CN107406258A - 使用极化的铁电聚合物无缺陷地直接干法层离cvd石墨烯 - Google Patents

使用极化的铁电聚合物无缺陷地直接干法层离cvd石墨烯 Download PDF

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Publication number
CN107406258A
CN107406258A CN201680017209.6A CN201680017209A CN107406258A CN 107406258 A CN107406258 A CN 107406258A CN 201680017209 A CN201680017209 A CN 201680017209A CN 107406258 A CN107406258 A CN 107406258A
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China
Prior art keywords
graphene
layer
substrate
polarization
ferroelectric
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CN201680017209.6A
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English (en)
Chinese (zh)
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B·欧伊尔迈兹
I·马丁费尔南德斯
C·T·卓
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National University of Singapore
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National University of Singapore
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Priority to CN202010984483.9A priority Critical patent/CN112194120B/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/06—Interconnection of layers permitting easy separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/10—Removing layers, or parts of layers, mechanically or chemically
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • B32B37/025—Transfer laminating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/16—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
    • B32B37/18—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating involving the assembly of discrete sheets or panels only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C01B32/19—Preparation by exfoliation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/194—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16—Homopolymers or copolymers of vinylidene fluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/246—Vapour deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0223—Vinyl resin fibres
    • B32B2262/0238—Vinyl halide, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2313/00—Elements other than metals
    • B32B2313/04—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Laminated Bodies (AREA)
CN201680017209.6A 2015-02-03 2016-02-03 使用极化的铁电聚合物无缺陷地直接干法层离cvd石墨烯 Pending CN107406258A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010984483.9A CN112194120B (zh) 2015-02-03 2016-02-03 使用极化的铁电聚合物无缺陷地直接干法层离cvd石墨烯

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562111195P 2015-02-03 2015-02-03
US62/111,195 2015-02-03
PCT/SG2016/050057 WO2016126208A1 (en) 2015-02-03 2016-02-03 Defect-free direct dry delamination of cvd graphene using a polarized ferroelectric polymer

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CN201680017209.6A Pending CN107406258A (zh) 2015-02-03 2016-02-03 使用极化的铁电聚合物无缺陷地直接干法层离cvd石墨烯

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JP (1) JP6749942B2 (ja)
KR (1) KR102256000B1 (ja)
CN (2) CN112194120B (ja)
WO (1) WO2016126208A1 (ja)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587040B (zh) * 2016-12-29 2019-02-15 浙江合特光电有限公司 石墨烯薄膜的衬底转移方法
GB2570127B (en) * 2018-01-11 2022-06-22 Paragraf Ltd A method of making graphene structures
CN113195230A (zh) * 2018-11-30 2021-07-30 纽约州州立大学研究基金会 用于将石墨烯从金属衬底中转移出来的方法
KR102319610B1 (ko) 2020-04-10 2021-10-29 서울대학교산학협력단 잔류물 없이 그래핀을 전사하는 방법
WO2022086449A1 (en) * 2020-10-22 2022-04-28 National University Of Singapore Photodetector with ferroelectric polymer, quantum dots and graphene
JP2024513683A (ja) * 2021-03-12 2024-03-27 ナショナル ユニヴァーシティー オブ シンガポール 多層複合材料

Citations (4)

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CN103318879A (zh) * 2013-06-28 2013-09-25 重庆墨希科技有限公司 基于转移薄膜的石墨烯制备方法
WO2014055040A1 (en) * 2012-10-03 2014-04-10 National University Of Singapore Touch screen devices employing graphene networks with polyvinylidene fluoride films
CN104016335A (zh) * 2014-05-30 2014-09-03 无锡格菲电子薄膜科技有限公司 一种石墨烯的转移方法
CN104016340A (zh) * 2014-06-30 2014-09-03 上海集成电路研发中心有限公司 一种转移石墨烯薄膜的方法

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US9082523B2 (en) * 2010-11-10 2015-07-14 National University Of Singapore Transparent conductor
SG11201405728XA (en) * 2012-03-23 2014-10-30 Univ Singapore Photovoltaic cell with graphene-ferroelectric electrode
US9184553B2 (en) * 2012-06-06 2015-11-10 National University Of Singapore Gate-tunable graphene-ferroelectric hybrid structure for photonics and plasmonics
WO2015084268A1 (en) * 2013-12-05 2015-06-11 National University Of Singapore Graphene tape

Patent Citations (4)

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WO2014055040A1 (en) * 2012-10-03 2014-04-10 National University Of Singapore Touch screen devices employing graphene networks with polyvinylidene fluoride films
CN103318879A (zh) * 2013-06-28 2013-09-25 重庆墨希科技有限公司 基于转移薄膜的石墨烯制备方法
CN104016335A (zh) * 2014-05-30 2014-09-03 无锡格菲电子薄膜科技有限公司 一种石墨烯的转移方法
CN104016340A (zh) * 2014-06-30 2014-09-03 上海集成电路研发中心有限公司 一种转移石墨烯薄膜的方法

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GUILHERMINO J.M. FECHINE等: "Direct dry transfer of chemical vapor deposition graphene to polymeric substrates", 《CARBON》 *

Also Published As

Publication number Publication date
KR102256000B1 (ko) 2021-05-25
KR20170110133A (ko) 2017-10-10
JP6749942B2 (ja) 2020-09-02
WO2016126208A1 (en) 2016-08-11
JP2018512370A (ja) 2018-05-17
CN112194120A (zh) 2021-01-08
CN112194120B (zh) 2022-06-10

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