CN107266095A - A kind of smelted furnace cinder is reused in the method that stove is built by laying bricks or stones - Google Patents

A kind of smelted furnace cinder is reused in the method that stove is built by laying bricks or stones Download PDF

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Publication number
CN107266095A
CN107266095A CN201710600085.0A CN201710600085A CN107266095A CN 107266095 A CN107266095 A CN 107266095A CN 201710600085 A CN201710600085 A CN 201710600085A CN 107266095 A CN107266095 A CN 107266095A
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CN
China
Prior art keywords
stove
stones
laying bricks
clinker
slag
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Pending
Application number
CN201710600085.0A
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Chinese (zh)
Inventor
张春雨
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HUNAN ZHONGXIN NEW MATERIALS TECHNOLOGY Co Ltd
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HUNAN ZHONGXIN NEW MATERIALS TECHNOLOGY Co Ltd
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Priority to CN201710600085.0A priority Critical patent/CN107266095A/en
Publication of CN107266095A publication Critical patent/CN107266095A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • C04B35/62209Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse using woody material, remaining in the ceramic products
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303Inorganic additives
    • C04B35/6316Binders based on silicon compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00637Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
    • C04B2111/00646Masonry mortars
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/76Use at unusual temperatures, e.g. sub-zero
    • C04B2111/763High temperatures

Abstract

The method that stove is built by laying bricks or stones is reused in the invention discloses a kind of smelted furnace cinder, specific operating method includes following steps:(1)Cooling:The clinker of blast furnace output is subjected to natural cooling, the final temperature after cooling is less than 30 DEG C;(2)Grinding:Clinker after cooling is crushed using grinder;(3)Screening:Using multilevel screening machine by step(2)Clinker afterwards is screened, and separates three kinds of fine slag, thick slag and large granule slag;(4)Mixing:By step(3)The fine slag of middle generation, thick slag are mixed with different amounts of clay, refractory material, adhesive according to certain ratio respectively;(5)Extrusion forming:Adobe is made in mixed raw material pressurization;Beneficial effect is:Clinker can be recycled, improve the utilization rate of clinker, and the stove for building by laying bricks or stones out is heat-resist, reduces the consumption of other raw materials, it is economic and environment-friendly.

Description

A kind of smelted furnace cinder is reused in the method that stove is built by laying bricks or stones
Technical field
The present invention relates to smelted furnace cinder reutilization technology field, more particularly to a kind of smelted furnace cinder is reused in stove block The method built.
Background technology
Blast furnace is a closed successional counter-current reactor, and furnace charge fills whole blast furnace space, forms stock column, furnace charge Predicted and on high-temperature coal air-flow act on, be constantly heated, decompose, reduction, softening, melting, drippage, ultimately form slag Iron melt body and separate.Molten iron and clinker are the final products of blast furnace process.Clinker by the gangue raw material and coke ash of furnace charge with And assistant reducing agent is formed.The main chemical compositions of clinker are substantially:Silica 4~30%, aluminum oxide accounts for 5~10%, oxygen Change calcium account for 26~44%, magnesia accounts for 8~36%, and iron oxide accounts for 3~12% etc., wherein also containing some sulphur, titanium, potassium, The elements such as sodium.Clinker is a kind of byproduct that blast furnace ironmaking is produced, by working process, is mainly used in making construction material, stove Temperature when slag comes out from blast furnace is generally 1450-1550 DEG C.Due to clinker by high temperature sintering as a kind of resistance to well High-temperature material, the raw material that can be used as building by laying bricks or stones stove is used.
The content of the invention
The purpose of the present invention is that to provide a kind of smelted furnace cinder to solve the above problems and be reused in stove and built by laying bricks or stones Method.
The present invention is achieved through the following technical solutions above-mentioned purpose:
A kind of smelted furnace cinder is reused in the method that stove is built by laying bricks or stones, and specific operating method includes following steps:
(1)Cooling:The clinker of blast furnace output is subjected to natural cooling, the final temperature after cooling is less than 30 DEG C;
(2)Grinding:Clinker after cooling is crushed using grinder;
(3)Screening:Using multilevel screening machine by step(2)Clinker afterwards is screened, and separates fine slag, the 5-50 purposes of -50 mesh Thick slag and 5 three kinds of mesh above large granule slags, 5 mesh above large granule slag return to step(2)Crush again or landfill disposal;
(4)Mixing:By step(3)The fine slag of middle generation and thick slag and clay, refractory material, wood-fibred particle, waterglass, sulfurous Simultaneously water filling stirs for sour sodium mixing;The weight proportion of the mixing is:Fine slag 38-42;Thick slag 7-12;Clay 12-18;Fire resisting Material 10-15;Wood-fibred particle 1-3;Waterglass 3-6;Sodium sulfite 0.5-1;Water 12-18;
(5)Extrusion forming:Adobe is made in raw material pressurization after mixing is mixed thoroughly;
(6)Sintering:By step(5)The adobe of middle production, is sintered at a temperature of 800 DEG C -1000 DEG C, is incubated 5~6 hours, system Into refractory brick;
(7)Cooling and storage:Refractory brick after sintering is cooled down, check sum code pile is deposited;
(8)Build by laying bricks or stones:Cementing materials, which are mixed, with refractory brick and flame-retardant fibre board carries out building by laying bricks or stones for stove;Described cementing material Material is formed by weight proportion 40-50 cement, 22-28 bauxites aggregates, 14-16 water, 8-10 phosphoric acid, the stirring of 2-7 sodium hydroxides dry powder;
(9)Examination is burnt, checked and accepted:After building by laying bricks or stones stove solidification after, in stove place furnace charge carry out examination burning, detection stove inside and outside whether There is crack.
Described bauxites aggregate is alumina aggregate, is also refractory aggregate.
According to the present invention, when being pressed into adobe, useless blast furnace slag and stick that steel and iron industry feels a delicacy about make use of Soil, refractory material, wood-fibred particle, waterglass, sodium sulfite mixing;Blast furnace slag is largely produce in metallurgical industry discarded Thing, severe contamination is will also result in environment, and blast furnace slag is pressed into brick, realizes the utilization to pollutant, again by the present invention Realization is turned waste into wealth, the effect of the treatment of wastes with processes of wastes against one another.Greatly reduce the usage amount of soil resource.
The beneficial effects of the present invention are:Clinker can be recycled, improve the utilization rate of clinker, and built by laying bricks or stones Stove out is heat-resist, reduces the consumption of other raw materials, economic and environment-friendly.
Embodiment
With reference to embodiment, the invention will be further described:
A kind of smelted furnace cinder is reused in the method that stove is built by laying bricks or stones, it is characterised in that:Specific operating method includes following Step:
(1)Cooling:The clinker of blast furnace output is subjected to natural cooling, the final temperature after cooling is less than 30 DEG C;
(2)Grinding:Clinker after cooling is crushed using grinder;
(3)Screening:Using multilevel screening machine by step(2)Clinker afterwards is screened, and separates fine slag, the 5-50 purposes of -50 mesh Thick slag and 5 three kinds of mesh above large granule slags, 5 mesh above large granule slag return to step(2)Crush again or landfill disposal;
(4)Mixing:By step(3)The fine slag of middle generation and thick slag and clay, refractory material, wood-fibred particle, waterglass, sulfurous Simultaneously water filling stirs for sour sodium mixing;The weight proportion of the mixing is:Fine slag 38-42;Thick slag 7-12;Clay 12-18;Fire resisting Material 10-15;Wood-fibred particle 1-3;Waterglass 3-6;Sodium sulfite 0.5-1;Water 12-18;
(5)Extrusion forming:Adobe is made in raw material pressurization after mixing is mixed thoroughly;
(6)Sintering:By step(5)The adobe of middle production, is sintered at a temperature of 800 DEG C -1000 DEG C, is incubated 5~6 hours, system Into refractory brick;
(7)Cooling and storage:Refractory brick after sintering is cooled down, check sum code pile is deposited;
(8)Build by laying bricks or stones:Cementing materials, which are mixed, with refractory brick and flame-retardant fibre board carries out building by laying bricks or stones for stove;Described cementing material Material is formed by 45 cement, 25 bauxites aggregates, 15 water, 10 phosphoric acid, the stirring of 5 sodium hydroxide dry powder;
(9)Examination is burnt, checked and accepted:After building by laying bricks or stones stove solidification after, in stove place furnace charge carry out examination burning, detection stove inside and outside whether There is crack.
Described bauxites aggregate is alumina aggregate, is also refractory aggregate.
Artificial body is influenceed in order to reduce pulverization process dust, step described in the present embodiment(2)In be provided with dedusting and set It is standby.
In order to lower sintering temperature, pressure brick intensity is ensure that again, by testing and creative analysis, the present embodiment institute State step(5)In extrusion forming, the press pressure for pressurization controls to be optimal between 20t-200t.
Ensure yield, the present embodiment step to save energy consumption(9)In examination burn the time be 4h-6h, examination burn temperature control Between 1350 DEG C~1450 DEG C.
The basic principles, principal features and advantages of the present invention have been shown and described above.The technical staff of the industry should Understand, the present invention is not limited to the above embodiments, the original for simply illustrating the present invention described in above-described embodiment and specification Reason, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes and improvements It all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appended claims and its Xiao Wu circle It is fixed.

Claims (4)

1. a kind of smelted furnace cinder is reused in the method that stove is built by laying bricks or stones, it is characterised in that:Specific operating method includes following several Individual step:
(1)Cooling:The clinker of blast furnace output is subjected to natural cooling, the final temperature after cooling is less than 30 DEG C;
(2)Grinding:Clinker after cooling is crushed using grinder;
(3)Screening:Using multilevel screening machine by step(2)Clinker afterwards is screened, and separates fine slag, the 5-50 purposes of -50 mesh Thick slag and 5 three kinds of mesh above large granule slags, 5 mesh above large granule slag return to step(2)Crush again or landfill disposal;
(4)Mixing:By step(3)The fine slag of middle generation and thick slag and clay, refractory material, wood-fibred particle, waterglass, sulfurous Simultaneously water filling stirs for sour sodium mixing;The weight proportion of the mixing is:Fine slag 38-42;Thick slag 7-12;Clay 12-18;Fire resisting Material 10-15;Wood-fibred particle 1-3;Waterglass 3-6;Sodium sulfite 0.5-1;Water 12-18;
(5)Extrusion forming:Adobe is made in raw material pressurization after mixing is mixed thoroughly;
(6)Sintering:By step(5)The adobe of middle production, is sintered at a temperature of 800 DEG C -1000 DEG C, is incubated 5~6 hours, system Into refractory brick;
(7)Cooling and storage:Refractory brick after sintering is cooled down, check sum code pile is deposited;
(8)Build by laying bricks or stones:Cementing materials, which are mixed, with refractory brick and flame-retardant fibre board carries out building by laying bricks or stones for stove;Described cementing material Material is formed by weight proportion 40-50 cement, 22-28 bauxites aggregates, 14-16 water, 8-10 phosphoric acid, the stirring of 2-7 sodium hydroxides dry powder;
(9)Examination is burnt, checked and accepted:After building by laying bricks or stones stove solidification after, in stove place furnace charge carry out examination burning, detection stove inside and outside whether There is crack.
2. a kind of smelted furnace cinder according to claim 1 is reused in the method that stove is built by laying bricks or stones, it is characterised in that:The step Suddenly(2)In be provided with cleaner.
3. a kind of smelted furnace cinder according to claim 1 is reused in the method that stove is built by laying bricks or stones, it is characterised in that:The step Suddenly(5)In extrusion forming, the press pressure for pressurization is between 20t-200t.
4. a kind of smelted furnace cinder according to claim 1 is reused in the method that stove is built by laying bricks or stones, it is characterised in that:The step Suddenly(9)In examination burn the time be 4h-6h, examination burn temperature control between 1350 DEG C~1450 DEG C.
CN201710600085.0A 2017-07-21 2017-07-21 A kind of smelted furnace cinder is reused in the method that stove is built by laying bricks or stones Pending CN107266095A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1141423A (en) * 1996-01-26 1997-01-29 承德钢铁集团有限公司 Method for repairing ratry kiln
CN1163388A (en) * 1996-04-24 1997-10-29 株洲桥梁工厂 Novel industrial furnace lining material and its use
KR20010060417A (en) * 1999-12-21 2001-07-07 신현준 A method for manufacturing solidification brick
CN1420097A (en) * 2002-12-17 2003-05-28 昆明理工大学 Technique for producing non-extrusion clayless solid slag sintering brick
CN103030371A (en) * 2012-12-13 2013-04-10 马鞍山市华宇环保设备制造有限公司 Method for manufacturing brick by high-content municipal sludge

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1141423A (en) * 1996-01-26 1997-01-29 承德钢铁集团有限公司 Method for repairing ratry kiln
CN1163388A (en) * 1996-04-24 1997-10-29 株洲桥梁工厂 Novel industrial furnace lining material and its use
KR20010060417A (en) * 1999-12-21 2001-07-07 신현준 A method for manufacturing solidification brick
CN1420097A (en) * 2002-12-17 2003-05-28 昆明理工大学 Technique for producing non-extrusion clayless solid slag sintering brick
CN103030371A (en) * 2012-12-13 2013-04-10 马鞍山市华宇环保设备制造有限公司 Method for manufacturing brick by high-content municipal sludge

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