CN107474513A - A kind of fire-retardant lithium battery precise plastic part formula - Google Patents

A kind of fire-retardant lithium battery precise plastic part formula Download PDF

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Publication number
CN107474513A
CN107474513A CN201710931934.0A CN201710931934A CN107474513A CN 107474513 A CN107474513 A CN 107474513A CN 201710931934 A CN201710931934 A CN 201710931934A CN 107474513 A CN107474513 A CN 107474513A
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CN
China
Prior art keywords
5phr
fire
lithium battery
plastic part
formula
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710931934.0A
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Chinese (zh)
Inventor
严焕标
龙志兴
吴琪丰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Baili Plastic Industry Co Ltd
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Zhejiang Baili Plastic Industry Co Ltd
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Publication date
Application filed by Zhejiang Baili Plastic Industry Co Ltd filed Critical Zhejiang Baili Plastic Industry Co Ltd
Priority to CN201710931934.0A priority Critical patent/CN107474513A/en
Publication of CN107474513A publication Critical patent/CN107474513A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/22Halogen free composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of fire-retardant lithium battery precise plastic part formula, the formula is made up of by weight ratio following composition:65~90phr makrolon, 5~20phr acrylonitrile butadient styrenes, 5~20phr halogen-free flame retardants, 0.1~5phr antioxidant, 0.1~5phr light stabilizers, 0.1~5phr lubricants, 0.1~5phr viscosity-controlling agents, 0.1~5phr compatilizers, 0.1~5phr impact modifiers, 0.1~5phr surface promoters, 0.1~5phr fire retarding synergists, 0.1~5phr inorganic pigments and 0.1~5phr organic pigments.The fire-retardant lithium battery precise plastic part after its injection molding is set on the one hand to have surface gloss good, easily shaping, the characteristics of laser marking effect is good, on the other hand with high-low temperature resistant impact, halogen-free flameproof and heat-proof aging ability are strong the characteristics of, it is hardly damaged, greatly prolongs service life.

Description

A kind of fire-retardant lithium battery precise plastic part formula
Technical field
The present invention relates to a kind of working of plastics formula, more particularly to a kind of fire-retardant lithium battery precise plastic part formula.
Background technology
Lithium battery is that one kind by lithium metal or lithium alloy is negative material, uses the battery of non-aqueous electrolytic solution.Originally Because the chemical characteristic of lithium metal is very active so that processing, preservation and all very high to environmental requirement, the institute of use of lithium metal It is not applied for a long time with lithium battery.With the continuous development of scientific technology, in recent years, lithium battery with its high-energy-density, Memory-less effect, have extended cycle life, be pollution-free, that the characteristics of in light weight and self discharge is small, is widely used in military and civilian is small-sized In electrical equipment.Lithium battery is in application process at present, in order to improve the security used, can all be set outside lithium battery a kind of fire-retardant Lithium battery precise plastic part, this fire-retardant lithium battery precise plastic part not only need to have high-low temperature resistant impact, halogen-free flameproof, resistance to The characteristics of heat ageing, and surface gloss will get well, and be applicable laser marking.And fire-retardant lithium battery precise plastic part in the market Because material prescription preparation is unreasonable, the fire-retardant lithium battery precise plastic part of its injection molding is not only set surface gloss one to be present As, the shortcomings that laser marking effect difference, and high-low temperature resistant impact, halogen-free flameproof and heat-proof aging ability, it is easily damaged, uses Short life, furthermore the phenomenon of not easy-formation occurs in manufacturing process.
The content of the invention
In view of the above-mentioned problems, the problem of present invention intends to solve is to provide a kind of rational fire-retardant lithium battery precise plastic of configuration Part formula.
To reach above-mentioned purpose, the present invention uses following technical scheme:A kind of fire-retardant lithium battery precise plastic part formula, should Formula is made up of by weight ratio following composition:65~90phr makrolon, 5~20phr acrylonitrile-butadiene-styrene (ABS)s Copolymer, 5~20phr halogen-free flame retardants, 0.1~5phr antioxidant, 0.1~5phr light stabilizers, 0.1~5phr lubricants, 0.1~5phr viscosity-controlling agents, 0.1~5phr compatilizers, 0.1~5phr impact modifiers, 0.1~5phr surfaces promote Agent, 0.1~5phr fire retarding synergists, 0.1~5phr inorganic pigments and 0.1~5phr organic pigments.
Preferably, the formula is made up of by weight ratio following composition:70~82phr makrolon, 8~16phr Acrylonitrile-butadiene-styrene copolymer, 6~13phr halogen-free flame retardants, 0.1~5phr antioxidant, 0.1~5phr light are stable Agent, 0.1~5phr lubricants, 0.1~5phr viscosity-controlling agents, 0.1~5phr compatilizers, 0.1~5phr impact modifiers, 0.1~5phr surface promoters, 0.1~5phr fire retarding synergists, 0.1~5phr inorganic pigments and 0.1~5phr organic pigments.
Effective achievement of the present invention:The present invention passes through the rational formula that repeatedly test is completed more than using, and is molded into it On the one hand fire-retardant lithium battery precise plastic part after type has surface gloss good, be easily molded, the good spy of laser marking effect Point, on the other hand with the characteristics of high-low temperature resistant impacts, halogen-free flameproof and heat-proof aging ability are strong, it is hardly damaged, greatly prolongs Service life.
Embodiment
In order that those skilled in the art are better understood from the present invention program, below in conjunction with embodiment to the present invention's Technical scheme carries out clear, complete description.
The invention discloses a kind of fire-retardant lithium battery precise plastic part formula, the formula by following composition by weight ratio Composition:65~90phr makrolon, 5~20phr acrylonitrile-butadiene-styrene copolymers, 5~20phr halogen-free flame retardants, 0.1~5phr antioxidant, 0.1~5phr light stabilizers, 0.1~5phr lubricants, 0.1~5phr viscosity-controlling agents, 0.1~ 5phr compatilizers, 0.1~5phr impact modifiers, 0.1~5phr surface promoters, 0.1~5phr fire retarding synergists, 0.1 ~5phr inorganic pigments and 0.1~5phr organic pigments.Specific embodiment is as follows:
Embodiment 1:The formula is made up of by weight ratio following composition:73phr makrolon, 8phr acrylic nitrile-butadienes Diene-styrene copolymer, 11phr halogen-free flame retardants, 1.1phr antioxidant, 0.6phr light stabilizers, 0.4phr lubricants, 0.6phr viscosity-controlling agents, 0.8phr compatilizers, 1.2phr impact modifiers, 0.7phr surface promoters, 0.7phr are fire-retardant Synergist, 0.9phr inorganic pigments and 1phr organic pigments.
Embodiment 2:The formula is made up of by weight ratio following composition:71phr makrolon, 10phr acrylic nitrile-butadienes Diene-styrene copolymer, 12phr halogen-free flame retardants, 0.8phr antioxidant, 0.6phr light stabilizers, 0.4phr lubricants, 0.5phr viscosity-controlling agents, 0.7phr compatilizers, 1phr impact modifiers, 0.7phr surface promoters, the fire-retardant associations of 0.4phr Imitate agent, 0.9phr inorganic pigments and 1phr organic pigments.
The present invention passes through the rational formula that repeatedly test is completed more than using, and makes the fire-retardant lithium battery after its injection molding smart The characteristics of on the one hand close working of plastics has surface gloss good, be easily molded, and laser marking effect is good, on the other hand with resistance to height The characteristics of low-temperature impact, strong halogen-free flameproof and heat-proof aging ability, it is hardly damaged, greatly prolongs service life.
Obviously, described embodiment is only the part of the embodiment of the present invention, rather than whole embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made Embodiment, it should all belong to the scope of protection of the invention.

Claims (2)

  1. A kind of 1. fire-retardant lithium battery precise plastic part formula, it is characterised in that:The formula is by following composition group by weight ratio Into:65~90phr makrolon, 5~20phr acrylonitrile-butadiene-styrene copolymers, 5~20phr halogen-free flame retardants, 0.1~5phr antioxidant, 0.1~5phr light stabilizers, 0.1~5phr lubricants, 0.1~5phr viscosity-controlling agents, 0.1~ 5phr compatilizers, 0.1~5phr impact modifiers, 0.1~5phr surface promoters, 0.1~5phr fire retarding synergists, 0.1 ~5phr inorganic pigments and 0.1~5phr organic pigments.
  2. 2. fire-retardant lithium battery precise plastic part formula according to claim 1, it is characterised in that:The formula is by following composition Form by weight ratio:70~82phr makrolon, 8~16phr acrylonitrile-butadiene-styrene copolymers, 6~ 13phr halogen-free flame retardants, 0.1~5phr antioxidant, 0.1~5phr light stabilizers, 0.1~5phr lubricants, 0.1~5phr are sticked Spend conditioning agent, 0.1~5phr compatilizers, 0.1~5phr impact modifiers, 0.1~5phr surface promoters, 0.1~5phr Fire retarding synergist, 0.1~5phr inorganic pigments and 0.1~5phr organic pigments.
CN201710931934.0A 2017-09-21 2017-09-21 A kind of fire-retardant lithium battery precise plastic part formula Withdrawn CN107474513A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710931934.0A CN107474513A (en) 2017-09-21 2017-09-21 A kind of fire-retardant lithium battery precise plastic part formula

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710931934.0A CN107474513A (en) 2017-09-21 2017-09-21 A kind of fire-retardant lithium battery precise plastic part formula

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CN107474513A true CN107474513A (en) 2017-12-15

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103180995A (en) * 2010-09-24 2013-06-26 拜耳知识产权有限责任公司 Flame-protected impact-modified battery housing based on polycarbonates ii
CN105001612A (en) * 2015-08-04 2015-10-28 苏州博云塑业有限公司 Highlight halogen-free flame-retardant PC/ABS composite material for electric appliance shell

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103180995A (en) * 2010-09-24 2013-06-26 拜耳知识产权有限责任公司 Flame-protected impact-modified battery housing based on polycarbonates ii
CN105001612A (en) * 2015-08-04 2015-10-28 苏州博云塑业有限公司 Highlight halogen-free flame-retardant PC/ABS composite material for electric appliance shell

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Application publication date: 20171215

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