CN107309253B - Production process and production line for preparing high-molecular resin composite solid powder from paint waste residues - Google Patents
Production process and production line for preparing high-molecular resin composite solid powder from paint waste residues Download PDFInfo
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- CN107309253B CN107309253B CN201710678283.9A CN201710678283A CN107309253B CN 107309253 B CN107309253 B CN 107309253B CN 201710678283 A CN201710678283 A CN 201710678283A CN 107309253 B CN107309253 B CN 107309253B
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- 239000003973 paint Substances 0.000 title claims abstract description 98
- 239000002699 waste material Substances 0.000 title claims abstract description 78
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 38
- 239000000843 powder Substances 0.000 title claims abstract description 18
- 239000007787 solid Substances 0.000 title claims abstract description 18
- 239000000805 composite resin Substances 0.000 title 1
- 239000002912 waste gas Substances 0.000 claims abstract description 29
- 239000000428 dust Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 18
- 239000002131 composite material Substances 0.000 claims abstract description 16
- 239000002952 polymeric resin Substances 0.000 claims abstract description 16
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 16
- 238000004064 recycling Methods 0.000 claims abstract description 15
- 239000002351 wastewater Substances 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims description 69
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 51
- 238000005260 corrosion Methods 0.000 claims description 45
- 239000010865 sewage Substances 0.000 claims description 30
- 239000004744 fabric Substances 0.000 claims description 26
- 239000000706 filtrate Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 17
- 239000002893 slag Substances 0.000 claims description 16
- 238000001035 drying Methods 0.000 claims description 15
- 239000007789 gas Substances 0.000 claims description 13
- 238000005520 cutting process Methods 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000010298 pulverizing process Methods 0.000 claims description 10
- 238000004806 packaging method and process Methods 0.000 claims description 9
- 238000011010 flushing procedure Methods 0.000 claims description 7
- 238000011084 recovery Methods 0.000 claims description 7
- 238000011085 pressure filtration Methods 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 5
- 238000012216 screening Methods 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 claims 4
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000003039 volatile agent Substances 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009933 burial Methods 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
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- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
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Abstract
Description
技术领域technical field
本发明涉及废料再生产利用技术领域,尤其涉及一种油漆废渣制备固体粉末生产工艺。The invention relates to the technical field of waste recycling and utilization, in particular to a production process for preparing solid powder from paint waste residue.
背景技术Background technique
涂装是机电产品制造过程中重要的生产工序,涂装方法不同,涂料利用率不同,一般都有20%-50%的油漆变成油漆废渣。废漆渣是国家认定的危险固体废物。据不完全统计,我国每年产生的油漆废渣达到几百万吨,给企业造成严重的经济负担,而且存在严重的环保风险。Coating is an important production process in the manufacturing process of mechanical and electrical products. Different coating methods and different coating utilization rates generally have 20%-50% of the paint turned into paint waste. Waste paint residue is a nationally recognized hazardous solid waste. According to incomplete statistics, my country produces several million tons of paint waste every year, causing serious economic burdens to enterprises and serious environmental risks.
油漆废渣成分与原漆相近,但经过絮凝、沉淀后,性能发生较大变化,而且含有大量水分,再生利用难度较大。目前报道的《一种油漆废渣再生方法(ZL1931928)》受油漆废渣种类、性状影响很大,处理能力有限,难以满足油漆废渣处理要求。也有高温高压裂解、高温焚烧及“无公害掩埋”的报道,但这都是破坏性的处理方法,无法实现资源循环利用,而且成本高、存在二次污染的可能性。还有将丙烯酸/聚氨酯氧涂料废渣作为填料使用的报道(ZL201310633439.3),为其再生利用拓展了渠道。但总体上来说,由于油漆废渣种类多,回收时状态差别大,大量再生利用及其困难,尤其是形成全封闭连续化自动处理的生产工艺与生产线,未见相关报道。The composition of paint waste is similar to that of the original paint, but after flocculation and precipitation, the performance changes greatly, and it contains a lot of water, so it is difficult to recycle. The currently reported "a method for regenerating paint waste residue (ZL1931928)" is greatly affected by the type and properties of paint waste residue, and the processing capacity is limited, which is difficult to meet the requirements of paint waste residue treatment. There are also reports of high temperature and high pressure pyrolysis, high temperature incineration and "pollution-free burial", but these are all destructive treatment methods that cannot realize resource recycling, and have high costs and the possibility of secondary pollution. There is also a report (ZL201310633439.3) on the use of acrylic/polyurethane oxygen paint waste as filler, which expands the channels for its recycling. But in general, due to the variety of paint waste, the state of recovery is very different, and it is difficult to recycle a large amount of waste, especially the production process and production line that forms a fully enclosed continuous automatic treatment, no relevant reports have been reported.
发明内容SUMMARY OF THE INVENTION
为了实现油漆废渣的完全再利用,本发明提供了油漆废渣制备高分子树脂复合固体粉末生产工艺及生产线。In order to realize the complete reuse of paint waste residue, the present invention provides a production process and a production line for preparing polymer resin composite solid powder from paint waste residue.
为了实现上述发明目的,本发明提供了油漆废渣制备高分子树脂复合固体粉末生产工艺及生产线。In order to achieve the above purpose of the invention, the present invention provides a production process and a production line for preparing polymer resin composite solid powder from paint waste.
一种油漆废渣制备高分子树脂复合固体粉末生产工艺,其特征在于,A production process for preparing polymer resin composite solid powder from paint waste, characterized in that:
S1,对油漆废渣进行分类,将最大外形尺寸大于30cm或体积与之相当的大块漆渣从油漆废渣中分离;S1, classify the paint waste, and separate the large pieces of paint slag with a maximum external dimension greater than 30cm or a volume equivalent to it from the paint waste;
S2,将S1中去掉大块漆渣的油漆废渣均匀布料至压滤系统;S2, evenly distribute the paint waste from S1 to the filter press system;
S3,对S2中完成布料后的油漆废渣进行压滤;压滤后得到废水及沥水后的油漆废渣;S3, the paint waste residue after the cloth is completed in S2 is subjected to pressure filtration; after the pressure filtration, waste water and the paint waste residue after draining are obtained;
S4,对S1分类出来的大块漆渣和S3得到的沥水后的油漆废渣进行破碎;S4, crushing the large pieces of paint slag classified in S1 and the drained paint slag obtained in S3;
S5,对S4破碎后的油漆废渣进行干燥;S5, drying the paint waste residue after being broken in S4;
S6,对S5干燥后的油漆废渣进行超细粉碎,超细粉碎后细度从50目到1000目分级收集;S6, superfinely pulverize the dried paint residue in S5, and collect the fineness from 50 mesh to 1000 mesh after superfine pulverization;
S7,对S6得到的物料进行包装;S7, packaging the materials obtained in S6;
所有步骤在封闭的罩体中进行,对S2中得到废水进行收集并做废水处理,对S4至6中得到废气进行收集并做废气处理。All steps are carried out in a closed enclosure, the waste water obtained in S2 is collected and treated with waste water, and the waste gas obtained in S4 to 6 is collected and treated with waste gas.
优选为,所述S2中,Preferably, in the S2,
S201,将S1中分离掉大块漆渣后的油漆废渣通过透水防腐网带进行初步沥水;S201, the paint waste residue after the large pieces of paint residue are separated in S1 is initially drained through the water-permeable anti-corrosion mesh belt;
S202,将初步沥水后的油漆废渣均匀分布;S202, evenly distributing the paint waste after preliminary draining;
S203,通过压辊对均匀分布的油漆进行压滤。S203, filter the evenly distributed paint by pressing rollers.
优选为,所述S2中的S202,将初步沥水后的油漆废渣分布在,上层为防腐滤布、下层为防腐透水网带组成的物料带上,沥水后的油漆废渣通过布料机分布在防腐滤布的中部区域,以中部区域向两侧延展、占防腐滤布的三分之二。Preferably, in S202 in the described S2, the paint waste after preliminary draining is distributed on the material belt composed of the anti-corrosion filter cloth and the lower layer, which is composed of an anti-corrosion filter cloth, and the drained paint waste is distributed on the anti-corrosion filter cloth by a distributing machine. The central area of the cloth extends to both sides from the central area, accounting for two-thirds of the anti-corrosion filter cloth.
优选为,所述S2中的S203步骤,所用压辊为自动调偏调压强挤压压辊。Preferably, in the step S203 in the S2, the pressure roller used is an automatic bias-adjusted pressure-strength extrusion pressure roller.
优选为,所述S4中,对S1分类出来的大块漆渣和S3得到的沥水后的油漆废渣进行破碎包括,Preferably, in the described S4, crushing the large pieces of paint slag classified in S1 and the drained paint slag obtained in S3 includes,
S401,用液压切割刀对位于切割位的废渣进行粗切,切至最大外形尺寸小于30cm或体积与之相当的块状;S401, use a hydraulic cutting knife to roughly cut the waste residue at the cutting position, and cut it to a block with a maximum external dimension less than 30cm or a volume equivalent to it;
S402,再用液压格栅破碎装置进行细切,切至最大外形尺寸小于10cm或体积与之相当的块状;S402, finely cut with a hydraulic grid crushing device, and cut to a block with a maximum external dimension less than 10cm or a volume equivalent to it;
S403,使用齿辊式破碎机进行粒化破碎,使之变为最大外形尺寸小于5mm或体积与之相当的粒状;S403, use a toothed roller crusher for granulation and crushing to make it into a granular shape with a maximum external dimension less than 5mm or a volume equivalent to it;
S404,将S403破碎后的物料进行筛选,过筛后的物料分经气流输送进入料仓,留下的物料再次进行S403。S404, screen the crushed materials in S403, the sieved materials are transported into the silo by air flow, and the remaining materials are again subjected to S403.
优选为,所述S5的干燥为使用旋转闪蒸干燥机对物料进行干燥,在100-260℃的热风下,使其内的物料停留10-180秒。Preferably, the drying of the S5 is to use a spin flash dryer to dry the material, and under the hot air of 100-260° C., the material in it is kept for 10-180 seconds.
优选为,所述S5中,经旋转闪蒸干燥机干燥后的物料,通过双筒旋风分离器分离后,经气流输送装置送入下一级步骤的料仓,水蒸气、有机挥发物气体和少量粉尘随着引风进入箱式脉冲除尘器。Preferably, in the S5, the materials dried by the spin flash dryer are separated by the double-barrel cyclone separator, and then sent to the silo of the next step through the airflow conveying device, and the water vapor, organic volatile gas and A small amount of dust enters the box-type pulse dust collector with the induced air.
优选为,所述S6为,将所述S5处理完毕的物料输送至气流粉碎机;经气流粉碎机在引风的作用下进入物料分级机,物料分级机由变频分级电机和两个串联的旋风下料器组成。Preferably, in the step S6, the material processed in the step S5 is transported to the jet mill; the jet mill enters the material classifier under the action of induced wind, and the material classifier is composed of a frequency conversion classification motor and two cyclones connected in series. The composition of the feeder.
一种油漆废渣制备高分子树脂复合固体粉末生产线,包括依次设置的自动上料系统、污水循环利用处理系统、压滤系统、破碎系统、干燥系统、废气回收处理系统、超细粉碎系统连接而成,系统单元之间设置有用于输送物料的物料输送系统,各系统单元和物料输送过程由罩体形成全封闭状态,由PLC控制系统对整个生产线设备运行及工艺参数实现自动控制。A production line for preparing polymer resin composite solid powder from paint waste, comprising an automatic feeding system, a sewage recycling treatment system, a filter press system, a crushing system, a drying system, a waste gas recovery and treatment system, and an ultrafine pulverization system that are connected in sequence. , There is a material conveying system for conveying materials between the system units. Each system unit and material conveying process are completely enclosed by the cover, and the PLC control system automatically controls the equipment operation and process parameters of the entire production line.
优选为,所述自动上料系统由上料机器人、支架、混合溢流罐、透水防腐网带、接水槽组成;上料机器人将油漆废渣以支架为支撑点倒入混合溢流罐中,混合溢流罐的溢流口正对透水防腐网带的进料端,透水防腐网带的出料端连接压滤系统的进料端,透水防腐网带的排水端与所述污水循环利用处理系统的进水口对应;Preferably, the automatic feeding system is composed of a feeding robot, a bracket, a mixed overflow tank, a water-permeable anti-corrosion mesh belt, and a water receiving tank; The overflow port of the overflow tank is facing the feed end of the permeable anti-corrosion mesh belt, the discharge end of the permeable anti-corrosion mesh belt is connected to the feed end of the filter press system, and the drain end of the permeable anti-corrosion mesh belt is connected to the sewage recycling treatment system. The water inlet corresponds to;
所述压滤系统由自动布料器、高强度防腐透水网带、防腐滤布、自动调偏调压挤压压辊、滤液池构成;防腐滤布设置在所述高强度防腐透水网带上侧,二者紧密接触组成物料带,自动布料器将油漆废渣均匀布在防腐滤布上,所述自动调偏调压挤压压辊在所述高强度防腐透水网带、防腐滤布组成的物料带上下两侧成对设置若干组;所述压滤系统的出料口设置接料斗,接料斗与所述破碎系统的进料端相对应;所述滤液池的排水口与所述污水循环利用处理系统的进水口对应;The filter press system is composed of an automatic distributor, a high-strength anti-corrosion water-permeable mesh belt, an anti-corrosion filter cloth, an automatic bias adjustment and pressure-regulating extrusion roller, and a filtrate pool; the anti-corrosion filter cloth is arranged on the upper side of the high-strength anti-corrosion and permeable mesh belt. , the two are in close contact to form a material belt. The automatic distributor evenly distributes the paint waste on the anti-corrosion filter cloth. Several groups are arranged in pairs on the upper and lower sides of the belt; the discharge port of the filter press system is provided with a receiving hopper, and the receiving hopper corresponds to the feeding end of the crushing system; the drainage port of the filtrate tank is recycled with the sewage The water inlet of the treatment system corresponds to;
所述破碎系统由自动液压切割刀、自动液压格栅破碎装置、变频调速封闭式大倾角输送机、自调压齿辊破碎机、变频调速封闭式皮带机、自动滚筒筛分装置组成;破碎系统还设置有用于吸收破碎过程中产生的粉尘的除尘器;The crushing system is composed of an automatic hydraulic cutting knife, an automatic hydraulic grille crushing device, a variable-frequency speed-regulating closed-type high-angle conveyor, a self-regulating pressure toothed roller crusher, a variable-frequency speed-regulating closed belt conveyor, and an automatic drum screening device; The crushing system is also provided with a dust collector for absorbing the dust generated in the crushing process;
干燥系统由多段调温燃气热风炉、旋转闪蒸干燥机、双筒旋转下料器、脉冲袋式除尘器一组成;多段调温燃气热风炉产生的热风进入旋转闪蒸干燥机,热风带着水蒸气、有机挥发物和少量粉尘进入箱式脉冲除尘器,去除粉尘后进入废气处理系统;漆渣物料经过旋转闪蒸干燥机、双筒旋转下料器进入气流粉碎系统。The drying system consists of a multi-stage temperature-adjusted gas-fired hot blast stove, a rotary flash dryer, a double-cylinder rotary feeder, and a pulse bag filter; Water vapor, organic volatiles and a small amount of dust enter the box-type pulse dust collector, and then enter the waste gas treatment system after removing the dust.
超细粉碎系统由气流粉碎机、物料分级机、单筒旋转下料器、脉冲袋式除尘器二、无尘包装机组成;物料进入气流粉碎机,在压缩空气冲击作用下被粉碎后,输送到物料分级机,物料分级机由变频分级电机和两个串联的旋风下料器组成,通过控制分级电机的频率,控制物料进入第二个旋转下料器的速度,从而控制物料细度。分级后物料进入料仓,使用无尘包装机进行包装,空气经脉冲袋式除尘器除尘后排放。The ultrafine pulverizing system consists of a jet pulverizer, a material classifier, a single-cylinder rotary feeder, a pulse bag filter 2, and a dust-free packaging machine; the material enters the jet pulverizer and is crushed under the impact of compressed air, and then conveyed. To the material classifier, the material classifier is composed of a frequency conversion classification motor and two cyclone feeders connected in series. By controlling the frequency of the classification motor, the speed of the material entering the second rotary feeder is controlled, thereby controlling the fineness of the material. After classification, the material enters the silo and is packaged by a dust-free packaging machine, and the air is discharged after being dedusted by a pulse bag filter.
污水循环利用系统是由滤液收集池、液位自控水泵、污水池、污水处理设备、清水池、液位自控冲洗水泵构成。滤出的水和冲洗带式压滤机的水混合后进入滤液收集池,滤液收集池设液位计,与液位自控水泵联动,滤液池中液位高时,启动污水泵,将污水泵入污水池,进入污水池的污水由污水处理设备进行处理,达标后进入清水池,清水池设有液位自控冲洗水泵,经处理的清水,由液位自控冲洗水泵再用于压滤机冲洗用水。The sewage recycling system is composed of filtrate collection tank, liquid level automatic control pump, sewage tank, sewage treatment equipment, clean water tank, and liquid level automatic control flushing pump. The filtered water is mixed with the water flushing the belt filter press and then enters the filtrate collection tank. The filtrate collection tank is equipped with a liquid level gauge, which is linked with the liquid level automatic control water pump. When the liquid level in the filtrate tank is high, the sewage pump is started and the sewage pump After entering the sewage tank, the sewage entering the sewage tank is treated by the sewage treatment equipment. After reaching the standard, it enters the clean water tank. The clean water tank is equipped with a liquid level automatic flushing pump. Use water.
废气处理溶剂回收系统由气水分离器和废气处理装置组成,气水分离器由换热器、油水分离器构成。、油漆废渣在破碎、干燥、粉碎过程中产生的废气,含有水气和甲苯、二甲苯等有机挥发物。废气先进入换热器,大部分水气、甲苯、二甲苯等有机挥发物冷凝为液体,经油水分离器分离后,水和有机溶剂分别回收回用。废气再进入废气处理装置进一步净化后,达标高空排放。The waste gas treatment solvent recovery system is composed of a gas-water separator and a waste gas treatment device. The gas-water separator is composed of a heat exchanger and an oil-water separator. , The waste gas produced in the process of crushing, drying and pulverizing paint waste contains water vapor and organic volatiles such as toluene and xylene. The waste gas first enters the heat exchanger, and most of the organic volatiles such as water vapor, toluene, and xylene are condensed into liquids. After being separated by an oil-water separator, water and organic solvents are recovered and reused respectively. After the exhaust gas enters the exhaust gas treatment device for further purification, it reaches the standard high-altitude discharge.
整条生产线全封闭于罩体内,进料口、出料口位置由于风机抽风形成负压,废气实现有组织收集处理,避免废气外溢。The entire production line is completely enclosed in the cover, and the position of the inlet and outlet is negative pressure due to the ventilation of the fan.
本发明实施例提供的技术方案带来的有益效果是:该生产线可实现油漆废渣再生利用的无害化、连续化、自动化运行处理,运行过程产生的废水循环使用,产生的废气回收处理,无废水、废气、粉尘等二次污染,工艺条件、产品质量可控,生产效率高。The beneficial effects brought about by the technical solutions provided in the embodiments of the present invention are: the production line can realize the harmless, continuous and automatic operation and treatment of the regeneration and utilization of paint waste residues, the waste water generated during the operation process can be recycled, the waste gas generated can be recycled and treated, and no waste gas is produced. Secondary pollution such as waste water, waste gas, dust, etc., the process conditions and product quality are controllable, and the production efficiency is high.
附图说明Description of drawings
图1为本发明实施例的生产线整体结构图示意图。FIG. 1 is a schematic diagram of the overall structure of a production line according to an embodiment of the present invention.
图中, 1、自动上料系统;1.01、上料机器人;1.02、支架;1.03、混合溢流罐;1.04、透水防腐网带;1.05、接水槽;2、压滤系统;2.01、自动布料器;2.02、防腐滤布;2.03、高强度防腐透水网带;2.04、自动调偏调压强挤压压辊;2.05、滤液池;3、破碎系统;3.01、自动液压切割刀;3.02、自动液压格栅破碎装置;3.03、变频调速封闭式大倾角输送机;3.04、自调压齿辊破碎机;3.05、变频调速封闭式皮带机;3.06、自动滚筒筛分装置;3.07、除尘器;4/6、输送系统;4.01/6.01、自调节气力输送机;4.02/6.02、高低料位自动控制料仓;4.03/6.03、自动控制送料装置;5、干燥系统;5.01、多段调温燃气热风炉;5.02、旋转闪蒸干燥机;5.03、双筒旋转下料器;5.04、、脉冲袋式除尘器一;7、超细粉碎系统;7.01、气流粉碎机;7.02、物料分级机;7.03、旋转下料器;7.04、脉冲袋式除尘器二;7.05、无尘包装机。In the figure, 1. automatic feeding system; 1.01, feeding robot; 1.02, bracket; 1.03, mixing overflow tank; 1.04, water-permeable and anti-corrosion mesh belt; 1.05, water receiving tank; 2. filter press system; 2.01, automatic distributor ; 2.02, anti-corrosion filter cloth; 2.03, high-strength anti-corrosion water-permeable mesh belt; 2.04, automatic offset adjustment pressure squeeze roller; 2.05, filtrate tank; 3, crushing system; 3.01, automatic hydraulic cutting knife; 3.02, automatic hydraulic Grid crushing device; 3.03, frequency conversion speed regulation closed type large inclination conveyor; 3.04, self-regulating pressure toothed roller crusher; 3.05, frequency conversion speed regulation closed belt conveyor; 3.06, automatic drum screening device; 3.07, dust collector; 4/6, conveying system; 4.01/6.01, self-adjusting pneumatic conveyor; 4.02/6.02, high and low material level automatic control silo; 4.03/6.03, automatic control feeding device; 5, drying system; 5.01, multi-stage tempering gas hot air Furnace; 5.02, rotary flash dryer; 5.03, double-cylinder rotary feeder; 5.04, pulse bag filter I; 7, ultra-fine grinding system; 7.01, jet mill; 7.02, material classifier; 7.03, Rotary feeder; 7.04, pulse bag filter II; 7.05, dust-free packaging machine.
具体实施方式Detailed ways
本发明实施例提供了油漆废渣制备高分子树脂复合固体粉末生产工艺及生产线,The embodiments of the present invention provide a production process and a production line for preparing polymer resin composite solid powder from paint waste,
S1,对油漆废渣进行分类,将最大外形尺寸大于30cm或体积与之相当的大块漆渣从油漆废渣中分离;S1, classify the paint waste, and separate the large pieces of paint slag with a maximum external dimension greater than 30cm or a volume equivalent to it from the paint waste;
S2,将S1中去掉大块漆渣的油漆废渣均匀布料至压滤系统;S2, evenly distribute the paint waste from S1 to the filter press system;
S3,对S2中完成布料后的油漆废渣进行压滤;压滤后得到废水及沥水后的油漆废渣;S3, the paint waste residue after the cloth is completed in S2 is subjected to pressure filtration; after the pressure filtration, waste water and the paint waste residue after draining are obtained;
S4,对S1分类出来的大块漆渣和S3得到的沥水后的油漆废渣进行破碎;S4, crushing the large pieces of paint slag classified in S1 and the drained paint slag obtained in S3;
S5,对S4破碎后的油漆废渣进行干燥;S5, drying the paint waste residue after being broken in S4;
S6,对S5干燥后的油漆废渣进行超细粉碎,超细粉碎后细度从50目到1000目分级收集;S6, superfinely pulverize the dried paint residue in S5, and collect the fineness from 50 mesh to 1000 mesh after superfine pulverization;
S7,对S6得到的物料进行包装;S7, packaging the materials obtained in S6;
所有步骤在封闭的罩体中进行,对S2中得到废水进行收集并做废水处理,对S4至6中得到废气进行收集并做废气处理。All steps are carried out in a closed enclosure, the waste water obtained in S2 is collected and treated with waste water, and the waste gas obtained in S4 to 6 is collected and treated with waste gas.
优选为,S2中,Preferably, in S2,
S201,将S1中分离掉大块漆渣后的油漆废渣通过透水防腐网带进行初步沥水;S201, the paint waste residue after the large pieces of paint residue are separated in S1 is initially drained through the water-permeable anti-corrosion mesh belt;
S202,将初步沥水后的油漆废渣均匀分布;S202, evenly distributing the paint waste after preliminary draining;
S203,通过压辊对均匀分布的油漆进行压滤。S203, filter the evenly distributed paint by pressing rollers.
优选为,S2中的S202,将初步沥水后的油漆废渣分布在,上层为防腐滤布、下层为防腐透水网带组成的物料带上,沥水后的油漆废渣通过布料机分布在防腐滤布的中部区域,以中部区域向两侧延展、占防腐滤布的三分之二。Preferably, in S202 in S2, the paint waste after preliminary draining is distributed on the material belt composed of the anti-corrosion filter cloth and the lower layer of the anti-corrosion filter cloth, and the paint waste after the drain is distributed on the anti-corrosion filter cloth by the distributing machine. The middle area, which extends to both sides from the middle area, accounts for two-thirds of the anti-corrosion filter cloth.
优选为,S2中的S203步骤,所用压辊为自动调偏调压强挤压压辊。Preferably, in step S203 in S2, the pressure roller used is an automatic offset adjustment pressure extrusion pressure roller.
优选为,S4中,对S1分类出来的大块漆渣和S3得到的沥水后的油漆废渣进行破碎包括,Preferably, in S4, crushing the large pieces of paint slag classified in S1 and the drained paint slag obtained in S3 includes,
S401,用液压切割刀对位于切割位的废渣进行粗切,切至最大外形尺寸小于30cm或体积与之相当的块状;S401, use a hydraulic cutting knife to roughly cut the waste residue at the cutting position, and cut it to a block with a maximum external dimension less than 30cm or a volume equivalent to it;
S402,再用液压格栅破碎装置进行细切,切至最大外形尺寸小于10cm或体积与之相当的块状;S402, finely cut with a hydraulic grid crushing device, and cut to a block with a maximum external dimension less than 10cm or a volume equivalent to it;
S403,使用齿辊式破碎机进行粒化破碎,使之变为最大外形尺寸小于5mm或体积与之相当的粒状;S403, use a toothed roller crusher for granulation and crushing to make it into a granular shape with a maximum external dimension less than 5mm or a volume equivalent to it;
S404,将S403破碎后的物料进行筛选,过筛后的物料分经气流输送进入料仓,留下的物料再次进行S403。S404, screen the crushed materials in S403, the sieved materials are transported into the silo by air flow, and the remaining materials are again subjected to S403.
优选为,S5的干燥为使用旋转闪蒸干燥机对物料进行干燥,在100-260℃的热风下,使其内的物料停留10-180秒。Preferably, the drying of S5 is to use a spin flash dryer to dry the material, and under the hot air of 100-260° C., the material in it is kept for 10-180 seconds.
优选为,S5中,经旋转闪蒸干燥机干燥后的物料,通过双筒旋风分离器分离后,经气流输送装置送入下一级步骤的料仓,水蒸气、有机挥发物气体和少量粉尘随着引风进入箱式脉冲除尘器。Preferably, in S5, the materials dried by the rotary flash dryer are separated by the double-barrel cyclone separator, and then sent to the silo of the next step through the airflow conveying device. The water vapor, organic volatile gas and a small amount of dust With the induced air entering the box-type pulse dust collector.
优选为,S6为,将S5处理完毕的物料输送至气流粉碎机;经气流粉碎机在引风的作用下进入物料分级机,物料分级机由变频分级电机和两个串联的旋风下料器组成。Preferably, in S6, the material processed in S5 is transported to the jet mill; the jet mill enters the material classifier under the action of induced wind, and the material classifier is composed of a frequency conversion classification motor and two series-connected cyclone feeders .
一种油漆废渣制备高分子树脂复合固体粉末生产线,包括依次设置的自动上料系统1、污水循环利用处理系统、压滤系统2、破碎系统3、干燥系统5、废气回收处理系统、超细粉碎系统7连接而成,系统单元之间设置有用于输送物料的物料输送系统6,各系统单元和物料输送过程由罩体形成全封闭状态,由PLC控制系统对整个生产线设备运行及工艺参数实现自动控制。A production line for preparing polymer resin composite solid powder from paint waste, comprising an automatic feeding system 1, a sewage recycling treatment system, a filter press system 2, a crushing system 3, a drying system 5, a waste gas recovery and treatment system, and an ultra-fine grinding system. The system 7 is connected, and a material conveying system 6 for conveying materials is arranged between the system units. Each system unit and the material conveying process are completely enclosed by the cover body, and the PLC control system automatically realizes the operation of the equipment and process parameters of the entire production line. control.
优选为,自动上料系统1由上料机器人1.01、支架1.02、混合溢流罐1.03、透水防腐网带1.04、接水槽1.05组成;上料机器人1.01将油漆废渣以支架1.02为支撑点倒入混合溢流罐1.03中,混合溢流罐1.03的溢流口正对透水防腐网带1.04的进料端,透水防腐网带1.04的出料端连接压滤系统2的进料端,经透水防腐网带1.04的排水端与污水循环利用处理系统的进水口对应;Preferably, the automatic feeding system 1 is composed of a feeding robot 1.01, a bracket 1.02, a mixing overflow tank 1.03, a water-permeable anti-corrosion mesh belt 1.04, and a water receiving tank 1.05; In the overflow tank 1.03, the overflow port of the mixed overflow tank 1.03 is facing the feed end of the permeable anti-corrosion mesh belt 1.04, and the discharge end of the permeable anti-corrosion mesh belt 1.04 is connected to the feed end of the filter press system 2. The drain end with 1.04 corresponds to the water inlet of the sewage recycling treatment system;
压滤系统2由自动布料器2.01、高强度防腐透水网带2.03、防腐滤布2.02、自动调偏调压挤压压辊2.04、滤液池2.05构成;防腐滤布2.02设置在高强度防腐透水网带2.03上侧,二者紧密接触组成物料带,滤液池2.05位于物料带下方,自动布料器2.01将油漆废渣均匀布在防腐滤布2.02上,自动调偏调压挤压压辊2.04在高强度防腐透水网带2.03、防腐滤布2.02组成的物料带上下两侧成对设置若干组;压滤系统2的出料口设置接料斗,接料斗与破碎系统3的进料端相对应;滤液池2.05的排水口与污水循环利用处理系统的进水口对应;The filter press system 2 is composed of automatic distributor 2.01, high-strength anti-corrosion permeable mesh belt 2.03, anti-corrosion filter cloth 2.02, automatic bias adjustment and pressure adjustment squeeze roller 2.04, and filtrate tank 2.05; The upper side of the belt 2.03 is in close contact with the two to form a material belt. The filtrate tank 2.05 is located under the material belt. The automatic distributor 2.01 evenly distributes the paint waste on the anti-corrosion filter cloth 2.02. The material belt composed of anti-corrosion water-permeable mesh belt 2.03 and anti-corrosion filter cloth 2.02 is set up in pairs on the upper and lower sides of the material belt; the discharge port of the filter press system 2 is provided with a receiving hopper, which corresponds to the feeding end of the crushing system 3; the filtrate tank The water outlet of 2.05 corresponds to the water inlet of the sewage recycling treatment system;
破碎系统3由自动液压切割刀3.01、自动液压格栅破碎装置3.02、变频调速封闭式大倾角输送机3.03、自调压齿辊破碎机3.04、变频调速封闭式皮带机3.05、自动滚筒筛分装置3.06组成;破碎系统3还设置有用于吸收破碎过程中产生的粉尘的除尘器3.07;The crushing system 3 consists of automatic hydraulic cutting knife 3.01, automatic hydraulic grille crushing device 3.02, frequency conversion speed regulation closed type large inclination conveyor 3.03, self pressure regulating tooth roller crusher 3.04, frequency conversion speed regulation closed belt conveyor 3.05, automatic trommel screen It is composed of sub-device 3.06; the crushing system 3 is also provided with a dust collector 3.07 for absorbing the dust generated in the crushing process;
干燥系统5由多段调温燃气热风炉5.01、旋转闪蒸干燥机5.02、双筒旋转下料器5.03、脉冲袋式除尘器一5.04组成;多段调温燃气热风炉5.01产生的热风进入旋转闪蒸干燥机5.02,热风带着水蒸气、有机挥发物和少量粉尘进入脉冲袋式除尘器一5.04,去除粉尘后进入废气处理系统;漆渣物料经过旋转闪蒸干燥机5.02、双筒旋转下料器5.03进入气流粉碎系统7。The drying system 5 is composed of a multi-stage temperature-adjusted gas hot blast stove 5.01, a rotary flash dryer 5.02, a double-cylinder rotary feeder 5.03, and a pulse bag filter 5.04; the hot air generated by the multi-stage temperature-adjusted gas hot blast stove 5.01 enters the rotary flash Dryer 5.02, the hot air enters the pulse bag filter 1 5.04 with water vapor, organic volatiles and a small amount of dust, and after removing the dust, it enters the waste gas treatment system; the paint residue material passes through the rotary flash dryer 5.02, the double-cylinder rotary feeder 5.03 Enter the jet mill system 7.
超细粉碎系统7由气流粉碎机7.01、物料分级机7.02、单筒旋转下料器7.03、脉冲袋式除尘器二7.04、无尘包装机7.05组成;物料进入气流粉碎机7.01,在压缩空气冲击作用下被粉碎后,输送到物料分级机7.02,物料分级机7.02由变频分级电机和两个串联的旋风下料器组成,通过控制分级电机的频率,控制物料进入第二个旋转下料器的速度,从而控制物料细度。分级后物料进入料仓,使用无尘包装机7.05进行包装,空气经脉冲袋式除尘器二7.04除尘后排放。Ultrafine crushing system 7 consists of jet mill 7.01, material classifier 7.02, single-cylinder rotary feeder 7.03, pulse bag filter 2 7.04, and dust-free packaging machine 7.05; the material enters the jet mill 7.01 and is impacted by compressed air. After being crushed under the action, it is transported to the material classifier 7.02. The material classifier 7.02 is composed of a frequency conversion classification motor and two cyclone feeders connected in series. By controlling the frequency of the classification motor, the material entering the second rotary feeder is controlled. speed, thereby controlling the fineness of the material. After classification, the material enters the silo and is packaged with a dust-free packaging machine 7.05, and the air is discharged after being dedusted by a pulse bag filter 2 7.04.
污水循环利用系统是由滤液收集池、液位自控水泵、污水池、污水处理设备、清水池、液位自控冲洗水泵构成。滤出的水和冲洗带式压滤机的水混合后进入滤液收集池,滤液收集池设液位计,与液位自控水泵联动,滤液池中液位高时,启动污水泵,将污水泵入污水池,进入污水池的污水由污水处理设备进行处理,达标后进入清水池,清水池设有液位自控冲洗水泵,经处理的清水,由液位自控冲洗水泵再用于压滤机冲洗用水。The sewage recycling system is composed of filtrate collection tank, liquid level automatic control pump, sewage tank, sewage treatment equipment, clean water tank, and liquid level automatic control flushing pump. The filtered water is mixed with the water flushing the belt filter press and then enters the filtrate collection tank. The filtrate collection tank is equipped with a liquid level gauge, which is linked with the liquid level automatic control water pump. When the liquid level in the filtrate tank is high, the sewage pump is started and the sewage pump After entering the sewage tank, the sewage entering the sewage tank is treated by the sewage treatment equipment. After reaching the standard, it enters the clean water tank. The clean water tank is equipped with a liquid level automatic flushing pump. Use water.
废气处理溶剂回收系统由气水分离器和废气处理装置组成,气水分离器由换热器、油水分离器构成。、油漆废渣在破碎、干燥、粉碎过程中产生的废气,含有水气和甲苯、二甲苯等有机挥发物。废气先进入换热器,大部分水气、甲苯、二甲苯等有机挥发物冷凝为液体,经油水分离器分离后,水和有机溶剂分别回收回用。废气再进入废气处理装置进一步净化后,达标高空排放。The waste gas treatment solvent recovery system is composed of a gas-water separator and a waste gas treatment device. The gas-water separator is composed of a heat exchanger and an oil-water separator. , The waste gas produced in the process of crushing, drying and pulverizing paint waste contains water vapor and organic volatiles such as toluene and xylene. The waste gas first enters the heat exchanger, and most of the organic volatiles such as water vapor, toluene, and xylene are condensed into liquids. After being separated by an oil-water separator, water and organic solvents are recovered and reused respectively. After the exhaust gas enters the exhaust gas treatment device for further purification, it reaches the standard high-altitude discharge.
整条生产线全封闭于罩体内,进料口、出料口位置由于风机抽风形成负压,废气实现有组织收集处理,避免废气外溢。The entire production line is completely enclosed in the cover, and the position of the inlet and outlet is negative pressure due to the ventilation of the fan.
以上所述仅为本发明的较佳实施例,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above are only preferred embodiments of the present invention and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included in the protection of the present invention. within the range.
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CN109971091B (en) * | 2019-03-20 | 2021-05-04 | 孔海朋 | Method for recycling waste paint residues and PVC sawdust |
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