CN107324556A - A kind of breeding wastewater pretreating process - Google Patents

A kind of breeding wastewater pretreating process Download PDF

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Publication number
CN107324556A
CN107324556A CN201710666999.7A CN201710666999A CN107324556A CN 107324556 A CN107324556 A CN 107324556A CN 201710666999 A CN201710666999 A CN 201710666999A CN 107324556 A CN107324556 A CN 107324556A
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CN
China
Prior art keywords
breeding wastewater
waste water
solid
passed
water outlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710666999.7A
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Chinese (zh)
Inventor
杨平
李大荣
叶姜瑜
张海军
韩水平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHONGQING RONG JI ENVIRONMENTAL ENGINEERING Co Ltd
Original Assignee
CHONGQING RONG JI ENVIRONMENTAL ENGINEERING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to CN201710666999.7A priority Critical patent/CN107324556A/en
Publication of CN107324556A publication Critical patent/CN107324556A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

Abstract

The present patent application belongs to the processing technology field of water, waste water, sewage or sludge, breeding wastewater pretreating process, including following process:A) separating dry space from moist space process:Breeding wastewater is sequentially passed through into preliminary sedimentation tank, first stage precipitation tank, coarse rack, fine fack and carries out preliminary separation of solid and liquid, the solid suspensions such as the excrement in breeding wastewater, food-residue and various excretas are subjected to preliminary sedimentation and isolation;B) precipitation regulation process:The water outlet of separating dry space from moist space process is passed through sedimentary adjustive pool, precipitated again so that residence time of the breeding wastewater in regulating reservoir is more than 3 days;C) electric flocculation process:Upper strata waste water in step b) in sedimentary adjustive pool is delivered to electric flocculation device with certain flow velocity, then water outlet is passed through in air supporting sedimentation basin and carries out separation of solid and liquid again, water outlet is further processed into rear process.The present invention can reduce phosphorus content, and can improve subsequent biochemical treatment effect.

Description

A kind of breeding wastewater pretreating process
Technical field
The invention belongs to the processing technology field of water, waste water, sewage or sludge.
Background technology
In terms of China's livestock and poultry cultivation, either family's distributing or large-scale cultivation, in the processing of the excretas such as excrement Upper major part is all to use flush-type technique.Flush-type technics comparing is convenient and swift, but shortcoming is also obvious:1st, can be poultry Poultry manure, food-residue and other excretas etc. are flushed in waste water together, therefore contain substantial amounts of solid in breeding wastewater Suspension, solid-liquid mixes viscosity and easily causes treatment facility line clogging greatly;2nd, excrement slag and residue can increase waste water CODcr it is dense Degree, CODcr is at concentrations up to 5000~20000mg/L in livestock breeding wastewater after tested, and BOD5 concentration reaches 2000~8000mg/ L, NH3-N concentration can reach more than 700mg/L, SS at concentrations up to 5000~10000mg/L, with organic concentration it is high, The characteristics of NH3-N concentration is high, SS concentration is high, causes post-processing difficulty big, such as uses biochemical treatment, it will make system operation Organic loading is increased, and the economic input of sewage treatment facility is increased, floor space is big, operation operation is complicated;3rd, in feces of livestock and poultry Containing substantial amounts of pathogenic microorganism, parasitic ovum and the mosquitos and flies multiplied, it can increase cause of disease species in environment, pathogen occur With parasite amount reproduction, spreading for people, animal infectious disease is caused;3rd, with livestock and poultry breeding industry scale, intensive development, The need for diseases prevention and promoting growth of animals or poultry, culturist is largely using antibiotic, hormone, metal trace element etc., medicament residue The excretas such as the excrement with livestock and poultry are emitted, and these are difficult to be degraded directly using biochemical treatment in residue, If discharged in environment, it will cause serious pollution to environment.
To solve the above problems, patent document a kind of " method of aquaculture sewage disposal(ZL201410414699.6)" public A kind of processing method has been opened, following steps are specifically included:(1)Pretreatment:First sewage is removed the gred, acidifying is then hydrolyzed and adjusts Section, makes the non-solubility organic matter in waste water be changed into dissolved organic matter;(2)Biochemical treatment:Pretreated sewage is first By upflow anaerobic sludge blanket reactor UASB processing, then in turn through one-level A/O processing systems, intermediate sedimentation pond, two Level A/O processing systems carry out corresponding biochemical treatment;(3)Dephosphorization and sterilization:Sewage after biochemical treatment is sequentially passed through again and removed Phosphorus, flocculation treatment, remove sediment, and supernatant liquid flows into final deposition pool again, further remove precipitation, and supernatant liquid flows into pH and returned again Pond is adjusted, it is 6~9 to make liquid pH value;Then sterilization processing is carried out, you can qualified discharge.
Pre-treatment step is removed the gred in the above method, solves the problem of solid-liquid is mixed, and has carried out water acidifying, is improved Sewage can life-stylize, but during actual use, also have a disadvantage that:1st, breeding wastewater is to belong to typical C/N and C/P is inclined It is required for carbon source on low waste water, existing denitrification dephosphorization technique, it is bad that carbon source deficiency will result in phosphor-removing effect, in this method Dephosphorization is not carried out in pretreatment process, the carbon source after biological treatment in waste water can be reduced again, so so that into removing When phosphorus is with disinfecting steps, carbon source content is just lower, causes final phosphor-removing effect not good, and the waste water phosphorus content after discharge is still very Height, can cause body eutrophication, cause serious problem of environmental pollution and break Environmental Ecological Balance;2nd, in pretreating process Slagging-off and water acidifying can not remove macromolecular substances, cause waste water still to contain substantial amounts of macromolecular substances, and macromolecular complex Matter can not be made full use of by the anaerobe in biochemical treatment step, cause the effect of biochemical treatment process not good.
The content of the invention
Phosphorus content is reduced the invention discloses one kind, and the pretreatment of the breeding wastewater of subsequent biochemical treatment effect can be improved Technique.
The solution of the present invention content is:Breeding wastewater pretreating process, including following process:
A) separating dry space from moist space process;
Breeding wastewater is sequentially passed through into preliminary sedimentation tank, first stage precipitation tank, coarse rack, fine fack and carries out preliminary separation of solid and liquid, is rested Grow the solid suspensions such as excrement, food-residue and various excretas in waste water and carry out preliminary sedimentation and isolation;
B) precipitation regulation process;
The water outlet of separating dry space from moist space process is passed through sedimentary adjustive pool, precipitated again so that breeding wastewater is in sedimentary adjustive pool The interior residence time is more than 3 days;
C) electric flocculation process;
Upper strata waste water in step b) in sedimentary adjustive pool is delivered to electric flocculation device, water outlet is then passed through air supporting sedimentation basin Separation of solid and liquid is inside carried out again, and water outlet is further processed into rear process.
Beneficial effect:Cause breeding wastewater separation of solid and liquid by precipitating and filtering in step a), make consolidating in breeding wastewater Body suspension removes more than 90% under the process conditions;Step b) effect is on the one hand the solid of part bulky grain is suspended Thing natural sedimentation again, the operating load that process is handled after reduction;On the other hand the organic loading of breeding wastewater is adjusted, makes waste water In insoluble COD materials and nitrogen-containing compound removed substantially, and can remove part solubility COD and nitrogen-containing compound, Not only substantially reduce the load in rear process processing, and the biodegradability of waste water can also be greatly improved, make after wastewater treatment Process is more stablized;The extremely strong high activity flocculation group of generation adsorptivity, on the one hand makes the non-solubility in waste water in step c) An organic matter part is able to air supporting and flocculation sediment, and another part non-solubility organic matter is converted into small molecule, pole by macromolecular The big biodegradability for improving waste water, on the other hand, by the offer of external electric charge, makes the class of protein present in waste water etc. one Electrically charged, nitrogenous organic matter reaches charge neutrality, is removed in the presence of air supporting and flocculation, reduces organic nitrogen in waste water Content, greatly improve the removal efficiency of ammonia nitrogen, finally, electrolysis can also cause phosphorus containg substances in waste water big Amount is removed, and show that the highest clearance of phosphorus can reach more than 98% by experiment.
To sum up, the breeding wastewater after pretreating process of the present invention, on the one hand will make livestock breeding wastewater by solid CODcr declines at least 50% or so again in water outlet after liquid separation, and making the organic loading of rear process at least reduces by 50%, greatly carries The high treatment effect of subsequent handling;On the other hand by reducing phosphorus content in advance, the phosphor-removing effect of finishing operations is improved, and The content of macromolecular substances is reduced, the effect of subsequent biological treatment can be improved, finally makes livestock breeding wastewater in pretreatment Effluent quality is more stablized.
Further, electric flocculation treatment process in the process of running, continuously adds flocculant at waste water inlet, in waste water Outlet continuously adds flocculation aid, to promote the treatment effect of electric flocculation process, reduces out water sedimentation disengaging time.
Further, in step c), deliver in control waste water flow velocity during flocculant, flocculant flow velocity and sedimentary adjustive pool The flow rate of upper strata waste water is 1:500~1:1000, to play the treatment effect of electric flocculation process to greatest extent, reduce it Energy consumption;Flocculant is entered electric flocculation device after being sufficiently mixed with waste water, to improve the treatment effect of electric flocculation, and promote flocculation Agent gives full play to effect.
Further, in step c), control flocculation aid and waste water flow velocity are 1 during dispensing flocculation aid:500~1:1000, The treatment effect of electric flocculation improves more than 10%.
Further, in step c) control waste water in 1~2min of electric flocculation device residence time, electrode plate current density 2~ 8mA/cm2, livestock breeding wastewater CODcr in the water outlet after separation of solid and liquid will be made to decline at least 50% or so again, after making The organic loading of process at least reduces by 50%, and the highest clearance of phosphorus can reach more than 98% during final exclusion waste water.
Further, the flocculant refers to aluminium polychloride or polyaluminium sulfate or ferrous sulfate being configured to mass concentration 10%~20% solution, flocculating effect is optimal.
Further, the flocculation aid is the PAM solution that mass concentration is 0.1%~0.2%, and empirical tests PAM solution helps solidifying Effect is preferable.
Embodiment
Below by embodiment, the present invention is further detailed explanation.
Embodiment
Breeding wastewater pretreating process, including following process:
1. separating dry space from moist space process
Breeding wastewater is sequentially passed through into preliminary sedimentation tank, first stage precipitation tank, coarse rack, fine fack and carries out preliminary separation of solid and liquid, is rested Grow the solid suspensions such as excrement, food-residue and various excretas in waste water and carry out preliminary sedimentation and isolation, make breeding wastewater In solid suspension more than 90% is removed under the process conditions;The process separation of solid and liquid can be using filtering, press filtration, centrifugation etc. Various physics and chemical flocculation and replace.
2. precipitation regulation process
Upper strata breeding wastewater Jing Guo preliminary separation of solid and liquid is passed through sedimentary adjustive pool, precipitated again, it is ensured that breeding wastewater Residence time in sedimentary adjustive pool is more than 3 days.The residence time can determine according to specific water quality situation;
3. electric flocculation process
Upper strata waste water in sedimentary adjustive pool is delivered to the electric flocculation device equipped with battery lead plate.During electric flocculation, in electricity Flocculation plant water inlet is continuously passed through in the polyaluminium chloride solution of mass concentration 10%, launch process and controlled in certain proportion Waste water flow velocity:The flow rate of polyaluminium chloride solution flow velocity and upper strata waste water in sedimentary adjustive pool is 1:600, make polyaluminium chloride molten Liquid enters electric flocculation device after being sufficiently mixed with waste water.Waste water is controlled in electric flocculation device residence time 1min, battery lead plate electric current 2~8mA/cm of density2
The PAM solution that mass concentration is 0.1% is passed through in electric flocculation device delivery port, PAM solution flow rates are controlled:Waste water stream Speed is 1:600.PAM solution can play Coagulation aiding during air supporting and flocculation sediment.
Electric flocculation device water outlet continuously enters the air supporting sedimentation basin of electric flocculation process, and stop is delivered to next for 4~8 hours again Individual biochemical treatment process.After testing, the COD in electric flocculation process in waste water be 1500~below 2000mg/L, ammonia nitrogen be 500~ 800mg/L, total phosphorus are 10~30mg/L.Waste water is sent into subsequent handling again.
Experimental design:The waste water for choosing certain pig breeding farm is handled, and is walked using the pretreatment disclosed in background technology Method is as processing one, pretreating process of the present invention as processing two, and the result after processing is as follows:
Test result indicates that:Compared to traditional preprocess method, by the breeding wastewater that handles of the present invention, CODcr concentration can It is reduced to 1500~2000mg/L, ammonia-nitrogen content can be reduced to 500~800mg/L, suspension content can be reduced to 50~ 400mg/L, total phosphorus content is reduced to 10~30mg/L.After breeding wastewater is by pretreatment process of the present invention, waste water is greatly improved Biodegradability, process is more stablized.

Claims (7)

1. breeding wastewater pretreating process, it is characterised in that including following process:
A) separating dry space from moist space process;
Breeding wastewater is sequentially passed through into preliminary sedimentation tank, first stage precipitation tank, coarse rack, fine fack and carries out preliminary separation of solid and liquid, is rested Grow the solid suspensions such as excrement, food-residue and various excretas in waste water and carry out preliminary sedimentation and isolation;
B) precipitation regulation process;
The water outlet of separating dry space from moist space process is passed through sedimentary adjustive pool, precipitated again, it is ensured that breeding wastewater is in sedimentary adjustive pool The interior residence time is more than 3 days;
C) electric flocculation process;
Upper strata waste water in step b) in sedimentary adjustive pool is delivered to electric flocculation device, water outlet is then passed through air supporting sedimentation basin Separation of solid and liquid is inside carried out again, and water outlet is further processed into rear process.
2. breeding wastewater pretreating process according to claim 1, it is characterised in that:Electric flocculation treatment process was being run Cheng Zhong, continuously adds flocculant at waste water inlet, and flocculation aid is continuously added in the outlet of waste water.
3. breeding wastewater pretreating process according to claim 2, it is characterised in that:In step c), flocculant mistake is delivered The flow rate that upper strata waste water in waste water flow velocity, flocculant flow velocity and sedimentary adjustive pool is controlled in journey is 1:500~1:1000.
4. breeding wastewater pretreating process according to claim 3, it is characterised in that:In step c), flocculation aid mistake is delivered Control flocculation aid with waste water flow velocity 1 in journey:500~1:1000.
5. breeding wastewater pretreating process according to claim 4, it is characterised in that:Control waste water is wadded a quilt with cotton in electricity in step c) Solidifying 1~2min of device residence time, 2~8mA/cm2 of electrode plate current density.
6. breeding wastewater pretreating process according to claim 5, it is characterised in that:The flocculant refers to that chlorine will be polymerize Change aluminium or polyaluminium sulfate or ferrous sulfate is configured to the solution of mass concentration 10%~20%.
7. breeding wastewater pretreating process according to claim 6, it is characterised in that:The flocculation aid is that mass concentration is 0.1%~0.2% PAM solution.
CN201710666999.7A 2017-08-07 2017-08-07 A kind of breeding wastewater pretreating process Pending CN107324556A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710666999.7A CN107324556A (en) 2017-08-07 2017-08-07 A kind of breeding wastewater pretreating process

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Application Number Priority Date Filing Date Title
CN201710666999.7A CN107324556A (en) 2017-08-07 2017-08-07 A kind of breeding wastewater pretreating process

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CN107324556A true CN107324556A (en) 2017-11-07

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113371943A (en) * 2021-06-29 2021-09-10 成都飞创科技有限公司 Method for treating wastewater of farm

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204022605U (en) * 2014-08-12 2014-12-17 毛斌全 A kind of EPN livestock and poultry cultivation blowdown treatment system
CN105541003A (en) * 2015-12-11 2016-05-04 青岛清科环保科技有限公司 Method for treating aquaculture wastewater

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204022605U (en) * 2014-08-12 2014-12-17 毛斌全 A kind of EPN livestock and poultry cultivation blowdown treatment system
CN105541003A (en) * 2015-12-11 2016-05-04 青岛清科环保科技有限公司 Method for treating aquaculture wastewater

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113371943A (en) * 2021-06-29 2021-09-10 成都飞创科技有限公司 Method for treating wastewater of farm

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Application publication date: 20171107