CN107130468B - A kind of production technology for the digital heat sublimation transfer printing paper that two-sided can be used - Google Patents

A kind of production technology for the digital heat sublimation transfer printing paper that two-sided can be used Download PDF

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Publication number
CN107130468B
CN107130468B CN201710311583.3A CN201710311583A CN107130468B CN 107130468 B CN107130468 B CN 107130468B CN 201710311583 A CN201710311583 A CN 201710311583A CN 107130468 B CN107130468 B CN 107130468B
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China
Prior art keywords
parts
sided
paper
transfer printing
printing paper
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CN201710311583.3A
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CN107130468A (en
Inventor
张凤山
刘燕韶
张金枝
冯好伟
周景蓬
李晓亮
魏文光
马厚悦
魏国华
李国顺
张彩虹
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SHANDONG HUATAI PAPER CO Ltd
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SHANDONG HUATAI PAPER CO Ltd
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/34—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/84—Paper comprising more than one coating on both sides of the substrate
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06—Paper forming aids
    • D21H21/12—Defoamers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
    • D21H23/56—Rolls

Abstract

The present invention relates to field of papermaking, it is especially high-end to use paper field, a kind of production technology of digital heat sublimation transfer printing paper that two-sided can be used specifically is provided, its used coating is prepared with sodium carboxymethylcellulose or sodium alginate, high hydroscopic resin and styrene-acrylic latex etc. for primary raw material, the two-sided of paper may be implemented while transferring, it improves work efficiency, saves the cost of transfer factory.

Description

A kind of production technology for the digital heat sublimation transfer printing paper that two-sided can be used
Technical field
The present invention relates to field of papermaking, are related to a kind of production work of digital heat sublimation transfer printing paper that two-sided can be used Skill.
Background technique
Present digital heat sublimation transfer printing paper is all to be coated with the special gelatin of digital transfer printing in the single side of page Material, another side is generally without coating, or applies one layer of different glue application solution to achieve the purpose that reduce page warpage, when use The one side for being coated with special sizing material can only be used.
Existing transfer printing paper is needed through overmolding and coating two procedures, and production cost is higher；Existing transfer print simultaneously The phenomenon that marble paper is easy to appear warpage since the tension being subject on paper two sides is inconsistent, the above problem is unfavorable for two-sided painting The industrialization of layer marble paper.
Summary of the invention
The present invention is directed to problems of the existing technology, provides a kind of digital heat sublimation that two-sided can be used turn The production technology of bat printing marble paper, used coating is with sodium carboxymethylcellulose or sodium alginate, high hydroscopic resin and phenylpropyl alcohol Latex etc. is prepared for primary raw material, and the two-sided of paper may be implemented while transferring, improve work efficiency, and saves transfer factory Cost.
Technical scheme is as follows:
A kind of production technology for the digital heat sublimation transfer printing paper that two-sided can be used: used sizing compound formula is by weight Amount part is calculated as:
Carboxymethyl cellulose or sodium alginate account for 20-60 parts, and soybean protein accounts for 30-50 parts, and high hydroscopic resin accounts for 1-5 parts, Other auxiliary materials account for 0.3-0.6 parts；
Adding its final solid content after water is 10-20wt%；
The every face spread 2-4g/m of paper2；
Preparation method is as follows:
50-70 DEG C of hot water dissolving 15-30min of carboxymethyl cellulose or sodium alginate, concentration is 10- after dissolution 20wt%；Soybean protein and high hydroscopic resin are uniformly dispersed with 30-50 DEG C of warm water respectively, the solid content after soybean protein dispersion 15-25wt%, the solid content 15-25wt% after high hydroscopic resin dispersion, is then added other auxiliary materials；Wherein:
Degree of substitution >=1.0 of carboxymethyl cellulose, carboxymethyl cellulose or sodium alginate are dense in 25 DEG C of at a temperature of 2wt% The solution viscosity of degree all≤50cp；
High hydroscopic resin of the present invention is with bentonite, phosphate ester starch, acrylic acid, acrylamide etc. for raw material Starch/bentonite complex high absorbent resin of production, preparation method can be according to " functional material " 17 interim, Wang Ruijie in 2015 Et al. hold in " starch/bentonite complex high absorbent resin Study on Preparation " write process production be prepared, Hereinafter referred to as high hydroscopic resin.
Other auxiliary materials include 0.05-0.1 parts of defoaming agent, 0.05-0.1 parts of fungicide, 0.2-0.5 parts of lubricant, Wherein defoaming agent is selected from polysiloxane defoamer, and fungicide is selected from isothiazolinone biocide agent, and lubricant is selected from stearic acid Calcium series lubricant agent, is selected from commercial products.
Prepare after above-mentioned sizing material can corresponding coating apparatus is two-sided to page through the invention spreads, every face Spread 2-4g/m2, into application roll page moisture be not higher than 25wt%, page enters back into rear portion dry section after sizing Domain makes into paper moisture not higher than 5wt%, using press polish, coils into qualified transfer printing paper.
Using obtaining following advantage after this coating:
The characteristics of positive coating materials: first, which is free of inorganic mineral, and the carboxymethyl of dosage is fine in the formula used Dimension element or sodium alginate film forming are more preferable, the more conducively carrying and transfer of ink；Second, due to the single side resin added of this patent There is 2-4g/m2, and the coating weight of the prior art can reach 6-10g/m2, therefore so low coating weight will improve rate of drying just Need special water suction raw material, that is, the addition of high hydroscopic resin of the distinctive formula ratio of this patent is realized；Third, soybean Albumen not only has certain viscose glue ability, and has good water-retaining property and lubricity, and this albumen curing rate Fastly, structure is uniform, improves the rate of drying of the blotting homogeneity on surface；
The present invention cooperates dedicated sizing material, it can be achieved that coated on both sides to calico paper；Its advantage is specific as follows:
The present invention can one-pass molding, reduction be coated with this procedure for the second time, save the cost of paper plant；Print produced by the invention Marble paper two sides is coated with the coating of same type, identical grams, solves the warpage issues of current one-side coated papers all on the market (because of an only finishing coat, causing the tension being subject on two sides inconsistent and warpage), paper formation is conducive to print and transfer；This It can be used repeatedly for the calico paper of invention production twice, reduces the usage amount of paper, cost-effective and environmentally friendly；4th, it is two-sided all to beat After being patterned, it may be implemented two-sided while transferring, improve work efficiency, save the cost of transfer factory.
Detailed description of the invention
Fig. 1 is the schematic diagram of coating apparatus of the present invention and coating process.
Specific embodiment
The present invention is further illustrated below with reference to embodiment, can make those skilled in the art that this hair be more completely understood It is bright, but do not limit the invention in any way.
Embodiment 1
A kind of production technology for the digital heat sublimation transfer printing paper that two-sided can be used: used sizing compound formula is by weight Amount part is calculated as:
By weight are as follows:
Carboxymethyl cellulose or sodium alginate account for 30 parts, and soybean protein accounts for 30 parts, and high hydroscopic resin accounts for 5 parts, other auxiliary materials Account for 0.45 part；
Adding its final solid content after water is 15wt%；
The every face spread 2-4g/m of paper2；
The preparation of sizing material: carboxymethyl cellulose stirring and dissolving in 50 DEG C of warm water, concentration 15wt% after dissolution；Soybean egg It is white that uniform suspension, solid content 20wt% are dispersed with stirring into 40 DEG C of warm water；High hydroscopic resin is according to " starch/swelling Process in the Study on Preparation of native composite highly-absorbent resin " is prepared, and controls solid content 20wt%；
In 5m3In storage tank with blender, the carboxymethyl cellulose aqueous solution prepared, soybean protein water are sequentially added Dispersion liquid, high hydroscopic resin, three kinds of raw materials are respectively 30 parts, 30 parts, 5 parts by the addition number of oven-dry weight, and every kind of raw material is added Mixing time afterwards is not less than 15min, and finally plus water adjusts concentration to 15wt%.
After mixing evenly, 0.1 part of defoaming agent, 0.05 part of fungicide, 0.3 part of lubricant is added, is sufficiently stirred, it is complete At the preparation of glue；Wherein defoaming agent is selected from polysiloxane defoamer, and fungicide is selected from isothiazolinone biocide agent, lubrication Agent is selected from calcium stearate series lubricant agent, is selected from commercial products.
Glue is pumped to the immersion sizing applicator with overflow mechanism, the moisture content that l Water Paper page enters sizing applicator is 22wt%, the pressure for adjusting application roll control the spread 2-4g/m in every face2, the l Water Paper page for being coated with sizing material, which enters drying section, to be continued Drying is finally not higher than 5wt% at paper moisture, becomes qualified product using press polish, reeling end.
Embodiment 2
A kind of production technology for the digital heat sublimation transfer printing paper that two-sided can be used: used sizing compound formula is by weight Amount part is calculated as:
By weight are as follows:
Sodium alginate accounts for 27 parts, and soybean protein accounts for 40 parts, and high hydroscopic resin accounts for 4 parts, and other auxiliary materials account for 0.38 part；
Adding its final solid content after water is 13wt%；
The every face spread 2-4g/m of paper2；
The preparation of sizing material: sodium alginate stirring and dissolving in 45~50 DEG C of warm water prepares concentration 13wt%；Soybean protein Uniform suspension, solid content 20wt% are dispersed with stirring into 40~45 DEG C of warm water；High hydroscopic resin is according to " starch/swollen Process in the Study on Preparation of the native composite highly-absorbent resin of profit " is prepared, and controls solid content 20wt%；
In 5m3In storage tank with blender, the sodium alginate aqueous solution prepared, soybean protein water dispersion are sequentially added Liquid, high hydroscopic resin, three kinds of raw materials are respectively 27 parts, 40 parts, 4 parts by the addition number of oven-dry weight, after every kind of raw material is added Mixing time is not less than 15min, and finally plus water adjusts concentration to 13wt%.
After mixing evenly, 0.1 part of defoaming agent, 0.08 part of fungicide, 0.2 part of lubricant is added, is sufficiently stirred, it is complete At the preparation of glue；Wherein defoaming agent is selected from polysiloxane defoamer, and fungicide is selected from isothiazolinone biocide agent, lubrication Agent is selected from calcium stearate series lubricant agent, is selected from commercial products.
Glue is pumped to the immersion sizing applicator with overflow mechanism, the moisture content that l Water Paper page enters sizing applicator is 24wt%, the pressure for adjusting application roll control the spread 2-4g/m in every face2, the l Water Paper page for being coated with sizing material, which enters drying section, to be continued Drying is finally not higher than 5wt% at paper moisture, becomes qualified product using press polish, reeling end.
Test example
1, the application method and economic efficiency contrast for the heat sublimation transfer printing paper that two-sided can be used:
The first application method: finished product transfer printing paper first prints any one side, after thermoprinting machine transfers and winds Transfer printing paper is attached on printer again and prints another side, and another side is transferred on cloth again, reuses twice, section About 50% paper.
Second of application method: turn-over continues to print another side after finished product transfer printing paper has printed one side, can print Identical or different decorative pattern when thermoprinting machine transfers, the upper surface of transfer printing paper and spreads cloth separately below, while entering print and scalding Machine, while transferring out two pieces of finished product textiles.Front and back sides are utilized in this kind of method transfer printing paper, and at the same time having printed off two parts Finished product cloth, being equivalent to cost of equipment, energy expenditure, labour cost etc. reduces 50%.
In addition, the production method of this patent does not need secondary coating, coating can be reduced with one-pass molding in paper machine The constant expenses such as the energy cost of process, artificial amount to about 20-30%.
2, product quality compares:
Have known to upper table in quantitatively comparable situation, in terms of the reflection density before transfer, printing effect is namely printed Color on to paper is suitable with conventional products；Reflection density after transfer is also not much different, and illustrates the ink of these products The rate of transform is suitable；Ink setting speed, the conventional products that the rate of drying of Examples 1 and 2 is faster than existing secondary coating are other Product.
It can be seen that production cost and use cost of the invention is significantly lower than the prior art, and product quality and conventional production Condition ratio advantageously, is more suitable for extensive promotion and application.

Claims (2)

1. the production technology for the digital heat sublimation transfer printing paper that one kind two-sided can use, it is characterised in that: used glue Material formula is by weight are as follows:
Carboxymethyl cellulose or sodium alginate account for 20-60 parts, and soybean protein accounts for 30-50 parts, and high hydroscopic resin accounts for 1-5 parts, other Auxiliary material accounts for 0.3-0.6 parts；
Other auxiliary materials are 0.05-0.1 by weight parts of defoaming agent, 0.05-0.1 parts of fungicide, 0.2-0.5 parts of lubrication Agent, wherein defoaming agent is selected from polysiloxane defoamer, and fungicide is selected from isothiazolinone biocide agent, and lubricant is selected from tristearin Sour calcium series lubricant agent；
Adding its final solid content after water is 10-20wt%；
The every face spread 2-4g/m of paper2；
Preparation method is as follows:
50-70 DEG C of hot water dissolving 15-30min of carboxymethyl cellulose or sodium alginate, concentration is 10-20wt% after dissolution； Soybean protein and high hydroscopic resin are uniformly dispersed with 30-50 DEG C of warm water respectively, the solid content 15- after soybean protein dispersion 25wt%, the solid content 15-25wt% after high hydroscopic resin dispersion, is then added other auxiliary materials.
2. the production technology of the digital heat sublimation transfer printing paper according to claim 1 that two-sided can be used, feature It is:
The at a temperature of 2wt% concentration of degree of substitution >=1.0 of carboxymethyl cellulose, carboxymethyl cellulose or sodium alginate at 25 DEG C Solution viscosity all≤50cp.
CN201710311583.3A 2016-12-30 2017-05-05 A kind of production technology for the digital heat sublimation transfer printing paper that two-sided can be used Active CN107130468B (en)

Applications Claiming Priority (2)

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CN201611253122 2016-12-30
CN2016112531227 2016-12-30

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CN107130468B true CN107130468B (en) 2019-06-11

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103184706A (en) * 2011-12-27 2013-07-03 湖北丽源数码工程技术有限公司 Preparation method and use method for paper for textile fabric printing
CN103882781A (en) * 2014-02-19 2014-06-25 刘景阳 Surface ink blotting type gold and silver cardboard and manufacturing method thereof
CN106223120A (en) * 2016-08-22 2016-12-14 浙江金泽纸品科技有限公司 A kind of heat sublimation transfer printing paper coating process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103184706A (en) * 2011-12-27 2013-07-03 湖北丽源数码工程技术有限公司 Preparation method and use method for paper for textile fabric printing
CN103882781A (en) * 2014-02-19 2014-06-25 刘景阳 Surface ink blotting type gold and silver cardboard and manufacturing method thereof
CN106223120A (en) * 2016-08-22 2016-12-14 浙江金泽纸品科技有限公司 A kind of heat sublimation transfer printing paper coating process

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Denomination of invention: Production process of digital sublimation transfer printing paper which can be used on both sides

Effective date of registration: 20211223

Granted publication date: 20190611

Pledgee: Industrial and Commercial Bank of China Limited Guangrao sub branch

Pledgor: SHANDONG HUATAI PAPER Co.,Ltd.

Registration number: Y2021980015852