CN107377153A - High temperature circulation nitrogen protects crushing and classification production line - Google Patents

High temperature circulation nitrogen protects crushing and classification production line Download PDF

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Publication number
CN107377153A
CN107377153A CN201710797040.7A CN201710797040A CN107377153A CN 107377153 A CN107377153 A CN 107377153A CN 201710797040 A CN201710797040 A CN 201710797040A CN 107377153 A CN107377153 A CN 107377153A
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CN
China
Prior art keywords
crushing
high temperature
nitrogen
production line
outlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710797040.7A
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Chinese (zh)
Inventor
吴建明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Miyou Powder New Equipment Manufacturing Co Ltd
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Jiangsu Miyou Powder New Equipment Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Miyou Powder New Equipment Manufacturing Co Ltd filed Critical Jiangsu Miyou Powder New Equipment Manufacturing Co Ltd
Priority to CN201710797040.7A priority Critical patent/CN107377153A/en
Publication of CN107377153A publication Critical patent/CN107377153A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C19/00Other disintegrating devices or methods
    • B02C19/06Jet mills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/18Adding fluid, other than for crushing or disintegrating by fluid energy
    • B02C23/24Passing gas through crushing or disintegrating zone
    • B02C23/34Passing gas through crushing or disintegrating zone gas being recirculated to crushing or disintegrating zone
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B21/00Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
    • F26B21/14Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects using gases or vapours other than air or steam, e.g. inert gases

Abstract

The invention provides high temperature circulation nitrogen to protect crushing and classification production line, and it make it that the Granularity Distribution that obtains is narrow after crushing, and product particle surface is smooth; shape is regular, and activity is big, good dispersion; polluted without metal, oxide etc., product purity is high, meets the needs of lithium ion battery material.It includes the feed bin for loading particle to be comminuted, the outlet of the feed bin connects the disintegrating area of the fluidized bed air flow crusher, the disintegrating area of the fluidized bed air flow crusher is connected to graded region, the corase particles for being unsatisfactory for Particle size requirements return disintegrating area is continued to crush by graded region, meet that the fine particle of Particle size requirements enters the entrance of deduster with air-flow, the material outlet connection finished product packaging facilities of the deduster, the non-material outlet in top of the deduster is connected to the entrance of first filter, the outlet of the first filter is connected to drier entrance, the outlet of the drier is connected to the air entry of the compressor.

Description

High temperature circulation nitrogen protects crushing and classification production line
Technical field
The present invention relates to the technical field of crushing material production, specially high temperature circulation nitrogen protection crushing and classification production Line.
Background technology
There is lithium ion battery high power capacity rechargeable battery, bigger than energy, have extended cycle life, and have a safety feature, and be mesh It is preceding most to have development potentiality battery.Anode material of lithium battery includes LiFePO4, Manganese acid lithium, lithium carbonate, Cobalt acid lithium, Nie Cobalt Manganese acid lithiums Ternary material etc., lithium cell cathode material include lithium titanate, graphite, Si-C composite material etc., and the common feature of these materials is Particle diameter is small, narrow particle size distribution, particle surface shape is regular, water content is low, product purity is high, but existing crushing and classification produces The raw material that line produces acquisition can not efficiently obtain above-mentioned material.
The content of the invention
In view of the above-mentioned problems, the invention provides high temperature circulation nitrogen to protect crushing and classification production line, after it causes crushing The Granularity Distribution of acquisition is narrow, and product particle surface is smooth, and shape is regular, and activity is big, good dispersion, no metal, oxide It is high Deng pollution, product purity, meet the needs of lithium ion battery material.
High temperature circulation nitrogen protects crushing and classification production line, it is characterised in that:It includes the feed bin for loading particle to be comminuted, The outlet of the feed bin connects the disintegrating area of the fluidized bed air flow crusher, and the disintegrating area of the fluidized bed air flow crusher connects Graded region is connected to, the corase particles for being unsatisfactory for Particle size requirements return disintegrating area is continued to crush by graded region, meets the thin of Particle size requirements Particle enters the entrance of deduster with air-flow, and the material outlet of the deduster connects finished product packaging facilities, the deduster The non-material outlet in top is connected to the entrance of first filter, and the outlet of the first filter is connected to drier entrance, institute The outlet for stating drier is connected to the air entry of the compressor, on the connecting line between the drier and the compressor It is provided with and adds nitrogen inlet, the gas outlet of the compressor is connected to the entrance of the second filter, second filter The entrance of outlet connection heater, the outlet of the heater access the nozzle entrance of the fluidized bed air flow crusher, material Accelerate in the supersonic jet that nozzle is ejected, and reach crushing in the repeated stock of injection stream intersection, collision, friction Effect, crushing while material are by high temperature drying nitrogen wink-dry.
It is further characterized by:
The production line is applied to crush lithium battery material;
The recovery low-pressure nitrogen of the non-material outlet separation in top of the deduster, compressor is returned after filtered, dry Air entry, and be mixed into compressor with adding nitrogen, high pressure nitrogen filters, heats laggard fluidized bed gas again after compression Stream, which crushes machine nozzle, to be continued to crush, and the low-pressure nitrogen of system recycles;
The pressure for entering the high temperature drying nitrogen that disintegrating area carries out comminution process is 0.3MPa-0.9MPa, temperature 120 ℃-200℃;
The product fineness d after the lithium battery positive and negative pole material crushing and classification that the production line is obtained50=0.3~10 μ m;
Preferably, the smashing fineness d of the crushing LiFePO 4 obtained by the production line97For 5.0 μm, as new Type lithium ion battery electrode material, battery security is improved, promote lithium ion battery maximization, the application of high power;
Preferably, the smashing fineness d of the crushing neodymium iron boron obtained by the production line97For 5.1 μm, it has high Magnetic energy product and high-energy-density, be applied widely in instrument and meter and electronic technology;
Preferably, the smashing fineness d for crushing lithium titanate, graphite obtained by the production line97For 5.5 μm, can use Make new type lithium ion battery negative electrode material;
Preferably, the smashing fineness d of the comminuting coke obtained by the production line505.0 μm of <, it is lithium ion battery Negative electrode material product opens a brand-new material.
After technology using the present invention, material dosing adds the disintegrating area of fluidized bed air flow crusher in feed bin, and material exists Accelerate in supersonic jet, and reach crushing effect in the repeated stock of injection stream intersection, collision, friction, crush lithium simultaneously Battery material is entered graded region with ascending air by the material for crushing dry, is classified by high temperature drying nitrogen wink-dry The corase particles return disintegrating area for being unsatisfactory for Particle size requirements afterwards continues to crush, and meets that the fine particle of Particle size requirements enters dedusting with air-flow Device is collected, and the recovery low-pressure nitrogen of deduster top separation, compressor air suction mouth is returned to after filtered, dry, and with adding nitrogen Gas is mixed into compressor, and high pressure nitrogen filters, heats laggard fluidized bed air-flow crushing machine nozzle continuation powder again after compression Broken, system low-voltage nitrogen circulation uses, and deduster lower product is collected into finished product packing machine, the system can meet it is safe and environment-friendly, Energy-conservation, clean manufacturing requirement;The water content 1000-8000ppm before anode material of lithium battery crushing, anode material of lithium battery crush Water content is that 500-1200ppm, its moisture content are low afterwards;It make it that the Granularity Distribution that obtains is narrow after crushing, product particle table Face is smooth, and shape is regular, and activity is big, good dispersion, and the pollution such as no metal, oxide, product purity is high, meets lithium ion battery The demand of material.
Brief description of the drawings
Fig. 1 is the front view structure schematic diagram of the present invention;
Title in figure corresponding to sequence number is as follows:
Feed bin 1, fluidized bed air flow crusher 2, deduster 3, finished product packing equipment 4, first filter 5, drier 6, pressure Contracting machine 7, add nitrogen inlet 8, the second filter 9, heater 10.
Embodiment
High temperature circulation nitrogen protects crushing and classification production line, sees Fig. 1:It includes the feed bin 1 for loading particle to be comminuted, feed bin The disintegrating area of 1 outlet connection fluidized bed air flow crusher 2, the disintegrating area of fluidized bed air flow crusher 2 are connected to graded region, point The corase particles for being unsatisfactory for Particle size requirements return disintegrating area is continued to crush by level area, meets that the fine particle of Particle size requirements enters with air-flow The entrance of deduster 3, the material outlet connection finished product packaging facilities 4 of deduster 3, the non-material outlet connection in top of deduster 3 To the entrance of first filter 5, the outlet of first filter 5 is connected to the entrance of drier 6, and the outlet of drier 6 is connected to pressure The air entry of contracting machine 7, it is provided with the connecting line between drier 6 and compressor 7 and adds nitrogen inlet 8, compressor 7 goes out Gas port is connected to the entrance of the second filter 9, the entrance of the outlet connection heater 10 of the second filter 9, and heater 10 goes out The nozzle entrance of mouth access fluidized bed air flow crusher 2, material accelerate in the supersonic jet that nozzle is ejected, and The repeated stock of injection stream intersection, collision, friction reaches crushing effect, crushed while material is done by high temperature drying nitrogen moment It is dry.
The production line is applied to crush lithium battery material;
The recovery low-pressure nitrogen of the non-material outlet separation in top of deduster 3, compressor 7 is returned after filtered, dry Air entry, and compressor 7 is mixed into adding nitrogen, high pressure nitrogen filters, heats laggard fluidized bed gas again after compression The nozzle of stream pulverizer 2 continues to crush, and the low-pressure nitrogen of system recycles;
The pressure for entering the high temperature drying nitrogen that disintegrating area carries out comminution process is 0.3MPa-0.9MPa, temperature 120 ℃-200℃;
The product fineness d after the lithium battery positive and negative pole material crushing and classification that production line is obtained50=0.3~10 μm.
It is caused to have the beneficial effect that after production line using the present invention:
1 Granularity Distribution is narrow, and particle diameter can be in d50=0.3~10 μ ms are arbitrarily selected;
2 product particle surfaces are smooth, and shape is regular, and activity is big, good dispersion, the pollution such as no metal, oxide, and product is pure Degree is high;
3 crushing and classifications are being carried out in closed system, no dust effusion;Charging system is totally-enclosed uniform feeding device, Charging rate automatically adjusts with systemic concentration change;
4 use advanced Automated condtrol, running status real-time display, realize full-automatic control.
Specific embodiment one:The smashing fineness d of the crushing LiFePO 4 obtained by production line97For 5.0 μm, it is used as New type lithium ion battery electrode material, battery security is improved, promote lithium ion battery maximization, the application of high power.
Specific embodiment two:The smashing fineness d of the crushing neodymium iron boron obtained by production line97For 5.1 μm, it has pole High magnetic energy product and high-energy-density, is applied widely in instrument and meter and electronic technology;
Specific embodiment three:The smashing fineness d for crushing lithium titanate, graphite obtained by production line97, can for 5.5 μm As new type lithium ion battery negative electrode material;
Specific embodiment four:The smashing fineness d of the comminuting coke obtained by production line505.0 μm of <, it is lithium-ion electric Pond negative electrode material product opens a brand-new material.
The specific embodiment of the present invention is described in detail above, but content is only the preferable implementation of the invention Example, it is impossible to be considered as the practical range for limiting the invention.All impartial changes made according to the invention application range Change and improvement etc., all should still be belonged within this patent covering scope.

Claims (9)

1. high temperature circulation nitrogen protects crushing and classification production line, it is characterised in that:It includes the feed bin for loading particle to be comminuted, institute The outlet for stating feed bin connects the disintegrating area of the fluidized bed air flow crusher, the disintegrating area connection of the fluidized bed air flow crusher To graded region, the corase particles for being unsatisfactory for Particle size requirements return disintegrating area is continued to crush by graded region, meets the particulate of Particle size requirements Son with air-flow enter deduster entrance, the deduster material outlet connection finished product packaging facilities, the deduster it is upper The non-material outlet in portion is connected to the entrance of first filter, and the outlet of the first filter is connected to drier entrance, described The outlet of drier is connected to the air entry of the compressor, is set on the connecting line between the drier and the compressor It is equipped with and adds nitrogen inlet, the gas outlet of the compressor is connected to the entrance of the second filter, and second filter goes out The entrance of mouth connection heater, the outlet of the heater access the nozzle entrance of the fluidized bed air flow crusher, and material exists Accelerate in the supersonic jet that nozzle is ejected, and reach crushing effect in the repeated stock of injection stream intersection, collision, friction Fruit, crushing while material are by high temperature drying nitrogen wink-dry.
2. high temperature circulation nitrogen as claimed in claim 1 protects crushing and classification production line, it is characterised in that:The production line is fitted For crushing lithium battery material.
3. high temperature circulation nitrogen as claimed in claim 1 protects crushing and classification production line, it is characterised in that:The deduster The recovery low-pressure nitrogen of the non-material outlet separation in top, the air entry of compressor is returned to after filtered, dry, and with adding nitrogen Compressor is mixed into, high pressure nitrogen filters, heats laggard fluidized bed air-flow crushing machine nozzle and continue to crush again after compression, The low-pressure nitrogen of system recycles.
4. high temperature circulation nitrogen as claimed in claim 1 protects crushing and classification production line, it is characterised in that:Enter disintegrating area The pressure for carrying out the high temperature drying nitrogen of comminution process is 0.3 MPa-0.9 MPa, temperature is 120 DEG C -200 DEG C.
5. high temperature circulation nitrogen as claimed in claim 1 protects crushing and classification production line, it is characterised in that:By the production Product fineness d after the lithium battery positive and negative pole material crushing and classification that line is obtained50=0.3~10 μm.
6. high temperature circulation nitrogen as claimed in claim 1 protects crushing and classification production line, it is characterised in that:By the production The smashing fineness d for the crushing LiFePO 4 that line is obtained97For 5.0 μm, as new type lithium ion battery electrode material, electricity is improved Pond security, promote lithium ion battery maximization, the application of high power.
7. high temperature circulation nitrogen as claimed in claim 1 protects crushing and classification production line, it is characterised in that:By the production The smashing fineness d for the crushing neodymium iron boron that line is obtained97For 5.1 μm, it has high magnetic energy product and high-energy-density, in instrument It is applied widely in instrument and electronic technology.
8. high temperature circulation nitrogen as claimed in claim 1 protects crushing and classification production line, it is characterised in that:By the production What line was obtained crushes lithium titanate, the smashing fineness d of graphite97For 5.5 μm, it can be used as new type lithium ion battery negative electrode material.
9. high temperature circulation nitrogen as claimed in claim 1 protects crushing and classification production line, it is characterised in that:By the production The smashing fineness d for the comminuting coke that line is obtained505.0 μm of <, one is opened entirely for lithium ion battery negative electrode material product New material.
CN201710797040.7A 2017-09-06 2017-09-06 High temperature circulation nitrogen protects crushing and classification production line Pending CN107377153A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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CN107377153A true CN107377153A (en) 2017-11-24

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Publication number Priority date Publication date Assignee Title
CN109092514A (en) * 2018-07-25 2018-12-28 信阳核工业新材料有限公司 A kind of preparation method of high fluidity silica flour
CN109956496A (en) * 2019-04-03 2019-07-02 西南科技大学 A kind of method and device thereof of supersonic airstream dissociation and traces of moisture control
CN111229419A (en) * 2020-01-19 2020-06-05 河北工业职业技术学院 Fluidizing device for shaping metal particles and using method thereof
CN112295717A (en) * 2020-10-14 2021-02-02 宁波江丰电子材料股份有限公司 Device and method for preparing high-purity low-oxygen silicon powder through crushing

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109092514A (en) * 2018-07-25 2018-12-28 信阳核工业新材料有限公司 A kind of preparation method of high fluidity silica flour
CN109956496A (en) * 2019-04-03 2019-07-02 西南科技大学 A kind of method and device thereof of supersonic airstream dissociation and traces of moisture control
CN109956496B (en) * 2019-04-03 2021-07-16 西南科技大学 Supersonic airflow dissociation and trace water content control method and device
CN111229419A (en) * 2020-01-19 2020-06-05 河北工业职业技术学院 Fluidizing device for shaping metal particles and using method thereof
CN112295717A (en) * 2020-10-14 2021-02-02 宁波江丰电子材料股份有限公司 Device and method for preparing high-purity low-oxygen silicon powder through crushing
CN112295717B (en) * 2020-10-14 2022-05-03 宁波江丰电子材料股份有限公司 Device and method for preparing high-purity low-oxygen silicon powder through crushing

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Application publication date: 20171124