CN107188493A - A kind of preparation method of unburned environment friendly pervious brick - Google Patents

A kind of preparation method of unburned environment friendly pervious brick Download PDF

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Publication number
CN107188493A
CN107188493A CN201710510738.6A CN201710510738A CN107188493A CN 107188493 A CN107188493 A CN 107188493A CN 201710510738 A CN201710510738 A CN 201710510738A CN 107188493 A CN107188493 A CN 107188493A
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unburned
water
mixed
preparation
brick
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石磊
林茂兰
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Changzhou Lan Sen Environmental Protection Equipment Co Ltd
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Changzhou Lan Sen Environmental Protection Equipment Co Ltd
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Priority to CN201710510738.6A priority Critical patent/CN107188493A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00284Materials permeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to construction material preparing technical field, and in particular to a kind of preparation method of unburned environment friendly pervious brick.The present invention is modified first to improve basaltic porosity, " ice is split " effect is utilized further to widen basaltic aperture, so that there is basalt more rich pore channel to be supplied to hydrone to pass through, with it brick body permeability rate can be improved as the raw material of water-permeable brick, increase silicone hydroxyl in basalt particle surface again, the chemical bonding of high bond energy is produced using the silicone hydroxyl on the silicone hydroxyl and portland cement on its surface, improve non-burning brick internal bond strength, so as to improve the problem of common baking-free water-permeable brick mechanical performance is undesirable, in addition, the compressing pressure that the enhancing of internal bond strength causes baking-free water-permeable brick required when reaching identical molding effect is reduced, so as to increase non-burning brick porosity, further increase non-burning brick water penetration, have broad application prospects.

Description

A kind of preparation method of unburned environment friendly pervious brick
Technical field
The present invention relates to construction material preparing technical field, and in particular to a kind of preparation method of unburned environment friendly pervious brick.
Background technology
With the aggravation of Development of Urbanization speed, urban surface is progressively by the water preventing ability such as building and various concrete Material is covered, and waterproof regional percentage is significantly increasing, and its coverage rate of some areas is more than 80%.Due to the draining in city Worse and worse, many cities one run into heavy rain to ability, and its rainwater on road surface can not quick seepage, it is easy to cause urban waterlogging.Cause This, to solve urban surface hardening problem, builds high-quality natural living environment, safeguards balance of city ecosystem, environmental protection Building material product-water-permeable brick arise at the historic moment, and be developed rapidly.At present, the conventional raw material of water-permeable brick is prepared main There are waterworks sludge, many term red muds, gold tailings, flyash, glazed ceramic, concrete etc..And prepared by these raw materials Water-permeable brick is typically necessary the high temperature sintering through 1000~1400 DEG C, wastes fossil fuel, and produces industrial waste gas and causes air Pollution.
At present, in order to avoid energy waste and atmosphere pollution that high temperature sintering is caused, occur in that it is non-burning brick, it is but unburned Brick is mainly that depended on pressure is compressing, and its internal bond strength is low, causes non-burning brick mechanical performance be not as excellent as fired brick, although Non-burning brick mechanical performance can be improved by improving compressing pressure, but the increase of pressure can cause non-burning brick internal holes again The reduction of gap rate, and then influence non-burning brick water permeability.
Therefore, a kind of baking-free water-permeable brick not only with good mechanical performance but also with excellent water penetration is invented to Building wood Material preparing technical field has positive meaning.
The content of the invention
Present invention mainly solves technical problem, for common baking-free water-permeable brick at present because brick body internal bond strength is low Causing the undesirable defect of mechanical performance, there is provided a kind of preparation method of unburned environment friendly pervious brick.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is:
A kind of preparation method of unburned environment friendly pervious brick, it is characterised in that specifically preparation process is:
(1)It is standing and soak for 10~15 days after basalt ore, Grape Skin and water are mixed, immersion takes out basalt ore deposit after terminating Stone, immediately with liquid nitrogen spraying 10~15min of freezing processing, freezing processing is crushed after terminating, and it is 1~2mm's to filter out particle diameter Basalt particle;
(2)Sonic oscillation is handled after above-mentioned basalt particle and dopamine solution are mixed, and is separated by filtration and is obtained filter residue;
(3)Mixed liquor is obtained after above-mentioned filter residue, sodium metasilicate and water are mixed, pH of mixed is adjusted to 5.0~5.5 with hydrochloric acid, then To mixed liquor heat temperature raising, after 1~2h of stirring reaction, filtering, isolated modified filter residue;
(4)Mashing is handled after pericarp and water are mixed, and mixed serum is obtained, by gained mixed serum sealing and fermenting, fermentation ends After filter, isolated ferment filtrate;
(5)Above-mentioned modified filter residue and Portland cement and bed-silt stirring is mixed to get compound, then will mixing After material and above-mentioned ferment filtrate are by waiting mass ratio well mixed, 5~10min is stood at 30~40 DEG C, adobe material is obtained;
(6)Above-mentioned adobe material is injected in stainless steel mould, compacting obtains adobe, then by brick bat drying, you can obtain unburned ring Protect water-permeable brick.
Step(1)Described in basalt ore, the mass ratio of Grape Skin and water be 1:1:10.
Step(2)Described in basalt particle and dopamine solution mass ratio be 1:8, the quality of dopamine solution is dense Spend for 2g/L, the frequency of sonic oscillation processing is that 30~40kHz, the power of sonic oscillation processing are 200~300W, sonic oscillation The time of processing is 1~2h.
Step(3)Described in filter residue, the mass ratio of sodium metasilicate and water be 1:3:10, the temperature of heat temperature raising is 60~70 ℃。
Step(4)Described in pericarp be Grape Skin, apple skin, pineapple peel, banana skin, kiwi peer in one kind or many Kind.
Step(4)Described in pericarp and water mass ratio be 1:3, the temperature of sealing and fermenting is 35~55 DEG C, sealing hair The time of ferment is 7~9 days.
Step(5)Described in modification filter residue and Portland cement and bed-silt mass ratio be 5:1:1.
Step(6)Described in stainless steel mould size be 250mm × 250mm × 50mm, pressing pressure be 2~ 4MPa, the press time is 12~15min, and dry mode is:Adobe is put into baking oven, 10~12h is dried at 30~40 DEG C Rise oven temperature continues to dry 20~24h to 70~80 DEG C afterwards.
The beneficial effects of the invention are as follows:
(1)The present invention is from having the basalt ore for enriching pore structure as raw material, first by it and with saccharomycete Grape Skin mixing immersion, on the one hand produces organic acid using saccharomycete degraded Grape Skin and basalt surface and internal void is produced Raw micro- corruption, improves basaltic porosity, on the other hand allows immersion process reclaimed water to enter in basalt hole, then use liquid Nitrogen flash-frozen, utilizes " ice is split " effect further to widen basaltic aperture, so that basalt has more rich hole Gap passage is supplied to hydrone to pass through, and brick body permeability rate can be improved as the raw material of water-permeable brick with it;
(2)The present invention will widen the basalt behind aperture and be soaked with dopamine solution, using dopamine oxygen in water work Occur oxidation cross-linked reaction with lower, one layer of sticking poly-dopamine film layer of tool is formed on basalt surface, then set is poly- more Basalt and the silicate solutions mixing of bar amine film layer, are precipitated with hydrochloric acid and silicate reaction generation silicic acid, then made in high temperature Simultaneously uniformly firmly adsorbed with lower silicic acid hydrolysis generation nanometer silicon dioxide particle in poly-dopamine film layer, nano silicon Set add a large amount of silicone hydroxyls, the silicone hydroxyl on basalt surface and the silicon on Portland cement surface to basalt surface Dehydration condensation occurs under high temperature action for hydroxyl, generates the great Si-O-Si keys of bond energy, while being enriched in pericarp zymotic fluid Active group as glued medium, abundant hydrogen bond and chemical bond, Si-O-Si can be formed between basalt and cement The generation of key, hydrogen bond and chemical bond adds the internal bond strength of brick body so that brick body internal bond strength is improved, so as to improve The problem of common baking-free water-permeable brick mechanical performance is undesirable, in addition, the enhancing of internal bond strength causes baking-free water-permeable brick reaching Required compressing pressure is reduced during identical molding effect, so as to increase non-burning brick porosity, is further improved Non-burning brick water penetration, has broad application prospects.
Embodiment
It is 1 in mass ratio:1:10 will be standing and soak for 10~15 days after the mixing of basalt ore, Grape Skin and water, immersion knot Basalt ore is taken out after beam, immediately with liquid nitrogen spraying 10~15min of freezing processing, freezing processing is put into stone crusher after terminating 20~30min is crushed, then is transferred to ball mill and continues to grind after 20~30min, the basalt particle that particle diameter is 1~2mm is filtered out; The dopamine solution for being 2g/L by basalt particle and mass concentration is 1 in mass ratio:It is put into after 8 mixing in sonic oscillation instrument, It is that 30~40kHz, power are that sonic oscillation handles 1~2h under conditions of 200~300W in frequency, is separated by filtration and obtains filter residue; It is 1 in mass ratio:3:10 will obtain mixed liquor after the mixing of filter residue, sodium metasilicate and water, the hydrochloric acid for being 0.5mol/L with concentration regulation PH of mixed is to 5.0~5.5, then mixed liquor is heated to after 60~70 DEG C, 1~2h of stirring reaction, filtering, isolated Modified filter residue;It is 1 in mass ratio:3 will pericarp and water mix after be put into beater and carry out mashing 15~20min of processing, obtain Mixed serum, gained mixed serum is fitted into fermentation tank, sealing tank mouth after at 35~55 DEG C sealing and fermenting 7~9 days, fermentation Filtered after end, isolated ferment filtrate;It is 5 in mass ratio:1:1 will modified filter residue and Portland cement and river bed Mud obtains compound with 3~5min of glass bar stirring mixing, then by compound and ferment filtrate by etc. mass ratio be well mixed Afterwards, 5~10min is stood at 30~40 DEG C, adobe material is obtained;It is 250mm × 250mm × 50mm's that adobe material is injected into size In stainless steel mould, 12~15min is suppressed with 2~4MPa pressure pressurize with press-forming machine, adobe is obtained, then adobe is put Enter baking oven, rise oven temperature after 10~12h is dried at 30~40 DEG C and, to 70~80 DEG C, continues to dry 20~24h, you can To unburned environment friendly pervious brick.Described pericarp is one kind or many in Grape Skin, apple skin, pineapple peel, banana skin, kiwi peer Kind.
Example 1
It is 1 in mass ratio:1:10 will be standing and soak for 10 days after the mixing of basalt ore, Grape Skin and water, and immersion is taken out after terminating Basalt ore, immediately with liquid nitrogen spraying freezing processing 10min, freezing processing is put into stone crusher after terminating and crushes 20min, then It is transferred to ball mill to continue to grind after 20min, filters out the basalt particle that particle diameter is 1mm;By basalt particle and mass concentration It is 1 in mass ratio for 2g/L dopamine solution:It is put into after 8 mixing in sonic oscillation instrument, is that 30kHz, power are in frequency Sonic oscillation handles 1h under conditions of 200W, is separated by filtration and obtains filter residue;It is 1 in mass ratio:3:10 by filter residue, sodium metasilicate and water Mixed liquor is obtained after mixing, the hydrochloric acid for being 0.5mol/L with concentration regulation pH of mixed is heated to 5.0, then to mixed liquor 60 DEG C, after stirring reaction 1h, filtering, isolated modified filter residue;It is 1 in mass ratio:3 will Grape Skin and water mix after be put into and beat In pulp grinder carry out mashing processing 15min, obtain mixed serum, gained mixed serum be fitted into fermentation tank, seal tank mouth after Sealing and fermenting 7 days at 35 DEG C, are filtered, isolated ferment filtrate after fermentation ends;It is 5 in mass ratio:1:1 will modified filter residue and Portland cement and bed-silt obtain compound with glass bar stirring mixing 3min, then by compound and ferment filtrate After waiting mass ratio well mixed, 5min is stood at 30 DEG C, adobe material is obtained;By adobe material injection size be 250mm × In 250mm × 50mm stainless steel mould, 12min is suppressed with 2MPa pressure pressurize with press-forming machine, adobe is obtained, then will Adobe is put into baking oven, and rise oven temperature after 10h is dried at 30 DEG C and, to 70 DEG C, continues to dry 20h, you can obtain unburned environmental protection Water-permeable brick.
Example 2
It is 1 in mass ratio:1:10 will be standing and soak for 13 days after the mixing of basalt ore, Grape Skin and water, and immersion is taken out after terminating Basalt ore, immediately with liquid nitrogen spraying freezing processing 13min, freezing processing is put into stone crusher after terminating and crushes 25min, then It is transferred to ball mill to continue to grind after 25min, filters out the basalt particle that particle diameter is 1mm;By basalt particle and mass concentration It is 1 in mass ratio for 2g/L dopamine solution:It is put into after 8 mixing in sonic oscillation instrument, is that 35kHz, power are in frequency Sonic oscillation handles 1h under conditions of 250W, is separated by filtration and obtains filter residue;It is 1 in mass ratio:3:10 by filter residue, sodium metasilicate and water Mixed liquor is obtained after mixing, the hydrochloric acid for being 0.5mol/L with concentration regulation pH of mixed is heated to 5.3, then to mixed liquor 65 DEG C, after stirring reaction 2h, filtering, isolated modified filter residue;It is 1 in mass ratio:3 will pineapple peel and water mix after be put into and beat In pulp grinder carry out mashing processing 18min, obtain mixed serum, gained mixed serum be fitted into fermentation tank, seal tank mouth after Sealing and fermenting 8 days at 45 DEG C, are filtered, isolated ferment filtrate after fermentation ends;It is 5 in mass ratio:1:1 will modified filter residue and Portland cement and bed-silt obtain compound with glass bar stirring mixing 4min, then by compound and ferment filtrate After waiting mass ratio well mixed, 8min is stood at 35 DEG C, adobe material is obtained;By adobe material injection size be 250mm × In 250mm × 50mm stainless steel mould, 13min is suppressed with 3MPa pressure pressurize with press-forming machine, adobe is obtained, then will Adobe is put into baking oven, and rise oven temperature after 11h is dried at 35 DEG C and, to 75 DEG C, continues to dry 22h, you can obtain unburned environmental protection Water-permeable brick.
Example 3
It is 1 in mass ratio:1:10 will be standing and soak for 15 days after the mixing of basalt ore, Grape Skin and water, and immersion is taken out after terminating Basalt ore, immediately with liquid nitrogen spraying freezing processing 15min, freezing processing is put into stone crusher after terminating and crushes 30min, then It is transferred to ball mill to continue to grind after 30min, filters out the basalt particle that particle diameter is 2mm;By basalt particle and mass concentration It is 1 in mass ratio for 2g/L dopamine solution:It is put into after 8 mixing in sonic oscillation instrument, is that 40kHz, power are in frequency Sonic oscillation handles 2h under conditions of 300W, is separated by filtration and obtains filter residue;It is 1 in mass ratio:3:10 by filter residue, sodium metasilicate and water Mixed liquor is obtained after mixing, the hydrochloric acid for being 0.5mol/L with concentration regulation pH of mixed is heated to 5.5, then to mixed liquor 70 DEG C, after stirring reaction 2h, filtering, isolated modified filter residue;It is 1 in mass ratio:3 will banana skin and water mix after be put into and beat In pulp grinder carry out mashing processing 20min, obtain mixed serum, gained mixed serum be fitted into fermentation tank, seal tank mouth after Sealing and fermenting 9 days at 55 DEG C, are filtered, isolated ferment filtrate after fermentation ends;It is 5 in mass ratio:1:1 will modified filter residue and Portland cement and bed-silt obtain compound with glass bar stirring mixing 5min, then by compound and ferment filtrate After waiting mass ratio well mixed, 10min is stood at 40 DEG C, adobe material is obtained;By adobe material injection size be 250mm × In 250mm × 50mm stainless steel mould, 15min is suppressed with 4MPa pressure pressurize with press-forming machine, adobe is obtained, then will Adobe is put into baking oven, and rise oven temperature after 12h is dried at 40 DEG C and, to 80 DEG C, continues to dry 24h, you can obtain unburned environmental protection Water-permeable brick.
Reference examples
With company of Zhengzhou City produce it is non-burning brick as a comparison case
Non-burning brick in unburned environment friendly pervious brick produced by the present invention and reference examples is detected, testing result is as shown in table 1:
1st, method of testing:
Sample Mechanics Performance Testing is carried out by JB/T 25993-2010 regulation.
Intensity test is detected that loading velocity is 0.3 MPa/s using WEW-600A universal hydraulic testing machines.It is anti- Folding strength test is detected that loading velocity is 0.1~0.2 MPa/s using WDW1020 micro-control electronic universal material testing machines.
Internal bond strength tests non-burning brick interior combination using universal material mechanics machine according to EN 319-11995 systems Intensity.
Water absorption rate and coefficient of permeability are tested by JB/T 25993-2010 regulations, and with water absorption rate and coefficient of permeability mark Show non-burning brick water penetration, water absorption rate and coefficient of permeability are higher, and water penetration is stronger.
The water absorption rate and coefficient of permeability of sample are calculated by formula below:Wa =(m2-m1)/m1× 100%,
K25 =QL/AHt
In formula, Wa(%)For sample water absorption rate;m1(g)Quality during for sample drying;m2(g)Quality after being absorbed water completely for sample;K25 (cm/s)It is the coefficient of permeability of the sample in 25 DEG C of water temperature;Q(mL)For the water oozed out in time t second;L(cm)For style Thickness;A(cm2)For the top surface area of style;H(cm)For water-head;t(s)For the time.
Table 1
Test event Example 1 Example 2 Example 3 Reference examples
Compression strength(MPa) 38.79 39.12 40.05 16.38
Rupture strength(MPa) 1.25 1.36 1.48 0.82
Internal bond strength(MPa) 0.87 0.92 0.97 0.51
Water absorption rate(%) 15.24 15.32 15.67 8.21
Coefficient of permeability(mm/s) 0.93 0.95 0.99 0.38
It can be seen from data in table 1, unburned environment friendly pervious brick internal bond strength produced by the present invention is high, and mechanical performance is excellent, tool There is splendid water permeability.

Claims (8)

1. a kind of preparation method of unburned environment friendly pervious brick, it is characterised in that specifically preparation process is:
(1)It is standing and soak for 10~15 days after basalt ore, Grape Skin and water are mixed, immersion takes out basalt ore deposit after terminating Stone, immediately with liquid nitrogen spraying 10~15min of freezing processing, freezing processing is crushed after terminating, and it is 1~2mm's to filter out particle diameter Basalt particle;
(2)Sonic oscillation is handled after above-mentioned basalt particle and dopamine solution are mixed, and is separated by filtration and is obtained filter residue;
(3)Mixed liquor is obtained after above-mentioned filter residue, sodium metasilicate and water are mixed, pH of mixed is adjusted to 5.0~5.5 with hydrochloric acid, then To mixed liquor heat temperature raising, after 1~2h of stirring reaction, filtering, isolated modified filter residue;
(4)Mashing is handled after pericarp and water are mixed, and mixed serum is obtained, by gained mixed serum sealing and fermenting, fermentation ends After filter, isolated ferment filtrate;
(5)Above-mentioned modified filter residue and Portland cement and bed-silt stirring is mixed to get compound, then will mixing After material and above-mentioned ferment filtrate are by waiting mass ratio well mixed, 5~10min is stood at 30~40 DEG C, adobe material is obtained;
(6)Above-mentioned adobe material is injected in stainless steel mould, compacting obtains adobe, then by brick bat drying, you can obtain unburned ring Protect water-permeable brick.
2. a kind of preparation method of unburned environment friendly pervious brick according to claim 1, it is characterised in that:Step(1)Middle institute The mass ratio of basalt ore, Grape Skin and the water stated is 1:1:10.
3. a kind of preparation method of unburned environment friendly pervious brick according to claim 1, it is characterised in that:Step(2)Middle institute The basalt particle and the mass ratio of dopamine solution stated are 1:8, the mass concentration of dopamine solution is at 2g/L, sonic oscillation The frequency of reason is that 30~40kHz, the power of sonic oscillation processing are 200~300W, and the time of sonic oscillation processing is 1~2h.
4. a kind of preparation method of unburned environment friendly pervious brick according to claim 1, it is characterised in that:Step(3)Middle institute The mass ratio of filter residue, sodium metasilicate and the water stated is 1:3:10, the temperature of heat temperature raising is 60~70 DEG C.
5. a kind of preparation method of unburned environment friendly pervious brick according to claim 1, it is characterised in that:Step(4)Middle institute The pericarp stated is the one or more in Grape Skin, apple skin, pineapple peel, banana skin, kiwi peer.
6. a kind of preparation method of unburned environment friendly pervious brick according to claim 1, it is characterised in that:Step(4)Middle institute The pericarp and the mass ratio of water stated are 1:3, the temperature of sealing and fermenting is 35~55 DEG C, and the time of sealing and fermenting is 7~9 days.
7. a kind of preparation method of unburned environment friendly pervious brick according to claim 1, it is characterised in that:Step(5)Middle institute The modification filter residue and Portland cement and the mass ratio of bed-silt stated are 5:1:1.
8. a kind of preparation method of unburned environment friendly pervious brick according to claim 1, it is characterised in that:Step(6)Middle institute The size for the stainless steel mould stated be 250mm × 250mm × 50mm, pressing pressure be 2~4MPa, the press time be 12~ 15min, dry mode is:Adobe is put into baking oven, dried at 30~40 DEG C after 10~12h rise oven temperature to 70~ 80 DEG C, continue to dry 20~24h.
CN201710510738.6A 2017-06-28 2017-06-28 A kind of preparation method of unburned environment friendly pervious brick Pending CN107188493A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113831629A (en) * 2021-11-03 2021-12-24 中科华坤(北京)科技有限公司 High-strength basalt fiber 3d printing composite material
IT202100030680A1 (en) * 2021-12-03 2023-06-03 Green Building S R L Improved material for making one layer of a multilayer structure.

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106518101A (en) * 2016-10-10 2017-03-22 马鞍山豹龙新型建材有限公司 Shock resistant refractory brick and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106518101A (en) * 2016-10-10 2017-03-22 马鞍山豹龙新型建材有限公司 Shock resistant refractory brick and preparation method thereof

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于方丽 等: "定向多孔陶瓷的制备与应用进展", 《稀有金属》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113831629A (en) * 2021-11-03 2021-12-24 中科华坤(北京)科技有限公司 High-strength basalt fiber 3d printing composite material
IT202100030680A1 (en) * 2021-12-03 2023-06-03 Green Building S R L Improved material for making one layer of a multilayer structure.
EP4190759A1 (en) 2021-12-03 2023-06-07 Green Building S.r.l. Improved layer of a multilayer structure of a building

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Application publication date: 20170922