CN107189603B - A kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant - Google Patents

A kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant Download PDF

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Publication number
CN107189603B
CN107189603B CN201710558278.4A CN201710558278A CN107189603B CN 107189603 B CN107189603 B CN 107189603B CN 201710558278 A CN201710558278 A CN 201710558278A CN 107189603 B CN107189603 B CN 107189603B
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proof
explosion
fire
resistant
temperature
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CN201710558278.4A
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CN107189603A (en
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张信露
谢永立
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ZHANGZHOU XINZHANWANG CHEMICAL CO Ltd
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ZHANGZHOU XINZHANWANG CHEMICAL CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant, raw materials used percentages are as follows: organosilicon modified crylic acid resin 70%-75%, auxiliary agent 20%-25%, solvent 3-6%, the sum of weight percent of above-mentioned raw materials are 100%;Wherein, the auxiliary agent is to be mixed to prepare modified Nano zirconium powder by weight 1:3-5 with fluorine silicon additive.Gained paint film is clear transparent after glass coating coating of the present invention, optical good, and has good high temperature resistant, fire prevention, explosion-proof performance.

Description

A kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant
Technical field
The invention belongs to coating preparation fields, and in particular to a kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant.
Background technique
From automobile occurs certainly, it just be unable to do without glass.Initial vehicle glass only plays resistance to colds, prevents The effect of rainwater and dust.With the development of the automobile industry, condition of road surface constantly improves and the increasingly raising of speed, vehicle glass Importance be gradually realized, vehicle glass not only will provide the good visual field to driver and passenger in running car, It also wants that driver and passenger can not be injured when encountering sudden accident, this requires its lightweight and multifunction.
In the area of hot weather either summer vehicle, due to outdoor larger with the temperature difference of car, especially noon vehicle Interior temperature is likely to be breached 50 DEG C or more, Yi Fasheng fire and explosion accident.And due to by foreign matters such as stones in startup procedure It hits, gently can then make glass broken hole, it is heavy then whole fan glass can be made incoherent.Therefore, vehicle glass not only need to keep out wind and rain, The important component of transparent heat insulating and automobile safety system is related to the personal safety of driver and passenger.
However, automobile comes out for over one hundred year, and the critical defect of vehicle glass extremely fragility is still generally existing, Thus bring security risk is all threaten the safety for travelling people on the way every day.
Summary of the invention
In order to overcome the shortcomings of the prior art, the present invention provides a kind of fire-proof and explosion-proof vehicle glass of aqueous high-temperature-resistant Coating.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant, raw materials used percentage are as follows: organosilicon Acrylic resin modified 70%-75%, auxiliary agent 20%-25%, solvent 3-6%, the sum of weight percent of above-mentioned raw materials are 100%.
The auxiliary agent is to be mixed to prepare modified Nano zirconium powder by weight 1:3-4 with fluorine silicon additive;The modified Nano Zirconium powder is that nanometer zirconium powder, PVDF are added to a certain amount of N- crassitude by mass volume ratio 1:0.1-0.3 g/mL jointly In ketone, it is stirred 6-8h, solvent is then volatilized under vacuum condition and is made.
The solvent is one or more of cyclohexanone, methyl iso-butyl ketone (MIBK).
The preparation method of the fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant, is by organosilicon-modified acrylic tree 1000r/min high speed dispersion 30-60min is made after rouge, auxiliary agent are mixed with solvent.
Compared with the prior art, the advantages of the present invention are as follows:
The present invention passes through the addition of modified Nano zirconium powder, to improve the glossiness of gained glass coating, enhances its thermal insulation Can, and PVDF is used to carry out coating modification to nanometer zirconium powder, the stability of nanometer zirconium powder can be improved;In conjunction with fluorine silicon additive with it is organic Firm network is collectively formed in fluorine-silicon modified acrylic resin, gained glass coating can on the one hand had good wear-resisting, resistance to On the other hand impact property can reach the effect of further stable modification nanometer zirconium powder, it avoided to fall off, apply to effectively extend The service life of material.
After glass coating coating of the present invention, gained paint film is clear transparent, optical good, and is detected, and can tolerate 600 DEG C The above high temperature bears the external force impact of 10kg or more, illustrates it with good high temperature resistant, fire prevention, explosion-proof performance.
Specific embodiment
In order to make content of the present invention easily facilitate understanding, With reference to embodiment to of the present invention Technical solution is described further, but the present invention is not limited only to this.
Embodiment 1
A kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant, raw materials used percentage are as follows: organosilicon Acrylic resin modified 70%, modified Nano zirconium powder 6%, fluorine silicon additive 18%, cyclohexanone 6%.
The modified Nano zirconium powder is that 10g nanometers of zirconium powders, 1mL PVDF are added to 50mL N-Methyl pyrrolidone jointly In, it is stirred 6h, solvent is then volatilized under vacuum condition and is made.
The fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant is by organosilicon modified crylic acid resin, modified Nano zirconium 1000r/min high speed dispersion 30min is made after powder, fluorine silicon additive are mixed with cyclohexanone.
In use, directly coating can be sprayed on vehicle glass according to the actual situation at the construction field (site), coating thickness 22- 35 μm, baking condition is 230-280 DEG C of baking 30-40min.
Embodiment 2
A kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant, raw materials used percentage are as follows: organosilicon Acrylic resin modified 72%, modified Nano zirconium powder 5%, fluorine silicon additive 20%, cyclohexanone 3%.
The modified Nano zirconium powder is that 10g nanometers of zirconium powders, 3mL PVDF are added to 50mL N-Methyl pyrrolidone jointly In, it is stirred 8h, solvent is then volatilized under vacuum condition and is made.
The fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant is by organosilicon modified crylic acid resin, modified Nano zirconium 1000r/min high speed dispersion 60min is made after powder, fluorine silicon additive are mixed with cyclohexanone.
In use, directly coating can be sprayed on vehicle glass according to the actual situation at the construction field (site), coating thickness 22- 35 μm, baking condition is 230-280 DEG C of baking 30-40min.
Embodiment 3
A kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant, raw materials used percentage are as follows: organosilicon Acrylic resin modified 75%, modified Nano zirconium powder 4%, fluorine silicon additive 16%, methyl iso-butyl ketone (MIBK) 5%.
The modified Nano zirconium powder is that 10g nanometers of zirconium powders, 2mL PVDF are added to 50mL N-Methyl pyrrolidone jointly In, it is stirred 6h, solvent is then volatilized under vacuum condition and is made.
The fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant is by organosilicon modified crylic acid resin, modified Nano zirconium 1000r/min high speed dispersion 50min is made after powder, fluorine silicon additive are mixed with methyl iso-butyl ketone (MIBK).
In use, directly coating can be sprayed on vehicle glass according to the actual situation at the construction field (site), coating thickness 22- 35 μm, baking condition is 230-280 DEG C of baking 30-40min.
The paint film obtained after the coating of glass coating obtained by embodiment 1-3 is clear transparent, optical good, and through detecting, can 600 DEG C of tolerance or more high temperature bears the external force impact of 10kg or more.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with Modification, is all covered by the present invention.

Claims (2)

1. a kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant, it is characterised in that: raw materials used percentage are as follows: Organosilicon modified crylic acid resin 70%-75%, auxiliary agent 20%-25%, solvent 3-6%, the sum of weight percent of above-mentioned raw materials are 100%;
The auxiliary agent is to be mixed to prepare modified Nano zirconium powder by weight 1:3-4 with fluorine silicon additive;
The modified Nano zirconium powder is that nanometer zirconium powder, PVDF are added to N- methyl pyrrole by mass volume ratio 1:0.1-0.3 jointly In pyrrolidone, it is stirred 6-8h, solvent is then volatilized under vacuum condition and is made.
2. the fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant according to claim 1, it is characterised in that: the solvent is ring One or more of hexanone, methyl iso-butyl ketone (MIBK).
CN201710558278.4A 2017-07-10 2017-07-10 A kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant Active CN107189603B (en)

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CN201710558278.4A CN107189603B (en) 2017-07-10 2017-07-10 A kind of fire-proof and explosion-proof vehicle glass coating of aqueous high-temperature-resistant

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CN107189603B true CN107189603B (en) 2019-08-27

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111452440A (en) * 2020-05-11 2020-07-28 景德镇陶瓷大学 Environment-friendly paint-spraying-free fireproof water printing film and water film watermark printing process

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101307210A (en) * 2008-07-02 2008-11-19 胡硕 Ultra-discharging water-soluble fluor-silicon-acrylic coatings with nano particles
CN102241936A (en) * 2011-05-26 2011-11-16 开平市日固力涂料有限公司 High temperature resistant thermal insulation coating
CN103275586A (en) * 2013-06-13 2013-09-04 朱良菊 Novel high-temperature resistant flame-retardant coating
CN104017444A (en) * 2014-05-29 2014-09-03 宁波诺沃新材料科技有限公司 Frost prevention coating and frost prevention coating layer and preparation methods thereof and application in evaporators
CN104725903A (en) * 2015-03-30 2015-06-24 佛山市新战略知识产权文化有限公司 Non-sticking wear-resistant high-temperature-resistant paint and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070141114A1 (en) * 2005-12-15 2007-06-21 Essilor International Compagnie Generale D'optique Article coated with an ultra high hydrophobic film and process for obtaining same
WO2014097309A1 (en) * 2012-12-17 2014-06-26 Asian Paints Ltd. Stimuli responsive self cleaning coating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101307210A (en) * 2008-07-02 2008-11-19 胡硕 Ultra-discharging water-soluble fluor-silicon-acrylic coatings with nano particles
CN102241936A (en) * 2011-05-26 2011-11-16 开平市日固力涂料有限公司 High temperature resistant thermal insulation coating
CN103275586A (en) * 2013-06-13 2013-09-04 朱良菊 Novel high-temperature resistant flame-retardant coating
CN104017444A (en) * 2014-05-29 2014-09-03 宁波诺沃新材料科技有限公司 Frost prevention coating and frost prevention coating layer and preparation methods thereof and application in evaporators
CN104725903A (en) * 2015-03-30 2015-06-24 佛山市新战略知识产权文化有限公司 Non-sticking wear-resistant high-temperature-resistant paint and preparation method thereof

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