CN107344038A - A kind of method for cooking of the complex sintered active carbon filter core of antibacterial zeolite particles - Google Patents

A kind of method for cooking of the complex sintered active carbon filter core of antibacterial zeolite particles Download PDF

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Publication number
CN107344038A
CN107344038A CN201710537070.4A CN201710537070A CN107344038A CN 107344038 A CN107344038 A CN 107344038A CN 201710537070 A CN201710537070 A CN 201710537070A CN 107344038 A CN107344038 A CN 107344038A
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China
Prior art keywords
filter core
bar
active carbon
activated carbon
carbon filter
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CN201710537070.4A
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Chinese (zh)
Inventor
王宗星
万军伟
夏新星
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China University of Geosciences
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China University of Geosciences
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Priority to CN201710537070.4A priority Critical patent/CN107344038A/en
Publication of CN107344038A publication Critical patent/CN107344038A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0442Antimicrobial, antibacterial, antifungal additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10Filtering material manufacturing

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Hydrology & Water Resources (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Agronomy & Crop Science (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

The invention discloses a kind of method for cooking of the complex sintered active carbon filter core of antibacterial zeolite particles, comprise the following steps:(1) raw material is well mixed;(2) well mixed raw material is fitted into mould, and is tentatively pressed into bar-shaped activated carbon;(3) the preliminary compressing bar-shaped activated carbon constant temperature of step (2) is toasted;(4) the bar-shaped activated carbon after step (3) is toasted is cooled to 70 120 DEG C, and is stripped, that is, the bar-shaped activated carbon being molded;(5) bar-shaped activated carbon is subjected to segment, that is, obtains active carbon filter core.Present invention additionally comprises a kind of application of the complex sintered active carbon filter core of antibacterial zeolite particles.Antibacterial effect of the present invention is stable, safe, has a broad antifungal spectrum, heat-resist, service life length, is effectively guaranteed water quality safety, suitable for almost all water purifier models on the market, has very big market value and application prospect.

Description

A kind of method for cooking of the complex sintered active carbon filter core of antibacterial zeolite particles
Technical field
The present invention relates to active carbon filter core technical field, more particularly to the active carbon filter core that a kind of antibacterial zeolite particles are complex sintered Method for cooking.
Background technology
In water purifier industry, all there is all kinds of filter cores, pressure after water purifier usage time has been grown in various water purifiers The accessory breed bacteria such as power bucket, tank, causes that water purifier discharge water Microorganism in Water Indexs measure is exceeded, and this problem is very Great brand water purifier also occurs often, exactly when water purifier is closed untapped, is had inside filter core The water of residual, and the water of this part residual causes water quality tight by immersion for a long time, water degradation, breed bacteria with filtrate reaction Weight is not up to standard, and some harmful bacterias are very big to human injury, and this phenomenon is in pressure pot, the rearmounted filter core of water purifier, such as:It is living Property filtration core, T33 filter cores, mineralising filter core, resin filter element etc. in it is the most serious, therefore, research and develop a kind of effective antibacterial filter core skill Art seems promising important in water purifier sector application.
At present, conventional antimicrobial technology is to utilize the active carbon bacterium resisting technology for carrying silver, but, because its silver-colored stability of load is bad Determine that its antibacterial effect is unstable, therefore, it is difficult to extensive use.
The content of the invention
In view of this, the embodiment provides a kind of antibacterial effect is stable, safe, has a broad antifungal spectrum, heat-resisting Property good, service life length the complex sintered active carbon filter core of antibacterial zeolite particles method for cooking.
Embodiments of the invention provide a kind of method for cooking of the complex sintered active carbon filter core of antibacterial zeolite particles, including following Step:
(1) raw material activated carbon powder, ultra high molecular polyethylene and load silver zinc complex 4A zeolites are well mixed;
(2) raw material that step (1) is well mixed is fitted into mould, and raw material is tentatively pressed into rod using steady pressure Shaped activated carbon;
(3) the preliminary compressing bar-shaped activated carbon constant temperature of step (2) is toasted, baking temperature is 180-205 DEG C, baking Time is 100-150min;
(4) the bar-shaped activated carbon after step (3) is toasted is cooled to 70-120 DEG C, and is stripped, that is, what is be molded is bar-shaped Activated carbon;
(5) bar-shaped activated carbon is subjected to segment, that is, obtains active carbon filter core.
Further, in the step (2), mould is stainless steel mould, steady pressure 8-14.08MPa, steady pressure Press time is 5-15s, and the steady pressure is applied by hydraulic press.
Further, in the step (3), preliminary compressing bar-shaped activated carbon carries out constant temperature baking by constant temperature baking box It is roasting.
Further, in the step (4), the bar-shaped activated carbon after cooling is stripped by hydraulic thrust carbon tool.
A kind of application of the complex sintered active carbon filter core of antibacterial zeolite particles, the active carbon filter core are applied to water purifier.
Compared with prior art, the invention has the advantages that:Resisted by the use of silver zinc complex 4A zeolites are carried as main Microbial inoculum, belong to silver-colored zinc system composite inorganic antibacterial zeolite particles, there is the spy such as safe, has a broad antifungal spectrum, heat-resist, service life length Point;4A zeolites with special construction have the empty structure that can firmly load antibacterial metal ions as carrier, because it is internal, Prepared antiseptic has certain slow-release capability, and stability is higher, is suitably applied in anti-biotic material, moreover, 4A types boil Stone has higher exchange selectivity to silver ion, and its exchange degree can reach more than 75%, and its excellent structure make its with When water contacts, there is great specific surface area, destroy bacterium living beings enzyme, can effectively kill multiple-microorganism in water, bacterium Deng, there is obvious advantage as carrier, and because the superior structural of 4A zeolites causes antiseptic hardly dissolution, Ag, Zn will not be exceeded in water, are effectively guaranteed water quality safety, and it is exceeded to solve purifier filter core, pressure pot bacterium, water outlet Water quality is not up to standard, it is impossible to the problem drunk, substantially increases the practicality and security of water purifier;And the antibacterial filter core cost Relatively low, appearance and size can customize, and not influence the use function and outward appearance of water purifier in itself, suitable for almost all net on the market Water dispenser model, it is used in original purifier to ensure filter core effluent quality security, has very big market value.
Brief description of the drawings
Fig. 1 is a kind of diagrammatic cross-section of the complex sintered active carbon filter core of antibacterial zeolite particles of the present invention.
Fig. 2 is the section enlarged diagram of antiseptic in the present invention.
Fig. 3 is the schematic diagram that a kind of complex sintered active carbon filter core of antibacterial zeolite particles of the present invention is applied to water purifier.
Fig. 4 is a kind of complex sintered active carbon filter core antibacterial effect lab diagram of antibacterial zeolite particles of the present invention.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with accompanying drawing to embodiment party of the present invention Formula is further described.
The embodiment provides a kind of complex sintered active carbon filter core of antibacterial zeolite particles, it is made up of following raw material:
Antiseptic 20-32g, the granularity of antiseptic is 130-220 mesh, and the antiseptic is the composite inorganic antibacterial boiling of silver-colored zinc system Stone, in one embodiment, the antiseptic is is preferably to carry silver zinc complex 4A zeolites, as shown in Fig. 2 carrying silver zinc complex 4A zeolites There is safe, has a broad antifungal spectrum, heat-resist, service life is long;4A zeolites with special construction as carrier, There is the empty structure that can firmly load antibacterial metal ions because it is internal, prepared antiseptic has certain sustained release energy Power, stability is higher, is suitably applied in anti-biotic material, moreover, 4A types zeolite has higher exchange selectivity to silver ion, Its exchange degree can reach more than 75%, and when its excellent structure makes it be contacted with water, have great specific surface area, destroy Fall bacterium living beings enzyme, can effectively kill multiple-microorganism in water, bacterium etc., there is obvious advantage as carrier, And because the superior structural of 4A zeolites causes antiseptic hardly dissolution, Ag, Zn will not be exceeded in water.
Activated carbon powder 300-390g, the granularity of the activated carbon powder is 120-200 mesh.
Ultra high molecular polyethylene 68-75g, the molecular weight of the ultra high molecular polyethylene is 72600-81500.
Also include following raw material:Smectite powder 15-30g, the granularity of the smectite powder is 120-200 mesh, Smectite powder has the function of auxiliary bonding, can effectively improve the pore structure homogeneity of obtained active carbon filter core.
Rectorite powder 10g, the granularity of the rectorite powder is 120-200 mesh.
Modified meerschaum powder 20g, the granularity of the modified meerschaum powder is 80-120 mesh, and modified meerschaum powder has auxiliary Antibacterial effect, enhancing carry the dispersiveness of silver zinc complex 4A zeolites, strengthen overall anti-microbial property.
A kind of method for cooking of the complex sintered active carbon filter core of antibacterial zeolite particles, comprises the following steps:
(1) raw material activated carbon powder, ultra high molecular polyethylene and load silver zinc complex 4A zeolites are well mixed;
(2) raw material that step (1) is well mixed is fitted into mould, and raw material is tentatively pressed into rod using steady pressure Shaped activated carbon;Mould is preferably stainless steel mould, and steady pressure 8-14.08MPa, the press time of steady pressure is 5-15s, The steady pressure is applied by hydraulic press.
(3) the preliminary compressing bar-shaped activated carbon constant temperature of step (2) is toasted, preferentially carried out from constant temperature baking box permanent Temperature baking, baking temperature are 180-205 DEG C, baking time 100-150min;
(4) the bar-shaped activated carbon after step (3) is toasted is cooled to 70-120 DEG C, and is stripped, the bar-shaped activity after cooling Charcoal is stripped by hydraulic thrust carbon tool, that is, the bar-shaped activated carbon being molded;
(5) bar-shaped activated carbon is subjected to segment, that is, active carbon filter core is obtained, as shown in figure 1, the active carbon filter core application In water purifier.
The water purifier is as shown in figure 3, it includes the complex sintered work of water inlet 1, end cap 2, delivery port 3, antibacterial zeolite particles Property filtration core 4 and filter flask 5.
According to standard size to bar-shaped activated carbon segment, and stick on end cap 2, will by taking ten cun of active carbon filter cores 4 as an example Active carbon filter core 4 is arranged in the general filter flask 5 of water purifier, ensures that the rubber blanket of end cap 2 up and down is stuck, by the water inlet of filter flask 5 Mouth 1 connects raw water water source with PE pipes, adjusts to the flow water flowing that water feeding pressure is 0.1-0.4MPa, 1L/min-2L/min.
Whole mark-on test is carried out to active carbon filter core 4, the bacteria-rich water used is voluntarily to place RO pure water 2-4 weeks to make .With 1.2L/min traffic filtering bacteria-rich water, use《The GB/T 5750.12-2006 drinking water standard methods of inspection are micro- Biological indicators》The total plate count of water and bacteria-rich water two water sample of the method detection by the filtering of antibacterial carbon-point, experimental result are as follows Fig. 4 is refer to, as can be seen from Figure 4 in whole mark-on test process, in the range of 0-4000L water process, water tank contains bacterium Water total plate count is in 800-1700CFU/ml, and water outlet total plate count (symbol below 100 after being filtered by active carbon filter core 4 Close national hygiene standard for drinking water), have bactericidal effect it is strong, effect is lasting, bactericidal effect can be maintained at 90 percent with On.
The complex sintered active carbon filter core of a kind of antibacterial zeolite particles provided by the invention can be widely used in household water-purifying machine, Among all filter core purifiers such as campus machine, commercial machine, engineering machine, the practicality of the equipment such as water purifier can be effectively improved And security, solve that purifier filter core, pressure pot bacterium are exceeded, and effluent quality is not up to standard, it is impossible to the problem drunk;And The antibacterial filter core cost is relatively low, and appearance and size can customize, and the use function and outward appearance of water purifier in itself is not influenceed, suitable for several All water purifier models on the market, it is used in original purifier to ensure filter core effluent quality security, had very Big market value.
In the case where not conflicting, the feature in embodiment and embodiment herein-above set forth can be combined with each other.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.

Claims (5)

1. the method for cooking of the complex sintered active carbon filter core of a kind of antibacterial zeolite particles, it is characterised in that comprise the following steps:
(1) raw material activated carbon powder, ultra high molecular polyethylene and load silver zinc complex 4A zeolites are well mixed;
(2) raw material that step (1) is well mixed is fitted into mould, and raw material is tentatively pressed into bar-shaped work using steady pressure Property charcoal;
(3) the preliminary compressing bar-shaped activated carbon constant temperature of step (2) is toasted, baking temperature is 180-205 DEG C, baking time For 100-150min;
(4) the bar-shaped activated carbon after step (3) is toasted is cooled to 70-120 DEG C, and is stripped, that is, the bar-shaped activity being molded Charcoal;
(5) bar-shaped activated carbon is subjected to segment, that is, obtains active carbon filter core.
2. the method for cooking of the complex sintered active carbon filter core of antibacterial zeolite particles according to claim 1, it is characterised in that institute To state in step (2), mould is stainless steel mould, and steady pressure 8-14.08MPa, the press time of steady pressure is 5-15s, The steady pressure is applied by hydraulic press.
3. the method for cooking of the complex sintered active carbon filter core of antibacterial zeolite particles according to claim 1, it is characterised in that institute State in step (3), preliminary compressing bar-shaped activated carbon carries out constant temperature baking by constant temperature baking box.
4. the method for cooking of the complex sintered active carbon filter core of antibacterial zeolite particles according to claim 1, it is characterised in that institute State in step (4), the bar-shaped activated carbon after cooling is stripped by hydraulic thrust carbon tool.
5. the application of the complex sintered active carbon filter core of a kind of antibacterial zeolite particles, it is characterised in that the active carbon filter core is applied to Water purifier.
CN201710537070.4A 2017-07-03 2017-07-03 A kind of method for cooking of the complex sintered active carbon filter core of antibacterial zeolite particles Pending CN107344038A (en)

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN108675429A (en) * 2018-05-21 2018-10-19 中国地质大学(武汉) A kind of alkalescent zinc, the complex sintered active carbon filter core of strontium mineralising and preparation method thereof
CN108726622A (en) * 2018-05-29 2018-11-02 佛山市盟发净水科技有限公司 A kind of activated carbon filter
CN109250781A (en) * 2018-09-30 2019-01-22 江苏斯沃得环保科技有限公司 A kind of preparation method of sintering activity charcoal water purification catridge
CN110935419A (en) * 2019-11-15 2020-03-31 西安重光明宸检测技术有限公司 Active carbon filter element with antibacterial effect and preparation method thereof

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CN1692722A (en) * 2005-04-30 2005-11-09 王明安 Method for producing and regenerating block type antibiotic active molecular product, and products thereof
CN104667634A (en) * 2015-01-29 2015-06-03 佛山市农业总公司 Filtering medium used for removing manganese in drinking water, filter element and preparation method

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675429A (en) * 2018-05-21 2018-10-19 中国地质大学(武汉) A kind of alkalescent zinc, the complex sintered active carbon filter core of strontium mineralising and preparation method thereof
CN108726622A (en) * 2018-05-29 2018-11-02 佛山市盟发净水科技有限公司 A kind of activated carbon filter
CN109250781A (en) * 2018-09-30 2019-01-22 江苏斯沃得环保科技有限公司 A kind of preparation method of sintering activity charcoal water purification catridge
CN110935419A (en) * 2019-11-15 2020-03-31 西安重光明宸检测技术有限公司 Active carbon filter element with antibacterial effect and preparation method thereof

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