CN107195603A - A kind of preparation method of the encapsulating structure based on high heat conduction phase-change material phase-change heat technology - Google Patents
A kind of preparation method of the encapsulating structure based on high heat conduction phase-change material phase-change heat technology Download PDFInfo
- Publication number
- CN107195603A CN107195603A CN201710520800.XA CN201710520800A CN107195603A CN 107195603 A CN107195603 A CN 107195603A CN 201710520800 A CN201710520800 A CN 201710520800A CN 107195603 A CN107195603 A CN 107195603A
- Authority
- CN
- China
- Prior art keywords
- chip
- cover plate
- wafer
- heat dissipation
- change material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W40/00—Arrangements for thermal protection or thermal control
- H10W40/70—Fillings or auxiliary members in containers or in encapsulations for thermal protection or control
- H10W40/73—Fillings or auxiliary members in containers or in encapsulations for thermal protection or control for cooling by change of state
- H10W40/735—Fillings or auxiliary members in containers or in encapsulations for thermal protection or control for cooling by change of state by melting or evaporation of solids
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W40/00—Arrangements for thermal protection or thermal control
- H10W40/01—Manufacture or treatment
- H10W40/03—Manufacture or treatment of arrangements for cooling
- H10W40/037—Assembling together parts thereof
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W40/00—Arrangements for thermal protection or thermal control
- H10W40/70—Fillings or auxiliary members in containers or in encapsulations for thermal protection or control
- H10W40/73—Fillings or auxiliary members in containers or in encapsulations for thermal protection or control for cooling by change of state
Landscapes
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
Abstract
Description
技术领域technical field
本发明属于集成电路封装技术领域,涉及一种晶圆级封装中芯片的主动散热技术,具体地说是一种利用芯片背面空腔内的高导热相变材料受温度变化易发生相态转变的特性,实现芯片主动散热的技术。The invention belongs to the technical field of integrated circuit packaging, and relates to an active heat dissipation technology for chips in wafer-level packaging, in particular to a technology that uses high thermal conductivity phase change materials in the cavity on the back of the chip to easily undergo phase transition due to temperature changes Features, technology to realize active cooling of chips.
背景技术Background technique
在分布式数据库系统中,主节点将数据表存储的多条数据记录分成多个数据表并分配到多个从节点上。当需要查询某些数据记录时,要将每个从节点上的数据表中存储的相关联的数据记录连接起来,具体实现过程中,是对每两个数据表进行连接,因而,这种数据记录的查询方式称为两表连接方式,以下进行举例说明。In a distributed database system, the master node divides multiple data records stored in the data table into multiple data tables and distributes them to multiple slave nodes. When it is necessary to query some data records, it is necessary to connect the associated data records stored in the data tables on each slave node. In the specific implementation process, every two data tables are connected. Therefore, this data The record query method is called the two-table join method, and an example is given below.
随着现代电子芯片的集成度的增加、功耗的上升和尺寸的减小,快速增加的芯片系统发热已经成为先进电子芯片系统研发和应用中的一项重大挑战。一般地,元器件的失效率随着器件温度的上升呈指数规律上升,器件在70~80 ℃水平上每升高1 ℃,其可靠性降低5%。With the increase of integration, power consumption and size reduction of modern electronic chips, the rapidly increasing heat generation of chip systems has become a major challenge in the development and application of advanced electronic chip systems. Generally, the failure rate of components increases exponentially with the increase of device temperature, and the reliability of the device decreases by 5% for every 1 ℃ increase in the level of 70-80 ℃.
因此传统的冷却手段已不能满足未来先进电子元器件(如高功率微波、毫米波器件及机载、星载电子设备等) 的散热要求。解决高热流密度电子元器件的散热问题需要新的突破,这使得热管理成为了电子芯片系统开发和应用中的一项关键技术,在客观上对微电子器件的散热技术提出了非常迫切的要求。 Therefore, traditional cooling methods can no longer meet the heat dissipation requirements of future advanced electronic components (such as high-power microwave, millimeter-wave devices, and airborne and spaceborne electronic equipment, etc.). Solving the heat dissipation problem of high heat flux electronic components requires a new breakthrough, which makes thermal management a key technology in the development and application of electronic chip systems, and objectively puts forward very urgent requirements for the heat dissipation technology of microelectronic devices .
相变散热技术是利用物质相态变化,释放相变潜热的技术。实验数据显示,相变方式比简单温差散热的能力高出数倍甚至数十倍。相变材料在相变过程中可以储存或释放大量的热量,且相变过程近似等温,对芯片可进行有效的过热保护。同时具有体积小、重量轻、性能可靠、经济性和不耗能等优点,使得相变散热成为近期热学领域的研究热点。Phase change heat dissipation technology is a technology that utilizes the phase change of matter to release the latent heat of phase change. Experimental data shows that the ability of phase change to dissipate heat is several times or even dozens of times higher than that of simple temperature difference. Phase change materials can store or release a large amount of heat during the phase change process, and the phase change process is approximately isothermal, which can effectively protect the chip from overheating. At the same time, it has the advantages of small size, light weight, reliable performance, economy and no energy consumption, which makes phase change heat dissipation become a research hotspot in the field of thermal science recently.
发明内容Contents of the invention
本发明提供一种基于高导热相变材料相变散热技术的封装结构的制备方法,以及一种晶圆级封装芯片的散热结构,可以快速地对集成电路芯片进行散热。The invention provides a method for preparing a packaging structure based on a high-thermal-conductivity phase-change material phase-change heat dissipation technology, and a heat dissipation structure for a wafer-level package chip, which can rapidly dissipate heat for an integrated circuit chip.
本发明实施例提供一种基于高导热相变材料相变散热技术的封装结构的制备方法,包括:采用标准刻蚀工艺在晶圆级芯片背面制作凹槽或盲孔;在晶圆级芯片背面凹槽或盲孔内放入作为传热媒介的高导热相变材料;晶圆级芯片背面焊接上盖板进行封帽,保证高导热相变材料在相态转变过程中不溢出封装体结构;通过常规划片工艺得到具有相变散热结构的单芯片。An embodiment of the present invention provides a method for preparing a packaging structure based on phase change heat dissipation technology of high thermal conductivity phase change materials, including: using a standard etching process to make grooves or blind holes on the back of the wafer-level chip; Put a high thermal conductivity phase change material as a heat transfer medium in the groove or blind hole; weld the upper cover plate on the back of the wafer level chip to seal the cap, so as to ensure that the high thermal conductivity phase change material does not overflow the package structure during the phase transition process; A single chip with a phase-change heat dissipation structure is obtained through a conventional planning wafer process.
可选的,所述凹槽或盲孔的尺寸大小根据具体的产品而定,刻蚀深度应不超过芯片本体厚度。Optionally, the size of the groove or the blind hole depends on the specific product, and the etching depth should not exceed the thickness of the chip body.
可选的,放入凹槽或盲孔内的相变材料的量视凹槽或盲孔尺寸而定。可选的,盖板与芯片的接合方式视盖板材料而定。Optionally, the amount of phase change material put into the groove or blind hole depends on the size of the groove or blind hole. Optionally, the bonding method of the cover plate and the chip depends on the material of the cover plate.
可选的,盖板与芯片的接合方式为硅硅直接键合,或,合金共熔接合方式。Optionally, the bonding method of the cover plate and the chip is silicon-silicon direct bonding, or alloy eutectic bonding.
本发明实施例还提供一种晶圆级封装芯片的散热结构,所述散热结构,包括晶圆级封装芯片3、导热盖板1,芯片3与盖板1通过焊料2焊接在一起;其特征在于:散热结构还包括晶圆级封装芯片3背面刻蚀的凹槽或盲孔,凹槽或盲孔内装有的高导热相变材料4;整个散热结构制作工艺都在晶圆上完成。The embodiment of the present invention also provides a heat dissipation structure for a wafer-level packaged chip. The heat dissipation structure includes a wafer-level packaged chip 3 and a heat-conducting cover plate 1. The chip 3 and the cover plate 1 are welded together by solder 2; its features The reason is that the heat dissipation structure also includes grooves or blind holes etched on the back of the wafer-level package chip 3, and the high thermal conductivity phase change material 4 is installed in the grooves or blind holes; the entire heat dissipation structure manufacturing process is completed on the wafer.
可选的,所述凹槽或盲孔的尺寸大小根据具体的产品而定,刻蚀深度应不超过芯片本体厚度。Optionally, the size of the groove or the blind hole depends on the specific product, and the etching depth should not exceed the thickness of the chip body.
可选的,盖板与芯片的接合方式视盖板材料而定。Optionally, the bonding method of the cover plate and the chip depends on the material of the cover plate.
可选的,盖板与芯片的接合方式为硅硅直接键合,或,合金共熔接合方式。Optionally, the bonding method of the cover plate and the chip is silicon-silicon direct bonding, or alloy eutectic bonding.
采用这样的技术方案,芯片产生的热量大部分可以通过芯片背面快速导出,具体的芯片散热原理为:芯片在工作过程中产生热量,芯片背面腔体内靠近芯片发热端的相变材料由固态变成液态或由液态变成汽态,吸收热量;靠近盖板冷端的相变材料由液态变成固态或由汽态变成液态,释放热量,形成一个导热循环。如此往复不断,完成芯片的主动散热过程,高导热相变材料起到了传热媒介的作用,从而实现快速地对集成电路芯片进行散热的目的,有效提高运行速度和功效、提高运行可靠性、延长使用寿命。With such a technical solution, most of the heat generated by the chip can be quickly exported through the back of the chip. The specific heat dissipation principle of the chip is: the chip generates heat during operation, and the phase change material in the cavity on the back of the chip near the heating end of the chip changes from solid to liquid Or change from liquid to vapor to absorb heat; the phase change material near the cold end of the cover plate changes from liquid to solid or from vapor to liquid to release heat, forming a heat conduction cycle. In this way, the active heat dissipation process of the chip is completed, and the high thermal conductivity phase change material acts as a heat transfer medium, thereby realizing the purpose of quickly dissipating heat from the integrated circuit chip, effectively improving the operating speed and efficiency, improving operating reliability, and extending service life.
附图说明Description of drawings
为了更清楚地说明本发明实施例中的技术方案,下面将对实施例描述中所需要使用的附图作简要介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域的普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings that need to be used in the description of the embodiments will be briefly introduced below. Obviously, the drawings in the following description are only some embodiments of the present invention. For Those of ordinary skill in the art can also obtain other drawings based on these drawings without any creative effort.
图1是晶圆级芯片背面示意图;1-1晶圆;1-2 芯片背面;Figure 1 is a schematic diagram of the back of the wafer-level chip; 1-1 wafer; 1-2 the back of the chip;
图2是刻蚀凹槽后芯片背面示意图;Figure 2 is a schematic diagram of the back of the chip after etching the groove;
图3是凹槽内放入高导热相变材料;Figure 3 is a phase change material with high thermal conductivity placed in the groove;
图4是焊接盖板并划片后得到的单芯片结构剖视图。Fig. 4 is a cross-sectional view of a single chip structure obtained after welding the cover plate and dicing.
其中,1 金属/硅盖板;2 焊料;3 芯片;4 高导热相变材料。Among them, 1 metal/silicon cover plate; 2 solder; 3 chip; 4 high thermal conductivity phase change material.
具体实施方式detailed description
为了使本发明的目的、技术方案和优点更加清楚,下面将结合附图对本发明作进一步地详细描述,显然,所描述的实施例仅仅是本发In order to make the objectives, technical solutions and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings. Obviously, the described embodiments are only the present invention.
明一部份实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例,都属于本发明保护的范围。Some of the embodiments are described, but not all of them. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
图1至图4给出了晶圆级封装芯片背面腔体散热结构的具体实施例。它包括金属/硅盖板1,盖板与芯片焊接焊料2,背面刻蚀有凹槽或盲孔的芯片3以及高导热相变材料4。FIG. 1 to FIG. 4 show specific embodiments of the heat dissipation structure of the cavity on the back side of the wafer-level packaged chip. It includes a metal/silicon cover plate 1 , solder 2 for welding the cover plate and the chip, a chip 3 with grooves or blind holes etched on the backside, and a phase-change material 4 with high thermal conductivity.
上述基于高导热相变材料相变散热技术的封装结构的制备方法,包括以下步骤:The above-mentioned preparation method of the packaging structure based on the high thermal conductivity phase change material phase change heat dissipation technology includes the following steps:
步骤一:采用标准刻蚀工艺在晶圆级芯片背面制作凹槽或盲孔,凹槽或盲孔的尺寸大小根据具体的产品而定,刻蚀深度应不超过芯片本体厚度。Step 1: Use a standard etching process to make grooves or blind holes on the back of the wafer-level chip. The size of the groove or blind hole depends on the specific product, and the etching depth should not exceed the thickness of the chip body.
步骤二:在晶圆级芯片背面凹槽或盲孔内放入作为传热媒介的高导热相变材料,放入量视凹槽或盲孔尺寸而定;Step 2: Put a high thermal conductivity phase change material as a heat transfer medium into the groove or blind hole on the back of the wafer-level chip, and the amount depends on the size of the groove or blind hole;
步骤三:晶圆级芯片背面焊接上盖板进行封帽,保证高导热相变材料在相态转变过程中不溢出封装体结构,盖板厚度视具体的产品而定。盖板与芯片的接合方式视盖板材料而定,包括但不限于硅硅直接键合、合金共熔等方式。Step 3: Weld the upper cover plate on the back of the wafer-level chip to seal the cap to ensure that the high thermal conductivity phase change material does not overflow the package structure during the phase transition process. The thickness of the cover plate depends on the specific product. The bonding method between the cover plate and the chip depends on the material of the cover plate, including but not limited to silicon-silicon direct bonding, alloy eutectic and other methods.
步骤四:通过常规划片工艺得到具有相变散热结构的单芯片,实现快速地对集成电路芯片进行散热的目的,有效提高运行速度和功效、提高运行可靠性、延长使用寿命。Step 4: Obtain a single chip with a phase-change heat dissipation structure through the conventional planning chip process, realize the purpose of quickly dissipating heat from the integrated circuit chip, effectively improve the operating speed and efficiency, improve the operating reliability, and prolong the service life.
尽管已描述了本发明的优选实施例,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例作出另外的变更和修改。所以,所附权利要求意欲解释为包括优选实施例以及落入本发明范围的所有变更和修改。While preferred embodiments of the invention have been described, additional changes and modifications to these embodiments can be made by those skilled in the art once the basic inventive concept is appreciated. Therefore, it is intended that the appended claims be construed to cover the preferred embodiment as well as all changes and modifications which fall within the scope of the invention.
显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内,则本发明也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the present invention without departing from the spirit and scope of the present invention. Thus, if these modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalent technologies, the present invention also intends to include these modifications and variations.
Claims (9)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710520800.XA CN107195603A (en) | 2017-06-30 | 2017-06-30 | A kind of preparation method of the encapsulating structure based on high heat conduction phase-change material phase-change heat technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710520800.XA CN107195603A (en) | 2017-06-30 | 2017-06-30 | A kind of preparation method of the encapsulating structure based on high heat conduction phase-change material phase-change heat technology |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107195603A true CN107195603A (en) | 2017-09-22 |
Family
ID=59881681
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710520800.XA Pending CN107195603A (en) | 2017-06-30 | 2017-06-30 | A kind of preparation method of the encapsulating structure based on high heat conduction phase-change material phase-change heat technology |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107195603A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109216301A (en) * | 2018-09-17 | 2019-01-15 | 中芯集成电路(宁波)有限公司 | Phase-change heat chip structure and preparation method thereof |
| CN113517243A (en) * | 2021-06-29 | 2021-10-19 | 北京时代民芯科技有限公司 | A non-hermetic ceramic flip-chip package heat dissipation structure |
| CN115394727A (en) * | 2021-05-24 | 2022-11-25 | 矽品精密工业股份有限公司 | Electronic package, heat dissipation structure thereof and manufacturing method thereof |
| US11754343B2 (en) | 2019-11-05 | 2023-09-12 | Toyota Motor Engineering & Manufacturing North America, Inc. | Phase change heat-storing mechanisms for substrates of electronic assemblies |
| CN119673773A (en) * | 2024-11-26 | 2025-03-21 | 浙江大学绍兴研究院 | Pulse chip heat dissipation structure based on phase change material and TTSV structure and preparation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070235847A1 (en) * | 2005-09-19 | 2007-10-11 | Shriram Ramanathan | Method of making a substrate having thermally conductive structures and resulting devices |
| US7335983B2 (en) * | 2005-12-16 | 2008-02-26 | Intel Corporation | Carbon nanotube micro-chimney and thermo siphon die-level cooling |
| CN101246862A (en) * | 2008-03-27 | 2008-08-20 | 日月光半导体制造股份有限公司 | Wafer with heat dissipation structure and manufacturing method thereof |
| CN104081518A (en) * | 2012-01-10 | 2014-10-01 | 原子能和替代能源委员会 | Passive thermal management device |
-
2017
- 2017-06-30 CN CN201710520800.XA patent/CN107195603A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070235847A1 (en) * | 2005-09-19 | 2007-10-11 | Shriram Ramanathan | Method of making a substrate having thermally conductive structures and resulting devices |
| US7335983B2 (en) * | 2005-12-16 | 2008-02-26 | Intel Corporation | Carbon nanotube micro-chimney and thermo siphon die-level cooling |
| CN101246862A (en) * | 2008-03-27 | 2008-08-20 | 日月光半导体制造股份有限公司 | Wafer with heat dissipation structure and manufacturing method thereof |
| CN104081518A (en) * | 2012-01-10 | 2014-10-01 | 原子能和替代能源委员会 | Passive thermal management device |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109216301A (en) * | 2018-09-17 | 2019-01-15 | 中芯集成电路(宁波)有限公司 | Phase-change heat chip structure and preparation method thereof |
| CN109216301B (en) * | 2018-09-17 | 2020-09-25 | 中芯集成电路(宁波)有限公司 | Phase-change heat dissipation chip structure and preparation method thereof |
| US11754343B2 (en) | 2019-11-05 | 2023-09-12 | Toyota Motor Engineering & Manufacturing North America, Inc. | Phase change heat-storing mechanisms for substrates of electronic assemblies |
| CN115394727A (en) * | 2021-05-24 | 2022-11-25 | 矽品精密工业股份有限公司 | Electronic package, heat dissipation structure thereof and manufacturing method thereof |
| CN113517243A (en) * | 2021-06-29 | 2021-10-19 | 北京时代民芯科技有限公司 | A non-hermetic ceramic flip-chip package heat dissipation structure |
| CN119673773A (en) * | 2024-11-26 | 2025-03-21 | 浙江大学绍兴研究院 | Pulse chip heat dissipation structure based on phase change material and TTSV structure and preparation method |
| CN119673773B (en) * | 2024-11-26 | 2025-09-30 | 浙江大学绍兴研究院 | Pulse chip heat dissipation structure based on phase change material and TTSV structure and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107195603A (en) | A kind of preparation method of the encapsulating structure based on high heat conduction phase-change material phase-change heat technology | |
| EP3474647B1 (en) | Cooling system of working medium contact type for high-power device, and working method thereof | |
| KR100757614B1 (en) | Apparatus and Method for Passive Phase Change Thermal Management | |
| Yang et al. | Liquid metal enabled combinatorial heat transfer science: toward unconventional extreme cooling | |
| US8743545B2 (en) | Thermal expansion-enhanced heat sink for an electronic assembly | |
| CN103712192B (en) | Integration phase transition heat sink high power LED light fitting heat radiator | |
| WO2020248905A1 (en) | Wafer-level 3d stacked microchannel heat dissipation structure and manufacturing method therefor | |
| CN105845648A (en) | Microelectronic device tree-shaped radiator | |
| WO2024093695A1 (en) | Liquid-cooling heat dissipation module embedded with three-dimensional vapor chamber element | |
| CN104154787A (en) | Multi-stage evaporation micro-channel heat pipe heat transferring and radiating device | |
| CN100557367C (en) | A high-power flat plate integral phase change heat dissipation method and radiator | |
| CN205428902U (en) | Soaking board radiating basal plate power modular structure | |
| TWI765184B (en) | Liquid cooling radiator | |
| WO2024066703A9 (en) | Heat dissipation system and power apparatus | |
| CN102446877A (en) | Semiconductor heat dissipation device | |
| CN106653712B (en) | The radiator structure and processing technology of single tube IGBT | |
| WO2025227721A1 (en) | Packaging structure and electronic device | |
| CN105957848A (en) | Base plate with integrated heat tubes and module device thereof | |
| Steller et al. | Microfluidic Interposer for High Performance Fluidic Chip Cooling | |
| CN106601704A (en) | Thyristor radiator | |
| CN212305944U (en) | Liquid cooling substrate with ultrahigh heat conductivity | |
| CN108711561A (en) | A kind of heat sinking channel for ceramic package | |
| CN105050371A (en) | High-heat-flux electronic equipment hot spot removing device | |
| CN104966713A (en) | Novel packaging structure for IGBT module | |
| Brunschwiler et al. | Dual-side heat removal by micro-channel cold plate and silicon-interposer with embedded fluid channels |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170922 |
|
| RJ01 | Rejection of invention patent application after publication |