CN107555934A - A kind of construction material for three-dimensional printing technology - Google Patents
A kind of construction material for three-dimensional printing technology Download PDFInfo
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- CN107555934A CN107555934A CN201710799960.2A CN201710799960A CN107555934A CN 107555934 A CN107555934 A CN 107555934A CN 201710799960 A CN201710799960 A CN 201710799960A CN 107555934 A CN107555934 A CN 107555934A
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- parts
- kaolin
- stirring
- added dropwise
- construction material
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- 238000010146 3D printing Methods 0.000 title claims abstract description 22
- 239000004035 construction material Substances 0.000 title claims abstract description 22
- 238000005516 engineering process Methods 0.000 title claims abstract description 22
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 45
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 45
- -1 kaolin compound Chemical class 0.000 claims abstract description 34
- 238000003756 stirring Methods 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 18
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 15
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims abstract description 14
- USFZMSVCRYTOJT-UHFFFAOYSA-N ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000019257 ammonium acetate Nutrition 0.000 claims abstract description 12
- 239000011230 binding agent Substances 0.000 claims abstract description 12
- FBPFZTCFMRRESA-KAZBKCHUSA-N D-Mannitol Natural products OC[C@@H](O)[C@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KAZBKCHUSA-N 0.000 claims abstract description 11
- FBPFZTCFMRRESA-KVTDHHQDSA-N Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims abstract description 11
- 235000010355 mannitol Nutrition 0.000 claims abstract description 11
- 239000000594 mannitol Substances 0.000 claims abstract description 11
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004568 cement Substances 0.000 claims abstract description 10
- 239000005695 Ammonium acetate Substances 0.000 claims abstract description 9
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 9
- 229940043376 ammonium acetate Drugs 0.000 claims abstract description 9
- DIZPMCHEQGEION-UHFFFAOYSA-H Aluminium sulfate Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 8
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000003638 reducing agent Substances 0.000 claims abstract description 8
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 8
- 229910000162 sodium phosphate Inorganic materials 0.000 claims abstract description 8
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 8
- 238000009777 vacuum freeze-drying Methods 0.000 claims abstract description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 13
- 239000004115 Sodium Silicate Substances 0.000 claims description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 7
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 7
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 7
- 239000003822 epoxy resin Substances 0.000 claims description 6
- 229920000647 polyepoxide Polymers 0.000 claims description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 5
- 235000015450 Tilia cordata Nutrition 0.000 claims description 5
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 5
- 239000004571 lime Substances 0.000 claims description 5
- 239000004425 Makrolon Substances 0.000 claims description 4
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 2
- 238000005057 refrigeration Methods 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 description 9
- 238000007493 shaping process Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 230000002687 intercalation Effects 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- FDNAPBUWERUEDA-UHFFFAOYSA-N Silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000002209 hydrophobic Effects 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Abstract
The invention discloses a kind of construction material for three-dimensional printing technology, its raw material includes by weight：60 70 parts of cement, 40 50 parts of industrial silt, 30 40 parts of shraff, 10 20 parts of kaolin compound, 30 40 parts of inserts, 6 12 parts of magnesia, 24 parts of aluminum sulfate, 1.5 2.5 parts of sodium phosphate, 15 25 parts of binding agent, 12 parts of water reducer, 60 80 parts of water.Kaolin compound is prepared using following technique：Lauryl sodium sulfate, ammonium acetate, kaolin, water, mannitol are mixed, heated up, stirring, it is added dropwise in stirring n-hexane, tetrachloro silicane, tetraethyl orthosilicate stirring are added after being added dropwise completely, is washed with n-hexane, vacuum freeze drying obtains kaolin compound.
Description
Technical field
The present invention relates to three-dimensional printing technology field, more particularly to a kind of construction material for three-dimensional printing technology.
Background technology
Three-dimensional printing technology is also known as 3D printing technique, is a kind of rapid shaping technique.It is one kind with mathematical model file
Based on, pass through the technology by way of successively printing come constructed object material.
In building field, due to the generation of 3D printing technique, construction material is printed as being built into order to quickly build
A direction, and most important of which is that construction material.Common buildings material can not be used as 3D printing materials'use, work(at present
Can be more single, its easy fracture, heat endurance are poor, and cost is high, is unfavorable for modern architecture demand.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of Building wood for three-dimensional printing technology
Material, not only fillibility is good, makes construction material more closely knit, and thermal stability is extremely excellent, and cost is extremely low, it is more pressure-resistant and
Folding, pressure-resistant degree everywhere is homogeneous, is not susceptible to crack or phenomenon of rupture.
A kind of construction material for three-dimensional printing technology proposed by the present invention, its raw material include by weight：Cement 60-
70 parts, industrial silt 40-50 parts, shraff 30-40 parts, kaolin compound 10-20 parts, inserts 30-40 parts, magnesia
6-12 parts, aluminum sulfate 2-4 parts, sodium phosphate 1.5-2.5 parts, binding agent 15-25 parts, water reducer 1-2 parts, water 60-80 parts.
Preferably, kaolin compound is prepared using following technique：By lauryl sodium sulfate, ammonium acetate, kaolin,
Water, mannitol mixing, are heated up, stirring, are added dropwise in stirring n-hexane, and tetrachloro silicane, silicic acid four are added after being added dropwise completely
Ethyl ester stirs, and is washed with n-hexane, vacuum freeze drying obtains kaolin compound.
Preferably, kaolin compound is prepared using following technique：By weight by 2-4 parts lauryl sodium sulfate, 2-4
Part ammonium acetate, 30-50 parts kaolin, 30-40 parts water, the mixing of 50-60 parts mannitol, heat up, stirring, are added dropwise to stirring
In 250-350 part n-hexanes, addition 2-4 parts tetrachloro silicane, the stirring of 2-4 parts tetraethyl orthosilicate, washing, vacuum are cold after being added dropwise completely
Jelly is dried to obtain kaolin compound.
Preferably, kaolin compound is prepared using following technique：By weight by 2-4 parts lauryl sodium sulfate, 2-4
Part ammonium acetate, 30-50 parts kaolin, 30-40 parts water, the mixing of 50-60 parts mannitol, are warming up to 80-90 DEG C, stir 20-
40min, mixing speed 1600-1800rpm, it is added dropwise in stirring 250-350 part n-hexanes, 2- is added after being added dropwise completely
4 parts of tetrachloro silicanes, 2-4 parts tetraethyl orthosilicate stirring 40-60min, are washed, vacuum freeze drying obtains kaolin and answered with n-hexane
Compound.
Preferably, inserts includes by weight：White lime 6-12 parts, gangue 4-8 parts, shale 8-16 parts.
Preferably, binding agent includes by weight：Makrolon 2-4 parts, epoxy resin 4-8 parts, sodium metasilicate 10-20 parts.
Material provided by the invention is easily constructed, and realizes printing speed and shaping, and the construction wall after shaping is closely knit, stable
Property it is high, pressure-resistant and folding quality is excellent, is not susceptible to crack or phenomenon of rupture；And material is prepared simply, suitable for pushing away extensively
Wide application, while solve industrial silt, shraff recovery problem, energy and material is greatlyd save, it is green.
For the present invention using cement, industrial silt, shraff, kaolin compound as aggregate, not only cost is extremely low, and fills out
Filling property is good, is matched by adjusting between each component, can ensure it is well mixed in the case of, construction material can be made more closely knit；
,, can sweet dew because the intercalation of interlayer hydrophobic chain under certain condition using ammonium acetate to kaolin intercalation in kaolin compound
Alcohol can enter in interlayer structure, and further by interfacial polymerization, Surface coating is carried out using silica, and moisture removal is removed in freezing,
Not only heat endurance is good, and excellent in compatibility with curing agent, and sodium metasilicate therein can be wrapped up, and pattern is excellent, chi
It is very little homogeneous, the high rigidity feature of silicate is not only remained, and can be molded by kaolin compound, stability significantly carries
Height, further coordinate cement effect, after construction material solidification, overall more closely knit, thermal stability is extremely excellent, without to slurry
Material, which applies excessive pressure, can make sizing material forming；Sodium metasilicate further coordinates with makrolon, epoxy resin, can effectively strengthen
Adhesive property, the mechanical property of construction material is effectively improved, make it more pressure-resistant and folding, pressure-resistant degree everywhere is homogeneous, no
Crack or phenomenon of rupture easily occurs.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of construction material for three-dimensional printing technology, its raw material include by weight：60 parts of cement, industrial silt 50
Part, 30 parts of shraff, 20 parts of kaolin compound, 30 parts of inserts, 12 parts of magnesia, 2 parts of aluminum sulfate, 2.5 parts of sodium phosphate,
15 parts of binding agent, 2 parts of water reducer, 60 parts of water.
Embodiment 2
A kind of construction material for three-dimensional printing technology, its raw material include by weight：70 parts of cement, industrial silt 40
Part, 40 parts of shraff, 10 parts of kaolin compound, 40 parts of inserts, 6 parts of magnesia, 4 parts of aluminum sulfate, 1.5 parts of sodium phosphate,
25 parts of binding agent, 1 part of water reducer, 80 parts of water.
Kaolin compound is prepared using following technique：By lauryl sodium sulfate, ammonium acetate, kaolin, water, mannitol
Mixing, heat up, stirring, be added dropwise in stirring n-hexane, tetrachloro silicane, tetraethyl orthosilicate stirring are added after being added dropwise completely,
Washed with n-hexane, vacuum freeze drying obtains kaolin compound.
Embodiment 3
A kind of construction material for three-dimensional printing technology, its raw material include by weight：62 parts of cement, industrial silt 48
Part, 33 parts of shraff, 18 parts of kaolin compound, 32 parts of inserts, 10 parts of magnesia, 2.5 parts of aluminum sulfate, sodium phosphate 2.2
Part, 18 parts of binding agent, 1.8 parts of water reducer, 65 parts of water.
Inserts includes by weight：6 parts of white lime, 8 parts of gangue, 8 parts of shale.Binding agent includes by weight：It is poly-
4 parts of carbonic ester, 4 parts of epoxy resin, 20 parts of sodium metasilicate.Kaolin compound is prepared using following technique：By weight by 3 part ten
Sodium dialkyl sulfate, 3 parts of ammonium acetates, 40 parts of kaolin, 35 parts of water, 55 parts of mannitol mixing, heat up, stirring, are added dropwise to stirring
In 300 parts of n-hexanes of state, 3 parts of tetrachloro silicanes, 3 parts of tetraethyl orthosilicate stirrings, washing are added after being added dropwise completely, vacuum refrigeration is done
It is dry to obtain kaolin compound.
Embodiment 4
A kind of construction material for three-dimensional printing technology, its raw material include by weight：68 parts of cement, industrial silt 42
Part, 37 parts of shraff, 12 parts of kaolin compound, 38 parts of inserts, 8 parts of magnesia, 3.5 parts of aluminum sulfate, sodium phosphate 1.8
Part, 22 parts of binding agent, 1.2 parts of water reducer, 75 parts of water.
Inserts includes by weight：12 parts of white lime, 4 parts of gangue, 16 parts of shale.Binding agent includes by weight：
2 parts of makrolon, 8 parts of epoxy resin, 10 parts of sodium metasilicate.Kaolin compound is prepared using following technique：By weight by 2 parts
Lauryl sodium sulfate, 4 parts of ammonium acetates, 30 parts of kaolin, 40 parts of water, 50 parts of mannitol mixing, are warming up to 80 DEG C, stirring
40min, mixing speed 1600rpm, it is added dropwise in 350 parts of n-hexanes of stirring, 2 parts of tetrachloro silicon is added after being added dropwise completely
Alkane, 4 parts of tetraethyl orthosilicate stirring 40min, are washed, vacuum freeze drying obtains kaolin compound with n-hexane.
Embodiment 5
A kind of construction material for three-dimensional printing technology, its raw material include by weight：65 parts of cement, industrial silt 45
Part, 35 parts of shraff, 15 parts of kaolin compound, 35 parts of inserts, 9 parts of magnesia, 3 parts of aluminum sulfate, 2 parts of sodium phosphate, glue
Tie 20 parts of agent, 1.5 parts of water reducer, 70 parts of water.
Inserts includes by weight：9 parts of white lime, 6 parts of gangue, 12 parts of shale.Binding agent includes by weight：It is poly-
3 parts of carbonic ester, 6 parts of epoxy resin, 15 parts of sodium metasilicate.Kaolin compound is prepared using following technique：By weight by 4 part ten
Sodium dialkyl sulfate, 2 parts of ammonium acetates, 50 parts of kaolin, 30 parts of water, 60 parts of mannitol mixing, are warming up to 90 DEG C, stir 20min,
Mixing speed is 1800rpm, is added dropwise in 250 parts of n-hexanes of stirring, and 4 parts of tetrachloro silicanes, 2 parts of silicon are added after being added dropwise completely
Sour tetra-ethyl ester stirs 60min, is washed with n-hexane, vacuum freeze drying obtains kaolin compound.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (6)
1. a kind of construction material for three-dimensional printing technology, it is characterised in that its raw material includes by weight：Cement 60-70
Part, industrial silt 40-50 parts, shraff 30-40 parts, kaolin compound 10-20 parts, inserts 30-40 parts, magnesia 6-
12 parts, aluminum sulfate 2-4 parts, sodium phosphate 1.5-2.5 parts, binding agent 15-25 parts, water reducer 1-2 parts, water 60-80 parts.
2. it is used for the construction material of three-dimensional printing technology according to claim 1, it is characterised in that kaolin compound uses
It is prepared by following technique：Lauryl sodium sulfate, ammonium acetate, kaolin, water, mannitol are mixed, heated up, stirring, is added dropwise to and stirs
Mix in state n-hexane, tetrachloro silicane, tetraethyl orthosilicate stirring are added after being added dropwise completely, is washed with n-hexane, vacuum refrigeration is done
It is dry to obtain kaolin compound.
3. the construction material according to claim 1 or claim 2 for three-dimensional printing technology, it is characterised in that kaolin compound
Prepared using following technique：By weight by 2-4 parts lauryl sodium sulfate, 2-4 parts ammonium acetate, 30-50 parts kaolin, 30-
40 parts of water, the mixing of 50-60 parts mannitol, heat up, stirring, are added dropwise in stirring 250-350 part n-hexanes, after being added dropwise completely
2-4 parts tetrachloro silicane, the stirring of 2-4 parts tetraethyl orthosilicate, washing are added, vacuum freeze drying obtains kaolin compound.
4. it is used for the construction material of three-dimensional printing technology according to claim any one of 1-3, it is characterised in that kaolin is multiple
Compound is prepared using following technique：By weight by 2-4 parts lauryl sodium sulfate, 2-4 parts ammonium acetate, 30-50 parts kaolin,
30-40 parts water, the mixing of 50-60 parts mannitol, are warming up to 80-90 DEG C, stir 20-40min, mixing speed 1600-
1800rpm, it is added dropwise in stirring 250-350 part n-hexanes, 2-4 parts tetrachloro silicane, 2-4 part silicic acid is added after being added dropwise completely
Tetra-ethyl ester stirs 40-60min, is washed with n-hexane, vacuum freeze drying obtains kaolin compound.
5. it is used for the construction material of three-dimensional printing technology according to claim any one of 1-4, it is characterised in that inserts is pressed
Parts by weight include：White lime 6-12 parts, gangue 4-8 parts, shale 8-16 parts.
6. it is used for the construction material of three-dimensional printing technology according to claim any one of 1-5, it is characterised in that binding agent is pressed
Parts by weight include：Makrolon 2-4 parts, epoxy resin 4-8 parts, sodium metasilicate 10-20 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710799960.2A CN107555934A (en) | 2017-09-07 | 2017-09-07 | A kind of construction material for three-dimensional printing technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710799960.2A CN107555934A (en) | 2017-09-07 | 2017-09-07 | A kind of construction material for three-dimensional printing technology |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107555934A true CN107555934A (en) | 2018-01-09 |
Family
ID=60979535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710799960.2A Withdrawn CN107555934A (en) | 2017-09-07 | 2017-09-07 | A kind of construction material for three-dimensional printing technology |
Country Status (1)
| Country | Link |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002141A (en) * | 2010-11-19 | 2011-04-06 | 安徽大学 | Preparation method of polyurethane-nano kaolin composite material |
| CN103359753A (en) * | 2013-07-05 | 2013-10-23 | 中国矿业大学(北京) | Preparation method of kaolin-silane embedded intercalating modified complex |
| CN104891891A (en) * | 2015-05-06 | 2015-09-09 | 同济大学 | 3D printing cement-based material and preparation method thereof |
| CN105645923A (en) * | 2015-12-24 | 2016-06-08 | 成都新柯力化工科技有限公司 | Filamentous clay material for 3D printing and preparation method thereof |
| CN106904924A (en) * | 2017-03-17 | 2017-06-30 | 山东大学 | The system and method for 3D printing material is built using municipal waste and Industrial Solid Waste |
-
2017
- 2017-09-07 CN CN201710799960.2A patent/CN107555934A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102002141A (en) * | 2010-11-19 | 2011-04-06 | 安徽大学 | Preparation method of polyurethane-nano kaolin composite material |
| CN103359753A (en) * | 2013-07-05 | 2013-10-23 | 中国矿业大学(北京) | Preparation method of kaolin-silane embedded intercalating modified complex |
| CN104891891A (en) * | 2015-05-06 | 2015-09-09 | 同济大学 | 3D printing cement-based material and preparation method thereof |
| CN105645923A (en) * | 2015-12-24 | 2016-06-08 | 成都新柯力化工科技有限公司 | Filamentous clay material for 3D printing and preparation method thereof |
| CN106904924A (en) * | 2017-03-17 | 2017-06-30 | 山东大学 | The system and method for 3D printing material is built using municipal waste and Industrial Solid Waste |
Non-Patent Citations (1)
| Title |
|---|
| 白春华: "《非金属矿物基二氧化钛制备改性及废水处理技术》", 31 December 2015, 中国矿业大学出版社 * |
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