CN107459422A - One kind utilizes salt resistance Liquid Fertilizer and its preparation and application made of nano-sized carbon glue - Google Patents
One kind utilizes salt resistance Liquid Fertilizer and its preparation and application made of nano-sized carbon glue Download PDFInfo
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- CN107459422A CN107459422A CN201710662210.0A CN201710662210A CN107459422A CN 107459422 A CN107459422 A CN 107459422A CN 201710662210 A CN201710662210 A CN 201710662210A CN 107459422 A CN107459422 A CN 107459422A
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 107
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 82
- 150000003839 salts Chemical class 0.000 title claims abstract description 77
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 76
- 239000002105 nanoparticle Substances 0.000 title claims abstract description 68
- 239000007788 liquid Substances 0.000 title claims abstract description 62
- 239000003292 glue Substances 0.000 title claims abstract description 61
- 238000002360 preparation method Methods 0.000 title claims description 12
- 239000002689 soil Substances 0.000 claims abstract description 58
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004021 humic acid Substances 0.000 claims abstract description 18
- 239000011573 trace mineral Substances 0.000 claims abstract description 15
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 15
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims abstract description 14
- 235000019796 monopotassium phosphate Nutrition 0.000 claims abstract description 14
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011591 potassium Substances 0.000 claims abstract description 14
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 14
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 6
- 239000010439 graphite Substances 0.000 claims abstract description 6
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 5
- 239000003513 alkali Substances 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 238000004080 punching Methods 0.000 claims description 9
- 239000000618 nitrogen fertilizer Substances 0.000 claims description 8
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 7
- 229960001763 zinc sulfate Drugs 0.000 claims description 7
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229940099596 manganese sulfate Drugs 0.000 claims description 5
- 235000007079 manganese sulphate Nutrition 0.000 claims description 5
- 239000011702 manganese sulphate Substances 0.000 claims description 5
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 5
- 235000013399 edible fruits Nutrition 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 235000013311 vegetables Nutrition 0.000 claims description 4
- 238000009395 breeding Methods 0.000 claims description 3
- 230000001488 breeding effect Effects 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- KNLQKHUBPCXPQD-UHFFFAOYSA-N manganese;sulfuric acid Chemical compound [Mn].OS(O)(=O)=O KNLQKHUBPCXPQD-UHFFFAOYSA-N 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 2
- 239000012895 dilution Substances 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- -1 wherein Substances 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 235000015097 nutrients Nutrition 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 description 8
- 240000008067 Cucumis sativus Species 0.000 description 7
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000035558 fertility Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003895 organic fertilizer Substances 0.000 description 2
- 239000003516 soil conditioner Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000013401 experimental design Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000002509 fulvic acid Substances 0.000 description 1
- 229940095100 fulvic acid Drugs 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002367 phosphate rock Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000004016 soil organic matter Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/40—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting fertiliser dosage or release rate; for affecting solubility
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C21/00—Methods of fertilising, sowing or planting
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Environmental Sciences (AREA)
- Fertilizers (AREA)
Abstract
The present invention relates to one kind to utilize salt resistance Liquid Fertilizer made of nano-sized carbon glue.The salt resistance Liquid Fertilizer includes nano-sized carbon glue, a great number of elements fertilizer, humic acid fertilizer and trace element fertilizer.Wherein, nano-sized carbon glue accounts for 70% 85% mass percents of salt resistance Liquid Fertilizer total amount；Potassium dihydrogen phosphate, humic acid potassium, trace element are added in nano-sized carbon glue according to proportioning, is sufficiently stirred, mixes, that is, salt resistance liquid fertilizer is made.The effect of function of nano-sized carbon glue characteristic and nutrient after the electrolysis of the invention using graphite, can reduce soil pH value, improve soil texture, improve utilization rate of fertilizer, and performance salt resistance is improved the soil, crop yield.The salt resistance Liquid Fertilizer is produced convenient and swift, countryside tax system cost can be reduced, without any pollution, safety and environmental protection.
Description
Technical field
It is more particularly to a kind of to utilize salt resistance liquid made of nano-sized carbon glue the invention belongs to salt resistance liquid fertilizer technical field
Body fertilizer and its preparation and application.
Background technology
Saline-alkali soil is a kind of higher soil types of the salt content formed under natural or artificial conditioning, at present, I
Nearly 100,000,000 hectares of state's saline-alkali soil area, with the increasingly reduction of cultivated area, transformation saline-alkali soil, its productive potentialities is excavated, be to realize
Total tilled amount, preserve the ecological environment, improve Overall Grain Production Capability in China, ensure China's grain security, promote
One of main path of agricultural sustainable development.The improvement yield-increasing technology of saline-alkali soil mainly includes engineering measure at present and agronomy is arranged
Apply two major classes, for example, hidden pipe salt discharge, build raised fields, salt-enduring cultivars selection, straw-returning foster and apply fertilizer, covers and press down salt, unconventional water conservancy
With and the technology such as soil conditioner.And in terms of the products such as soil conditioner be largely using desulfurated plaster, humic acid etc. into
Point, addition nutrition composition or biological agent etc. are manured into soil, so as to realize purpose that the reclamation of salinep-alkali soil utilizes.
Nano-sized carbon is to be prepared using being electrolysed graphite, production equipment is simple, technique as a kind of carbon-based nano level material
It is easy.And because carbon is widely present in soil-vegetation-atmospheric air circulation body, therefore there is preferable environment friendly.
At present, water-loss reducer of soil raw material, heavy metal-polluted soil sorbing material etc. are used as more to applications to nanostructures, as preparing fertilizer
A kind of nano-sized carbon fertilizer is disclosed primarily as fertilizer synergist etc., such as CN103772043A, utilizes biology enzyme combination nanometer
Material, improve organic fertilizer utilization rate；CN105646111A discloses a kind of micro-nano carbon multi-Functional Fertilizers with Humic Acid and its system
Preparation Method, crop yield section fertilizer can be promoted, greenhouse gas emission is reduced, reduce heavy metal pollution of soil.Patent text disclosed above
Although part has used nano-sized carbon, but what it utilized is that nano-sized carbon can strengthen suction-operated of the plant to fertilizer, is reduced with this organic
Fertilizer loss.It has not been used to report in terms of the reclamation of salinep-alkali soil.And its composition such as common reclamation of salinep-alkali soil product collects more at present
In in the raw material of routine, such as patent document CN103749022A is disclosed a kind of accelerates Tidal Flat Reclamation salt using desulfurized gesso of flue gas
Alkali desalination method, patent document CN103553808A provides a kind of humic acid alkaline land modifying agent, by the fulvic acid, low
The raw materials such as rank coal, ground phosphate rock are mixed, and above raw material either need to be equipped with specific industry or preparation technology complexity, cost
It is high.
The content of the invention
For saline-alkali soil because reasons such as soil salt content are high, the content of organic matter is low, soil texture is poor, nutrient is barren, this
Invention provides one kind and utilizes salt resistance Liquid Fertilizer made of nano-sized carbon glue；A great number of elements and micro member are added in nano-sized carbon glue
Element etc., the function of nano-sized carbon glue characteristic and other compositions after graphite electrolysis is made full use of, performance salt resistance is improved the soil, crop yield
The effect of.
Term explanation：
Nano-sized carbon glue：Also referred to as nanometer carbon liquid, it is prepared by utilizing electrode ink electrolysis water.PH value is between 1-5.It is made
Preparation Method case prior art, such as CN1853764A.Nano-sized carbon glue at present, it can be bought by market, such as Jining is brilliant
New carbon Science and Technology Ltd. is on sale.
According to the extent of injury to plant, saline-alkali soil is divided into slight, three indexs of moderate and severe：Wherein to crop
Underproduction 10-20% for slight saline-alkali soil, be moderate saline-alkali soil to crop failure 20-50%, to crop failure 50-80%'s
For severe saline-alkali soil.
Technical scheme is as follows：
One kind utilizes salt resistance Liquid Fertilizer made of nano-sized carbon glue, including nano-sized carbon glue, a great number of elements fertilizer, humic acid fertilizer
And trace element fertilizer, wherein, nano-sized carbon glue accounts for the 69%-86% mass percents of salt resistance Liquid Fertilizer total amount；
The nano-sized carbon glue is by graphite electrode electrolysis water prepared by.
According to currently preferred, nano-sized carbon glue pH value 2-3, granularity 10-25nm, the electromotive force 230-320mV, electricity
Conductance 1000-2000us/cm, carbon 0.45-0.65%, water 99.0-99.5%.
Described a great number of elements fertilizer is selected from potassium dihydrogen phosphate；Mass percent is 8%-19%；
Described humic acid fertilizer is selected from humic acid potassium；Mass percent is 3%-10%；
Described trace element fertilizer is sulfate state, preferably sulfuric acid manganese and/or zinc sulfate；Mass percent is 1%-5%.
Currently preferred technical scheme is as follows：
One kind utilizes salt resistance Liquid Fertilizer made of nano-sized carbon glue, is made up of the raw material of following parts by weight：
Described nano-sized carbon glue, potassium dihydrogen phosphate, humic acid potassium are commercially available convenient source.
Described trace element fertilizer is sulfate, and preferably sulfuric acid manganese and/or zinc sulfate, market are commercially available.
It is further preferred that a kind of utilize salt resistance Liquid Fertilizer made of nano-sized carbon glue, by the raw material system of following parts by weight
Into：Nano-sized carbon glue 85-90 parts, potassium dihydrogen phosphate 15-20 parts, potassium humate 8-10 parts, trace element fertilizer 2-5 parts.
Still more preferably, it is a kind of to utilize salt resistance Liquid Fertilizer made of nano-sized carbon glue, by the raw material of following parts by weight
It is made：90 parts of nano-sized carbon glue, 15 parts of potassium dihydrogen phosphate, 10 parts of potassium humate, 1 part of manganese sulfate, 1 part of zinc sulfate.
The preparation method of salt resistance liquid fertilizer of the present invention, is concretely comprised the following steps：Added greatly in nano-sized carbon glue according to proportioning
Secondary element fertilizer, humic acid fertilizer, trace element fertilizer, are sufficiently stirred, mix, that is, salt resistance liquid fertilizer is made.
The application using salt resistance Liquid Fertilizer made of nano-sized carbon glue of the present invention, improved for the salt resistance of saline-alkali soil soil.
It is particularly suitable for being used for moderate, heavy salinized soil.
The application using salt resistance Liquid Fertilizer made of nano-sized carbon glue of the present invention, it can be widely used for the plantation of saline-alkali soil soil
Fruit tree, vegetables and/or field crop.Described field crop mainly includes wheat, corn, rice etc..
A kind of application using salt resistance Liquid Fertilizer made of nano-sized carbon glue of the present invention, application process are：Fruit tree,
Used in vegetables and/or field crop breeding time as punching fertilising or foliar fertilizer, dosage is as follows：When being applied fertilizer as punching, 75kg/
hm2/ time~150kg/hm2/ time, Sui Shuichong is applied；During as foliar fertilizer, 25kg/hm2/ time~50kg/hm2/ time, dilution
100 times spray.Depending on access times are according to different crops demand.
The application using salt resistance Liquid Fertilizer made of nano-sized carbon glue of the present invention, is administered simultaneously when being applied for saline-alkali soil
Nitrogenous fertilizer.The salt resistance Liquid Fertilizer of the present invention can be used as nitrogen fertilizer slow releasing agent, improve utilization rate of nitrogen fertilizer, reduce soil nitrogen residual and damage
Lose.
The technical characterstic and excellent results of the present invention：
In nano-sized carbon glue preparation process, water forms acid-base property electric potential water under graphite electrode effect, has and is different from often
Advise the specific response of Natural Water.The salt resistance Liquid Fertilizer of the present invention, break through the existing fertilizer prepared with nano-sized carbon and only pass through nano-sized carbon
Absorption improves the effect of utilization rate of fertilizer, but based on highly acid electric potential water pH value is relatively low, can significantly reduce soil pH value, with
Nutrient especially plays salt resistance and improved the soil effect together, and has environment-friendly, crop yield function concurrently, is to adapt to green production
Safety and environmental protection fertilizer.Its advantage is as follows：
1st, salt resistance is improved the soil.The salt resistance Liquid Fertilizer of the present invention is due to compositions such as nano-sized carbon, humic acid fertilizer and trace element fertilizers
Effect, pH value is relatively low, applies in the salt affected soil in alkalescence, can significantly reduce soil pH value, adjusts soil pH value；In addition it is rotten
The formation of soil agreegate can also be promoted by growing sour fertilizer, improve soil texture.
2nd, safety and environmental protection.The salt resistance Liquid Fertilizer of the present invention is produced convenient and swift, can reduce countryside tax system cost；Fertilizer component
It is beneficial to crop, any chemical hazard will not be caused to environment, without any residual contamination.
3rd, utilization rate of nitrogen fertilizer is improved.The principal component nano-sized carbon glue of the salt resistance Liquid Fertilizer of the present invention is in agricultural production and nitrogenous fertilizer
There is unique advantage on sustained release, taken the course of its own in terms of nitrogenous fertilizer holding, therefore applied nitrogen while fertilizer of the present invention is applied,
Utilization rate of nitrogen fertilizer can be improved, reduces soil nitrogen residual and loss, remarkably promotes plant growth, and then improve crop yield.
Embodiment
With reference to embodiment, the present invention will be further described, and nano-sized carbon glue is by the limited public affairs of the brilliant new carbon science and technology in Jining
Department provides.Non- elaborate presses state of the art in embodiment.
Embodiment 1：A kind of preparation using salt resistance liquid fertilizer made of nano-sized carbon glue
One kind utilizes salt resistance liquid fertilizer made of nano-sized carbon glue, is made up of the raw material of following parts by weight：Nano-sized carbon
90 parts of glue, 15 parts of potassium dihydrogen phosphate, 10 parts of potassium humate, 1 part of manganese sulfate, 1 part of zinc sulfate.Proportionally in nano-sized carbon glue
Middle addition potassium dihydrogen phosphate, humic acid potassium, trace element, are sufficiently stirred, mix, produce.Apply, push away with water punching in Crop growing stage
It is 75kg/hm to recommend amount of application2/ time~150kg/hm2/ time be advisable.
Embodiment 2：A kind of preparation using salt resistance liquid fertilizer made of nano-sized carbon glue
One kind utilizes salt resistance liquid fertilizer made of nano-sized carbon glue, is made up of the raw material of following parts by weight：Nano-sized carbon
85 parts of glue, 20 parts of potassium dihydrogen phosphate, 10 parts of potassium humate, 1 part of manganese sulfate, 2 parts of zinc sulfate.Proportionally in nano-sized carbon glue
Middle addition potassium dihydrogen phosphate, humic acid potassium, trace element, are sufficiently stirred, mix, produce.Apply, push away with water punching in Crop growing stage
It is 75kg/hm to recommend amount of application2/ time~150kg/hm2/ time be advisable.
Embodiment 3：A kind of preparation using salt resistance liquid fertilizer made of nano-sized carbon glue
One kind utilizes salt resistance liquid fertilizer made of nano-sized carbon glue, is made up of the raw material of following parts by weight：Nano-sized carbon
80 parts of glue, 10 parts of potassium dihydrogen phosphate, 10 parts of potassium humate, 2 parts of manganese sulfate, 1 part of zinc sulfate.Proportionally in nano-sized carbon glue
Middle addition potassium dihydrogen phosphate, humic acid potassium, trace element, are sufficiently stirred, mix, produce.Apply, push away with water punching in Crop growing stage
It is 75kg/hm to recommend amount of application2/ time~150kg/hm2/ time be advisable.
Embodiment 4：A kind of cucumber field efficacy experiment using salt resistance liquid fertilizer made of nano-sized carbon glue
1st, test site and confession examination soil property：
Test site：Dongying city.
Experimental field soil：Saline-alkali soil, soil total salt amount 0.29%, belong to moderate saline-alkali soil.
2nd, test period：In September, 2015~2016 year 2 months, in September, 2016~2017 year 2 months.
3rd, experimental design：
Experiment sets 4 processing altogether, is respectively：(1) compare：Salt resistance Liquid Fertilizer is not applied；(2) salt resistance Liquid Fertilizer 1：Using reality
Apply salt resistance Liquid Fertilizer made from example 1；(3) salt resistance Liquid Fertilizer 2：Using salt resistance Liquid Fertilizer made from embodiment 2；(4) salt resistance liquid
Fertilizer 3：Using salt resistance Liquid Fertilizer made from embodiment 3.Salt resistance Liquid Fertilizer dosage is identical, is 100kg/hm2/ time, all processing
Chemical fertilizer input N, P2O5、K2O dosages are accustomed to local farmers, are respectively：450kg/hm2、225kg/hm2、300kg/hm2。
Each processing is repeated 3 times.
Experiment carried out altogether two season cucumber, per count production respectively in season.Salt resistance Liquid Fertilizer is applied with water punching, is total to per cucumber breeding time in season
Punching is applied 4 times, respectively in October 25, November 25, December 25, January 25.After the off-test of two seasons, measure soil is organic
The physicochemical character index such as matter, salt content.
4th, result of the test：
The cucumber production promoting effect of the salt resistance Liquid Fertilizer of table 1
As can be seen from Table 1, shown in the cucumber test in two seasons substantially using the salt resistance Liquid Fertilizer of the present invention
Volume increase advantage.Compared with the peasant habit of control does not apply the processing of salt resistance Liquid Fertilizer, 2015-2016 season cucumber yields point
Not Zeng Chan 4.43%, 6.90%, 6.64%, 2016-2017 season cucumber yields increase production 4.85%, 7.41%, 7.66% respectively.Say
Bright, using the salt resistance Liquid Fertilizer of the present invention, crop yield is notable, and effect of increasing production, long-term effect are obvious year by year for presentation.
The soil improvement soil fertilities of the salt resistance Liquid Fertilizer of table 2
As can be seen from Table 2, after using the salt resistance Liquid Fertilizer 2 years of the present invention, soil organic matter content rise, than control
Processing increases by 1.94%, 4.85%, 6.80% respectively；Soil total salt amount content reduces, and is reduced respectively than control treatment
20.00%th, 26.67%, 33.33%；Soil alkaline hydrolysis nitrogen content raises, increase by 4.94% respectively than control treatment, 11.76%,
15.53%；Content of soil available phosphor raises, and increases by 1.91%, 7.18%, 9.09% respectively than control treatment；Soil available nitrogen
Content raises, and increases by 2.95%, 5.90%, 6.57% respectively than control treatment；Soil pH value reduces, and is dropped respectively than control treatment
Low 4.23%, 8.22%, 9.15%.Illustrate, salt resistance Liquid Fertilizer of the invention can increase soil fertility, and reduce soil salt content.
Claims (10)
1. one kind utilizes salt resistance Liquid Fertilizer made of nano-sized carbon glue, it is characterised in that including nano-sized carbon glue, a great number of elements
Fertilizer, humic acid fertilizer and trace element fertilizer, wherein, nano-sized carbon glue accounts for the 69%-86% mass percents of salt resistance Liquid Fertilizer total amount.
2. utilize salt resistance Liquid Fertilizer made of nano-sized carbon glue as claimed in claim 1, it is characterised in that the nanometer carbon paste
Liquid is by graphite electrode electrolysis water prepared by；The nano-sized carbon glue pH value 2~3, granularity 10-25nm, electromotive force 230-
320mV, electrical conductivity 1000-2000us/cm, carbon 0.45-0.65%, water 99.0-99.5%.
3. utilize salt resistance Liquid Fertilizer made of nano-sized carbon glue as claimed in claim 1, it is characterised in that described a large amount of members
Plain fertilizer is selected from potassium dihydrogen phosphate；Mass percent is 8%-19%；Described humic acid fertilizer is selected from humic acid potassium；Mass percent
For 3%-10%；Described trace element fertilizer is sulfate state, preferably sulfuric acid manganese and/or zinc sulfate；Mass percent is 1%-
5%.
4. one kind as claimed in claim 3 utilizes salt resistance Liquid Fertilizer made of nano-sized carbon glue, it is characterised in that by following heavy
The raw material of amount part is made：
5. one kind as claimed in claim 4 utilizes salt resistance Liquid Fertilizer made of nano-sized carbon glue, it is characterised in that by following heavy
The raw material of amount part is made：Nano-sized carbon glue 85-90 parts, potassium dihydrogen phosphate 15-20 parts, potassium humate 8-10 parts, trace element fertilizer
2-5 parts.
6. one kind as described in claim 3 or 5 utilizes salt resistance Liquid Fertilizer made of nano-sized carbon glue, it is characterised in that by with
The raw material of lower parts by weight is made：90 parts of nano-sized carbon glue, 15 parts of potassium dihydrogen phosphate, 10 parts of potassium humate, 1 part of manganese sulfate, sulfuric acid
1 part of zinc.
7. the preparation method using salt resistance Liquid Fertilizer made of nano-sized carbon glue described in claim any one of 1-6, step is such as
Under：
A great number of elements fertilizer, humic acid fertilizer, trace element fertilizer are added in nano-sized carbon glue according to proportioning, is sufficiently stirred, mixes, i.e.,
.
8. any described applications using salt resistance Liquid Fertilizer made of nano-sized carbon glue of claim 1-6, for saline-alkali soil soil
Earth salt resistance improves；Or while administration for saline-alkali soil applied nitrogen as nitrogen fertilizer slow releasing agent.
9. the application of salt resistance Liquid Fertilizer made of nano-sized carbon glue is utilized as claimed in claim 8, it is characterised in that for salt
Fruit tree, vegetables and/or the field crop of alkaline earth soil plantation.
10. the application of salt resistance Liquid Fertilizer made of nano-sized carbon glue is utilized as claimed in claim 8, it is characterised in that administration side
Method is：Used in fruit tree, vegetables and/or field crop breeding time as punching fertilising or foliar fertilizer；Preferably, dosage is as follows：Make
When being applied fertilizer for punching, 75kg/hm2/ time~150kg/hm2/ time, Sui Shuichong is applied；During as foliar fertilizer, 25kg/hm2/ time~
50kg/hm2/ time, 100 times of dilution sprays.
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| CN201710662210.0A CN107459422A (en) | 2017-08-04 | 2017-08-04 | One kind utilizes salt resistance Liquid Fertilizer and its preparation and application made of nano-sized carbon glue |
| CN202311062954.0A CN116986956A (en) | 2017-08-04 | 2017-08-04 | Salt-resistant liquid fertilizer prepared from nano carbon glue solution and preparation and application thereof |
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| CN201710662210.0A CN107459422A (en) | 2017-08-04 | 2017-08-04 | One kind utilizes salt resistance Liquid Fertilizer and its preparation and application made of nano-sized carbon glue |
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| CN202311062954.0A Pending CN116986956A (en) | 2017-08-04 | 2017-08-04 | Salt-resistant liquid fertilizer prepared from nano carbon glue solution and preparation and application thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109232091A (en) * | 2018-10-30 | 2019-01-18 | 四川施邦威生物科技发展有限公司 | A kind of preparation method of humic acid water soluble fertilizer |
| CN109265291A (en) * | 2018-10-30 | 2019-01-25 | 四川施邦威生物科技发展有限公司 | A kind of humic acid water soluble fertilizer |
| CN112806207A (en) * | 2021-03-09 | 2021-05-18 | 陕西中农厚朴农业科技有限公司 | Method for preventing and treating blackhead disease of kiwi fruits by adopting traditional Chinese medicine agricultural production mode and application |
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| CN1853764A (en) * | 2005-04-20 | 2006-11-01 | 北京天中树科技发展有限公司 | Production and producer for nanometer carbon liquid |
| CN103107315A (en) * | 2011-11-10 | 2013-05-15 | 北京有色金属研究总院 | Nano silicon-carbon composite material and preparation method thereof |
| CN104478634A (en) * | 2014-12-23 | 2015-04-01 | 风禾尽起科技(北京)有限公司 | Method for preparing saline-alkali soil amendment by utilizing nano carbon-silicon material |
| CN105859484A (en) * | 2016-06-21 | 2016-08-17 | 吉林省农业科学院 | Saline-alkali soil improver |
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| CN1853764A (en) * | 2005-04-20 | 2006-11-01 | 北京天中树科技发展有限公司 | Production and producer for nanometer carbon liquid |
| CN103107315A (en) * | 2011-11-10 | 2013-05-15 | 北京有色金属研究总院 | Nano silicon-carbon composite material and preparation method thereof |
| CN104478634A (en) * | 2014-12-23 | 2015-04-01 | 风禾尽起科技(北京)有限公司 | Method for preparing saline-alkali soil amendment by utilizing nano carbon-silicon material |
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| CN109232091A (en) * | 2018-10-30 | 2019-01-18 | 四川施邦威生物科技发展有限公司 | A kind of preparation method of humic acid water soluble fertilizer |
| CN109265291A (en) * | 2018-10-30 | 2019-01-25 | 四川施邦威生物科技发展有限公司 | A kind of humic acid water soluble fertilizer |
| CN112806207A (en) * | 2021-03-09 | 2021-05-18 | 陕西中农厚朴农业科技有限公司 | Method for preventing and treating blackhead disease of kiwi fruits by adopting traditional Chinese medicine agricultural production mode and application |
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| CN116986956A (en) | 2023-11-03 |
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