resin, fluorocarbon resin, long oil alkyd, 191 unsaturated polyester resins, organic siliconresin.
  3. A kind of 3. coating on metal connecting tube according to claim 1, it is characterised in that:The coupling agent is silicon Alkane coupling agent KH-550.
  4. A kind of 4. coating on metal connecting tube according to claim 1, it is characterised in that:The defoamer is silicon One kind in oil, soap salt, higher alcohols, polyether-modified silicon.
  5. A kind of 5. coating on metal connecting tube according to claim 1, it is characterised in that:The modified activated carbon The preparation method of powder is:Activated carbon is crushed and crosses 300-400 mesh sieves, is added mixed with its weight identical anion water, stirring 1 hour is closed, then adds dicyclopentadiene acrylate, 2 hours of mixing are stirred at room temperature, then dries, grind, obtain Modified active powdered carbon.
  6. A kind of 6. coating on metal connecting tube according to claim 5, it is characterised in that:The dicyclopentadiene The mass ratio of acrylate and activated carbon is 1:5.
  7. A kind of 7. coating on metal connecting tube according to claim 1, it is characterised in that:It is described a kind of for gold The preparation method of coating in category connecting tube is,
    I is put into resin, coupling agent, modified active powdered carbon, palm wax emulsion, clear water in reactor, is stirred at 30-35 DEG C mixed Close 1.5 hours;
    II by defoamer, acrylic acid, dimethylbenzene, trimethylolpropane trimethacrylate, is added in reactor, and be warming up to 38-43 DEG C, continue to stir 1.5 hours;
    Zinc dialkyl dithiophosphate, APP are continued to be added in reactor by III, are stirred 2 hours.
  8. A kind of 8. coating on metal connecting tube according to claim 7, it is characterised in that:The speed of the stirring For 2000-2500r/min.
CN201710746067.3A 2017-08-26 2017-08-26 A kind of coating on metal connecting tube and preparation method thereof Pending CN107629520A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710746067.3A CN107629520A (en) 2017-08-26 2017-08-26 A kind of coating on metal connecting tube and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710746067.3A CN107629520A (en) 2017-08-26 2017-08-26 A kind of coating on metal connecting tube and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107629520A true CN107629520A (en) 2018-01-26

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103694867A (en) * 2013-11-29 2014-04-02 蚌埠市正园电子科技有限公司 Fire-resistant and weather-resistant metal protective insulating paint
CN103881571A (en) * 2014-02-25 2014-06-25 安徽普源分离机械制造有限公司 Refractory and weather-resistant metal protective insulating paint
CN104031497A (en) * 2014-05-26 2014-09-10 山东瑞邦涂层科技有限公司 Yellow-gray quick-drying anti-corrosive paint for galvanized stainless pipe fitting and preparation method thereof
CN105885490A (en) * 2016-06-22 2016-08-24 杨玉双 Environmentally friendly coating added with modified nano bamboo charcoal powder and preparation method of environmentally friendly coating
CN106752584A (en) * 2016-12-23 2017-05-31 安徽国威电动车制造有限公司 A kind of outside coating of electro-tricycle seat handrail

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103694867A (en) * 2013-11-29 2014-04-02 蚌埠市正园电子科技有限公司 Fire-resistant and weather-resistant metal protective insulating paint
CN103881571A (en) * 2014-02-25 2014-06-25 安徽普源分离机械制造有限公司 Refractory and weather-resistant metal protective insulating paint
CN104031497A (en) * 2014-05-26 2014-09-10 山东瑞邦涂层科技有限公司 Yellow-gray quick-drying anti-corrosive paint for galvanized stainless pipe fitting and preparation method thereof
CN105885490A (en) * 2016-06-22 2016-08-24 杨玉双 Environmentally friendly coating added with modified nano bamboo charcoal powder and preparation method of environmentally friendly coating
CN106752584A (en) * 2016-12-23 2017-05-31 安徽国威电动车制造有限公司 A kind of outside coating of electro-tricycle seat handrail

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Application publication date: 20180126

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