CN107445668A - Arsenic content and the method that Swine manure is prepared using the pig manure in a kind of reduction pig manure - Google Patents

Arsenic content and the method that Swine manure is prepared using the pig manure in a kind of reduction pig manure Download PDF

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Publication number
CN107445668A
CN107445668A CN201710802488.3A CN201710802488A CN107445668A CN 107445668 A CN107445668 A CN 107445668A CN 201710802488 A CN201710802488 A CN 201710802488A CN 107445668 A CN107445668 A CN 107445668A
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China
Prior art keywords
pig manure
manure
stirring
pig
swine
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CN201710802488.3A
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Chinese (zh)
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蔡燕芬
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Meizhou Huanyuan Renewable Resources Development And Utilization Co ltd
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Meizhou Huanyuan Renewable Resources Development And Utilization Co ltd
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Priority to CN201710802488.3A priority Critical patent/CN107445668A/en
Publication of CN107445668A publication Critical patent/CN107445668A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • C05D3/02Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products

Abstract

The method that Swine manure is prepared the invention discloses arsenic content in a kind of reduction pig manure and using the pig manure, belongs to organic fertilizer technical field, technical points comprise the steps:(1) 30 80 kilograms of ethanol is added by pig manure per ton, carries out first time stirring, 12 48 hours are stood after stirring;(2) 30 80 kilograms of sodium hydroxides are added by pig manure per ton to enter in processing pond, is stood after stirring;(3) add 20 70 kilograms of pulverized limestones by pig manure per ton to enter in processing pond, the lower microbe conversion of static state;(4) 10 40 kilograms of sulfuric acid are added by pig manure per ton to be stirred into processing pond, obtains the pig manure that arsenic content meets national standard;(5) auxiliary material of material gross weight 35 40% is accounted for toward addition in processing pond, is transferred to stack retting area, covered plastic film is converted, and obtains Swine manure;The present invention is intended to provide arsenic content and the method that Swine manure is prepared using the pig manure in a kind of reduction pig manure easy to operate, processing cost is low and using effect is good;Prepared for organic fertilizer.

Description

Arsenic content and the method that Swine manure is prepared using the pig manure in a kind of reduction pig manure
Technical field
The present invention relates to a kind of swine manure treatment technique, more specifically, more particularly to it is a kind of reduce in pig manure arsenic content and The method that Swine manure is prepared using the pig manure.
Background technology
Swine excrement recycling is the developing goal that country advocates, but due to containing heavy metal in swine excrement --- arsenic, to pig Dung recovery and the surface layer pollution problem for solving the problems, such as to bring rural culture are difficult with realizing.
How to dissolve the contradiction between development scale cultivation and protecting ecology, be the important step for realizing poultry healthy aquaculture One of.Contaminant transportation process and pollution result and how to handle be research new problem.
The content of the invention
It is an object of the invention to for above-mentioned the deficiencies in the prior art, there is provided a kind of easy to operate, processing cost it is low and Arsenic content and the method that Swine manure is prepared using the pig manure in the good reduction pig manure of using effect.
The technical proposal of the invention is realized in this way:One kind reduces arsenic content in pig manure and prepares pig manure using the pig manure The method of organic fertilizer, this method comprise the steps:
(1) pig manure in plant is collected using suction-type sewer scavenger and is transported to factory and pours into processing pond, by pig manure per ton Add 30-80 kilograms of ethanol, carry out first time stirring, after stirring stand 12-48 hours, pig manure by original lumps it is sour, it is smelly, Fishy smell changes into dispersed by ethanol and produces stronger ammonia taste, and pig manure Ph values are 1-5 after standing;
(2) add after the completion of ethanol stirring standing, adding 30-80 kilograms of sodium hydroxide by pig manure per ton enters processing pond In, 12-48 hours are stood after stirring, pig manure is yellowish by blacking;
(3) add after the completion of sodium hydroxide standing, adding 20-70 kilograms of pulverized limestone by pig manure per ton enters in processing pond, After stirring, static lower microbe conversion 12-36 hours;
(4) add after the completion of pulverized limestone standing, add 10-40 kilograms of sulfuric acid by pig manure per ton is stirred into processing pond Mix, using the Ph values in acid-base neutralization regulation pig manure to 6.5-8, obtain the pig manure that arsenic content meets national standard;
(5) material gross weight 35-40% auxiliary material is accounted for toward addition in processing pond, stack retting area is transferred to after being again stirring for uniformly, Covered plastic film is converted, and obtains Swine manure.
Arsenic content and prepared in a kind of above-mentioned reduction pig manure using the pig manure in the method for Swine manure, step (3) Specially:Adding after the completion of sodium hydroxide standing, the standard that 20-70 kilograms of pulverized limestone is added by pig manure per ton weighs pulverized limestone, Uniformly be divided into trisection, often plus a pulverized limestone, added again after stirring, so repeatedly uniform stirring three times after, pig manure Ph Value brings up to 7-13 by original 1-5, and pig manure temperature is lifted to 40 ° -43 ° by original normal temperature, the lower microbe conversion 12-36 of static state Hour.
Arsenic content and prepared in a kind of above-mentioned reduction pig manure using the pig manure in the method for Swine manure, step (5) Specially:Addition accounts for material gross weight 35-40% auxiliary material in toward processing pond, and stack retting area is transferred to after being again stirring for uniformly, is capped Plastic sheeting is converted, and conversion temperature is controlled at 50 ° -80 °, and interval is turned over once for 2-3 days;Transformation time is 20-60 days, obtains pig Excrement organic fertilizer.
Arsenic content and prepared in a kind of above-mentioned reduction pig manure using the pig manure in the method for Swine manure, step (5) In, the auxiliary material is made up of the material of following weight percentage:Mineral powder 0-8%, coarse fiber material 90-98%, vinasse powder 1- 3%.
Arsenic content and prepared in a kind of above-mentioned reduction pig manure using the pig manure in the method for Swine manure, step (5) In, the mineral powder is the powder that residual ore is ground into coal mining.
Arsenic content and prepared in a kind of above-mentioned reduction pig manure using the pig manure in the method for Swine manure, it is described thick fine It is the combination of any one or more in mushroom fertilizer slag, celestial being's grass meal, coffee grounds, bran powder and dregs of beans to tie up material.
The present invention uses above-mentioned technique, by the effect of ethanol, the material in pig manure is produced change, then with highly basic And have positive effect to drop low arsenic content, realize pig manure recycling, reduce the As polluted soil in pig manure, then pass through Addition auxiliary material stack retting obtains Swine manure, ensures food safety.
Embodiment
With reference to specific embodiment, the present invention is described in further detail, but does not form to any of the present invention Limitation.
Arsenic content and the method that Swine manure is prepared using the pig manure, this method bag in a kind of reduction pig manure of the present invention Include following step:
(1) pig manure in plant is collected using suction-type sewer scavenger and is transported to factory and pours into processing pond, by pig manure per ton Add 30-80 kilograms of ethanol, carry out first time stirring, after stirring stand 12-48 hours, pig manure by original lumps it is sour, it is smelly, Fishy smell changes into dispersed by ethanol and produces stronger ammonia taste, and pig manure Ph values are 1-5 after standing.
(2) add after the completion of ethanol stirring standing, adding 30-80 kilograms of sodium hydroxide by pig manure per ton enters processing pond In, 12-48 hours are stood after stirring, pig manure is yellowish by blacking.Neutralized using highly basic, have positive effect to drop low arsenic content.
(3) add after the completion of sodium hydroxide standing, the standard that 20-70 kilograms of pulverized limestone is added by pig manure per ton weighs lime Powder, be uniformly divided into trisection, often plus a pulverized limestone, added again after stirring, so repeatedly uniform stirring three times after, pig manure Ph values bring up to 7-13 by original 1-5, and pig manure temperature is lifted to 40 ° -43 ° by original normal temperature, the lower microbe conversion 12- of static state 36 hours.Pulverized limestone, which meets water, can produce calcium carbonate, play mitigation and stabilization, while produce high heat in its course of reaction, Pig manure temperature can be improved, there is deodorization, sterilization and sterilization.
(4) add after the completion of pulverized limestone standing, add 10-40 kilograms of sulfuric acid by pig manure per ton is stirred into processing pond Mix, using the Ph values in acid-base neutralization regulation pig manure to 6.5-8, obtain the pig manure that arsenic content meets national standard.
(5) material gross weight 35-40% auxiliary material is accounted for toward addition in processing pond, stack retting area is transferred to after being again stirring for uniformly, Covered plastic film is converted, and conversion temperature is controlled at 50 ° -80 °, and interval is turned over once for 2-3 days;Transformation time is 20-60 days, Obtain Swine manure.The auxiliary material is made up of the material of following weight percentage:Mineral powder 0-8%, coarse fiber material 90- 98%th, vinasse powder 1-3%.The coarse fiber material is any in mushroom fertilizer slag, celestial being's grass meal, coffee grounds, bran powder and dregs of beans One or more combinations.Mineral powder is the powder that residual ore is ground into coal mining.
Mushroom fertilizer slag, itself it is to use the crude fibre materials such as straw, cornstalk, adds active bacteria to form, after the harvesting of mushroom class, its Remaining bacterium and crude fibre in waste material are all present, and play a part of to suppress conversion, water suction as auxiliary material.
Celestial being's grass meal, alkalescence, category crude fibre, have the function that to absorb water and suppress acid.
Coffee grounds, there is strong fragrance, plays a part of to neutralize stink, Coffea pulse family class, protein in process of production Content is high, can increase nutrient.
Dregs of beans, Main Ingredients and Appearance are protein, increase organic fertilizer nutrient content.
Bran powder, Main Ingredients and Appearance is lignin and crude fibre, for absorbing water, and turns into the nutrient of organic fertilizer after decomposed.
It vinasse powder, also containing wine composition, can both absorb water, and be the material of the high nutrient of organic fertilizer again, while can also increase Fermentation temperature.
Pig manure moisture content reaches 70-80%, though being converted through ethanol, ground caustic, pulverized limestone, arsenic element therein still has residual, no It may be wholly absent, pig manure develops as recycling, the reduction of water content, it is necessary to have crude fibre material to absorb water Part, the auxiliary material used in this project is all related to alkalescence and crude fibre, although ethanol decomposes the lumps in pig manure, pig Starch residual proportion in excrement is excessive, when fading away for alcohol, the very strong agglomerate phenomenon of viscosity still occurs, with alkalescence Crude fibre makees auxiliary material, plays complementary effect.
Test case 1
Same Meizhou pork pig field takes 1000 grams of pig manure sample, adds 30 grams of ethanol and is tentatively stirred, pig in stirring Excrement glues bulk and decomposed rapidly, and sour fishy smell switchs to one ammonia taste.Stirring adds 30 grams of sodium hydroxide after 2 to 3 minutes, carries out second Stirring, ammonia taste starts to alleviate in stirring, pig manure color by it is black change into it is faint yellow.After stirring 2 to 3 minutes, pulverized limestone 20 is added Gram it is again stirring for, pig manure is brown after stirring, slightly alkali taste, and the sour raw meat and ammonia taste in pig manure all disappear.The Ph of pig manure Value is brought up between 9-10, and temperature is brought up between 30-33 degree, and static transformation fermentation adds 10 grams of sulfuric acid and carried out after 12 hours Stirring, adjusts Ph values, and pH value is controlled between 7-8.
After sample dries after seven days, 250 grams of feeding sample detects to the chemical examination of Meizhou City Minister of the General Administration for Quality Supervision, testing result arsenic content (with Wet basis meter):8.8mg/kg, the dry and wet scale merit (testing number × 100 ÷ 70) provided according to quality testing department calculate:To dry base Meter arsenic is 8.8 × 100 ÷ 70=11.73mg/kg, and arsenic contains compared with the content 18.9mg/kg of the arsenic of first time examining report Amount disappears 38%.
Test case 2
Same Meizhou pork pig field takes 1000 grams of pig manure sample, adds 50 grams of ethanol and is tentatively stirred, pig in stirring Excrement glues bulk and decomposed rapidly, and sour fishy smell switchs to pungent ammonia taste.Stirring adds 50 grams of sodium hydroxide after 2 to 3 minutes, carries out second Secondary stirring, ammonia taste starts to alleviate in stirring, and pig manure color changes into buff by black.After stirring 2 to 3 minutes, pulverized limestone is added 40 grams are again stirring for, and pig manure is brown after stirring, slightly heavy alkali taste, and the sour raw meat and ammonia taste in pig manure all disappear.Pig manure PH value bring up between 11-12, temperature is brought up between 36-38 degree, and static transformation fermentation is after 24 hours, adds 25 grams of sulfuric acid It is stirred, adjusts pH value, pH value is controlled between 7-8.
Sample drying is dry after seven days takes 500 grams to be sent to the chemical examination detection of Meizhou City Minister of the General Administration for Quality Supervision, and testing result arsenic content is (with wet basis Meter):5.6mg/kg, the dry and wet scale merit (testing number × 100 ÷ 70) provided according to quality testing department calculate:The arsenic in terms of drying base For 5.6 × 100 ÷ 70=8mg/kg, the disappearance amplitude of arsenic reduces by 27% again compared with case 1.
Case 2 compares with former pig manure censorship for the first time, and the content of arsenic disappears 10.9mg/kg, and disappearance amplitude is 65%.
Test case 3
Same Meizhou pork pig field takes 1000 grams of pig manure sample, adds 80 grams of ethanol and is tentatively stirred, pig in stirring Excrement glues bulk and decomposed rapidly, and sour fishy smell switchs to stronger pungent ammonia taste.Stirring adds 80 grams of sodium hydroxide after 2 to 3 minutes, carries out Second of stirring, ammonia taste starts to alleviate in stirring, and pig manure color changes into buff by black.After stirring 2 to 3 minutes, stone is added 70 grams of ashes is again stirring for, and pig manure is brown after stirring, band weight alkali taste, and the sour raw meat and ammonia taste in pig manure all disappear.Pig The pH value of excrement is brought up between 12-13, and temperature is brought up between 40-43 degree, and static transformation fermentation adds 40 grams of sulphur after 36 hours Acid is stirred, and adjusts pH value, and pH value is controlled between 6.5-8.
Sample drying is dry after seven days takes 250 grams to be sent to the chemical examination detection of Meizhou City Minister of the General Administration for Quality Supervision, and testing result arsenic content is (with drying Base meter):4.8mg/kg, count arsenic with former pig manure censorship for the first time to dry base and compareed as 18.9mg/kg, the content of arsenic disappears 14.1mg/kg, disappearance amplitude are 75%.
Prove through test of many times, first stimulated with ethanol, pig manure is changed, then the arsenic in pig manure is disappeared with ground caustic, Effect develops it is clear that along with the regulation of " day clear day is clean " is implemented to the recycling of pig manure.Reduce cultivation opposite Layer pollution must be feasible.
Embodiment provided above is the better embodiment of the present invention, is only used for the convenient explanation present invention, not to this hair It is bright to make any formal limitation, any those of ordinary skill in the art, if putting forward skill not departing from the present invention In the range of art feature, using the equivalent embodiment for locally changing or modifying made by disclosed technology contents, and Without departing from the technical feature content of the present invention, in the range of still falling within the technology of the present invention feature.

Claims (6)

1. a kind of reduce arsenic content and the method that Swine manure is prepared using the pig manure in pig manure, it is characterised in that this method Comprise the steps:
(1) pig manure in plant is collected using suction-type sewer scavenger and is transported to factory and pours into processing pond, added by pig manure per ton 30-80 kilograms of ethanol, first time stirring is carried out, 12-48 hours are stood after stirring, pig manure is by original lumps are sour, smelly, fishy smell Dispersed is changed into by ethanol and produces stronger ammonia taste, pig manure Ph values are 1-5 after standing;
(2) add after the completion of ethanol stirring standing, adding 30-80 kilograms of sodium hydroxide by pig manure per ton enters in processing pond, stirs 12-48 hours are stood after mixing, pig manure is yellowish by blacking;
(3) add after the completion of sodium hydroxide standing, adding 20-70 kilograms of pulverized limestone by pig manure per ton enters in processing pond, stirring After uniformly, static lower microbe conversion 12-36 hours;
(4) add after the completion of pulverized limestone standing, add 10-40 kilograms of sulfuric acid by pig manure per ton is stirred into processing pond, profit With the Ph values in acid-base neutralization regulation pig manure to 6.5-8, the pig manure that arsenic content meets national standard is obtained;
(5) material gross weight 35-40% auxiliary material is accounted for toward addition in processing pond, stack retting area is transferred to after being again stirring for uniformly, is capped Plastic sheeting is converted, and obtains Swine manure.
A kind of reduce arsenic content in pig manure 2. according to claim 1 and the side of Swine manure is prepared using the pig manure Method, it is characterised in that step (3) is specially:Add after the completion of sodium hydroxide standing, 20-70 kilograms of stone is added by pig manure per ton The standard of ashes weighs pulverized limestone, is uniformly divided into trisection, often adds a pulverized limestone, is added again after stirring, so repeatedly Uniform stirring three times after, pig manure Ph values bring up to 7-13 by original 1-5, pig manure temperature by original normal temperature lifting to 40 °- 43 °, static lower microbe conversion 12-36 hours.
A kind of reduce arsenic content in pig manure 3. according to claim 1 and the side of Swine manure is prepared using the pig manure Method, it is characterised in that step (5) is specially:Addition accounts for material gross weight 35-40% auxiliary material in toward processing pond, is again stirring for Stack retting area is transferred to after uniformly, covered plastic film is converted, and conversion temperature is controlled at 50 ° -80 °, and interval is turned over once for 2-3 days; Transformation time is 20-60 days, obtains Swine manure.
4. arsenic content and prepare Swine manure using the pig manure in a kind of reduction pig manure according to claim 1 or 3 Method, it is characterised in that in step (5), the auxiliary material is made up of the material of following weight percentage:Mineral powder 0-8%, thick fibre Tie up material 90-98%, vinasse powder 1-3%.
A kind of reduce arsenic content in pig manure 5. according to claim 4 and the side of Swine manure is prepared using the pig manure Method, it is characterised in that in step (5), the mineral powder is the powder that residual ore is ground into coal mining.
A kind of reduce arsenic content in pig manure 6. according to claim 4 and the side of Swine manure is prepared using the pig manure Method, it is characterised in that the coarse fiber material is any one in mushroom fertilizer slag, celestial being's grass meal, coffee grounds, bran powder and dregs of beans Or a variety of combination.
CN201710802488.3A 2017-09-07 2017-09-07 Arsenic content and the method that Swine manure is prepared using the pig manure in a kind of reduction pig manure Pending CN107445668A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101322974A (en) * 2008-07-04 2008-12-17 安徽省农业科学院土壤肥料研究所 Soil heavy metal passivation agent for vegetable field
CN101712040A (en) * 2009-12-02 2010-05-26 童风 Heavy metal relative-inactivation treating agent and use method thereof
CN103723897A (en) * 2013-12-04 2014-04-16 刘军亮 Processing technology for sterilization, deodorization, dehydration and heavy metal removing of sludge
CN104645385A (en) * 2013-11-18 2015-05-27 青岛水世界环保科技有限公司 Pig manure deodorant
CN106977312A (en) * 2017-05-12 2017-07-25 巴马原种香猪农牧实业有限公司 A kind of preparation method of efficient biologic-organic fertilizer
CN107129323A (en) * 2017-05-12 2017-09-05 巴马原种香猪农牧实业有限公司 A kind of preparation method of solid organic fertilizer

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101322974A (en) * 2008-07-04 2008-12-17 安徽省农业科学院土壤肥料研究所 Soil heavy metal passivation agent for vegetable field
CN101712040A (en) * 2009-12-02 2010-05-26 童风 Heavy metal relative-inactivation treating agent and use method thereof
CN104645385A (en) * 2013-11-18 2015-05-27 青岛水世界环保科技有限公司 Pig manure deodorant
CN103723897A (en) * 2013-12-04 2014-04-16 刘军亮 Processing technology for sterilization, deodorization, dehydration and heavy metal removing of sludge
CN106977312A (en) * 2017-05-12 2017-07-25 巴马原种香猪农牧实业有限公司 A kind of preparation method of efficient biologic-organic fertilizer
CN107129323A (en) * 2017-05-12 2017-09-05 巴马原种香猪农牧实业有限公司 A kind of preparation method of solid organic fertilizer

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Application publication date: 20171208