CN107474660A - A kind of energy-saving heat preserving exterior wall latex paint, its preparation method and external wall - Google Patents
A kind of energy-saving heat preserving exterior wall latex paint, its preparation method and external wall Download PDFInfo
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- CN107474660A CN107474660A CN201710727293.7A CN201710727293A CN107474660A CN 107474660 A CN107474660 A CN 107474660A CN 201710727293 A CN201710727293 A CN 201710727293A CN 107474660 A CN107474660 A CN 107474660A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
Abstract
The present invention provides a kind of energy-saving heat preserving exterior wall latex paint, its preparation method and external wall, is related to energy-conserving and environment-protective technical fiel.A kind of energy-saving heat preserving exterior wall latex paint, is counted in parts by weight, is prepared the raw material of energy-saving heat preserving exterior wall latex paint and is included:30~50 parts of 1~5 part of carbon fiber powder, 5~15 parts of polyphenyl powder, 30~50 parts of mineral filler, 20~40 parts of acrylic emulsion, 2~16 parts of additive and water, additive include 1~5 part of dispersant.The energy-saving heat preserving exterior wall latex paint has good heat-insulating property, energy-saving safe, environmental protection, has preferable application prospect.A kind of preparation method of energy-saving heat preserving exterior wall latex paint, including:Raw material is mixed.This method preparation technology is simple, and controllability is strong, and preparation cost is low, is adapted to large-scale production.
Description
Technical field
The present invention relates to energy-conserving and environment-protective technical fiel, and more particularly to a kind of energy-saving heat preserving exterior wall latex paint, its preparation side
Method and external wall.
Background technology
In building coating field, emulsion paint be using synthetic resin acrylic emulsion as base-material add pigment, mineral filler and
A kind of water paint that various auxiliary agents are formulated, preparation technology is simple, easy for construction, and environmental pollution is small, and its application has been got over
Favored to get over by market.The major function of exterior wall latex paint is decoration and protection building surface, makes building appearance clean and tidy
It is attractive in appearance, it so as to reach the purpose of beautifying urban environment, while can play a part of protecting skin, extend it and use the longevity
Life.
Sustained, stable growth and people's living standards continue to improve with China's economy, building and decoration trade are just swift and violent
Development, people gradually recognize building energy consumption account for mankind's energy resource consumption proportion it is big, reach 30~40%, in the flourishing city summer
The energy that season freezes, warming is consumed has accounted for the 40~50% of building total energy consumption.Novel energy-conserving emulsion paint is for saving
Resource, environmental protection have material impact.
The content of the invention
It is an object of the invention to provide a kind of energy-saving heat preserving exterior wall latex paint, the energy-saving heat preserving exterior wall latex paint has good
Good heat-insulating property, energy-saving safe, environmental protection, has preferable application prospect.
Another object of the present invention is to provide a kind of preparation method of energy-saving heat preserving exterior wall latex paint, this method prepares work
Skill is simple, and controllability is strong, and preparation cost is low, is adapted to large-scale production.
A further object of the present invention is to provide a kind of external wall, and the external wall has good heat-insulating property, peace
Full energy-conservation.
The present invention is solved its technical problem and realized using following technical scheme.
The present invention proposes a kind of energy-saving heat preserving exterior wall latex paint, counts in parts by weight, prepares energy-saving heat preserving exterior wall latex paint
Raw material include:1~5 part of carbon fiber powder, 5~15 parts of polyphenyl powder, 30~50 parts of mineral filler, 20~40 parts of acrylic emulsion,
30~50 parts of 2~16 parts of additive and water, additive include 1~5 part of dispersant, it is preferable that dispersant include odium stearate,
At least two in neopelex, dodecyl phenol polyethenoxy ether, triethanolamine stearate, cetyl ammonium phosphate
Kind.
The present invention proposes a kind of preparation method of energy-saving heat preserving exterior wall latex paint, including:Raw material is mixed.
The present invention proposes a kind of external wall, and its outer layer is coated with above-mentioned energy-saving heat preserving exterior wall latex paint.
The beneficial effect of the embodiment of the present invention is:
A kind of energy-saving heat preserving exterior wall latex paint provided by the invention, it is fine as raw material, carbon using carbon fiber powder and polyester powder
Dimension powder has pore structure so that emulsion paint has good heat-insulating property, while carbon fiber powder intensity is high, can strengthen emulsion paint
Wearability;Carbon fiber powder light weight, reduce the load-carrying of building;Carbon fiber powder is corrosion-resistant, can strengthen the corrosion resistance of emulsion paint.
Polyphenyl powder have in light weight, intensity is high, insulating water-proof, anti-rain drop erosion the characteristics of, the cracking resistance of polyphenyl powder is excellent, it is nontoxic,
It is pollution-free, safety and environmental protection.Polyphenyl powder thermal conductivity factor is low, and thermal and insulating performance is good, is used in conjunction with increasing latex with carbon fiber powder
The thermal and insulating performance of paint.Polyphenyl powder is non-conductive, is used in conjunction with improving the security of emulsion paint with carbon fiber powder.Raw material also includes
Carbon aerogels.Carbon aerogels are the minimum loose structures of density, and the structure can strengthen the heat-insulating property of emulsion paint.Carbon fiber
Powder, polyphenyl powder and carbon aerogels are used in conjunction with synergistic function, be may be such that emulsion paint has preferable heat-insulating property, are subtracted
The transmission of few heat, reduces energy loss so that emulsion paint has the characteristics of energy-conserving and environment-protective, while carbon aerogels enhancing emulsion paint
Intensity.
Because carbon fiber powder is not soluble in water, latex is influenceed in order to prevent carbon fiber powder from being sunk in storage and transportation poly-
The heat insulation effect of paint, dispersant include odium stearate, neopelex, dodecyl phenol polyethenoxy ether, stearic acid
At least two in triethanolamine, cetyl ammonium phosphate, when being carried out compounding use, carbon fiber powder can be dramatically increased
Dispersiveness, strengthen the stability of emulsion paint, extend the holding time.
A kind of preparation method of energy-saving heat preserving exterior wall latex paint, this method preparation process is simple, makes raw material fully dispersed, mixed
Close, help to strengthen the performance of energy-saving heat preserving exterior wall latex paint, preparation cost is low, is adapted to large-scale production.
Embodiment
, below will be in the embodiment of the present invention to make the purpose, technical scheme and advantage of the embodiment of the present invention clearer
Technical scheme be clearly and completely described.Unreceipted actual conditions person, builds according to normal condition or manufacturer in embodiment
The condition of view is carried out.Agents useful for same or the unreceipted production firm person of instrument, it is the conventional production that can be obtained by commercially available purchase
Product.
Have below to a kind of energy-saving heat preserving exterior wall latex paint, its preparation method and the external wall of the embodiment of the present invention
Body explanation.
A kind of energy-saving heat preserving exterior wall latex paint provided in an embodiment of the present invention, counts, prepares outside energy-saving heat preserving in parts by weight
The raw material of wall emulsion paint includes:1~5 part of carbon fiber powder, 5~15 parts of polyphenyl powder, 30~50 parts of mineral filler, acrylic emulsion 20
30~50 parts of~40 parts, 2~16 parts of additive and water, additive include 1~5 part of dispersant, it is preferable that dispersant includes hard
In resin acid sodium, neopelex, dodecyl phenol polyethenoxy ether, triethanolamine stearate, cetyl ammonium phosphate
At least two.
Further, in the preferred embodiment of the present invention, count in parts by weight, raw material includes:1~5 part of carbon fiber powder,
5~15 parts of polyphenyl powder, 35~45 parts of mineral filler, 25~35 parts of acrylic emulsion, 10~16 parts of additive and water 35~45
Part.
Further, in the preferred embodiment of the present invention, the particle diameter of carbon fiber powder and polyphenyl powder is 10~30 μm.Carbon is fine
Dimension powder and polyphenyl powder footpath is small helps to disperse, can be uniformly dispersed in the presence of dispersant, make the stable performance of emulsion paint.
Carbon fiber powder is also ground carbon fiber, be high-strength high-modules carbon fibre long filament is surface-treated through special technique, ground,
The micro- isometric cylindrical particulate screening, screen, being obtained after high temperature drying, it remains numerous premium properties of carbon fiber,
It is the composite filler of function admirable and shape is tiny, surface is pure.Carbon fiber has pore structure, and the structure causes
Emulsion paint has good heat-insulating property;Carbon fiber powder intensity is high, can strengthen the wearability of emulsion paint;Carbon fiber powder light weight,
Reduce the load-carrying of building;Carbon fiber powder is corrosion-resistant, can strengthen the corrosion resistance of emulsion paint.
Polyphenyl powder is the fine powder after polyphenyl particle heat-insulating mortar crushes, and polyphenyl powder has that in light weight, intensity is high, heat-insulated anti-
The characteristics of water, anti-rain drop erosion, the cracking resistance of polyphenyl powder is excellent, nontoxic, pollution-free, safety and environmental protection.Polyphenyl powder thermal conductivity factor
Low, thermal and insulating performance is good, is used in conjunction with increasing the thermal and insulating performance of emulsion paint with carbon fiber powder.Polyphenyl powder is non-conductive,
The security for improving emulsion paint is mixed with carbon fiber powder.
Conventional energy-saving heat preserving exterior wall latex paint primary raw material is mineral filler, such as powdered whiting, wollastonite in powder, thin,tough silk cloud
Female powder, silica flour etc..When adding other mineral fillers on a small quantity, the performance of energy-saving heat preserving exterior wall latex paint can be strengthened, at this
In invention, other mineral fillers include talcum powder, calcined kaolin, mica powder, precipitated calcium carbonate.The particle diameter of mineral filler is got over
Small, scattered more uniform, the performance of emulsion paint is better.Preferably, the particle diameter of mineral filler is 10~20 μm.
Emulsion has direct influence to the quality of emulsion paint quality.Emulsion plays increase in energy-saving heat preserving exterior wall latex paint
Coating intensity, improve the effect for smearing scrubbing resistance number.In the present invention, acrylic emulsion and other raw materials and each additive
Species, proportioning make materials compatibility good, and obtained energy-saving heat preserving exterior wall latex paint performance is good.In embodiments of the present invention, mainly
From acrylate acrylic emulsion, pure third acrylic emulsion and the acrylic emulsion of silicon third etc..
Further, in the preferred embodiment of the present invention, count in parts by weight, raw material also includes carbon aerogels 0.1~1
Part.Carbon aerogels are the minimum loose structures of density, and the structure can strengthen the heat-insulating property of emulsion paint.Carbon fiber powder, polyphenyl
Powder and carbon aerogels are used in conjunction with may be such that emulsion paint has preferable heat-insulating property, reduce energy loss so that emulsion paint has
There is the characteristics of energy-conserving and environment-protective.
In the preparation process of emulsion paint, different additives is added according to being actually needed, to reach required performance.
In the preferred embodiment of the present invention, additive also includes in thickener, defoamer, Antisepticize and mildew preventive, coalescents, pH adjusting agent
At least one.
Thickener is mainly used in improving and increasing energy-saving heat preserving as additive important in energy-saving heat preserving exterior wall latex paint
The viscosity of exterior wall latex paint, certain rheological characteristic is kept, prevent sagging phenomenon occur in construction, while assign outside energy-saving heat preserving
Wall emulsion paint excellent mechanical performance and storage stability.Because carbon fiber powder is not soluble in water, in order to prevent carbon fiber powder from storing up
Deposit and transportation in sink poly- and influence the heat insulation effect of emulsion paint, in embodiments of the present invention, thickener selects association type alkali
At least two in swelling type thickener, hydroxyethyl cellulose, hydroxymethyl cellulose., can in the above-mentioned thickener of compounding use
To strengthen the dispersion stabilization of carbon fiber powder, emulsion paint is set to occur without layering, heavy poly- phenomenon.Preferably, thickener is nonionic
The mixture of hydrophobically modified ethoxylated urethanes copolymer and hydroxyethyl cellulose.
Dispersant reduces the jitter time of raw material, stabilising dispersions, has and reduces flocculation phenomenon, strengthens stability, lifting
Gloss, increase the effect of color developing.Dispersant includes anionic dispersing agent, non-ionic dispersing agent, hydrophobic type dispersant.By
Not soluble in water in carbon fiber powder, the insulation for gathering to prevent carbon fiber powder from being sunk in storage and transportation and influenceing emulsion paint is imitated
Fruit, dispersant include odium stearate, neopelex, dodecyl phenol polyethenoxy ether, triethanolamine stearate, ten
At least two in six alkyl phosphoric acid ammoniums.By above-mentioned surfactant carry out two kinds particularly a variety of compounding uses when, Ke Yixian
The dispersiveness of increase carbon fiber powder is write, strengthens the stability of emulsion paint, extends the holding time.Preferably, dodecylphenol polyoxy
Vinethene and neopelex use simultaneously, preferable to the dispersion effect of carbon fiber powder.
A large amount of bubbles can be produced in the mixing process of raw material, these bubbles can influence energy-saving heat preserving in work progress
The planarization and mechanical performance of exterior wall latex paint.Defoamer can suppress foam and produce, eliminate foam, be added in preparation process
Appropriate defoamer, the stability and performance of energy-saving heat preserving exterior wall latex paint can be improved.In an embodiment of the present invention, defoamer
Organic silicon defoamer and organic-silicon-modified defoamer etc. can be used.
When energy-saving heat preserving exterior wall latex paint is used in building etc. it is necessary to have the performance of anticorrosive mildewproof, avoid applying
Body is covered by the corrosion of the corrosive substances such as chemical substance and corroding for mould.Also include Antisepticize and mildew preventive in additive to improve
The performance of energy-saving heat preserving exterior wall latex paint.
Coalescents make energy-conservation heat preserving exterior wall emulsion paint as one of additive important in energy-saving heat preserving exterior wall latex paint
Reach workability and quality of forming film.The film forming procedure of energy-saving heat preserving exterior wall latex paint is complex, from scattered polymer particles
Grain is to being mutually coalesced as overall process.Coalescents promote the Plastic Flow and elastic deformation of latex particle, make particle table
Thin-skinnedization, promote the easy compressive deformation of polymer particle, merge film forming;Coalescents can reduce acrylic emulsion and energy-saving heat preserving
The MFT of exterior wall latex paint.
PH adjusting agent is used for the pH value of energy-saving adjusting heat preserving exterior wall emulsion paint, increases the stabilization of energy-saving heat preserving exterior wall latex paint
Property, while also there is wetting, disperse.In an embodiment of the present invention, pH adjusting agent includes organic ammonium conditioning agent etc..
In order that the energy-saving heat preserving exterior wall latex paint that must be prepared has preferably mechanical performance and chemical property, additive bag
Include 1~3 part of thickener, 1~2 part of defoamer, 1~3 part of Antisepticize and mildew preventive, 1~3 part of coalescents, 0.1~1 part of pH adjusting agent
At least one of.
The embodiment of the present invention additionally provides a kind of preparation method of energy-saving heat preserving exterior wall latex paint, including:
Raw material is weighed in proportion, by carbon nanopowder, polyphenyl powder, water, thickener, dispersant, part defoamer and anti-corrosion
Mould inhibitor is sufficiently mixed 10~20min of stirring under 500~600rpm stir speed (S.S.).
After stirring, mineral filler is added, in an embodiment of the present invention, other mineral fillers can also be added,
5~40min of coarse dispersion under 1000~1500rpm stir speed (S.S.).
Coarse dispersion mashing is scattered.Fineness is tested, preferably, fineness is less than 35 μm, produces finely dispersed pigment
Slurries.
Acrylic emulsion, coalescents, remaining defoamer and the levelling agent of metering are slowly added in slurries.
Under conditions of 300~500rpm, after stirring at low speed is uniform, the pH value of pH adjusting agent regulation system is added, is produced after stirring
Energy-saving heat preserving exterior wall latex paint sample.
The feature and performance of the present invention are described in further detail with reference to embodiments.
Embodiment 1
A kind of energy-saving heat preserving exterior wall latex paint is present embodiments provided, is counted in parts by weight, including:
1 part of carbon fiber powder, 30 parts of mineral filler, 20 parts of acrylic emulsion, 1 part of thickener, 1 part of dispersant, defoamer 1
Part, 1 part of Antisepticize and mildew preventive, 1 part of coalescents, 0.1 part of pH adjusting agent and 30 parts of water.The particle diameter of carbon fiber powder is 30 μm.Point
Powder is odium stearate.
Mainly it is made by the following method:
The stirring of carbon fiber powder, water, thickener, dispersant, part defoamer and Antisepticize and mildew preventive in 500rpm is fast
Stirring 10min is sufficiently mixed under rate.
After stirring, mineral filler, the coarse dispersion 5min under 1000rpm stir speed (S.S.) are added.Coarse dispersion is beaten
Slurry is scattered, tests fineness, and fineness is 35 μm, produces finely dispersed slurries.
Acrylic emulsion, coalescents, remaining defoamer and the levelling agent of metering are slowly added in slurries.
Under conditions of 300rpm, after stirring at low speed is uniform, the pH value of pH adjusting agent regulation system is added, energy-conservation is produced after stirring and is protected
Warm exterior wall latex paint sample.
Embodiment 2
A kind of energy-saving heat preserving exterior wall latex paint is present embodiments provided, is counted in parts by weight, including:
5 parts of polyphenyl powder, 33 parts of mineral filler, 25 parts of acrylic emulsion, 2 parts of thickener, 2 parts of dispersant, 1 part of defoamer,
35 parts of 1 part of Antisepticize and mildew preventive, 1 part of coalescents, 0.4 part of pH adjusting agent and water.The particle diameter of carbon fiber powder and polyphenyl powder is 25 μ
m.Dispersant is neopelex.
Mainly it is made by the following method:
By polyphenyl powder, water, thickener, dispersant, part defoamer and Antisepticize and mildew preventive 600rpm stir speed (S.S.)
Under be sufficiently mixed stirring 20min.
After stirring, mineral filler, the coarse dispersion 40min under 1500rpm stir speed (S.S.) are added.Coarse dispersion is beaten
Slurry is scattered, tests fineness, and fineness is 35 μm, produces finely dispersed slurries.
Acrylic emulsion, coalescents, remaining defoamer and the levelling agent of metering are slowly added in slurries.
Under conditions of 300rpm, after stirring at low speed is uniform, the pH value of pH adjusting agent regulation system is added, energy-conservation is produced after stirring and is protected
Warm exterior wall latex paint sample.
Embodiment 3
A kind of energy-saving heat preserving exterior wall latex paint is present embodiments provided, is counted in parts by weight, including:
2 parts of carbon fiber powder, 8 parts of polyphenyl powder, 38 parts of mineral filler, 32 parts of acrylic emulsion, 2 parts of thickener, dispersant 4
Part, 1 part of defoamer, 2 parts of Antisepticize and mildew preventive, 2 parts of coalescents, 0.8 part of pH adjusting agent and 45 parts of water.Carbon fiber powder and polyphenyl
The particle diameter of powder is 10 μm.Dispersant triethanolamine stearate.
Mainly it is made by the following method:
Carbon fiber powder, polyphenyl powder, water, thickener, dispersant, part defoamer and Antisepticize and mildew preventive are mixed
10min。
After stirring, mineral filler, coarse dispersion 40min are added.
Acrylic emulsion, coalescents, remaining defoamer and the levelling agent of metering are slowly added in slurries.
Under conditions of 300rpm, after stirring, the pH value of pH adjusting agent regulation system is added, is produced after stirring outside energy-saving heat preserving
Wall emulsion paint sample.
Embodiment 4
A kind of energy-saving heat preserving exterior wall latex paint is present embodiments provided, is counted in parts by weight, including:
2 parts of carbon fiber powder, 8 parts of polyphenyl powder, 39 parts of mineral filler, 35 parts of acrylic emulsion, 3 parts of thickener, dispersant 5
Part, 2 parts of defoamer, 3 parts of Antisepticize and mildew preventive, 3 parts of coalescents, 1 part of pH adjusting agent and 50 parts of water.Carbon fiber powder and polyphenyl powder
Particle diameter be 40 μm.Dispersant is the mixture of triethanolamine stearate and cetyl ammonium phosphate.
Mainly it is made by the following method:
By carbon fiber powder, polyphenyl powder, water, thickener, dispersant, part defoamer and Antisepticize and mildew preventive 500rpm's
Stirring 20min is sufficiently mixed under stir speed (S.S.).
After stirring, mineral filler, the coarse dispersion 20min under 1200rpm stir speed (S.S.) are added.Coarse dispersion is beaten
Slurry is scattered, tests fineness, and fineness is 35 μm, produces finely dispersed slurries.
Acrylic emulsion, coalescents, remaining defoamer and the levelling agent of metering are slowly added in slurries.
Under conditions of 400rpm, after stirring at low speed is uniform, the pH value of pH adjusting agent regulation system is added, energy-conservation is produced after stirring and is protected
Warm exterior wall latex paint sample.
Embodiment 5
A kind of energy-saving heat preserving exterior wall latex paint is present embodiments provided, is counted in parts by weight, including:
4 parts of carbon fiber powder, 12 parts of polyphenyl powder, 50 parts of mineral filler, 30 parts of acrylic emulsion, 2 parts of thickener, dispersant 4
Part, 2 parts of defoamer, 3 parts of Antisepticize and mildew preventive, 3 parts of coalescents, 0.7 part of pH adjusting agent and 37 parts of water.Carbon fiber powder and polyphenyl
The particle diameter of powder is 22 μm.Dispersant is the mixture of odium stearate and cetyl ammonium phosphate.
Mainly it is made by the following method:
By carbon fiber powder, polyphenyl powder, water, thickener, dispersant, part defoamer and Antisepticize and mildew preventive 530rpm's
Stirring 13min is sufficiently mixed under stir speed (S.S.).
After stirring, mineral filler, the coarse dispersion 10min under 800rpm stir speed (S.S.) are added.Coarse dispersion is beaten
Slurry is scattered, obtains finely dispersed slurries.
Acrylic emulsion, coalescents, remaining defoamer and the levelling agent of metering are slowly added in slurries.
Under conditions of 400rpm, after stirring at low speed is uniform, the pH value of pH adjusting agent regulation system is added, energy-conservation is produced after stirring and is protected
Warm exterior wall latex paint sample.
Embodiment 6
A kind of energy-saving heat preserving exterior wall latex paint is present embodiments provided, is counted in parts by weight, including:
1 part of carbon fiber powder, 5 parts of polyphenyl powder, 0.1 part of carbon aerogels, 30 parts of mineral filler, 40 parts of acrylic emulsion, thickening
50 parts of 1 part of agent, 1 part of dispersant, 2 parts of defoamer, 3 parts of Antisepticize and mildew preventive, 3 parts of coalescents, 0.1 part of pH adjusting agent and water.
The particle diameter of carbon fiber powder and polyphenyl powder is 20 μm.Dispersant is odium stearate, the mixture of neopelex.
Mainly it is made by the following method:
By carbon fiber powder, polyphenyl powder, carbon aerogels, water, thickener, dispersant, part defoamer and Antisepticize and mildew preventive
Stirring 15min is sufficiently mixed under 550rpm stir speed (S.S.).
After stirring, mineral filler, the coarse dispersion 25min under 1100rpm stir speed (S.S.) are added.Coarse dispersion is beaten
Slurry is scattered, tests fineness, and fineness is 35 μm, produces finely dispersed slurries.
Acrylic emulsion, coalescents, remaining defoamer and the levelling agent of metering are slowly added in slurries.
Under conditions of 500rpm, after stirring at low speed is uniform, the pH value of pH adjusting agent regulation system is added, energy-conservation is produced after stirring and is protected
Warm exterior wall latex paint sample.
Embodiment 7
A kind of energy-saving heat preserving exterior wall latex paint is present embodiments provided, is counted in parts by weight, including:
3 parts of carbon fiber powder, 10 parts of polyphenyl powder, 0.5 part of carbon aerogels, 40 parts of mineral filler, 30 parts of acrylic emulsion, thickening
40 parts of 2 parts of agent, 3 parts of dispersant, 2 parts of defoamer, 3 parts of Antisepticize and mildew preventive, 3 parts of coalescents, 0.5 part of pH adjusting agent and water.
The average grain diameter of carbon fiber powder and polyphenyl powder is 20 μm.Dispersant is dodecyl phenol polyethenoxy ether and DBSA
The mixture of sodium.
Mainly it is made by the following method:
By carbon fiber powder, polyphenyl powder, carbon aerogels, water, thickener, dispersant, part defoamer and Antisepticize and mildew preventive
Stirring 15min is sufficiently mixed under 550rpm stir speed (S.S.).
After stirring, mineral filler, the coarse dispersion 30min under 1250rpm stir speed (S.S.) are added.Coarse dispersion is beaten
Slurry is scattered, tests fineness, and fineness is 35 μm, produces finely dispersed slurries.
Acrylic emulsion, coalescents, remaining defoamer and the levelling agent of metering are slowly added in slurries.
Under conditions of 100rpm, after stirring at low speed is uniform, the pH value of pH adjusting agent regulation system is added, energy-conservation is produced after stirring and is protected
Warm exterior wall latex paint sample.
Comparative example 1
This comparative example provides a kind of emulsion paint, counts in parts by weight, including:
30 parts of mineral filler, 20 parts of acrylic emulsion, 1 part of thickener, 1 part of dispersant, 1 part of defoamer, Antisepticize and mildew preventive 1
Part, 1 part of coalescents, 0.1 part of pH adjusting agent and 30 parts of water.
Mainly it is made by the following method:
By water, thickener, odium stearate, part defoamer and Antisepticize and mildew preventive under 500rpm stir speed (S.S.) fully
Mix 10min.
After stirring, mineral filler, the coarse dispersion 5min under 1000rpm stir speed (S.S.) are added.Coarse dispersion is beaten
Slurry is scattered, tests fineness, and fineness is 35 μm, produces finely dispersed slurries.
Acrylic emulsion, coalescents, remaining defoamer and the levelling agent of metering are slowly added in slurries.
Under conditions of 300rpm, after stirring at low speed is uniform, the pH value of pH adjusting agent regulation system is added, energy-conservation is produced after stirring and is protected
Warm exterior wall latex paint sample.
Comparative example 2
This comparative example provides a kind of exterior wall latex paint bought on the market.
Test example
Embodiment 1~7, energy-saving heat preserving exterior wall latex paint prepared by comparative example 1 and the emulsion paint that comparative example 2 provides is chosen to enter
Row performance detection is as a result as follows:
The performance test results of table 1
As shown in Table 1, compared to comparative example 1 and comparative example 2, the energy-saving heat preserving exterior wall latex paint that embodiment 1~7 provides is equal
With preferable stability, heat insulating ability, have good workability, drying time is short, and outward appearance is preferable.Wherein, embodiment 6 and embodiment 7
Carbon fiber powder, polyphenyl powder and carbon aerogels are included in raw material, dispersant includes two kinds of surfactants so that the dispersiveness of raw material
Preferably, there is provided energy-saving heat preserving exterior wall latex paint heat-insulating property it is preferable.The energy-saving heat preserving exterior wall latex paint that embodiment 7 provides is most
It is good, illustrate that the raw material of the offer of embodiment 7 and its proportioning, preparation method are more scientific and reasonable.
In summary, a kind of energy-saving heat preserving exterior wall latex paint provided by the invention, using carbon fiber powder and polyester powder conduct
Raw material, carbon fiber powder have pore structure so that emulsion paint has good heat-insulating property, while carbon fiber powder intensity is high, can
Strengthen the wearability of emulsion paint;Carbon fiber powder light weight, reduce the load-carrying of building;Carbon fiber powder is corrosion-resistant, can strengthen emulsion paint
Corrosion resistance.Polyphenyl powder have in light weight, intensity is high, insulating water-proof, anti-rain drop erosion the characteristics of, the cracking resistance of polyphenyl powder
It is excellent, nontoxic, pollution-free, safety and environmental protection.Polyphenyl powder thermal conductivity factor is low, and thermal and insulating performance is good, makes jointly with carbon fiber powder
With the thermal and insulating performance of increase emulsion paint.Polyphenyl powder is non-conductive, is used in conjunction with improving the security of emulsion paint with carbon fiber powder.
Raw material also includes carbon aerogels.Carbon aerogels are the minimum loose structures of density, and the structure can strengthen the heat insulating ability of emulsion paint
Energy.Carbon fiber powder, polyphenyl powder and carbon aerogels are used in conjunction with synergistic function, be may be such that emulsion paint has and are preferably protected
Warm nature energy, the transmission of heat is reduced, reduce energy loss so that emulsion paint has the characteristics of energy-conserving and environment-protective.
Because carbon fiber powder is not soluble in water, latex is influenceed in order to prevent carbon fiber powder from being sunk in storage and transportation poly-
The heat insulation effect of paint, dispersant include odium stearate, neopelex, dodecyl phenol polyethenoxy ether, stearic acid
At least two in triethanolamine, cetyl ammonium phosphate, when being carried out compounding use, carbon fiber powder can be dramatically increased
Dispersiveness, strengthen the stability of emulsion paint, extend the holding time.
Embodiments described above is part of the embodiment of the present invention, rather than whole embodiments.The reality of the present invention
The detailed description for applying example is not intended to limit the scope of claimed invention, but is merely representative of the selected implementation of the present invention
Example.Based on the embodiment in the present invention, what those of ordinary skill in the art were obtained under the premise of creative work is not made
Every other embodiment, belongs to the scope of protection of the invention.
Claims (10)
1. a kind of energy-saving heat preserving exterior wall latex paint, it is characterised in that count in parts by weight, prepare the energy-saving heat preserving exterior wall latex
The raw material of paint includes:1~5 part of carbon fiber powder, 5~15 parts of polyphenyl powder, 30~50 parts of mineral filler, acrylic emulsion 20~40
Part, 2~16 parts of additive and 30~50 parts of water, the additive include 1~5 part of dispersant, it is preferable that the dispersant bag
Include odium stearate, neopelex, dodecyl phenol polyethenoxy ether, triethanolamine stearate, cetyl phosphoric acid
At least two in ammonium.
2. energy-saving heat preserving exterior wall latex paint according to claim 1, it is characterised in that count in parts by weight, the raw material
Including:1~5 part of the carbon fiber powder, 5~15 parts of the polyphenyl powder, 35~45 parts of the mineral filler, the acrylic emulsion
35~45 parts of 25~35 parts, 10~16 parts of the additive and the water.
3. energy-saving heat preserving exterior wall latex paint according to claim 1, it is characterised in that count in parts by weight, the raw material
Also include 0.1~1 part of carbon aerogels.
4. energy-saving heat preserving exterior wall latex paint according to claim 1, it is characterised in that the additive also includes thickening
At least one of agent, defoamer, Antisepticize and mildew preventive, coalescents and pH adjusting agent.
5. energy-saving heat preserving exterior wall latex paint according to claim 4, it is characterised in that count in parts by weight, the addition
Agent also includes 1~3 part of the thickener, 1~2 part of the defoamer, 1~3 part of the Antisepticize and mildew preventive, the coalescents 1
At least one of~3 parts and 0.1~1 part of the pH adjusting agent.
6. energy-saving heat preserving exterior wall latex paint according to claim 1, it is characterised in that the carbon fiber powder and the polyphenyl
The particle diameter of powder is 10~30 μm.
A kind of 7. preparation method of energy-saving heat preserving exterior wall latex paint as described in any one of claim 1 to 6, it is characterised in that
Including:The raw material is mixed.
8. the preparation method of energy-saving heat preserving exterior wall latex paint according to claim 7, it is characterised in that including:By described in
Carbon fiber powder, the polyphenyl powder are scattered in described with the dispersant in the additive, thickener, defoamer, Antisepticize and mildew preventive
In water, mix that to carry out mashing scattered with the mineral filler, with the defoamer in the acrylic emulsion and the additive, into
Film auxiliary agent, pH adjusting agent mixing.
9. the preparation method of energy-saving heat preserving exterior wall latex paint according to claim 8, it is characterised in that mashing dispersion mixing
The jitter time of thing is 10~30min, and it is 1000~1500rpm to disperse rotating speed.
10. a kind of external wall, it is characterised in that the outer layer coating of the external wall is just like any one of claim 1 to 6 institute
The energy-saving heat preserving exterior wall latex paint stated.
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Cited By (3)
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CN108892986A (en) * | 2018-06-13 | 2018-11-27 | 合肥欧克斯新型建材有限公司 | A kind of energy saving and environment friendly exterior wall latex paint and preparation method thereof |
CN113493639A (en) * | 2021-08-04 | 2021-10-12 | 广东宝伯力新材料科技有限公司 | Water-based epoxy self-leveling finish paint and preparation method thereof |
CN113512340A (en) * | 2021-08-03 | 2021-10-19 | 广东宝伯力新材料科技有限公司 | Water-based colored ultraviolet-proof finish paint and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108892986A (en) * | 2018-06-13 | 2018-11-27 | 合肥欧克斯新型建材有限公司 | A kind of energy saving and environment friendly exterior wall latex paint and preparation method thereof |
CN113512340A (en) * | 2021-08-03 | 2021-10-19 | 广东宝伯力新材料科技有限公司 | Water-based colored ultraviolet-proof finish paint and preparation method thereof |
CN113493639A (en) * | 2021-08-04 | 2021-10-12 | 广东宝伯力新材料科技有限公司 | Water-based epoxy self-leveling finish paint and preparation method thereof |
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Application publication date: 20171215 |