CN107117974B - A kind of chamotte and preparation method thereof for being bonded containing carbon brick - Google Patents
A kind of chamotte and preparation method thereof for being bonded containing carbon brick Download PDFInfo
- Publication number
- CN107117974B CN107117974B CN201710377807.0A CN201710377807A CN107117974B CN 107117974 B CN107117974 B CN 107117974B CN 201710377807 A CN201710377807 A CN 201710377807A CN 107117974 B CN107117974 B CN 107117974B
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- China
- Prior art keywords
- chamotte
- bonded
- containing carbon
- carbon brick
- mesh
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
Abstract
The invention discloses a kind of chamotte and preparation method thereof for being bonded containing carbon brick, wherein the parts by weight of raw materials composition of the chamotte is as follows: alumina particle 5~30;Corundum fine powder 10~40;Magnesia powder 20~50;Alumina powder 5~15;Carbon containing resinoid bond 10~30.The carbon containing resinoid bond is furane resins.Provided by the present invention for being bonded the chamotte containing carbon brick, preparation method is simple, has good ductility, mobility and cementability, and the bonding time is appropriate, and is bonded when containing carbon brick with good intensity.
Description
Technical field
The present invention relates to fire resisting material fields, and in particular to a kind of chamotte and preparation method thereof for being bonded containing carbon brick.
Background technique
Fire clay, also known as chamotte, the puzzle joint material as refractory product masonry, mainly by refractory powder, bonding agent and outer
Agent is added to form.The construction method that ladle is built is that the smooth magnesia carbon brick in surface is built layer by layer, is then glued from level to level with chamotte
It picks up and, so that refractory brick and chamotte is combined into an entirety by sintering.
What is used currently used for chamotte of the bonding containing carbon brick is all magnesia chamotte or magnalium chamotte, uses water as combination
Agent, this allows for chamotte and shrinks at high temperature larger, and biggish contraction leads to risk there are bleed-out, at the same magnesia chamotte or
The poor water retention property of magnalium chamotte causes the construction time of chamotte that cannot reach the requirement of steel mill sometimes.
Intensity is low after common chamotte is burnt, and is especially bonded when containing carbon brick, and common chamotte is very poor to the cementability containing carbon brick,
Almost without intensity under high temperature, once having loosening containing carbon brick, common chamotte can not provide the fixed intensity containing carbon brick.
Summary of the invention
The present invention provides a kind of chamotte for being bonded containing carbon brick, have good ductility, mobility and cementability,
It is appropriate to be bonded the time, and is bonded when containing carbon brick with good intensity.
The parts by weight of raw materials composition of a kind of chamotte for being bonded containing carbon brick, the chamotte is as follows:
Chamotte provided by the invention, raw material are easy to obtain, and preparation method is simple, and prepared chamotte has good extension
Property, mobility and caking property, bonding when containing carbon brick, is with good intensity.
The vanadine particle preferably uses superfine vanadine particle.The mass fraction of aluminium oxide is not less than in the vanadine particle
85%.Further preferably, the partial size of the vanadine particle is 1~0.088mm.
Preferably, the carbon containing resinoid bond is furane resins.Further preferably, the viscosity of the furane resins is
1000~15000mPas.The solid content of the furane resins is 55~60%, and Residual carbon is 30~33%.
Preferably, the partial size of the corundum fine powder is 150 mesh~325 mesh.The partial size of the magnesia powder be 150 mesh~
325 mesh.The partial size of the alumina powder is -320 mesh.The i.e. described alumina powder can pass through 320 meshes.
In the present invention unless otherwise specified, mesh number is all made of Taylor system.
Preferably, the parts by weight of raw materials composition of the chamotte is as follows:
Further preferably, the parts by weight of raw materials composition of the chamotte is as follows:
The present invention also provides a kind of preparation methods of chamotte, and each raw material is mixed according to weight
It arrives.
Provided by the present invention for being bonded the chamotte containing carbon brick, there is good ductility, mobility and cementability, bonding
Time is appropriate, and is bonded when containing carbon brick with good intensity.
Specific embodiment
Embodiment 1
Raw material is weighed by the composition of parts by weight shown in table 1, each raw material is obtained into chamotte with blender after mixing evenly.
Table 1
Raw material | Partial size | Parts by weight |
85 high grade bauxite particles | 1~0.088mm | 20 |
Corundum fine powder | 150 mesh~325 mesh | 20 |
Magnesia powder | 150 mesh~325 mesh | 40 |
Alumina powder | 15 | |
Furane resins | —— | 20 |
Embodiment 2
Raw material is weighed by the composition of parts by weight shown in table 2, each raw material is obtained into chamotte with blender after mixing evenly.
Table 2
Raw material | Partial size | Parts by weight |
85 high grade bauxite particles | 1~0.088mm | 10 |
Corundum fine powder | 150 mesh~325 mesh | 40 |
Magnesia powder | 150 mesh~325 mesh | 30 |
Alumina powder | 10 | |
Furane resins | —— | 25 |
Embodiment 3
Raw material is weighed by the composition of parts by weight shown in table 3, each raw material is obtained into chamotte with blender after mixing evenly.
Table 3
Embodiment 4
Raw material is weighed by the composition of parts by weight shown in table 4, each raw material is obtained into chamotte with blender after mixing evenly.
Table 4
Raw material | Partial size | Parts by weight |
85 high grade bauxite particles | 1~0.088mm | 25 |
Corundum fine powder | 150 mesh~325 mesh | 25 |
Magnesia powder | 150 mesh~325 mesh | 35 |
Alumina powder | 5 | |
Furane resins | —— | 10 |
Embodiment 5
Raw material is weighed by the composition of parts by weight shown in table 5, each raw material is obtained into chamotte with blender after mixing evenly.
Table 5
Raw material | Partial size | Parts by weight |
85 high grade bauxite particles | 1~0.088mm | 30 |
Corundum fine powder | 150 mesh~325 mesh | 30 |
Magnesia powder | 150 mesh~325 mesh | 20 |
Alumina powder | 10 | |
Furane resins | —— | 10 |
Embodiment 6
Raw material is weighed by the composition of parts by weight shown in table 6, each raw material is obtained into chamotte with blender after mixing evenly.
Table 6
Raw material | Partial size | Parts by weight |
85 high grade bauxite particles | 1~0.088mm | 20 |
Corundum fine powder | 150 mesh~325 mesh | 30 |
Magnesia powder | 150 mesh~325 mesh | 30 |
Alumina powder | 5 | |
Furane resins | —— | 15 |
In Examples 1 to 6, the partial size of alumina powder is 2 μm.In Examples 1 to 3, the viscosity of furane resins is
3000mPas, solid content 55%, Residual carbon 30%;In embodiment 4~6, the viscosity of furane resins is 12000mPa
S, solid content 60%, Residual carbon 33%.
Performance characterization
Using the adhesion strength of national standard test chamotte, the results are shown in Table 7.
Table 7
As shown in table 7, there is good intensity containing carbon brick using chamotte provided by the invention bonding, especially in high temperature item
Under part.The tack time of the chamotte of Examples 1 to 6 is between 60~180s.
Claims (10)
1. a kind of chamotte for being bonded containing carbon brick, which is characterized in that the parts by weight of raw materials composition of the chamotte is as follows:
2. as described in claim 1 for being bonded the chamotte containing carbon brick, which is characterized in that the carbon containing resinoid bond is furan
Furane resins.
3. as claimed in claim 2 for being bonded the chamotte containing carbon brick, which is characterized in that the viscosity of the furane resins is
1000~15000mPas.
4. as claimed in claim 3 for being bonded the chamotte containing carbon brick, which is characterized in that the solid content of the furane resins is
55~60%, Residual carbon is 30~33%.
5. as described in claim 1 for being bonded the chamotte containing carbon brick, which is characterized in that the partial size of the vanadine particle is 1
~0.088mm.
6. as described in claim 1 for being bonded the chamotte containing carbon brick, which is characterized in that the partial size of the corundum fine powder is
150 mesh~325 mesh.
7. as described in claim 1 for being bonded the chamotte containing carbon brick, which is characterized in that the partial size of the magnesia powder is
150 mesh~325 mesh.
8. as described in claim 1 for being bonded the chamotte containing carbon brick, which is characterized in that the partial size of the alumina powder
For -320 mesh.
9. as described in any one of claims 1 to 8 for being bonded the chamotte containing carbon brick, which is characterized in that the original of the chamotte
Expect that parts by weight composition is as follows:
10. a kind of preparation method of chamotte as described in any one of claims 1 to 9, which is characterized in that by each raw material according to weight
Amount part proportion is uniformly mixed so as to obtain.
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CN201710377807.0A CN107117974B (en) | 2017-05-25 | 2017-05-25 | A kind of chamotte and preparation method thereof for being bonded containing carbon brick |
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CN201710377807.0A CN107117974B (en) | 2017-05-25 | 2017-05-25 | A kind of chamotte and preparation method thereof for being bonded containing carbon brick |
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CN107117974B true CN107117974B (en) | 2019-09-10 |
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CN108727002B (en) * | 2018-06-28 | 2021-06-08 | 中冶武汉冶金建筑研究院有限公司 | Plugging press-in material for air leakage of bottom foundation of hot blast stove |
CN110885233A (en) * | 2019-12-16 | 2020-03-17 | 钢城集团凉山瑞海实业有限公司 | Ladle brick aluminum-magnesium fire clay and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1058948A (en) * | 1991-07-29 | 1992-02-26 | 鞍山钢铁公司 | Magnesium daub |
CN1827556A (en) * | 2005-02-28 | 2006-09-06 | 宝山钢铁股份有限公司 | Fire clay for replacement of tuyere brick in converter |
CN102020477A (en) * | 2010-12-10 | 2011-04-20 | 河南瑞泰耐火材料科技有限公司 | Alkaline high-temperature refractory mortar |
CN102617168A (en) * | 2012-04-01 | 2012-08-01 | 濮阳濮耐高温材料(集团)股份有限公司 | Wet process refractory mortar |
CN105541356A (en) * | 2015-12-25 | 2016-05-04 | 山东鲁阳节能材料股份有限公司 | High-temperature-resistant cement and preparation method for same |
-
2017
- 2017-05-25 CN CN201710377807.0A patent/CN107117974B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1058948A (en) * | 1991-07-29 | 1992-02-26 | 鞍山钢铁公司 | Magnesium daub |
CN1827556A (en) * | 2005-02-28 | 2006-09-06 | 宝山钢铁股份有限公司 | Fire clay for replacement of tuyere brick in converter |
CN102020477A (en) * | 2010-12-10 | 2011-04-20 | 河南瑞泰耐火材料科技有限公司 | Alkaline high-temperature refractory mortar |
CN102617168A (en) * | 2012-04-01 | 2012-08-01 | 濮阳濮耐高温材料(集团)股份有限公司 | Wet process refractory mortar |
CN105541356A (en) * | 2015-12-25 | 2016-05-04 | 山东鲁阳节能材料股份有限公司 | High-temperature-resistant cement and preparation method for same |
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Address after: 312300 Zhejiang city of Shaoxing province Hangzhou Bay Juxian two East District of Shangyu economic and Technological Development Zone two Road No. 9 Patentee after: Zhejiang Zili High Temperature Technology Co., Ltd Address before: 312300 Zhejiang city of Shaoxing province Hangzhou Bay Juxian two East District of Shangyu economic and Technological Development Zone two Road No. 9 Patentee before: ZHEJIANG ZILI HIGH TEMPERATURE TECHNOLOGY CO., LTD. |
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