CN107176749A - Integral continuous Fenton oxidation-reduction sewage disposal device - Google Patents

Integral continuous Fenton oxidation-reduction sewage disposal device Download PDF

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Publication number
CN107176749A
CN107176749A CN201610149026.1A CN201610149026A CN107176749A CN 107176749 A CN107176749 A CN 107176749A CN 201610149026 A CN201610149026 A CN 201610149026A CN 107176749 A CN107176749 A CN 107176749A
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CN
China
Prior art keywords
regulating reservoir
pond
sewage
fenton oxidation
sludge
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610149026.1A
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Chinese (zh)
Inventor
吴洪
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Zhejiang Guoqing Environmental Protection Technology Co Ltd
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Zhejiang Guoqing Environmental Protection Technology Co Ltd
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Priority to CN201610149026.1A priority Critical patent/CN107176749A/en
Publication of CN107176749A publication Critical patent/CN107176749A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/026Fenton's reagent
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes

Abstract

The present invention discloses integral continuous Fenton oxidation-reduction sewage disposal device, belong to technical field of sewage, be made up of high concentration regulating reservoir, low concentration regulating reservoir, Fe-C micro cells, Fenton oxidation pond, sedimentation basin, anoxic pond, contact-oxidation pool, MBR ponds, complex biological filter and sludge-tank.In the equipment each reaction tank for serially with parallel combined structure pattern, be sequentially connected constituted serial structure from front to back by high concentration regulating reservoir, Fe-C micro cells, Fenton oxidation pond, sedimentation basin, anoxic pond, contact-oxidation pool, MBR ponds and complex biological filter;Low concentration regulating reservoir is parallel with high concentration regulating reservoir, is directly connected with sedimentation basin;Complex biological filter and sludge-tank are parallel, and sewage enters exhaust system after complex biological filter, and precipitating sludge enters sludge-tank and carries out subsequent treatment.Suitable for the high concentrations such as various chemical industry, pharmacy, the processing of severe sewage.

Description

Integral continuous Fenton oxidation-reduction sewage disposal device
Technical field
The invention belongs to technical field of sewage, it is related to sewage disposal device, especially integral continuous Fenton oxidation-reduction sewage disposal device.
Background technology
The features such as chemical industry, pharmacy sewage often have concentration height, complicated, toxicity is big, biodegradability is poor, therefore chemical engineering sewage is one of sewage species difficult to deal with sewage treatment area.At present, mainly there are two kinds of physico-chemical process and biochemical process using more technology in chemical industry, pharmacy sewage processing, to there is water quality reaching standard situation in two kinds of technologies unstable in actual applications, or investment construction cost is excessive, energy consumption and O&M are costly, considerably increases enterprise governance sewage cost.With social progress, the enhancing of people's environmental consciousness, various circles of society focus more on to environmental protection, for severe sewage effective method must be taken to handle, reach state sewage emission standard.
The invention of application number 201310584440.1, the modular Fenton reagent processing method for waste water and device of a kind of interlocked control are disclosed, waste water is continued through the first regulating reservoir, the second regulating reservoir, Strong oxdiative reaction tank, pH value readjustment five reaction tanks in pond and flocculation basin successively.Waste water adjusts pH value in the first regulating reservoir, and waste water, which enters in the second regulating reservoir, adds H2O2, make the oxidation reduction potential control of waste water in Strong oxdiative Ying Chi in 1.8V-2.8V, add sodium hydroxide in pH value readjustment pond, adjust back pH value of waste water, finally waste water is entered flocculation basin, flocculant is added in flocculation basin.Device is obvious for common wastewater treatment efficiency disclosed in the patent, but there is drawback one for severe sewage disposals such as impurity more, the industry, the pharmacy that there are a large amount of sludge and lack Treatment of Sludge place, the sludge precipitated for sewage disposal process, formed lacks effective processing means, easily triggers the secondary harm of sewage disposal.
The content of the invention
The present invention is solves the deficiencies in the prior art there is provided integral continuous Fenton oxidation-reduction sewage disposal device, to realize the qualified discharge of the severe sewage such as chemical industry, pharmacy.
Technical scheme is as follows:
Integral continuous Fenton oxidation-reduction sewage disposal device, is made up of high concentration regulating reservoir, low concentration regulating reservoir, Fe-C micro cells, Fenton oxidation pond, sedimentation basin, anoxic pond, contact-oxidation pool, MBR (membrane biological reaction) pond, complex biological filter and sludge-tank.In the sewage disposal device each reaction tank for serially with parallel combined structure pattern, be sequentially connected constituted serial structure from front to back by high concentration regulating reservoir, Fe-C micro cells, Fenton oxidation pond, sedimentation basin, anoxic pond, contact-oxidation pool, MBR ponds and complex biological filter;Low concentration regulating reservoir is parallel with high concentration regulating reservoir, is directly connected with sedimentation basin;Complex biological filter and sludge-tank are parallel, and sewage enters exhaust system after complex biological filter, and precipitating sludge enters sludge-tank and carries out subsequent treatment.
The severe such as chemical industry, pharmacy sewage separately flows into high concentration regulating reservoir and low concentration regulating reservoir according to its concentration level by pipe-line system, in high concentration regulating reservoir sewage carry out water quality, water, pH value regulation, its pH value is maintained 3-4 ranks.
After high concentration regulating reservoir, sewage is pumped into Fe-C micro cells.The mixed fillers of iron filings and carbon granule are filled with inside Fe-C micro cells, pH value 3-4 sewage enters after Fe-C micro cells, under acid medium effect, miniature galvanic cell chemical reaction is formed between iron and charcoal, discharge activity extremely strong [H], now sewage PH value is 5-6, and under weak acid environment with many components in solution redox reaction can occur for nascent state [H].Organic matter after Fe-C micro cells in sewage is all aoxidized, and COD is greatly reduced, and biodegradability is greatly improved, the Fe of generation2+It can trap.
Sewage enters Fenton oxidation pond through Fe-C micro cells, and H is added in Fenton oxidation pond2O2, and keep Fe2+Concentration is about 0.5mg/l, H2O2Concentration is 4mg/l, can form oxidisability stronger Fenton (Fenton) reagent, reacts 30~60min, and the hydroxyl radical free radical of strong oxidizing property is generated by redox reaction, carries out the open loop chain rupture oxidation of organic pollution.The Fe of nascent state also has higher activity, generates Fe2+, as reaction is further carried out, formed with Fe2+For the floccule body at the center that is gelled.
The Fe of Fenton oxidation generation2+It can trap, hold under the arm and wrap up in and adsorb the coprecipitated effect of suspension colloid generation, it is 7-8 now to add composite flocculation agent PAC and regulation sewage PH value, then enter reaction in sedimentation basin in the lump with low concentration regulating reservoir sewage and flocculate.After flocculation reaction, little particle, particle suspension thing in waste water further flocculate into bulky grain suspension, so that improve the sludge after its settleability, precipitation flows into sludge-tank certainly.
Through the waste water after precipitation reason, its SS, CODer, BOD5Substantially reduced Deng contamination index, water outlet flows into anoxic pond.Anoxic pond built-in biological filler, it is possible to decrease the turnover rate of activated sludge, dirty Organic substance in water of further degrading, it is the single-stranded organic matter of small molecule macromolecular is combined the oxidation operation of chain, and improves the biodegradability of sewage.
Sewage flows into contact-oxidation pool through anoxic pond, carries out aeration aerobic reaction.Air is provided using blower fan for contact-oxidation pool to be aerated, it is using bioactivity in built-in high-performance bio filler, Aerobic Pond in pond high, microorganism substantial amounts of biomembrane in filler surface attachment, biochemical treatment is swapped to sewage by biomembrane, the pollution index of sewage is greatly reduced.
Sewage enters MBR ponds through contact-oxidation pool, carries out ultrafiltration membrane bio-reaction.Under blower fan blasting action, more efficient biochemical reaction is carried out in MBR ponds, pollutant component is further removed.Sewage flows into complex biological filter behind MBR ponds, and partly precipitated sludge reflux is to anoxic pond, and most sludge enter sludge-tank.
Sewage anaerobic bio-treated, Aerobic biological process and filtering in complex biological filter are once completed, and through multistage purification, are realized to multinomial processing such as the organic matter degradations, denitrogenation dephosphorizing, filtering of sewage.Water quality gets a promotion after sewage disposal, reaches discharge standard, can directly be discharged through floss hole.
In sludge-tank collection sedimentation basin, MBR ponds after sludge, it is lifted into Stacked sludge dewatering machine by membrane pump and is dehydrated, sludge outward transport or security landfill after dehydration and drying, filtrate is back in comprehensive adjustment pond, prevent secondary pollution.
The invention has the advantages that the integral continuous Fenton oxidation-reduction sewage disposal device, the multiple reaction tanks of continous way, make sewage disposal reaction more abundant, reduce the generation of intermediate product, the utilization rate of oxidant is improved, continuum micromeehanics, successive reaction are realized;Disposable input, is used for a long time, and safeguards simple, reduces operation and maintenance expenses and uses;Suitable for the high concentrations such as various chemical industry, pharmacy, the processing of severe sewage.
Brief description of the drawings
Fig. 1 integral continuous Fenton oxidation-reduction sewage disposal device schematic flow sheets.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described.
Integral continuous Fenton oxidation-reduction sewage disposal device, as shown in Figure of description 1, it is made up of high concentration regulating reservoir, low concentration regulating reservoir, Fe-C micro cells, Fenton oxidation pond, sedimentation basin, anoxic pond, contact-oxidation pool, MBR ponds, complex biological filter and sludge-tank.
Embodiment
Sludge-tank, size:φ10.0m×3.5m;Structure:Underground type Reinforced Concrete Structure;Volume:235m3;It is equipped with equipment:Sludge pump, Stacked sludge dewatering machine etc.;Quantity:1.
High concentration regulating reservoir and low concentration regulating reservoir, size:8.0m×4.0m×3.0m;Structure:Underground type Reinforced Concrete Structure;Volume:100m3;Quantity:12 lattice.
Fe-C micro cells, size:φ1.5m×4.0m;Structure:Complete sets of anticorrosive structure;Dischargeable capacity:3.0m3;Quantity:1.
Fenton oxidation pond, size:3.5m×5.5m×2.5m;Structure:Semi-underground type steel concrete, anticorrosion structure;Dischargeable capacity:38m3;Quantity:1.
Sedimentation basin, size:4.0m×4.0m×3.0m;Structure:Semi-underground type Reinforced Concrete Structure;Dischargeable capacity:45m3;Quantity:1.
Anoxic pond, size:8.0m×3.0m×4.0m;Structure:Semi-underground type Reinforced Concrete Structure;Dischargeable capacity: 80m3;It is equipped with equipment:1 set of biochemical filler, bottom stirring system;Quantity:1.
Contact Aerobic Pond, size:6.0m×7.5m×4.0m;Structure:Underground type Reinforced Concrete Structure;Dischargeable capacity:158m3;It is equipped with equipment:Micro-hole aerator and bracket, biochemical filler 158m3;Quantity:12 lattice.
MBR ponds, size:4.0m×7.5m×4.0m;Structure:Underground type Reinforced Concrete Structure;Dischargeable capacity:105m3;It is equipped with equipment:Micro-hole aerator and bracket, biochemical filler 105m3, 1 set of MBR films and mould bases;Quantity:1.
Complex biological filter, size:φ3.0m×4.0m;Structure:Complete sets of anticorrosive structure;Volume:25m3;It is equipped with equipment:1 set of filter plate, filtrate 25m3;Quantity:1.
The handling process of integral continuous Fenton oxidation-reduction sewage disposal device is cut dirt and see the table below:
Figure of description is only used as the structure of product, principle schematic, and actual product structure snd size are defined by inventor's design production drawing.
Embodiment described above is only that embodiments of the present invention are described, and not the spirit and scope of the present invention are defined.On the premise of design concept of the present invention is not departed from, all variations and modifications that this area ordinary person makes to technical scheme all should drop into protection scope of the present invention, and the scope of the present invention is limited by appended claims rather than described above.

Claims (4)

1. integral continuous Fenton oxidation-reduction sewage disposal device, by high concentration regulating reservoir, low concentration regulating reservoir, Fe-C micro cells, Fenton oxidation pond, sedimentation basin, anoxic pond, contact-oxidation pool, MBR (membrane bioreactions Should) pond, complex biological filter and sludge-tank composition, it is characterised in that each reaction tank is string in the equipment Row and parallel combined structure pattern, by high concentration regulating reservoir, Fe-C micro cells, Fenton oxidation pond, heavy Shallow lake pond, anoxic pond, contact-oxidation pool, MBR ponds and complex biological filter are sequentially connected composition string from front to back Row structure;Low concentration regulating reservoir is parallel with high concentration regulating reservoir, is directly connected with sedimentation basin;Compound bio is filtered Pond and sludge-tank are parallel, and sewage enters exhaust system after complex biological filter, and precipitating sludge enters sludge-tank Carry out subsequent treatment.
2. integral continuous Fenton oxidation-reduction sewage disposal device according to claim 1, its feature exists In the sewage PH value in the high concentration regulating reservoir maintains 3-4.
3. integral continuous Fenton oxidation-reduction sewage disposal device according to claim 1, its feature exists In being filled with the mixed fillers of iron filings and carbon granule inside the Fe-C micro cells, wherein sewage PH value is 5-6.
4. integral continuous Fenton oxidation-reduction sewage disposal device according to claim 1, its feature exists In adding H in the Fenton oxidation pond2O2, and keep Fe2+Concentration is about 0.5mg/l, H2O2Concentration is 4mg/l。
CN201610149026.1A 2016-03-11 2016-03-11 Integral continuous Fenton oxidation-reduction sewage disposal device Pending CN107176749A (en)

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Application Number Priority Date Filing Date Title
CN201610149026.1A CN107176749A (en) 2016-03-11 2016-03-11 Integral continuous Fenton oxidation-reduction sewage disposal device

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Application Number Priority Date Filing Date Title
CN201610149026.1A CN107176749A (en) 2016-03-11 2016-03-11 Integral continuous Fenton oxidation-reduction sewage disposal device

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CN107176749A true CN107176749A (en) 2017-09-19

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108191150A (en) * 2017-12-29 2018-06-22 武汉恒通源环境工程技术有限公司 A kind of vehicle moving sewage treatment equipment
CN108409042A (en) * 2018-03-26 2018-08-17 哈尔滨工业大学 It is a kind of using qualified discharge as the organic-inorganic heavy metal production wastewater treatment method of core
CN108455768A (en) * 2018-03-26 2018-08-28 哈尔滨工业大学 It is a kind of using water reuse as the organic-inorganic polluted heavy metals production wastewater treatment method of core
CN110563282A (en) * 2019-10-10 2019-12-13 上海玉畔环保设备有限公司 Treatment system and treatment method for amino resin production wastewater

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013010388A1 (en) * 2011-07-21 2013-01-24 波鹰(厦门)科技有限公司 Apparatus for treating landfill leachate and treatment method therefor
CN103910470A (en) * 2014-04-04 2014-07-09 南京大学盐城环保技术与工程研究院 System and method for treating comprehensive wastewater in chemical industrial parks
CN104649512A (en) * 2014-12-23 2015-05-27 安徽省天虹绿洲环保科技有限公司 High-concentration medicinal adjuvant wastewater treatment process
CN205061784U (en) * 2015-01-28 2016-03-02 珠海市规划设计研究院 Treatment of domestic sewage recycling system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013010388A1 (en) * 2011-07-21 2013-01-24 波鹰(厦门)科技有限公司 Apparatus for treating landfill leachate and treatment method therefor
CN103910470A (en) * 2014-04-04 2014-07-09 南京大学盐城环保技术与工程研究院 System and method for treating comprehensive wastewater in chemical industrial parks
CN104649512A (en) * 2014-12-23 2015-05-27 安徽省天虹绿洲环保科技有限公司 High-concentration medicinal adjuvant wastewater treatment process
CN205061784U (en) * 2015-01-28 2016-03-02 珠海市规划设计研究院 Treatment of domestic sewage recycling system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108191150A (en) * 2017-12-29 2018-06-22 武汉恒通源环境工程技术有限公司 A kind of vehicle moving sewage treatment equipment
CN108409042A (en) * 2018-03-26 2018-08-17 哈尔滨工业大学 It is a kind of using qualified discharge as the organic-inorganic heavy metal production wastewater treatment method of core
CN108455768A (en) * 2018-03-26 2018-08-28 哈尔滨工业大学 It is a kind of using water reuse as the organic-inorganic polluted heavy metals production wastewater treatment method of core
CN110563282A (en) * 2019-10-10 2019-12-13 上海玉畔环保设备有限公司 Treatment system and treatment method for amino resin production wastewater

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Application publication date: 20170919