CN107456941B - A kind of chemical reaction kettle adjusted convenient for temperature - Google Patents

A kind of chemical reaction kettle adjusted convenient for temperature Download PDF

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Publication number
CN107456941B
CN107456941B CN201710854818.3A CN201710854818A CN107456941B CN 107456941 B CN107456941 B CN 107456941B CN 201710854818 A CN201710854818 A CN 201710854818A CN 107456941 B CN107456941 B CN 107456941B
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CN
China
Prior art keywords
heat
fin
conducting seat
cooling water
autoclave body
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201710854818.3A
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Chinese (zh)
Other versions
CN107456941A (en
Inventor
刘毅
刘国强
李玉玲
丁克富
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Anhui Futai Fine Chemical Co ltd
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Anhui Futai Fine Chemical Industry LLC
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Publication date
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Priority to CN201710854818.3A priority Critical patent/CN107456941B/en
Publication of CN107456941A publication Critical patent/CN107456941A/en
Application granted granted Critical
Publication of CN107456941B publication Critical patent/CN107456941B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/0013Controlling the temperature of the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • B01J19/0066Stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00092Tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00132Controlling the temperature using electric heating or cooling elements
    • B01J2219/00135Electric resistance heaters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Accessories For Mixers (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

The present invention relates to a kind of reaction kettles, specially a kind of chemical reaction kettle adjusted convenient for temperature, the inner wall of autoclave body is equipped with multiple adjustment modules, adjustment module can be used for the heating to industrial chemicals, heat dissipation and stirring, adjustment module includes along the heat-conducting seat arranged vertically, fin for radiating and heating and the driving motor to swing back and forth for fin, heat-conducting seat is equipped with the cooling water hole through heat-conducting seat, when adding thermal resistance heats chemical reaction, one end of fin is hinged on heat-conducting seat, fin is provided with multiple, multiple fins are evenly arranged along the length direction of heat-conducting seat;Driving motor is mounted on the top of heat-conducting seat, and driving motor drives fin to swing by connecting rod.The present invention is by shuttle-type fin of setting, it can be achieved that the stirring of reactant and the quick transmission of heat, can either heat reactant, and can cool down to reactant, while can also be stirred the control, it can be achieved that temperature of charge to reactant.

Description

A kind of chemical reaction kettle adjusted convenient for temperature
Technical field
The present invention relates to a kind of reaction kettle, specially a kind of chemical reaction kettle adjusted convenient for temperature belongs to chemical reaction Kettle applied technical field.
Background technology
The broad understanding of reaction kettle has the container physically or chemically reacted, is matched with parameter by the structure design to container It sets, realizes the mixture function of the heating of technological requirement, evaporation, cooling and low high speed, reaction kettle is by autoclave body, kettle cover, chuck, stirring The compositions such as device, transmission device, gland seal device, bearing.Whipped form generally has anchor formula, paddle, turbine type, push type or frame Deng, agitating device when ratio of height to diameter is larger, multiple impellers leaf can be used, also can arbitrarily be matched acording to the requirement of user.And in kettle Chuck is set outside wall, or heat-transfer surface is set in device, can also be exchanged heat by outer circulation.Mode of heating has electrical heating, hot water Heating, the heating of conduction oil circulating-heating, Far-infrared Heating, outer inner coil pipe etc., the type of cooling are that chuck cooling and kettle inner coil pipe are cold But, the form etc. of stirrer paddle.Fulcrum bearing has supporting type or hanging support etc..Rotating speed is more than 160 turns or more and is preferably subtracted using gear Fast machine.
At present therefore domestic medium and small chemical plant unconditionally fills the higher chemical industry equipment of each reaction temperature, can not also produce The higher chemical products of reaction temperature.And it is slowly difficult using there is temperature adjustment for steam-heated chemical industry equipment.Chemical plant Sometimes it is that pyroreaction kettle, tank is separately provided, using line-frequency induction electric heater unit, keeps the cost of equipment and investment very big, no With insulation jacket and heating system, effectively reaction kettle cannot be heated in time and temperature regulates and controls, and optional equipment occupies factory Room sky asks the capital intensives such as big and tank kettle, pump valve, pipeline, and electric-thermal transfer efficiency is low and temperature is difficult to control.
Invention content
The purpose of the present invention be that solve the above-mentioned problems and provide it is a kind of convenient for temperature adjust chemical reaction kettle, The present invention by shuttle-type fin of setting, it can be achieved that the stirring of reactant and the quick transmission of heat, can either be to reaction Object heats, and can cool down to reactant, while can also be stirred to reactant.
The present invention is achieved through the following technical solutions above-mentioned purpose, a kind of chemical reaction kettle adjusted convenient for temperature, packet Autoclave body is included, reaction chamber is equipped in autoclave body, chuck is equipped on the outside of autoclave body, head cover is additionally provided on the upside of autoclave body, pedestal is equipped on the downside of autoclave body, The pedestal lower end is equipped with support leg, and base end is equipped with drainage conduit, and drainage conduit is equipped with discharge electromagnetic valve, is equipped in reaction chamber Rotary shaft, the rotary shaft downside are movably attached to by rotary shaft support inside autoclave body, and multigroup stirring is equipped on the outside of rotary shaft Leaf, rotary shaft upside are connected with retarder, and retarder setting is equipped with feed inlet, head cover in head cover upper end, the head cover upper left side There is upside to be equipped with pressure valve, retarder upper end is connected with motor, and inner wall of kettle is equipped with multiple temperature sensors, is set on the outside of autoclave body There is a control cabinet, the control cabinet is equipped with touch screen, and the inner wall of autoclave body is equipped with multiple adjustment modules, and adjustment module can be used for pair Heating, heat dissipation and the stirring of industrial chemicals, adjustment module include along the heat-conducting seat arranged vertically, the fin for radiating and heating With the driving motor to swing back and forth for fin, the heat-conducting seat is equipped with the cooling water hole through heat-conducting seat, adding thermal resistance pair Chemical reaction is when being heated, can be by cooling water hole if the actual temperature of chemical reaction is more than required reaction temperature Injection cooling water cools down, and the cooling water in cooling water hole can block rapidly adding thermal resistance to continue to heat to chemical reaction, Ensure the safety of chemical reaction, further, cooling water hole is bellmouth, and the small end water inlet of cooling water hole, big end is discharged, cold But when water flows to big end by small end, under the action of negative pressure, the distance between cooling water hydrone increases, and can cooling water be inhaled More heat is received, the fast cooling to reactant is conducive to, one end of the fin is hinged on heat-conducting seat, and fin is provided with Multiple, multiple fins are evenly arranged along the length direction of heat-conducting seat;The driving motor is mounted on the top of heat-conducting seat, driving electricity Machine drives fin to swing by connecting rod, in use, driving motor drives fin to swing back and forth by connecting rod, realizes to reactant Stirring, while fin can carry out the transmission of heat between heat-conducting seat, be conducive to the heat dissipation or heating of reactant.
It is provided with triangle open mouth slot as a kind of technical solution of the present invention, on the heat-conducting seat, the one of the fin End is mounted in open slot, can be contacted with the side wall of open slot when fin upwardly or downwardly rotates, fin and open slot Side wall be in contact, the contact area between fin and heat-conducting seat can be improved, to be conducive to increase between fin and heat-conducting seat The transmission efficiency of heat.
As a kind of technical solution of the present invention, the spiral shape cooling water wound along autoclave body outer wall is equipped on the inside of the chuck Road and spiral shape adding thermal resistance, the back of the heat-conducting seat be provided with cooling water channel and the matched groove of adding thermal resistance, lead It is tightly connected between hot seat and autoclave body, the chemical reaction that can be radiated to needs by cooling water channel is radiated, by heating electricity The chemical reaction that resistance can heat needs is heated.Cooling water channel and adding thermal resistance are directly contacted with heat-conducting seat, be can be improved and are led The transmission speed of hot seat heat, is conducive to rapid cooling or heating.
The beneficial effects of the invention are as follows:
1. the present invention can coordinate paddle to be stirred reactant by shuttle-type fin of setting, make chemical anti- The triangle open mouth slot that should be able to fully react, while pass through design so that the contact area between fin and heat-conducting seat increases, The transmission area of heat is increased, rapid cooling or heating can be carried out to reactant, to realize the fast of reaction cavity temperature Speed control.
2. the present invention can be realized by the spiral shape cooling water channel of setting to needing cooling chemical reaction to cool down, lead to The spiral adding thermal resistance of setting is crossed, it can be achieved that the chemical reaction heated to needs is heated, by being set on heat-conducting seat Set cooling water hole, can the chemical reaction excessively high to heating temperature cool down, the transmission of the heat of adding thermal resistance is blocked, to have Conducive to the rapid cooling of chemical reaction, to ensure the safety of chemical reaction.
Description of the drawings
Fig. 1 is the sectional view of the present invention;
Fig. 2 is the sectional view of the heat-conducting seat of the present invention;
In figure:1, autoclave body, 2, reaction chamber, 3, chuck, 4, head cover, 5, pedestal, 6, cooling water channel, 8, adding thermal resistance, 9, into Water pipe, 10, outlet pipe, 11, water pump, 12, support leg, 13, drainage conduit, 14, rotary shaft, 15, paddle, 16, rotary shaft support, 17, motor, 18, retarder, 19, charge door, 20, pressure valve, 21, temperature sensor, 22, control cabinet, 23, touch screen, 24, Heat-conducting seat, 241, cooling water hole, 242, open slot, 25, fin, 26, driving motor, 27, connecting rod.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
It please refers to Fig.1 shown in -2, a kind of chemical reaction kettle adjusted convenient for temperature, including autoclave body 1, is equipped in autoclave body 1 anti- Answer chamber 2,1 outside of autoclave body is equipped with chuck 3, and 1 upside of autoclave body is additionally provided with head cover 4, and 1 downside of autoclave body is equipped with pedestal 5, under the pedestal 5 End is equipped with support leg 12, and 5 end of pedestal is equipped with drainage conduit 13, and drainage conduit 13 is equipped with discharge electromagnetic valve, rotation is equipped in reaction chamber 2 Shaft 14,14 downside of the rotary shaft are movably attached to by rotary shaft support 16 inside autoclave body 1, and 14 outside of rotary shaft is equipped with more Group paddle 15,14 upside of rotary shaft are connected with retarder 18, and retarder 18 is arranged in 4 upper end of head cover, 4 upper left side of the head cover Equipped with feed inlet 19, head cover 4 has upside to be equipped with pressure valve 20, and 18 upper end of retarder is connected with motor 17, and 1 inner wall of autoclave body is equipped with Multiple temperature sensors 21,1 outside of autoclave body are equipped with control cabinet 22, and the control cabinet 22 is equipped with touch screen 23, the inner wall of autoclave body 1 Multiple adjustment modules are installed, adjustment module can be used for heating, heat dissipation and stirring to industrial chemicals, and adjustment module includes along perpendicular The heat-conducting seat 24 directly arranged, the fin 25 for radiating and heating and the driving motor 26 to swing back and forth for fin 25, it is described Heat-conducting seat 24 is equipped with the cooling water hole 241 through heat-conducting seat 24, when adding thermal resistance 8 heats chemical reaction, if changed When learning the actual temperature of reaction more than required reaction temperature, it can be cooled down by injecting cooling water to cooling water hole 241, it is cooling Cooling water in water hole 241 can block rapidly adding thermal resistance 8 to continue to heat to chemical reaction, ensure the safety of chemical reaction Property, further, cooling water hole 241 is bellmouth, and the small end of cooling water hole 241 is intake, big end water outlet, and cooling water is by small end stream When to big end, under the action of negative pressure, the distance between cooling water hydrone increases, and cooling water can be made to absorb more heat Amount, is conducive to the fast cooling to reactant, one end of the fin 25 is hinged on heat-conducting seat 24, and fin 25 is provided with more A, multiple fins 25 are evenly arranged along the length direction of heat-conducting seat 24;The driving motor 26 is mounted on the top of heat-conducting seat 24, Driving motor 26 drives fin 25 to swing by connecting rod 27, in use, driving motor 26 drives fin 25 back and forth by connecting rod 27 It swings, realizes the stirring to reactant, while fin 25 can carry out the transmission of heat between heat-conducting seat 24, be conducive to react The heat dissipation or heating of object.
As one embodiment of the present invention, triangle open mouth slot 242, the fin are provided on the heat-conducting seat 24 25 one end is mounted in open slot 242, can be connect with the side wall of open slot 242 when fin 25 upwardly or downwardly rotates It touches, fin 25 is in contact with the side wall of open slot 242, and the contact area between fin 25 and heat-conducting seat 24 can be improved, to have Conducive to the transmission efficiency of heat between increase fin 25 and heat-conducting seat 24.
As one embodiment of the present invention, 3 inside of the chuck is equipped with the spiral shape cooling wound along 1 outer wall of autoclave body Water channel 6 and spiral shape adding thermal resistance 8, the back of the heat-conducting seat 24 are provided with matched with cooling water channel 6 and adding thermal resistance 8 Groove is tightly connected between heat-conducting seat 24 and autoclave body 1, and the chemical reaction that can be radiated to needs by cooling water channel 6 is radiated, The chemical reaction that can be heated to needs by adding thermal resistance 8 is heated.Cooling water channel 6 and adding thermal resistance 8 are directly and heat-conducting seat 24 contacts, can be improved the transmission speed of 24 heat of heat-conducting seat, are conducive to rapid cooling or heating.
In the use of the present invention, the material chemically reacted is added to by charge door 19 in autoclave body 1 successively, Then reaction dissolvent is added, opens motor 17, motor 17 drives rotary shaft 14 to be rotated according to certain speed, passes through control Case 22 can control the rotating speed of motor 17, while rotary shaft 14 drives paddle 15 to be rotated, and passes through the rotation of paddle 15 Reaction mass can adequately be stirred, while driving motor 26 can drive fin 25 to swing back and forth, the cooperation of fin 25 is stirred Mix stirring of the realization to reactant jointly of leaf 15 so that reaction mass mixing is more uniform, and reaction is more rapid and thorough, simultaneously During reaction, by the reaction temperature in temperature sensor 21 in real time monitoring reaction chamber 2, when real-time in reaction chamber 2 When temperature is more than optimal reaction temperature, water pump 11 is started by control cabinet 22, from water pump 11 by water inlet pipe 9 to cooling water hole It is pumped into cooling water in 241, by the alternating action of cooling water and adding thermal resistance 8 in cooling water hole 241, chemical reaction can be made to protect Hold the speed and quality for being conducive to improve chemical reaction in optimum temperature;It needs to dissipate when chemical reaction gives out a large amount of heat When hot, can comprehensively it be cooled down to chemical reaction by injecting cooling water into cooling water channel 6.
The basic principles, main features and advantages of the invention have been shown and described above.The technical staff of the industry should Understand, the present invention is not limited to the above embodiments, and the description in above embodiments and description only illustrates the present invention Principle, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these change and change Into all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appended claims and its equivalent It defines.

Claims (1)

1. a kind of chemical reaction kettle adjusted convenient for temperature, including autoclave body (1), it is characterised in that:Reaction chamber is equipped in autoclave body (1) (2), it is equipped with chuck (3) on the outside of autoclave body (1), head cover (4) is additionally provided on the upside of autoclave body (1), pedestal (5), institute are equipped on the downside of autoclave body (1) It states pedestal (5) lower end and is equipped with support leg (12), pedestal (5) end is equipped with drainage conduit (13), and drainage conduit (13) is equipped with discharge electromagnetism Valve, reaction chamber (2) is interior to be equipped with rotary shaft (14), is movably attached to by rotary shaft support (16) on the downside of the rotary shaft (14) Autoclave body (1) is internal, and multigroup paddle (15) is equipped on the outside of rotary shaft (14), retarder (18) is connected on the upside of rotary shaft (14), Retarder (18) setting is equipped with feed inlet (19) in head cover (4) upper end, head cover (4) upper left side, and head cover (4) upper right side is equipped with Pressure valve (20), retarder (18) upper end are connected with motor (17), and autoclave body (1) inner wall is equipped with multiple temperature sensors (21), Control cabinet (22) is equipped on the outside of autoclave body (1), the control cabinet (22) is equipped with touch screen (23), and the inner wall of autoclave body (1) is equipped with Multiple adjustment modules, adjustment module can be used for heating, heat dissipation and stirring to industrial chemicals, and adjustment module includes along vertical arrangement Heat-conducting seat (24), the fin (25) for radiating and heating and the driving motor (26) to swing back and forth for fin (25), institute It states heat-conducting seat (24) and is equipped with the cooling water hole (241) for running through heat-conducting seat (24), one end of the fin (25) is hinged on heat conduction On seat (24), fin (25) is provided with multiple, and multiple fins (25) are evenly arranged along the length direction of heat-conducting seat (24);The drive Dynamic motor (26) is mounted on the top of heat-conducting seat (24), and driving motor (26) drives fin (25) to swing by connecting rod (27);
Triangle open mouth slot (242) is provided on the heat-conducting seat (24), one end of the fin (25) is mounted on open slot (242) it in, can be contacted with the side wall of open slot (242) when fin (25) upwardly or downwardly rotates;Fin (25) with open The side wall of mouth slot (242) is in contact, and the contact area between fin (25) and heat-conducting seat (24) can be improved, to be conducive to increase The transmission efficiency of heat between fin (25) and heat-conducting seat (24);
The spiral shape cooling water channel (6) wound along autoclave body (1) outer wall and spiral shape adding thermal resistance are equipped on the inside of the chuck (3) (8), the back of the heat-conducting seat (24) is provided with and cooling water channel (6) and adding thermal resistance (8) matched groove, heat-conducting seat (24) it is tightly connected between autoclave body (1);When adding thermal resistance (8) heats chemical reaction, if the reality of chemical reaction When temperature is more than required reaction temperature, cooled down by injecting cooling water to cooling water hole (241), in cooling water hole (241) Cooling water adding thermal resistance (8) can be blocked to continue to heat to chemical reaction rapidly;
The cooling water hole (241) is bellmouth, and the small end of cooling water hole (241) is intake, big end water outlet.
CN201710854818.3A 2017-09-20 2017-09-20 A kind of chemical reaction kettle adjusted convenient for temperature Expired - Fee Related CN107456941B (en)

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CN107456941B true CN107456941B (en) 2018-09-25

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CN110624268A (en) * 2019-09-16 2019-12-31 广州汇富研究院有限公司 Chlorosilane purifying device and purifying method thereof
CN110923672A (en) * 2019-12-17 2020-03-27 Tcl华星光电技术有限公司 Heating device and chemical vapor deposition equipment
WO2024033187A1 (en) * 2022-08-09 2024-02-15 Shell Internationale Research Maatschappij B.V. An electrically heated apparatus and a method of heating a fluid
CN116689132B (en) * 2023-06-20 2025-09-12 新兴铸管股份有限公司 Single valve core unloader material flow dredging device

Citations (6)

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Publication number Priority date Publication date Assignee Title
US4752640A (en) * 1984-07-27 1988-06-21 Kanegafuchi Chemical Industry Co., Ltd. Temperature controlling method for polymerization reactors
CN201921686U (en) * 2010-12-07 2011-08-10 李建英 Reaction kettle
CN204891874U (en) * 2015-08-13 2015-12-23 河南莱帕克化工设备制造有限公司 Semi -physical simulation's chlorination reaction kettle
CN205042480U (en) * 2015-10-23 2016-02-24 临沂大学 Chemical synthesis device
CN205413035U (en) * 2016-04-06 2016-08-03 河南工程学院 Rapid reaction kettle system adjusts temperature
CN206249216U (en) * 2016-11-08 2017-06-13 东莞市澍华五金制品有限公司 An electronic radiator

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4752640A (en) * 1984-07-27 1988-06-21 Kanegafuchi Chemical Industry Co., Ltd. Temperature controlling method for polymerization reactors
CN201921686U (en) * 2010-12-07 2011-08-10 李建英 Reaction kettle
CN204891874U (en) * 2015-08-13 2015-12-23 河南莱帕克化工设备制造有限公司 Semi -physical simulation's chlorination reaction kettle
CN205042480U (en) * 2015-10-23 2016-02-24 临沂大学 Chemical synthesis device
CN205413035U (en) * 2016-04-06 2016-08-03 河南工程学院 Rapid reaction kettle system adjusts temperature
CN206249216U (en) * 2016-11-08 2017-06-13 东莞市澍华五金制品有限公司 An electronic radiator

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Effective date of registration: 20180817

Address after: 236600 D District, Taihe County Economic Development Zone, Fuyang, Anhui

Applicant after: ANHUI FUTAI FINE CHEMICAL CO.,LTD.

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Granted publication date: 20180925