CN107177330A - A kind of use in construction of door and window adhesive and preparation method - Google Patents
A kind of use in construction of door and window adhesive and preparation method Download PDFInfo
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- CN107177330A CN107177330A CN201710585483.XA CN201710585483A CN107177330A CN 107177330 A CN107177330 A CN 107177330A CN 201710585483 A CN201710585483 A CN 201710585483A CN 107177330 A CN107177330 A CN 107177330A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a kind of use in construction of door and window adhesive and preparation method, described adhesive includes following component：Polyvinyl alcohol, Sodium Polyacrylate, pine tree glue, hydroxyethyl cellulose, high viscous Concave-convex clay rod, graphene, age resister, insect-proof agent, filler.Preparation method includes：The effective component of insect-proof agent is extracted first, it is standby；By polymers compositions and graphene modification, then it is well mixed again with remaining ingredient and insect-proof agent extract, produces described adhesive.Described adhesive is applied in building doors and windows, can not only be played preferable bond effect, also with certain waterproof, antiseptic effect, be expanded the application field of adhesive, in addition, described adhesive makees solvent using water, it is to avoid the harm brought using organic solvent.
Description
Technical field
The present invention relates to building doors and windows technical field, in particular it relates to a kind of use in construction of door and window adhesive and preparation method.
Background technology
At present, the industry such as building, decoration increasingly increases the demand of architecture adhesion agent, the adhesive strength of traditional adhesive,
The indexs such as waterproof can not meet current quality requirement, and contain the nuisances such as substantial amounts of organic additive and organic solvent
Matter, life living environment for people and healthy exerts an adverse impact.Current architecture adhesion agent is in order to improve glue
The adhesion strength of stick can add a variety of property-modifying additives, and base resin is modified, although adhesive property is good, but addition
The consumption of agent is more, and the harmful substance in finished adhesive is more, to the life living environment and healthy shadow of people
Sound is bigger.
Architecture adhesion agent is material essential in architectural engineering, very extensive using scope, can apply what is be related in building
Every aspect.With the development of China's economic, City Building increases into geometric progression, and in building decoration and fitment process
In, it is related to sheet material bonding, metope pretreatment, ceramic wall and floor bricks, floor covering layers and bonds, is required in terms of the bonding of door and window using
Increase a series of performances such as sealing, water proofing property to building glue, this can not only improve building decoration quality, increase attractive in appearance
Comfort, can also improve construction technology, improve construction efficiency and quality etc..
Therefore, researching and developing a kind of building doors and windows that is applied to has the adhesive of preferable bond effect, with preferable
Application value, also complies with existing market requirement.
The content of the invention
For defect of the prior art, it is an object of the invention to provide a kind of use in construction of door and window adhesive and preparation side
Method, described adhesive is applied in building doors and windows, can not only play preferable bond effect, also with certain waterproof, is prevented
Rotten effect, expands the application field of adhesive, in addition, described adhesive makees solvent using water, it is to avoid use organic solvent band
The harm come.
The present invention solves technical problem and adopted the following technical scheme that：
The present invention relates to a kind of use in construction of door and window adhesive, include each component of following parts by weight：It is 20 ~ 38 parts of polyvinyl alcohol, poly-
2 ~ 7 parts of PAA, 10 ~ 15 parts of pine tree glue, 4 ~ 9 parts of hydroxyethyl cellulose, 10 ~ 17 parts of high viscous Concave-convex clay rod, graphene
0.5 ~ 3.5 part, 3 ~ 6 parts of age resister, 5 ~ 12 parts of insect-proof agent, 8 ~ 15 parts of filler.
Preferably, 32 parts of the polyvinyl alcohol, 6 parts of Sodium Polyacrylate, 12 parts of pine tree glue, 7 parts of hydroxyethyl cellulose, high viscous bumps
15 parts of rod stone clay, 1.5 parts of graphene, 5 parts of age resister, 8 parts of insect-proof agent, 12 parts of filler.
Preferably, the insect-proof agent includes each component of following parts by weight：10 ~ 20 parts of Dalmatian chrysanthemum, 5 ~ 9 parts of wrinkled giant hyssop, clover 7
~ 11 parts, 8 ~ 15 parts of calamus, 3 ~ 8 parts of cloves, 3 ~ 6 parts of Herba Andrographitis.
Preferably, the high viscous attapulgite be that natural attapulgite is purified, the product after thermal activation.
Preferably, the filler is one or more mixing in white carbon, precipitated calcium carbonate, ultrafine mica powder.
The invention further relates to a kind of method for preparing use in construction of door and window adhesive, comprise the following steps：
（1）The each component of insect-proof agent is weighed according to proportioning, crushes and crosses 150 ~ 200 mesh sieves, be well mixed, be subsequently placed in Soxhlet and carry
Take in device, in ethanol in the in the mixed solvent of water, 4 ~ 6h of refluxing extraction obtains extract solution, standby；
（2）Polyvinyl alcohol, Sodium Polyacrylate, pine tree glue are weighed respectively according to proportioning to be added in reactor, are added water and are stirred,
70 ~ 80 DEG C are then heated to, graphene is added, 1 ~ 2h of stirring reaction obtains reaction product；
（3）To step（2）Product in add proportional quantity, hydroxyethyl cellulose and step（1）Obtained extract solution, mixing is stirred
Mix it is uniform after, add high viscous Concave-convex clay rod, age resister, filler, be well mixed, be subsequently placed in rotating speed for 500 ~
Scattered 20 ~ 30min is sheared in 1000 turns/min cutter, described adhesive is produced.
Preferably, the step（1）The volume of middle mixed solvent and the mass ratio of mixed powder are 15 ~ 20mL：1g.
Preferably, the step（1）The volume ratio of middle ethanol and water is 1:1~2.
Preferably, the step（2）The middle method for adding graphene is to add the graphene water that concentration is 0.1 ~ 0.3g/L
Solution.
Preferably, the step（3）The preparation method of middle high viscous Concave-convex clay rod includes：
Take natural attapulgite clay to be crushed and cross 200 mesh sieves, add water, stirring forms mud in suspension, takes upper suspension
5 ~ 10min of centrifugal treating in 3000 turns/min centrifuge, vacuum filtration；Filter cake is dried, be subsequently placed in Muffle furnace with
20 DEG C/min speed program is warming up to 800 DEG C ~ 900 DEG C, then 3 ~ 4h of constant temperature calcining, and particle diameter is ground to after cooling for 200 mesh,
Obtain high viscous Concave-convex clay rod.
Compared with prior art, the present invention has following beneficial effect：
（1）Use in construction of door and window adhesive of the present invention, effect is preferably bonded applied to that in building doors and windows, can not only play
Really, the application field of adhesive also is expanded with certain waterproof, antiseptic effect, in addition, described adhesive does molten using water
Agent, it is to avoid the harm brought using organic solvent.
（2）The insect-proof agent added in use in construction of door and window adhesive of the present invention uses a variety of medicinal herb componentses, not only
The parasitism of door and window junction insects can effectively be prevented, it is to avoid door and window combines unstable phenomenon caused by insects are parasitic, and
The composition will not be damaged to environment and human body, with preferable safety in utilization and the feature of environmental protection.
（3）High viscous Concave-convex clay rod is added with use in construction of door and window adhesive of the present invention, due to attapulgite
Unique chain layer structure and larger specific surface area, makes it have preferable absorption property, can effectively adsorb surrounding environment
In bad smell, the effect with certain purification air；Along with the viscous characteristic of its height, adhesive and door and window are considerably increased
Between being firmly bonded property.
（4）Graphene is also added with use in construction of door and window adhesive of the present invention, first by graphene and polymer
Component is modified processing, due to the mechanical property that graphene is excellent so that the adhesive prepared has excellent bonding
Fastness and antistripping, the performance of scratch-resistant, graphene is laminar structured in addition, the modified polymer adhesive for being also
Water resistance and corrosion resistance it is getable it is larger improve.
（5）The preparation method of use in construction of door and window adhesive of the present invention is simple and convenient to operate, and process conditions are gentle,
It is adapted to industrialization promotion production.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1：
The present embodiment is related to a kind of use in construction of door and window adhesive and preparation method；
Described adhesive is prepared from by following component：
32 parts of polyvinyl alcohol, 6 parts of Sodium Polyacrylate, 12 parts of pine tree glue, 7 parts of hydroxyethyl cellulose, high viscous Concave-convex clay rod 15
Part, 1.5 parts of graphene, 5 parts of age resister, 8 parts of insect-proof agent, 12 parts of filler.
Wherein, the insect-proof agent includes each component of following parts by weight：16 parts of Dalmatian chrysanthemum, 7 parts of wrinkled giant hyssop, 8 parts of clover, calamus
10 parts, cloves sub 6 parts, 5 parts of Herba Andrographitis.
The high viscous Concave-convex clay rod is that natural attapulgite is purified, the product after thermal activation.
The filler be white carbon, the mixing of ultrafine mica powder, wherein, both mass ratioes be 1:1.2.
The method that the present invention prepares use in construction of door and window adhesive, comprises the following steps：
（1）The each component of insect-proof agent is weighed according to proportioning, crushes and crosses 200 mesh sieves, be well mixed, be subsequently placed in apparatus,Soxhlet's
In, in ethanol in the in the mixed solvent of water, refluxing extraction 5h obtains extract solution, standby；
（2）Polyvinyl alcohol, Sodium Polyacrylate, pine tree glue are weighed respectively according to proportioning to be added in reactor, are added water and are stirred,
80 DEG C are then heated to, graphene is added, stirring reaction 2h obtains reaction product；
（3）To step（2）Product in add proportional quantity, hydroxyethyl cellulose and step（1）Obtained extract solution, mixing is stirred
After mixing uniformly, high viscous Concave-convex clay rod, age resister, filler are added, is well mixed, it is 1000 to be subsequently placed in rotating speed
Turn/min cutter in shear scattered 20min, produce described adhesive.
Step（1）The volume of middle mixed solvent and the mass ratio of mixed powder are 18mL：1g.
Step（1）The volume ratio of middle ethanol and water is 1:1.5.
Step（2）The middle method for adding graphene is to add the graphene aqueous solution that concentration is 0.3g/L.
Step（3）The preparation method of middle high viscous Concave-convex clay rod includes：
Take natural attapulgite clay to be crushed and cross 200 mesh sieves, add water, stirring forms mud in suspension, takes upper suspension
The centrifugal treating 10min in 3000 turns/min centrifuge, vacuum filtration；Filter cake is dried, is subsequently placed in Muffle furnace with 20
DEG C/min speed program is warming up to 800 DEG C, then constant temperature calcining 4h, is ground to particle diameter for 200 mesh after cooling, obtains high viscous recessed
Convex rod stone clay.
Embodiment 2：
The present embodiment is related to a kind of use in construction of door and window adhesive and preparation method；
Described adhesive is prepared from by following component：
20 parts of polyvinyl alcohol, 2 parts of Sodium Polyacrylate, 10 parts of pine tree glue, 4 parts of hydroxyethyl cellulose, high viscous Concave-convex clay rod 10
Part, 0.5 part of graphene, 3 parts of age resister, 5 parts of insect-proof agent, 8 parts of filler.
Wherein, the insect-proof agent includes each component of following parts by weight：10 parts of Dalmatian chrysanthemum, 5 parts of wrinkled giant hyssop, 7 parts of clover, 8 parts of calamus,
Cloves son 3 parts, 3 parts of Herba Andrographitis.
The high viscous Concave-convex clay rod is that natural attapulgite is purified, the product after thermal activation.
The filler is white carbon.
The method that the present invention prepares use in construction of door and window adhesive, comprises the following steps：
（1）The each component of insect-proof agent is weighed according to proportioning, crushes and crosses 150 mesh sieves, be well mixed, be subsequently placed in apparatus,Soxhlet's
In, in ethanol in the in the mixed solvent of water, refluxing extraction 4h obtains extract solution, standby；
（2）Polyvinyl alcohol, Sodium Polyacrylate, pine tree glue are weighed respectively according to proportioning to be added in reactor, are added water and are stirred,
70 DEG C are then heated to, graphene is added, stirring reaction 2h obtains reaction product；
（3）To step（2）Product in add proportional quantity, hydroxyethyl cellulose and step（1）Obtained extract solution, mixing is stirred
Mix it is uniform after, add high viscous Concave-convex clay rod, age resister, filler, be well mixed, be subsequently placed in rotating speed for 500 turns/
Scattered 30min is sheared in min cutter, described adhesive is produced.
Step（1）The volume of middle mixed solvent and the mass ratio of mixed powder are 15mL：1g.
Step（1）The volume ratio of middle ethanol and water is 1:1.
Step（2）The middle method for adding graphene is to add the graphene aqueous solution that concentration is 0.1g/L.
Step（3）The preparation method of middle high viscous Concave-convex clay rod includes：
Take natural attapulgite clay to be crushed and cross 200 mesh sieves, add water, stirring forms mud in suspension, takes upper suspension
The centrifugal treating 5min in 3000 turns/min centrifuge, vacuum filtration；Filter cake is dried, is subsequently placed in Muffle furnace with 20
DEG C/min speed program is warming up to 800 DEG C, then constant temperature calcining 4h, is ground to particle diameter for 200 mesh after cooling, obtains high viscous recessed
Convex rod stone clay.
Embodiment 3：
The present embodiment is related to a kind of use in construction of door and window adhesive and preparation method；
Described adhesive is prepared from by following component：
38 parts of polyvinyl alcohol, 7 parts of Sodium Polyacrylate, 15 parts of pine tree glue, 9 parts of hydroxyethyl cellulose, high viscous Concave-convex clay rod 17
Part, 3.5 parts of graphene, 6 parts of age resister, 12 parts of insect-proof agent, 15 parts of filler.
Wherein, the insect-proof agent includes each component of following parts by weight：20 parts of Dalmatian chrysanthemum, 9 parts of wrinkled giant hyssop, 11 parts of clover, calamus 15
Part, cloves sub 8 parts, 6 parts of Herba Andrographitis.
The high viscous Concave-convex clay rod is that natural attapulgite is purified, the product after thermal activation.
The filler is precipitated calcium carbonate.
The method that the present invention prepares use in construction of door and window adhesive, comprises the following steps：
（1）The each component of insect-proof agent is weighed according to proportioning, crushes and crosses 200 mesh sieves, be well mixed, be subsequently placed in apparatus,Soxhlet's
In, in ethanol in the in the mixed solvent of water, refluxing extraction 6h obtains extract solution, standby；
（2）Polyvinyl alcohol, Sodium Polyacrylate, pine tree glue are weighed respectively according to proportioning to be added in reactor, are added water and are stirred,
80 DEG C are then heated to, graphene is added, stirring reaction 1h obtains reaction product；
（3）To step（2）Product in add proportional quantity, hydroxyethyl cellulose and step（1）Obtained extract solution, mixing is stirred
After mixing uniformly, high viscous Concave-convex clay rod, age resister, filler are added, is well mixed, it is 1000 to be subsequently placed in rotating speed
Turn/min cutter in shear scattered 20min, produce described adhesive.
Step（1）The volume of middle mixed solvent and the mass ratio of mixed powder are 20mL：1g.
Step（1）The volume ratio of middle ethanol and water is 1: 2.
Step（2）The middle method for adding graphene is to add the graphene aqueous solution that concentration is 0.3g/L.
Step（3）The preparation method of middle high viscous Concave-convex clay rod includes：
Take natural attapulgite clay to be crushed and cross 200 mesh sieves, add water, stirring forms mud in suspension, takes upper suspension
The centrifugal treating 10min in 3000 turns/min centrifuge, vacuum filtration；Filter cake is dried, is subsequently placed in Muffle furnace with 20
DEG C/min speed program is warming up to 900 DEG C, then constant temperature calcining 3h, is ground to particle diameter for 200 mesh after cooling, obtains high viscous recessed
Convex rod stone clay.
In summary, use in construction of door and window adhesive of the present invention, applied in building doors and windows, can not only play compared with
Good bond effect, also with certain waterproof, antiseptic effect, expands the application field of adhesive, in addition, described adhesive
Solvent is done using water, it is to avoid the harm brought using organic solvent.In addition, the preparation method of described use in construction of door and window adhesive
It is simple and convenient to operate, process conditions are gentle, is adapted to industrialization promotion production.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (10)
1. a kind of use in construction of door and window adhesive, it is characterised in that include each component of following parts by weight：20 ~ 38 parts of polyvinyl alcohol,
2 ~ 7 parts of Sodium Polyacrylate, 10 ~ 15 parts of pine tree glue, 4 ~ 9 parts of hydroxyethyl cellulose, 10 ~ 17 parts of high viscous Concave-convex clay rod, graphite
0.5 ~ 3.5 part of alkene, 3 ~ 6 parts of age resister, 5 ~ 12 parts of insect-proof agent, 8 ~ 15 parts of filler.
2. use in construction of door and window adhesive according to claim 1, it is characterised in that 32 parts of the polyvinyl alcohol, polypropylene
Sour 6 parts of sodium, 12 parts of pine tree glue, 7 parts of hydroxyethyl cellulose, 15 parts of high viscous Concave-convex clay rod, 1.5 parts of graphene, age resister 5
Part, 8 parts of insect-proof agent, 12 parts of filler.
3. use in construction of door and window adhesive according to claim 1, it is characterised in that the insect-proof agent includes following parts by weight
Each component：10 ~ 20 parts of Dalmatian chrysanthemum, 5 ~ 9 parts of wrinkled giant hyssop, 7 ~ 11 parts of clover, 8 ~ 15 parts of calamus, 3 ~ 8 parts of cloves, Herba Andrographitis 3 ~ 6
Part.
4. use in construction of door and window adhesive according to claim 1, it is characterised in that the high viscous Concave-convex clay rod is day
Right attapulgite is purified, the product after thermal activation.
5. use in construction of door and window adhesive according to claim 1, it is characterised in that the filler is white carbon, lightweight
One or more mixing in calcium carbonate, ultrafine mica powder.
6. the method that one kind prepares the use in construction of door and window adhesive as described in any one of claim 1 ~ 5, it is characterised in that including
Following steps：
（1）The each component of insect-proof agent is weighed according to proportioning, crushes and crosses 150 ~ 200 mesh sieves, be well mixed, be subsequently placed in Soxhlet and carry
Take in device, in ethanol in the in the mixed solvent of water, 4 ~ 6h of refluxing extraction obtains extract solution, standby；
（2）Polyvinyl alcohol, Sodium Polyacrylate, pine tree glue are weighed respectively according to proportioning to be added in reactor, are added water and are stirred,
70 ~ 80 DEG C are then heated to, graphene is added, 1 ~ 2h of stirring reaction obtains reaction product；
（3）To step（2）Product in add proportional quantity, hydroxyethyl cellulose and step（1）Obtained extract solution, mixing is stirred
Mix it is uniform after, add high viscous Concave-convex clay rod, age resister, filler, be well mixed, be subsequently placed in rotating speed for 500 ~
Scattered 20 ~ 30min is sheared in 1000 turns/min cutter, described adhesive is produced.
7. the preparation method of use in construction of door and window adhesive according to claim 6, it is characterised in that the step（1）In
The volume of mixed solvent and the mass ratio of mixed powder are 15 ~ 20mL：1g.
8. the preparation method of use in construction of door and window adhesive according to claim 6, it is characterised in that the step（1）In
The volume ratio of ethanol and water is 1:1~2.
9. the preparation method of use in construction of door and window adhesive according to claim 6, it is characterised in that the step（2）In
The method for adding graphene is to add the graphene aqueous solution that concentration is 0.1 ~ 0.3g/L.
10. the preparation method of use in construction of door and window adhesive according to claim 6, it is characterised in that the step（3）In
The preparation method of high viscous Concave-convex clay rod includes：
Take natural high viscous Concave-convex clay rod to be crushed and cross 200 mesh sieves, add water, stirring forms mud in suspension, take upper strata to hang
Turbid liquid 5 ~ 10min of centrifugal treating in 3000 turns/min centrifuge, vacuum filtration；Filter cake is dried, Muffle furnace is subsequently placed in
In be warming up to 800 DEG C ~ 900 DEG C with 20 DEG C/min speed program, then 3 ~ 4h of constant temperature calcining, being ground to particle diameter after cooling is
200 mesh, obtain high viscous Concave-convex clay rod.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710585483.XA CN107177330A (en) | 2017-07-18 | 2017-07-18 | A kind of use in construction of door and window adhesive and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710585483.XA CN107177330A (en) | 2017-07-18 | 2017-07-18 | A kind of use in construction of door and window adhesive and preparation method |
Publications (1)
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| CN107177330A true CN107177330A (en) | 2017-09-19 |
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ID=59838393
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| CN201710585483.XA Withdrawn CN107177330A (en) | 2017-07-18 | 2017-07-18 | A kind of use in construction of door and window adhesive and preparation method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109849397A (en) * | 2019-03-01 | 2019-06-07 | 安徽森泰木塑集团股份有限公司 | A kind of preparation process of PVC core surface layer thermal transfer outdoor flooring |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1807535A (en) * | 2006-02-07 | 2006-07-26 | 江苏南大紫金科技集团有限公司 | Nanometer composite polyvinyl alcohol adhesive and its preparation method |
| CN104877627A (en) * | 2015-05-26 | 2015-09-02 | 柳州市亿廷贸易有限责任公司 | Adhesive for buildings |
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2017
- 2017-07-18 CN CN201710585483.XA patent/CN107177330A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1807535A (en) * | 2006-02-07 | 2006-07-26 | 江苏南大紫金科技集团有限公司 | Nanometer composite polyvinyl alcohol adhesive and its preparation method |
| CN104877627A (en) * | 2015-05-26 | 2015-09-02 | 柳州市亿廷贸易有限责任公司 | Adhesive for buildings |
Non-Patent Citations (2)
| Title |
|---|
| 刘兆平 等: "浅谈石墨烯产业化应用现状与发展趋势", 《新材料产业》 * |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109849397A (en) * | 2019-03-01 | 2019-06-07 | 安徽森泰木塑集团股份有限公司 | A kind of preparation process of PVC core surface layer thermal transfer outdoor flooring |
| CN109849397B (en) * | 2019-03-01 | 2021-04-06 | 安徽森泰木塑集团股份有限公司 | Preparation process of PVC core surface layer heat transfer printing outdoor floor |
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Application publication date: 20170919 |
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