CN107188616B - A kind of crack brick and preparation method thereof - Google Patents

A kind of crack brick and preparation method thereof Download PDF

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Publication number
CN107188616B
CN107188616B CN201710368958.XA CN201710368958A CN107188616B CN 107188616 B CN107188616 B CN 107188616B CN 201710368958 A CN201710368958 A CN 201710368958A CN 107188616 B CN107188616 B CN 107188616B
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China
Prior art keywords
polish
crack
dry granular
mesh
glue
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CN107188616A (en
Inventor
冉舰波
刘俊荣
蒋祥莉
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FOSHAN OUSHENNUO CERAMIC Co Ltd
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FOSHAN OUSHENNUO CERAMIC Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation

Abstract

A kind of preparation method of crack brick comprising following processing step: 1) by charity overglaze after dry Ceramic Tiles adobe spray clear water, then spray printing decorative ink;2) spray printing light protects ink, then spray printing glue on decorative ink layer;3) using dry granular distributing device after spray printing glue charity frit dry granular in 3~8s;4) it blows away in step 3) and is not burnt into obtain semi-finished product after the extra frit dry granular of glue adherency;5) the polished technique of semi-finished product and edging processing.By adjusting the dry granular amount of charity and between decorative ink and glue, spray printing light protects ink to the present invention, so that ideal crack effect can be achieved in the combination of frit dry granular and glue, and light protection ink further increases the fidelity of crack effect.For the crack brick that the present invention is prepared on the basis of with good mechanical property, face crack effect width is up to 12mm, and crack width is controllable, more more life-like than the crack effect that existing functional ink on the market is formed by 3~4mm wide.

Description

A kind of crack brick and preparation method thereof
Technical field
The present invention relates to decorative building material field, in particular to a kind of crack brick and preparation method thereof.
Background technique
The fast development of ink-jet technology brings earth-shaking variation, while ink-jet to the pattern decorative of ceramic product The universal height homogeneity for also bringing ceramic tile surface pattern effect of machine, in order to make ceramic tile surface that there is distinguished decoration Effect, numerous ceramics producers just increase the surface decoration effect of Ceramic Tiles using various function glaze and functional ink one after another.Its In the ornamental porcelain brick with crackle and sagging effect be loved by consumers because it has the effect of parian texture.And The existing ornamental porcelain brick with crackle and sagging effect is realized by functional materials such as crack glaze, lower collapsible inks, Its simulated effect is not good enough and is difficult to.
The use of dry granular brings new development to the brick face decorative effect of Ceramic Tiles.Now on the market still without a crackle The crack brick with ideal and controllable cracking lines is prepared using dry granular in brick.
Summary of the invention
It is an object of the invention to what is regulated and controled for the above-mentioned brick of crack brick in the prior art facial cleft line less effective and being difficult to Deficiency provides a kind of crack brick and preparation method thereof.
The technical solution used in the present invention is: a kind of preparation method of crack brick comprising following processing step:
1) by dry Ceramic Tiles adobe through removing surface, charity overglaze after clear water is sprayed, control overglaze glaze volume is 100 ± The Measuring plate of 2g/333 × 667 forms cover coat, and further according to required design, spray printing decorative ink, formation are filled on cover coat Adorn ink layer;
2) spray printing light protects ink on decorative ink layer, and control light protection ink jet amount is greater than 45g/m2, shape At protective layer, then spray printing glue on the protection layer, control glue ink ejection amount are greater than 45g/m2
3) using dry granular distributing device after spray printing glue charity frit dry granular in 3~8s, the dry granular amount for controlling charity is 250 ~450g/m2
4) it blows away in step 3) and is not burnt into obtain semi-finished product after the extra frit dry granular of glue adherency;
5) the polished technique of semi-finished product obtained by step 4) and edging are handled, obtains crack brick finished product.
As a further improvement of the foregoing solution, the beginning fusing point of frit dry granular described in step 3) is in 750~950 DEG C of ranges Interior, high with sintering temperature, high temperature viscosity is high characteristic, ensure that it can form apparent crack without being melted by frit The glass phase of formation is molten flat.
As a further improvement of the foregoing solution, the partial size of frit dry granular described in step 3) is 100~200 mesh.Specifically Ground can further provide for the binding ability of itself and glue, to optimize later period sintering process by limiting the partial size of frit dry granular Formed in crack effect.
As a further improvement of the foregoing solution, dry granular distributing device described in step 3) uses leather belt material distributing device, the skin Band distributing device is with 20~30 mesh single layers vibration sieve, to keep its cloth effect more preferable, frit dry granular is more evenly distributed.
As a further improvement of the foregoing solution, the beginning fusing point of overglaze described in step 1) is higher than 800 DEG C, overglaze tool Have the characteristic that degree of sintering is high, be conducive to dry granular formation glaze surface evenness it is good, crack effect does not collapse and edge of crack rises steeply and Be not it is round and smooth, can really restore the natural effects in stone material crack.
As a further improvement of the foregoing solution, Ceramic Tiles adobe temperature is controlled in the jet printing process of step 1) and step 2) Within the scope of 40~50 DEG C.The present invention is improved ink and existed by adobe temperature when limiting spray printing so that spray printing effect is more preferable Adhesive force in adobe guarantees that the mechanical property of adobe in jet printing process itself is unaffected simultaneously.
As a further improvement of the foregoing solution, it is blown away using accurate air knife by the extra of glue adherency in step 4) Frit dry granular, so that extra frit dry granular can be thoroughly removed while not destroy the attached of the frit dry granular adhered to by glue ?.
As a further improvement of the foregoing solution, firing temperature described in step 4) is 1180~1200 DEG C, firing time For 60~80min.
As a further improvement of the foregoing solution, the polishing process in step 5) be 320 mesh polish module polish 4 groups, 400 Mesh polishes module and polishes 6 groups, and 600 mesh polish module and polish 3 groups, and 800 mesh polish module and polish 4 groups, and 1000 mesh polish module and throw 3 groups of light, 3 groups of polishing of 1200 mesh polishing module, 3 groups of polishing of 1500 mesh polishing module, 3 groups of polishing of 2000 mesh polishing module, 3000 Mesh polishes module and polishes 3 groups, and grinding head for polishing pressure is 2.0~2.5MPa.Specifically, which can throw brick face more It is avoided that while flat, brighter and does not fall to form defect by the pattern throwing that slit region does not have glaze to protect.
Another technical solution adopted by the present invention is: a kind of crack brick being prepared with above-mentioned preparation method, Surface hardness is formed by crack width up to 12mm, while fracture edges are upright and stern up to 4 grades 2200 turns, has excellent emulation Property.
The beneficial effects of the present invention are: present invention optimizes the preparation process of crack brick, by adjusting the dry granular amount of charity And spray printing light protects ink between decorative ink and glue, so that ideal can be achieved in the combination of frit dry granular and glue Crack effect, and on the one hand light protection ink is formed by pattern to decorative ink and shields, on the other hand significantly The adhesive force of glue and frit dry granular on decorative ink is improved, the fidelity of crack effect is further increased.System of the present invention For the standby crack brick obtained on the basis of with good mechanical property, face crack effect width is up to 12mm, and crackle is wide Degree is controllable, more more life-like than the crack effect that existing functional ink on the market is formed by 3~4mm wide.
Specific embodiment
The present invention is specifically described below with reference to embodiment, in order to technical field personnel to of the invention Understand.It is necessary to it is emphasized that embodiment is only intended to, the present invention will be further described herein, should not be understood as to this The limitation of invention protection scope, fields person skilled in the art, the non-intrinsically safe that the present invention is made according to foregoing invention content The modifications and adaptations of property, should still fall within protection scope of the present invention.Mentioned raw materials following simultaneously are unspecified, are Commercial product;The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or Preparation method.
A kind of preparation method of crack brick comprising following processing step:
1) by dry Ceramic Tiles adobe through removing surface, charity overglaze after clear water is sprayed, control overglaze glaze volume is 100 ± The Measuring plate of 2g/333 × 667 forms cover coat, and further according to required design, spray printing decorative ink, formation are filled on cover coat Adorn ink layer;
2) spray printing light protects ink on decorative ink layer, and control light protection ink jet amount is greater than 45g/m2, shape At protective layer, then spray printing glue on the protection layer, control glue ink ejection amount are greater than 45g/m2
3) using dry granular distributing device after spray printing glue charity frit dry granular in 3~8s, the dry granular amount for controlling charity is 250 ~450g/m2
4) it blows away in step 3) and is not burnt into obtain semi-finished product after the extra frit dry granular of glue adherency;
5) the polished technique of semi-finished product obtained by step 4) and edging are handled, obtains crack brick finished product.
It is further used as preferred embodiment, the beginning fusing point of frit dry granular described in step 3) is in 750~950 DEG C of ranges Interior, high with sintering temperature, high temperature viscosity is high characteristic, ensure that it can form apparent crack without being melted by frit The glass phase of formation is molten flat.
It is further used as preferred embodiment, the partial size of frit dry granular described in step 3) is 100~200 mesh.Specifically Ground can further provide for the binding ability of itself and glue, to optimize later period sintering process by limiting the partial size of frit dry granular Formed in crack effect.
It is further used as preferred embodiment, dry granular distributing device described in step 3) uses leather belt material distributing device, the skin Band distributing device is with 20~30 mesh single layers vibration sieve, to keep its cloth effect more preferable, frit dry granular is more evenly distributed.
It is further used as preferred embodiment, the beginning fusing point of overglaze described in step 1) is higher than 800 DEG C, overglaze tool Have the characteristic that degree of sintering is high, be conducive to dry granular formation glaze surface evenness it is good, crack effect does not collapse and edge of crack rises steeply and Be not it is round and smooth, can really restore the natural effects in stone material crack.
It is further used as preferred embodiment, controls Ceramic Tiles adobe temperature in step 1) and the jet printing process of step 2) Within the scope of 40~50 DEG C.The present invention is improved ink and existed by adobe temperature when limiting spray printing so that spray printing effect is more preferable Adhesive force in adobe guarantees that the mechanical property of adobe in jet printing process itself is unaffected simultaneously.
It is further used as preferred embodiment, is blown away using accurate air knife by the extra of glue adherency in step 4) Frit dry granular, so that extra frit dry granular can be thoroughly removed while not destroy the attached of the frit dry granular adhered to by glue ?.
It is further used as preferred embodiment, firing temperature described in step 4) is 1180~1200 DEG C, firing time For 60~80min.
Be further used as preferred embodiment, the polishing process in step 5) be 320 mesh polish module polish 4 groups, 400 Mesh polishes module and polishes 6 groups, and 600 mesh polish module and polish 3 groups, and 800 mesh polish module and polish 4 groups, and 1000 mesh polish module and throw 3 groups of light, 3 groups of polishing of 1200 mesh polishing module, 3 groups of polishing of 1500 mesh polishing module, 3 groups of polishing of 2000 mesh polishing module, 3000 Mesh polishes module and polishes 3 groups, and grinding head for polishing pressure is 2.0~2.5MPa.Specifically, which can throw brick face more It is avoided that while flat, brighter and does not fall to form defect by the pattern throwing that slit region does not have glaze to protect.
The preparation-obtained crack brick of the present invention, its surface hardness is formed by crack width up to 4 grades 2200 turns after tested Up to 12mm, while fracture edges are upright and stern, have excellent simulation quality.
Above-described embodiment is the preferred embodiment of the present invention, all with similar technique of the invention and made equivalence changes, It should belong to protection category of the invention.

Claims (8)

1. a kind of preparation method of crack brick, which is characterized in that comprise the technical steps that:
1) dry Ceramic Tiles adobe is sprayed into charity overglaze after clear water through removing surface, control overglaze glaze volume is 100 ± 2g/ 333 × 667 Measuring plates form cover coat, and the beginning fusing point of the overglaze is higher than 800 DEG C, further according to required design in overglaze Spray printing decorative ink on layer forms decorative ink layer;
2) spray printing light protects ink on decorative ink layer, and control light protection ink jet amount is greater than 45g/m2, form protection Layer, then spray printing glue on the protection layer, control glue ink ejection amount are greater than 45g/m2
3) using dry granular distributing device after spray printing glue charity frit dry granular in 3~8s, the dry granular amount for controlling charity is 250~ 450g/m2, the beginning fusing point of the frit dry granular is within the scope of 750~950 DEG C;
4) it blows away in step 3) and is not burnt into obtain semi-finished product after the extra frit dry granular of glue adherency, the firing temperature is 1180~1200 DEG C;
5) the polished technique of semi-finished product obtained by step 4) and edging are handled, obtains crack brick finished product.
2. a kind of preparation method of crack brick according to claim 1, it is characterised in that: frit dry granular described in step 3) Partial size be 100~200 mesh.
3. a kind of preparation method of crack brick according to claim 1, it is characterised in that: dry granular cloth described in step 3) Device uses leather belt material distributing device, and the leather belt material distributing device is with 20~30 mesh single layers vibration sieve.
4. a kind of preparation method of crack brick according to claim 1, it is characterised in that: the spray printing of step 1) and step 2) Control Ceramic Tiles adobe temperature is within the scope of 40~50 DEG C in the process.
5. a kind of preparation method of crack brick according to claim 1, it is characterised in that: using accurate air knife in step 4) Blow away the extra frit dry granular not adhered to by glue.
6. a kind of preparation method of crack brick according to claim 1, it is characterised in that: firing time described in step 4) For 60~80min.
7. a kind of preparation method of crack brick according to claim 1, it is characterised in that: the polishing process in step 5) is 320 mesh polish module and polish 4 groups, and 400 mesh polish module and polish 6 groups, and 600 mesh polish module and polish 3 groups, and 800 mesh polish module 4 groups are polished, 1000 mesh polish module and polish 3 groups, and 1200 mesh polish module and polish 3 groups, and 1500 mesh polish module and polish 3 groups, 2000 mesh polish module and polish 3 groups, and 3000 mesh polish module and polish 3 groups, and grinding head for polishing pressure is 2.0~2.5MPa.
8. a kind of crack brick being prepared with the described in any item preparation methods of claim 1~7.
CN201710368958.XA 2017-05-23 2017-05-23 A kind of crack brick and preparation method thereof Active CN107188616B (en)

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CN108623331B (en) * 2018-04-12 2020-05-22 佛山欧神诺陶瓷有限公司 Glazed tile with crack effect and preparation process thereof
CN108587320A (en) * 2018-05-11 2018-09-28 广西欧神诺陶瓷有限公司 A kind of function glue applied to inkjet printing, ornamental porcelain brick and preparation method thereof
CN109293399B (en) * 2018-11-09 2021-05-07 蒙娜丽莎集团股份有限公司 Dry granular brick with stone grain embossed feeling and preparation method thereof
CN109867446B (en) * 2019-03-15 2021-09-10 蒙娜丽莎集团股份有限公司 Ultra-flat frit dry particle glaze fully-polished brick and preparation method thereof
CN110372212A (en) * 2019-07-24 2019-10-25 东莞市唯美陶瓷工业园有限公司 Adobe film forming moisturizer, ink-jet printing ink and decoration glue and preparation method
TWI764750B (en) * 2021-06-08 2022-05-11 遠東科技大學 Method for producing scaly pattern on surface of ceramic object

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CN103224725A (en) * 2013-04-08 2013-07-31 佛山市道氏科技有限公司 White glaze printing ink for ceramic ink-jet printing and preparation method thereof

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CN102225680A (en) * 2011-04-26 2011-10-26 昆山美邦搪瓷有限公司 Manufacturing method for enamel decorative plate imitating wood grains
CN102515869A (en) * 2011-12-30 2012-06-27 江苏拜富科技有限公司 Gold glaze pigment for glass and method for applying gold glaze on glass wine bottles
CN103073335A (en) * 2013-01-29 2013-05-01 福建省晋江市舒适陶瓷有限公司 Production method of inkjet ceramic plate for dry-hanging building curtain wall
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