CN107528002A - A kind of perovskite solar cell based on the insertion of dye sensitization upconverter - Google Patents

A kind of perovskite solar cell based on the insertion of dye sensitization upconverter Download PDF

Info

Publication number
CN107528002A
CN107528002A CN201710538855.3A CN201710538855A CN107528002A CN 107528002 A CN107528002 A CN 107528002A CN 201710538855 A CN201710538855 A CN 201710538855A CN 107528002 A CN107528002 A CN 107528002A
Authority
CN
China
Prior art keywords
upconverter
dye sensitization
perovskite
solar cell
perovskite solar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710538855.3A
Other languages
Chinese (zh)
Other versions
CN107528002B (en
Inventor
郑言贞
赖学森
陶霞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing University of Chemical Technology
Original Assignee
Beijing University of Chemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing University of Chemical Technology filed Critical Beijing University of Chemical Technology
Priority to CN201710538855.3A priority Critical patent/CN107528002B/en
Publication of CN107528002A publication Critical patent/CN107528002A/en
Application granted granted Critical
Publication of CN107528002B publication Critical patent/CN107528002B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01BASIC ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H01L51/00Solid state devices using organic materials as the active part, or using a combination of organic materials with other materials as the active part; Processes or apparatus specially adapted for the manufacture or treatment of such devices, or of parts thereof
    • H01L51/42Solid state devices using organic materials as the active part, or using a combination of organic materials with other materials as the active part; Processes or apparatus specially adapted for the manufacture or treatment of such devices, or of parts thereof specially adapted for sensing infra-red radiation, light, electro-magnetic radiation of shorter wavelength or corpuscular radiation and adapted for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation using organic materials as the active part, or using a combination of organic materials with other material as the active part; Multistep processes for their manufacture
    • H01L51/4213Comprising organic semiconductor-inorganic semiconductor hetero-junctions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

Abstract

A kind of perovskite solar cell based on the insertion of dye sensitization upconverter, belongs to organic/inorganic composite material and optoelectronic materials technology.Mainly comprise the following steps and prepare the perovskite precursor liquid containing dye sensitization upconverter, the perovskite solar cell of this preparation dye sensitization upconverter insertion of base.This perovskite solar cell based on the insertion of dye sensitization upconverter has widened battery spectrum absorption region, has improved the opto-electronic conversion performance of solar cell by the absorbable near infrared light using 800 1000nm of dye sensitization upconverter.Present invention process is simple, and cost is cheap, has widened the absorption spectrum of perovskite solar cell, improves the photoelectric properties of battery, to perovskite too can the development of battery serve impetus.

Description

A kind of perovskite solar cell based on the insertion of dye sensitization upconverter
Technical field
The invention belongs to organic/inorganic composite material and optoelectronic materials technology, more particularly to based in dye sensitization turns Application of the parallel operation in perovskite solar cell.
Background technology
In recent years, energy shortage problem, not only reserves are limited, non-renewable for traditional fossil energy, and it uses process In huge pollution can be also brought to environment.And solar energy cleans renewable, the inexhaustible energy as a kind of Just receive more and more attention.In this context, exploitation novel efficient low-cost solar battery causes various countries researcher Huge interest, especially perovskite solar cell relies on good light absorptive and charge transport rate, and huge opens Send out potentiality, 3.8% efficiency till now 22.1% risen since 2009, development is particularly rapid, be described as " photovoltaic art it is new Wish ".The film of hundreds of nanometer thickness can fully absorb the sunshine below wavelength 800nm in perovskite solar cell.Though Right absorption region is very wide, but utilizes upconverter, can be obvious so as to make infrared light invisible to the human eye be changed into visible ray Improve the photoelectric efficiency of perovskite.But upconverter problem present in perovskite solar cell application is such as infrared/near The absorption band of infrared light district is narrower, charge-conduction poor performance, hinders electron-stream transmission, causes the reduction of carrier collection efficiency, Intermiscibility of the up-conversion nanoparticles in perovskite precursor liquid is poor.Researcher has found to take on up-conversion nanoparticles surface Carry organic dyestuff IR-806 structure dye sensitization upconverter (absorption spectrum ranges are 800~1000nm) shapes of carboxyl-functional Into energy and connection mode, the luminous intensity of upper conversion nano particle is obviously improved, has widened the absorption spectrum of nano-particle [Wenqiang Zou1, Cindy Visser1, Jeremio A.Maduro, Nature Photonics 6,560-564 (2012)].Therefore, by using dye sensitization up-conversion, widen the absorption spectrum of perovskite solar cell, improve electricity The application study of pond photoelectric properties does not have document report also so far.
The content of the invention
The problem of present invention is difficult by near infrared light for existing perovskite thin film material, it is therefore an objective to provide a kind of dye Application of the material sensitization upconverter in perovskite solar cell.Dye sensitization upconverter is added in precursor solution, Method, silk screen print method, scalpel knife coating, spraying process are applied by spin-coating method, drop, dye sensitization is formed in the presence of anti-solvent The perovskite thin film of upconverter insertion, by this film with solar cells, widen the absorption of perovskite solar cell Spectrum, improve cell photoelectric performance.
Perovskite solar cell based on the insertion of dye sensitization upconverter prepared by the present invention, is comprised the following steps that:
1) preparation of hydrophilic group dye sensitization upconverter:
The upconverter of coated by hydrophobic group is prepared, then prepared composition dispersion liquid, then add excessive inorganic salts NOBF4 Polar organic solvent so that hydrophobic grouping part is by BF4 -Substitute, the upconverter polarity after isolated ligand exchange is organic molten Liquid;The organic dyestuff that excessive carboxyl-functional is added into the upconverter organic solution after ligand exchange carries out overlap joint reaction Hydrophilic group dye sensitization upconverter is prepared, precipitation is then carried out and isolates hydrophilic group dye sensitization upconverter, redisperse arrives In polar organic solvent, hydrophilic group dye sensitization upconverter dispersion liquid is formed;Polar organic solvent preferred DMF or DMSO;Bag The material for including hydrophobic grouping preferably is selected from oleyl amine, oleic acid etc..
2) preparation of the perovskite precursor liquid of the upconverter containing dye sensitization:
The dispersion liquid of the upconverter containing dye sensitization prepared by step 1) is added to perovskite precursor liquid by a certain percentage In, it is not higher than 100mg/mL to obtain the concentration of upconverter containing dye sensitization in mixed liquor;
3) assembling of the perovskite solar cell of dye sensitization upconverter insertion:
In conductive substrates spin coating prepare one layer of 2~800nm electron transfer layer, after dyestuff will be contained prepared by step 2) The perovskite precursor liquid for being sensitized upconverter applies method, silk screen print method, scalpel knife coating or spraying process by spin-coating method, drop, Form the perovskite thin film i.e. dye sensitization of dye sensitization upconverter insertion on the electron transport layer in the presence of anti-solvent Upper converter is coated by perovskite crystal, and after annealed processing, then spin coating prepares the thick hole transmission layers of 2~500nm, finally Prepare 10~1000nm it is thick to electrode, integrate perovskite solar cell.
Wherein, the upconverter described in step 1) be selected from undoped with β-NaYF4:Yb,Er、NaLnF4(Ln=Y, Gd, Lu), oxysulfide M2O2S (M=Gd, Y, La), triplet state-triplet state annihilation (Triplet-triplet annihilation, ), and Er TTA3+、Yb3+-Er3+、Yb3+-Tm3+、Yb3+-Ho3+In one or more of doping, and doping, undoped with Any at least two between core shell structure on turn device.
The organic dyestuff of carboxyl-functional described in step 1) is selected from IR-783, IR-806, IR-808, IR-820, IR- 845、Er(TTA)4(IR-806) one or more in.
The compound method of perovskite solution described in step 2) is by the one or more in AX, MX2In one kind or several Kind is mixed in organic solvent, is configured to the perovskite solution that total mass concentration is 10~60wt%, wherein AX and MX2Mole Than for 1:1;A groups in wherein AX are selected from CH3NH3、NH2- CH=NH2、CH3CH2NH3、CH3(CH2)2NH3、CH3(CH2)3NH3、 C6H5(CH2)2NH3Group and Cs;MX2Metal M be Pb, Sn in one kind, the mixture of two or more compounds;AX and MX2In X be a kind of in I, Br, Cl;Perovskite precursor liquid uses organic solvent, and organic solvent is DMF (DMF), at least one of dimethyl sulfoxide (DMSO), gamma-butyrolacton (GBL).
Anti-solvent described in step 3) is chlorobenzene, the one or more in toluene, ether, hexamethylene.
Conductive substrates described in step 3) are FTO electro-conductive glass, ITO electro-conductive glass or flexible conducting substrate.
Electron transfer layer described in step 3) for zinc oxide, tin ash, titanium dioxide, the barium stannate of La doped, richness Strangle the one or more in alkene and derivative.
Annealing on hot plate described in step 3) is 50~300 DEG C of 5~120min of heating.
Hole transmission layer described in step 3) for Spiro-OMeTAD, PEDOT:PSS、CuPc、P3HT、PTAA、FDT、 CuI、MoO3, one or more in CuSCN and NiO.
Described in step 3) is the one or more in Ag, Au, Al, C electrode to electrode.
Compared with prior art, the invention has the advantages that:
The absorption that perovskite solar cell prepared by the present invention improves infrared/near-infrared all band solar spectrum is strong Degree, the especially absorbable near infrared light using 800-1000nm, have widened battery spectrum absorption region, have improved solar cell Opto-electronic conversion performance., battery spectrum absorption region has further been widened, has improved the photoelectric properties of solar cell.
Brief description of the drawings
The ultraviolet-visible absorption spectroscopy of dye sensitization upconverter insertion perovskite thin film material prepared by Fig. 1, embodiment 1 Figure.
The I-V curve of dye sensitization upconverter insertion perovskite solar cell prepared by Fig. 2, embodiment 1.
Fig. 3 is perovskite solar cell frame assumption diagram.
Embodiment
Below in conjunction with accompanying drawing and example, the invention will be further described, but the present invention is not limited to following examples.
Embodiment 1
1) preparation of dye sensitization upconverter:
(1) oleyl amine coating beta-NaYF4:The preparation of Yb, Er upconverter:Prepared using rare earth trifluoroacetate pyrolysis method 544mg CF3COONa,667.7mg Y(CF3COO)3,204.8mg Yb(CF3COO)3, 20.3mg Er (CF3COO)3And 30mL It is added to after oleyl amine mixing in 100mL three-necked flask, is heated to 100 DEG C, is vacuumized 30min and remove H2O and O2, after in N2Atmosphere Be heated under enclosing 330 DEG C, keep 1h, react completely after cooling down to 80 DEG C, then add 30mL ethanol with separate out β- NaYF4:Yb, Er particle, last 5000rpm centrifuge 5min, precipitation are scattered in n-hexane solvent, formed 30mg/mL β- NaYF4:Yb, Er n-hexane dispersion liquid.
(2) IR-806 organic dyestuff is carried:Take 3mL β-NaYF4:Yb, Er n-hexane dispersion liquid and 3mLNOBF4DMF it is molten It is stirred vigorously after liquid (100mg/mL) mixing, after stratification, upper conversion nano particle is transferred to down from upper strata n-hexane solvent In layer DMF solvent, oleyl amine part is by BF4 -Substitution, after take subnatant, add 2~4mg IR-806 organic dyestuff, stirred at 40 DEG C 12h is mixed, the rear isopropanol and toluene Mixed Solvent (volume ratio 1 for adding equal volume amounts:1) precipitation, 5000rpm centrifugations are separated out 5min, after take precipitation to be scattered in DMF solvent, form in 60mg/mL dye sensitization conversion DMF dispersion liquids.
2) preparation of the perovskite precursor liquid of the upconverter containing dye sensitization:
162.5mg iodine methylamine and 470mg lead iodides are mixed and added in 1ml DMF (DMF), normal temperature It is stirred overnight, is configured to the perovskite precursor solution that weight/mass percentage composition is 40%.Can be by changing CH3NH3I、PbI2、 The amount of DMF three, change the mass fraction and molar fraction of perovskite.Then again by dispersion liquid prepared by step 1) by certain ratio Example is added in perovskite precursor liquid, forms mixing precursor aqueous solution.
3) assembling of perovskite solar cell:
(1) cleaning of glass:The adhesive tape remained on glass is first washed with acetone, then respectively with liquid detergent, running water, go from Son, acetone, (twice) of the order of isopropanol clean glass, every time the ultrasonic 10min in excusing from death is bathed.It is put into UV-ozone cleaning Processing is irradiated in machine to substrate of glass.
(2) preparation of electron transfer layer (ETM)
Electron transfer layer (ETM) play the role of in the structure of perovskite solar cell it is irreplaceable, on the one hand not Electronics can be only transmitted, on the other hand can stop the transmission in hole.In general electronics collecting layer selects ZnO, is coagulated using colloidal sol Glue method prepares ZnO solution, and one layer of fine and close ZnO film is formed after the rear method calcining using spin coating.
(3) preparation of calcium titanium ore bed
Different volumes are dispersed with to the β-NaYF for carrying IR-8064:(polarity is organic by Yb, Er dye sensitization upconverter DMF Solvent) dispersion liquid is added in perovskite precursor liquid, form mixing precursor aqueous solution.Using the method for one-step method spin coating in sol evenning machine Upper spin coating (5000r/min, 30s), be added dropwise in spin coating the 6th second in the presence of chlorobenzene anti-solvent and form perovskite thin film, after 70 DEG C of heating 30min in heating plate.After spin coating, converter is coated by perovskite crystal in dye sensitization, forms one layer of dyestuff It is sensitized β-NaYF4:Yb, Er@perovskite crystal nucleocapsid light-absorption layers.
(4) preparation of hole transmission layer (HTM)
HTM layers play transporting holes in whole battery structure, obstruct the effect of electronics.This experiment HTM materials used For Spiro-MeOTAD.72.3mg Spiro-MeOTAD solid powders are taken, are dissolved in 1ml chlorobenzene, 60 DEG C of heating stirrings 20min, then the second for the lithium salts for being 520mg/mL toward the tetra-tert pyridine (TBP) and 17.5 μ L concentration that 28.8 μ L are added in solution Nitrile solution stirring at normal temperature 2h, drip on perovskite-based bottom, spin coating 30s under 2500rpm.Under the conditions of lucifuge, it is allowed slowly to dry in the air naturally It is dry.
(5) evaporation of metal electrode
The battery assembled is put into evaporator, two Argent grains is put into, control evaporation temperature and time, 70nm is deposited Silver metal electrodes.

Claims (10)

  1. A kind of 1. preparation method of the perovskite solar cell based on the insertion of dye sensitization upconverter, it is characterised in that bag Include following steps:
    1) preparation of hydrophilic group dye sensitization upconverter:
    The upconverter of coated by hydrophobic group is prepared, then prepared composition dispersion liquid, then add excessive inorganic salts NOBF4Polarity Organic solution so that hydrophobic grouping part is by BF4 -Substitute, the upconverter polar organic solvent after isolated ligand exchange; The organic dyestuff that excessive carboxyl-functional is added into the upconverter organic solution after ligand exchange carries out overlap joint reaction system Standby hydrophilic group dye sensitization upconverter, then carries out precipitation and isolates hydrophilic group dye sensitization upconverter, redisperse to pole Property organic solution in, formed hydrophilic group dye sensitization upconverter dispersion liquid;
    2) preparation of the perovskite precursor liquid of the upconverter containing dye sensitization:
    The dispersion liquid of the upconverter containing dye sensitization prepared by step 1) is added in perovskite precursor liquid by a certain percentage, obtains Into mixed liquor, the concentration of upconverter containing dye sensitization is not higher than 100mg/mL;
    3) assembling of the perovskite solar cell of dye sensitization upconverter insertion:
    In conductive substrates spin coating prepare one layer of 2~800nm electron transfer layer, after dye sensitization will be contained prepared by step 2) The perovskite precursor liquid of upconverter applies method, silk screen print method, scalpel knife coating or spraying process by spin-coating method, drop, anti- The perovskite thin film for forming the insertion of dye sensitization upconverter in the presence of solvent on the electron transport layer turns i.e. in dye sensitization Change device to be coated by perovskite crystal, after annealed processing, then spin coating prepares the thick hole transmission layers of 2~500nm, finally prepares 10~1000nm it is thick to electrode, integrate perovskite solar cell.
  2. 2. according to the preparation method described in claim 1, it is characterised in that upconverter described in step 1) be selected from undoped with β-NaYF4:Yb,Er、NaLnF4, oxysulfide M2O2S, triplet state-triplet state annihilation (Triplet-triplet Annihilation, TTA), and Er3+、Yb3+-Er3+、Yb3+-Tm3+、Yb3+-Ho3+In one or more of doping, and Doping, undoped with any at least two between core shell structure on turn device, Ln=Y, Gd, Lu, M=Gd, Y, La.
  3. 3. according to the preparation method described in claim 1, it is characterised in that the organic dyestuff of carboxyl-functional be selected from IR-783, IR-806、IR-808、IR-820、IR-845、Er(TTA)4(IR-806) one or more in.
  4. 4. according to the preparation method described in claim 1, it is characterised in that the compound method of the perovskite solution described in step 2) For by the one or more in AX, MX2In one or more be mixed in organic solvent, be configured to total mass concentration for 10~ 60wt% perovskite solution, wherein AX and MX2Mol ratio be 1:1;A groups in wherein AX are selected from CH3NH3、NH2- CH= NH2、CH3CH2NH3、CH3(CH2)2NH3、CH3(CH2)3NH3、C6H5(CH2)2NH3Group and Cs;MX2Metal M be Pb, Sn in One kind, the mixture of two or more compounds;AX and MX2In X be a kind of in I, Br, Cl;Perovskite precursor liquid is adopted With organic solvent, organic solvent is in DMF (DMF), dimethyl sulfoxide (DMSO), gamma-butyrolacton (GBL) It is at least one.
  5. 5. according to the preparation method described in claim 1, it is characterised in that the anti-solvent described in step 3) is chlorobenzene, toluene, second One or more in ether, hexamethylene.
  6. 6. according to the preparation method described in claim 1, it is characterised in that the conductive substrates described in step 3) are FTO conduction glass Glass, ITO electro-conductive glass or flexible conducting substrate;Electron transfer layer described in step 3) is selected from zinc oxide, tin ash, titanium dioxide One or more in titanium, the barium stannate of La doped, fullerene and derivative.
  7. 7. according to the preparation method described in claim 1, it is characterised in that the annealing described in step 3) is 50~300 DEG C 5~120min is heated, is made annealing treatment on hot plate.
  8. 8. according to the preparation method described in claim 1, it is characterised in that hole transmission layer described in step 3) is selected from Spiro-OMeTAD、PEDOT:PSS、CuPc、P3HT、PTAA、FDT、CuI、MoO3, one or more in CuSCN and NiO; Described in step 3) is the one or more in Ag, Au, Al, C electrode to electrode.
  9. 9. according to the preparation method described in claim 1, it is characterised in that step 1) polar organic solvent preferred DMF or DMSO; Material including hydrophobic grouping preferably is selected from the one or more in oleyl amine, oleic acid.
  10. 10. according to any one of claim 1-9 method be prepared based on dye sensitization upconverter insertion perovskite too Positive energy battery.
CN201710538855.3A 2017-07-04 2017-07-04 A kind of perovskite solar battery based on the insertion of dye sensitization upconverter Active CN107528002B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710538855.3A CN107528002B (en) 2017-07-04 2017-07-04 A kind of perovskite solar battery based on the insertion of dye sensitization upconverter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710538855.3A CN107528002B (en) 2017-07-04 2017-07-04 A kind of perovskite solar battery based on the insertion of dye sensitization upconverter

Publications (2)

Publication Number Publication Date
CN107528002A true CN107528002A (en) 2017-12-29
CN107528002B CN107528002B (en) 2019-08-02

Family

ID=60748818

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710538855.3A Active CN107528002B (en) 2017-07-04 2017-07-04 A kind of perovskite solar battery based on the insertion of dye sensitization upconverter

Country Status (1)

Country Link
CN (1) CN107528002B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108574046A (en) * 2018-05-24 2018-09-25 中节能万润股份有限公司 A kind of perovskite solar cell and preparation method thereof
CN108682702A (en) * 2018-06-06 2018-10-19 北京大学 A kind of photoelectric device composite hole transporting layer material and preparation method thereof
CN108847428A (en) * 2018-06-08 2018-11-20 苏州宝澜环保科技有限公司 A kind of solar battery and preparation method thereof based on silicon nanowire array
CN110649160A (en) * 2018-06-26 2020-01-03 华中科技大学鄂州工业技术研究院 Inorganic charge transport layer, preparation method thereof and application of perovskite solar cell
WO2020029205A1 (en) * 2018-08-09 2020-02-13 苏州大学张家港工业技术研究院 Method for preparing inorganic perovskite battery based on synergistic effect of gradient annealing and antisolvent, and prepared inorganic perovskite battery

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103346203A (en) * 2013-05-31 2013-10-09 浙江正泰太阳能科技有限公司 Up-conversion solar cell and preparation method thereof
CN105001583A (en) * 2015-07-03 2015-10-28 福州大学 Organic-inorganic composite up-conversion photoluminescence film and preparation method thereof
CN106118628A (en) * 2016-06-15 2016-11-16 武汉理工大学 A kind of preparation method of the upconversion fluorescence nano material with nucleocapsid structure

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103346203A (en) * 2013-05-31 2013-10-09 浙江正泰太阳能科技有限公司 Up-conversion solar cell and preparation method thereof
CN105001583A (en) * 2015-07-03 2015-10-28 福州大学 Organic-inorganic composite up-conversion photoluminescence film and preparation method thereof
CN106118628A (en) * 2016-06-15 2016-11-16 武汉理工大学 A kind of preparation method of the upconversion fluorescence nano material with nucleocapsid structure

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108574046A (en) * 2018-05-24 2018-09-25 中节能万润股份有限公司 A kind of perovskite solar cell and preparation method thereof
CN108682702A (en) * 2018-06-06 2018-10-19 北京大学 A kind of photoelectric device composite hole transporting layer material and preparation method thereof
CN108847428A (en) * 2018-06-08 2018-11-20 苏州宝澜环保科技有限公司 A kind of solar battery and preparation method thereof based on silicon nanowire array
CN108847428B (en) * 2018-06-08 2020-07-10 海门名驰工业设计有限公司 Solar cell based on silicon nanowire array and preparation method thereof
CN110649160A (en) * 2018-06-26 2020-01-03 华中科技大学鄂州工业技术研究院 Inorganic charge transport layer, preparation method thereof and application of perovskite solar cell
WO2020029205A1 (en) * 2018-08-09 2020-02-13 苏州大学张家港工业技术研究院 Method for preparing inorganic perovskite battery based on synergistic effect of gradient annealing and antisolvent, and prepared inorganic perovskite battery

Also Published As

Publication number Publication date
CN107528002B (en) 2019-08-02

Similar Documents

Publication Publication Date Title
CN107528002B (en) A kind of perovskite solar battery based on the insertion of dye sensitization upconverter
CN104409642B (en) Preparation method of perovskite/P-type quantum dot composite solar cell
Zhang et al. A quasi-solid-state dye-sensitized solar cell based on the stable polymer-grafted nanoparticle composite electrolyte
CN106887520B (en) A kind of perovskite solar battery and preparation method thereof of additive auxiliary
CN107093641A (en) A kind of thin film solar cell based on inorganic flat hetero-junctions and preparation method thereof
CN102930993B (en) Dye solar cell two dye-sensitized nano gold doped electrode and preparation method
CN110350089B (en) Bi2O2S-modified SnO2Perovskite solar cell of electron transport layer and preparation method
CN110109311A (en) A kind of full-solid electrochromic device and preparation method thereof
CN109216557A (en) One kind being based on citric acid/SnO2Perovskite solar battery of electron transfer layer and preparation method thereof
CN103839687B (en) A kind of lamination dye-sensitized solar cells
CN106128772B (en) A kind of preparation method of vulcanized lead quantum dot photovoltaic battery
CN102394272A (en) Method for increasing organic polymer solar cell efficiency
CN108470833A (en) Application of the nanometic zinc oxide rod array of modifying interface as electron transfer layer in preparing perovskite solar cell
CN102544378A (en) Organic/inorganic hybridization solar cell based on zinc oxide (ZnO) homogeneous core-shell structure nanorod array and production method thereof
CN108447995A (en) Precursor solution and preparation method thereof, the preparation of solar cell electron transfer layer and solar cell
CN108963032A (en) The two-sided inorganic perovskite solar battery and its preparation method and application adulterated based on alkali metal ion and alkaline-earth metal ions
CN109065733A (en) A kind of full-inorganic perovskite solar battery and preparation method thereof
CN110350090A (en) Bi2O2The perovskite solar battery and preparation method of Se modifying interface
CN103137868A (en) Organic/ inorganic hybridization solar battery based on ternary nanometer array and preparation method thereof
CN106972104B (en) A kind of perovskite solar cell preparation method of alkali metal fluoride doping
CN104377036B (en) Method for preparing AgInS2 quantum dot sensitized TiO2 photoelectrode with In2S3 used as buffer layer
JP2019134159A (en) Solar cell
CN109659394A (en) A kind of preparation method and application of high quality full-inorganic perovskite thin film material
CN108807676A (en) Wide spectrum based on organic photoactive layers responds inorganic perovskite solar cell and its preparation method and application
CN103904217B (en) Multi-element organic/ inorganic hybridization solar cell and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant