CN107155739A - A kind of humic acid exempts from film cover bag and preparation method thereof and application method - Google Patents
A kind of humic acid exempts from film cover bag and preparation method thereof and application method Download PDFInfo
- Publication number
- CN107155739A CN107155739A CN201710289276.XA CN201710289276A CN107155739A CN 107155739 A CN107155739 A CN 107155739A CN 201710289276 A CN201710289276 A CN 201710289276A CN 107155739 A CN107155739 A CN 107155739A
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- China
- Prior art keywords
- humic acid
- film cover
- cover bag
- exempts
- chitosan
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
- A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
- A01G13/0237—Devices for protecting a specific part of a plant, e.g. roots, trunk or fruits
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
- C09D105/08—Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
Exempt from film cover bag and preparation method thereof and application method the invention discloses a kind of humic acid, by Nano-meter SiO_22It is dissolved in acetic acid aqueous solution, adds chitosan, fully add glycerine after dissolving, chitosan is made and is combined mother liquor.Then potassium humate solution is made, a certain amount of trigonella bean gum is dissolved in wherein；Chitosan is combined mother liquor in the case of stirring and the potassium humate solution of trigonella bean gum is dissolved in, stir obtain it is a kind of it is new and effective with freeze proof, antibacterial, insect pest, provide nutriment multifunctional humic acid exempt from film cover bag mother liquor, it is diluted with water before use, directly it is sprayed onto fruit surface, you can film forming.It is nontoxic, harmless easy to use that the humic acid of the present invention exempts from film cover bag, avoid plastic pollution and troublesome poeration that traditional bagging is brought, simultaneously can make fruit have cold-resistant, antibacterial, insect pest, can also to fruit provide growth and development process in required for nutriment it is many, so as to effectively improve the quality of fruit.
Description
Technical field
The invention belongs to agriculture applied technology field, and in particular to a kind of humic acid is exempted from film cover bag and preparation method thereof and made
Use method.
Background technology
The Apple Bags generally used in the market are generally paper and membrane (interior black extrusion coating paper blackens plastic foil) fruit bag, hair
The fruit bag that bright patent 02128086.X is announced is as such, and paper and membrane fruit bag is imitated in terms of water conservation, fresh-keeping, weightening and chlorisis
Fruit preferably, but in its use there is also it is certain the problem of, i.e., apple is stored easily occurring to burn day and pluck apple after fruit after plucking bag
Phase is short.
Exempt from the substitute that film cover bag is plastic foil bagging, mainly highly enriched set pouch-type new high fat film pulvis sprays when using
Apply fruit face and quickly form a floor height molecule ultra-thin flexible film, although effect is significantly, the existing feature for exempting from film cover bag compares
It is single, without bacteriostasis, in addition it is also necessary to suitably spray insecticide to ensure the good growth of fruit.Humic acid is applied and is exempting from mantle
There is not yet any report on bag.
The content of the invention
In order to overcome the defect that above-mentioned prior art is present, film cover bag is exempted from it is an object of the invention to provide a kind of humic acid
And preparation method thereof and application method, this method is simple to operate, low for equipment requirements, environment-friendly；Through exempting from made from this method
Film cover bag can effective bacteria growing inhibiting, extend the Storage period of fruit, with good water conservation, fresh-keeping effect.
The present invention is to be achieved through the following technical solutions：
A kind of humic acid exempts from the preparation method of film cover bag, comprises the following steps：
1) by Nano-meter SiO_22It is dissolved in acetic acid aqueous solution, is stirring evenly and then adding into chitosan, fully adds glycerine after dissolving,
Stir, chitosan is made and is combined mother liquor；
2) take humic acid to be dissolved in potassium hydroxide solution, potassium humate solution is made, trigonella bean gum is then added, fully
Stir；
3) chitosan under agitation, is combined mother liquor and step 2) potassium humate of obtained addition trigonella bean gum is molten
Liquid is stirred, and adds glycerine, is sufficiently stirred for until it is dispersed into homogeneous system, it is female that obtained humic acid exempts from film cover bag
Liquid, is sprayed on fruit surface and obtains humic acid and exempt from film cover bag when using.
The chitosan is the chitosan that degree of acetylation is 70%~90%.
The mass concentration of acetic acid aqueous solution is 0.2%~0.6%.
Step 1) in, chitosan：Nano-meter SiO_22：Glycerine：Mass ratio=15 of water：(0.2-1.4)：(0.4-1.6)：30.
Step 2) in, the humic acid is fulvic acid, ulmic acid or humic acid.
Step 2) in, trigonella bean gum：The mass ratio of humic acid=(0.8-2)：10.
Step 3) in add glycerine and humic acid mass ratio be (0.5-2)：10.
The invention also discloses exempt from film cover bag using humic acid made from the above method.
The invention also discloses the application method that above-mentioned humic acid exempts from film cover bag, by humic acid exempt from film cover bag mother liquor add water it is dilute
100~1000 times are released, in fruit young fruit period, sprays the 1st time, was sprayed 1 time every 10-20 days later, in fruit after spraying 2-3 times
Surface forms one layer of complete diaphragm；Wherein, the time of sprinkling film forming is 0.5-2h every time.
Compared with prior art, the present invention has following beneficial technique effect：
Humic acid disclosed by the invention exempts from the preparation method of film cover bag, using humic acid, chitosan and glycerine as primary raw material,
Humic acid has the functions such as good physiologically active and absorption, complexing, exchange, it is possible to increase the effect of plant resistance, simultaneously
Due to the effect of its complexing (chelating) metal ion, the moderate-element and trace element needed for plant are easily carried to plant
In vivo, utilization rate of the fruit to various nutrients is improved, the essential element of humic acid has carbon, hydrogen, oxygen, nitrogen, sulphur and phosphorus, can be to fruit
The real nutritional ingredient provided required for growth.Preparation method is simple to operate, low for equipment requirements, environmental protection, is adapted to industrialization
Amplification production.
The obtained of the present invention exempts from film cover bag, with bacteriostasis antibiosis ability, while the growth of fruit normal health is ensured,
The use of agricultural chemicals can effectively be reduced.Humic acid using the present invention exempts from film cover bag, can protect fruit and blade, effective pre- anti-bacteria
The influence of infection and insect pest to apple development, optimizes fruit development level, while not influenceing illumination and coloring, can make fruit face
It is bright and clean, it is bright in colour.Cleaned before fruit is edible with water, film forming can automatically disengage fruit body.
Bagging is carried out to fruit using the method for the present invention, the entrance of air and bacterium can be effectively prevented, delay fruit
Real corruption, extends the Storage period of fruit, with good water conservation, fresh-keeping effect.
Embodiment
With reference to specific embodiment, the present invention is described in further detail, it is described be explanation of the invention and
It is not to limit.
Embodiment 1
Prepare novel and multifunctional humic acid and exempt from film cover bag, be prepared from the following components by quality：Humic acid 10kg, hydrogen-oxygen
Change potassium 10kg, chitosan 15kg, Nano-meter SiO_221.1kg, glycerine 0.6kg, trigonella bean gum 1.0kg, water 30kg.
Above raw material is commercially available prod, and producer is not limited.
Preparation method：First by 0.6kg Nano-meter SiO_22, it is dissolved in 0.2% acetic acid aqueous solution, is stirring evenly and then adding into
0.6kg glycerine is added after 15kg chitosans, fully dissolving, is stirred, chitosan is made and is combined mother liquor.
Then take 10kg humic acid to be dissolved in potassium hydroxide solution, potassium humate solution is made, by 1.0kg cucurbit
Bar peptization is in wherein；Chitosan is combined mother liquor in the case of stirring and the potassium humate solution of trigonella bean gum is dissolved in, then
Remaining glycerine is added in the presence of being stirred for, until forming the system of stable uniform, that is, humic acid is obtained and exempts from film cover bag mother liquor.
Embodiment 2
Prepare novel and multifunctional humic acid and exempt from film cover bag, be prepared from the following components by weight：Humic acid 15kg, hydrogen-oxygen
Change potassium 15kg, chitosan 20kg, Nano-meter SiO_220.8kg, glycerine 2.3kg, trigonella bean gum 1.5kg, water 30kg.
Above raw material is commercially available prod, and producer is not limited.
Preparation method：First by 0.8kg Nano-meter SiO_22, it is dissolved in 0.8% acetic acid aqueous solution, is stirring evenly and then adding into
0.8kg glycerine is added after 20kg chitosans, fully dissolving, is stirred, chitosan is made and is combined mother liquor.Then take 15kg's
Humic acid is dissolved in potassium hydroxide solution, and potassium humate solution is made, 1.5kg trigonella bean gum is dissolved in wherein；In stirring
In the case of chitosan be combined mother liquor and be dissolved in the potassium humate solution of trigonella bean gum, added in the presence of being then stirred for surplus
Remaining glycerine, until forming the system of stable uniform, that is, obtains humic acid and exempts from film cover bag mother liquor.
Embodiment 3
Prepare novel and multifunctional humic acid and exempt from film cover bag, be prepared from the following components by weight：Humic acid 20kg, hydrogen-oxygen
Change potassium 20kg, chitosan 25kg, Nano-meter SiO_221.0kg, glycerine 4.0kg, trigonella bean gum 2kg, water 30kg.
Above raw material is commercially available prod, and producer is not limited.
Preparation method：First by 1.0kg Nano-meter SiO_22, it is dissolved in 1.5% acetic acid aqueous solution, is stirring evenly and then adding into
1.0kg glycerine is added after 25kg chitosans, fully dissolving, is stirred, chitosan is made and is combined mother liquor.Then take 20kg's
Humic acid is dissolved in potassium hydroxide solution, and potassium humate solution is made, 2.0kg trigonella bean gum is dissolved in wherein；In stirring
In the case of chitosan be combined mother liquor and be dissolved in the potassium humate solution of trigonella bean gum, added in the presence of being then stirred for surplus
Remaining glycerine, until forming the system of stable uniform, that is, obtains humic acid and exempts from film cover bag mother liquor.
【Verification experimental verification】
Described in this experiment is the application test experiments that a kind of novel and multifunctional humic acid exempts from film cover bag.
Experimental design is as follows：
1st, experiment place and crop：Shaanxi Hu County, red fuji apple.
2nd, experimental method：Product made from Example 1-3, is diluted with water 800 times, and carrying out sprinkling to experiment crop applies
Fertilizer；And one group of control experiment is taken, bagging processing is carried out to apple with conventional plastic bag, growth of the different baggings to apple is explored
The influence of situation.
3rd, application experiment result is as follows：
1) with mother liquor made from embodiment 1,1.5h film forming is needed after sprinkling, using film produced by the present invention bag after 60 days,
Apple development situation is good compared with control group, can effectively reduce pest and disease damage, and breed bacteria influences on apple development；It is made with embodiment 2
Mother liquor sprinkling after need 1h film forming, and intensity is preferably, and using effect is excellent, effectively reduces pest and disease damage to apple development shadow
Ring；With 0.8h film forming is needed after mother liquor, sprinkling made from embodiment 3, apple development situation is preferable.
2) sprinkling film forming is carried out to apple with mother liquor made from embodiment 1-3 respectively, experimental result is as follows：
The growing state of apple after the bagging of table 1
Thus, it will be seen that carry out sprinkling film forming using mother liquor made from 1-3 is implemented, compared to comparative example, can be carried significantly after use
The survival rate of high fruit, can reduce the influences such as malnutritive, the aggrieved insect infection of apple development process appearance, while can make fruit
Color and luster is exquisitely carved, fuller, the quality of the apple improved.
3) the storage situation of apple after bagging at room temperature (25 DEG C), is explored, experimental result is as follows：
The storage situation of apple after the bagging of table 2
Bagging is carried out to apple using the method for the present invention thus, it is possible to find out, air and bacterium can be effectively prevented
Into having delayed the corruption of apple, extended the Storage period of apple, with good water conservation, fresh-keeping effect.
Bagging film of exempting from prepared by the method provided using the present invention can be additionally used in：Pears, Kiwi berry, jujube, peach, apricot, pomegranate, Portugal
The various fruit such as grape, Lee, citrus, loquat, lichee, longan, mango, banana, cherry, persimmon, strawberry, there is good effect.
It is described above, only it is presently preferred embodiments of the present invention, not the present invention is imposed any restrictions, it is every according to the present invention
Any simple modification, change and equivalent structure transformation that technical spirit is made to above example, still fall within skill of the present invention
In the protection domain of art scheme.
Claims (9)
1. a kind of humic acid exempts from the preparation method of film cover bag, it is characterised in that comprise the following steps：
1) by Nano-meter SiO_22It is dissolved in acetic acid aqueous solution, is stirring evenly and then adding into chitosan, fully adds glycerine after dissolving, stir
Uniformly, chitosan is made and is combined mother liquor；
2) take humic acid to be dissolved in potassium hydroxide solution, potassium humate solution is made, then adds trigonella bean gum, is sufficiently stirred for
Uniformly；
3) chitosan under agitation, is combined mother liquor and step 2) the potassium humate solution of obtained addition trigonella bean gum fills
Divide and stir, add glycerine, be sufficiently stirred for until it is dispersed into homogeneous system, obtained humic acid is exempted from film cover bag mother liquor, made
Used time, which is sprayed on fruit surface and obtains humic acid, exempts from film cover bag.
2. humic acid according to claim 1 exempts from the preparation method of film cover bag, it is characterised in that the chitosan is acetyl
Change degree is 70%~90% chitosan.
3. humic acid according to claim 1 exempts from the preparation method of film cover bag, it is characterised in that the quality of acetic acid aqueous solution
Concentration is 0.2%~0.6%.
4. humic acid according to claim 1 exempts from the preparation method of film cover bag, it is characterised in that step 1) in, chitosan：
Nano-meter SiO_22：Glycerine：Mass ratio=15 of water：(0.2-1.4)：(0.4-1.6)：30.
5. humic acid according to claim 1 exempts from the preparation method of film cover bag, it is characterised in that step 2) in, the corruption
It is fulvic acid, ulmic acid or humic acid to grow acid.
6. humic acid according to claim 1 exempts from the preparation method of film cover bag, it is characterised in that step 2) in, faenum graecum
Glue：The mass ratio of humic acid=(0.8-2)：10.
7. humic acid according to claim 1 exempts from the preparation method of film cover bag, it is characterised in that step 3) in add it is sweet
The mass ratio of oil and humic acid is (0.5-2)：10.
8. film cover bag is exempted from using humic acid made from the method described in any one in claim 1~7.
9. the humic acid described in claim 8 exempts from the application method of film cover bag, it is characterised in that：Humic acid is exempted from into film cover bag mother liquor
100~1000 times are diluted with water, in fruit young fruit period, sprays the 1st time, was sprayed 1 time every 10-20 days later, after spraying 2-3 times
In fruit surface one layer of complete diaphragm of formation；
Wherein, the time of sprinkling film forming is 0.5-2h every time.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710289276.XA CN107155739B (en) | 2017-04-27 | 2017-04-27 | Humic acid film-covering-free bag and preparation method and use method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710289276.XA CN107155739B (en) | 2017-04-27 | 2017-04-27 | Humic acid film-covering-free bag and preparation method and use method thereof |
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| CN107155739A true CN107155739A (en) | 2017-09-15 |
| CN107155739B CN107155739B (en) | 2020-04-28 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109328786A (en) * | 2018-11-01 | 2019-02-15 | 卢国政 | A kind of preparation method of liquid fruit bag |
| CN112219625A (en) * | 2020-10-12 | 2021-01-15 | 张大庆 | Chitosan degradable biological fruit nutrition film and preparation method thereof |
| CN112980253A (en) * | 2021-02-25 | 2021-06-18 | 陕西品物皆春生态科技有限公司 | Humic acid type fruit bagging-free film agent and using method thereof |
| CN112970493A (en) * | 2021-02-25 | 2021-06-18 | 陕西品物皆春生态科技有限公司 | Humic acid-polyglutamic acid fruit mask and using method thereof |
| CN113383817A (en) * | 2021-07-08 | 2021-09-14 | 陕西科技大学 | Fulvic acid type natural fruit fresh-keeping liquid and preparation and use methods thereof |
| CN113667360A (en) * | 2021-08-24 | 2021-11-19 | 陕西品物皆春生态科技有限公司 | Humic acid type jujube fruit cracking prevention film agent and preparation method and application thereof |
| CN114391402A (en) * | 2021-12-16 | 2022-04-26 | 陕西汉唐农业标准化研究院有限公司 | Apple bagging-free film and preparation and use methods thereof |
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| CN105724433A (en) * | 2016-01-21 | 2016-07-06 | 中国农业科学院郑州果树研究所 | Pesticide composition for bagging pre-treatment of grapes |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109328786A (en) * | 2018-11-01 | 2019-02-15 | 卢国政 | A kind of preparation method of liquid fruit bag |
| CN112219625A (en) * | 2020-10-12 | 2021-01-15 | 张大庆 | Chitosan degradable biological fruit nutrition film and preparation method thereof |
| CN112980253A (en) * | 2021-02-25 | 2021-06-18 | 陕西品物皆春生态科技有限公司 | Humic acid type fruit bagging-free film agent and using method thereof |
| CN112970493A (en) * | 2021-02-25 | 2021-06-18 | 陕西品物皆春生态科技有限公司 | Humic acid-polyglutamic acid fruit mask and using method thereof |
| CN112980253B (en) * | 2021-02-25 | 2022-01-07 | 陕西品物皆春生态科技有限公司 | Humic acid type fruit bagging-free film agent and using method thereof |
| CN112970493B (en) * | 2021-02-25 | 2024-01-26 | 陕西品物皆春生态科技有限公司 | Humic acid-polyglutamic acid fruit mask and application method thereof |
| CN113383817A (en) * | 2021-07-08 | 2021-09-14 | 陕西科技大学 | Fulvic acid type natural fruit fresh-keeping liquid and preparation and use methods thereof |
| CN113667360A (en) * | 2021-08-24 | 2021-11-19 | 陕西品物皆春生态科技有限公司 | Humic acid type jujube fruit cracking prevention film agent and preparation method and application thereof |
| CN114391402A (en) * | 2021-12-16 | 2022-04-26 | 陕西汉唐农业标准化研究院有限公司 | Apple bagging-free film and preparation and use methods thereof |
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| CN107155739B (en) | 2020-04-28 |
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