CN107031154A - A kind of composite membrane - Google Patents
A kind of composite membrane Download PDFInfo
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- CN107031154A CN107031154A CN201710287335.XA CN201710287335A CN107031154A CN 107031154 A CN107031154 A CN 107031154A CN 201710287335 A CN201710287335 A CN 201710287335A CN 107031154 A CN107031154 A CN 107031154A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/418—Refractive
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- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of composite membrane; include IM films and diaphragm; the IM films include refractive index matching layers; the first base material layer and the first hardened layer; the first hardening layer surface is bonded by adhesive layer and diaphragm; the problem of IM very property difference is solved by fitting diaphragm in one sides of the IM away from refractive index matching layers, substantially increases IM films surface by the solution of the problem and sputters silica or ITO flatness.
Description
Technical field：
The present invention relates to optical film field, and in particular to composite membrane.
Background technology：
Existing IM (Index Match) film mainly includes IM films (1+1 structures) and IM films (1+3 structures).Wherein, IM films (1
+ 1 structure) mist degree reach more than 1.2%, need to be in height folding HC faces sputter trilaminate material (low fold and ITO as the ito film used time
Layer).Traditional IM films can have the problem of IM property endured is not enough, cause sputtering surface out-of-flatness when sputtering silica or ITO,
It has impact on the outward appearance of ITO layer.
The present invention have devised composite membrane IM films and pass through diaphragm of fitting so that IM very property is improved, and is greatly improved
The flatness of IM films surfaces sputtering silica or ITO, and it is coated with hardening coat, the hardening in the side of the diaphragm
Coating can effectively prevent that low molecule and Solvent migration reduce Surface haze to the surface of diaphragm in base material.
The content of the invention：
The purpose of the present invention is on the one hand there is provided a kind of composite membrane, and the very property for solving IM is improved, and substantially increases IM films
Surface sputters silica or ITO flatness, on the other hand, sets a hardened layer effectively to prevent low molecule on the outside of diaphragm
Its Surface haze is reduced with the surface of Solvent migration to diaphragm, improves its outward appearance.
To achieve the above object, the technical scheme is that：
A kind of composite membrane, comprising IM films and diaphragm, the IM films include refractive index matching layers, the first base material layer and first
Hardened layer, the first hardening layer surface is fitted diaphragm by adhesive layer.
Further, the diaphragm includes adhesive layer, the second substrate layer and the second hardened layer, second hardened layer
It is arranged far from the optical surface of the second substrate layer one of IM films, the thickness of second hardened layer is 80-120nm.
Further, the gross thickness of the IM films and diaphragm is 150-200 μm.
Further, the substrate layer thickness is 50-125 μm, and the protection film thickness is 50-125 μm.
Further, the refractive index matching layers ranges of indices of refraction is 1.4-1.52.
Further, the refractive index matching layers ranges of indices of refraction is 1.4-1.75.
Further, the refractive index matching layers include low-index layer and high refractive index layer, the low-index layer
Ranges of indices of refraction is 1.4-1.49, and the ranges of indices of refraction of the high refractive index layer is 1.50-1.52.
Further, the refractive index matching layers include low-index layer and high refractive index layer, the low-index layer
Ranges of indices of refraction is 1.4-1.55, and the ranges of indices of refraction of the high refractive index layer is 1.60-1.75.
Further, the base material is selected from PET, COP and POP.
Further, the thickness of second substrate layer is 30-80 μm.
Further, the thickness range of the low-index layer is 25-35nm.
Further, the thickness range of the high refractive index layer is 1.0-1.5 μm.
Further, second hardened layer includes esters of acrylic acid prepolymer resin.
Further, the esters of acrylic acid prepolymer resin include be polymerized by a components, b components oligomer M,
Silicone compounds, curing agent, curing accelerator, surfactant；
The oligomer M, silicone compounds, curing agent, curing accelerator and surfactant weight percentage ranges
For (800~1250)：(160~250)：(0.8~1.2)：(0.8~1.2)：(0.8~1.2)；
The a components are selected from methy oxetane, GMA, methacrylic acid 6,7- epoxy radicals
Heptyl ester, to vinylbenzyl glycidyl base ether, 3- methyl -3- (methyl) acryloyloxymethyls oxetanes, 3- ethyls -
3- (methyl) acryloxy, allyl methacrylate；
The b components be selected from (methyl) hydroxyalkyl acrylates, methyl methacrylate, Tert-butyl Methacrylate,
Cyclohexyl acrylate, methacrylic acid bicyclopentyl ester, acrylic acid 2- methyl cyclohexyls, N-phenylmaleimide, N- hexamethylenes
Base maleimide, styrene, to methoxy styrene, 1,3-butadiene.
Further, the silicone compounds are selected from 3- glycidoxypropyltrime,hoxysilanes, the oxygen of 3- epoxies third
Base propyl-triethoxysilicane, 3- glycidoxypropyls dimethoxysilane, 3- glycidoxypropyl diethyls
TMOS, (3- Ethyloxetane -3- bases) propyl trimethoxy silicane, (3- Ethyloxetane -3- bases) propyl group
Triethoxysilane, tetramethoxy-silicane, tetraethoxysilane, MTMS, MTES, phenyl
Trimethoxy silane, phenyl triethoxysilane, dimethyldimethoxysil,ne, dimethyldiethoxysilane, diphenyl two
Methoxy silane, diphenyl diethoxy silane, 3- (methyl) acryloyloxymethyls trimethoxy silane, 3- (methyl) propylene
Pivaloyloxymethyl triethoxysilane, the positive propoxy silane of 3- (methyl) acryloyloxymethyl three.
Further, the curing agent is selected from hexahydrophthalic anhydride, dicarboxylic anhydride, the trimellitic anhydride of glycerine three, first
Base tetrabydrophthalic anhydride, pentamethylene tetracarboxylic dianhydride, 1,2,3,4- butane tetracarboxylic acid dianhydrides, the double trimellitic acids of ethylene glycol
Acid anhydride.
Further, the surfactant is selected from polyoxyethylene alkyl ether, polyoxyethylene aryl ether, polyoxyethylene dioxane
Base, polyoxyethylene lauryl ether, polyoxyethylene stearyl base ether, polyoxyethylene oleyl ether, polyoxyethylene aryl ether polyoxyethylene is pungent
Base phenyl ether, ethylene nonyl phenyl ether.Polyoxyethylene dialkyl ester, polyoxyethylene dilaurate, polyoxyethylene two are hard
Resin acid ester.
Beneficial effect：
A kind of composite membrane, IM very property difference is solved by fitting diaphragm in one sides of the IM away from refractive index matching layers
Problem, substantially increases IM films surface by the solution of the problem and sputters silica or ITO flatness, and in diaphragm
Outside sets a hardened layer its specific component, silicone compounds, curing agent, curing accelerator, surfactant effectively to prevent
Having stopped the surface of low molecule and Solvent migration to diaphragm in substrate layer reduces its Surface haze, improves its outward appearance.
Brief description of the drawings：
Fig. 1 shows a kind of typical composite membrane of the present invention, and Fig. 1 provides embodiment 1, embodiment 2, embodiment 3 and embodiment 4
The structural representation of composite membrane.
In figure, IM films 21, diaphragm 22, refractive index matching layers 211, the first base material layer 213, the first hardened layer 214, high index of refraction
Layer 2112, adhesive layer 225, the second substrate layer 226, the second hardened layer 227, low-index layer 2111.
Embodiment：
Embodiment 1
A kind of composite membrane, comprising IM films 21 and diaphragm 22, the base material of the IM films 21 is 50 μm of bases of COP first of thickness
Material layer 213, the first base material layer 213 includes the first optical surface and the second optical surface, is coated with and reflects in first optical surface
Rate is 1.50 hardened glue, and it is 1.5 μm of first hardened layer 214 that thickness is formed after solidification, is coated with and rolls in second optical surface
The rate of penetrating is that the high refractive index layer 2112 that thickness is 1.2 μm is formed after 1.52 high index of refraction glue curings；The diaphragm 22 is included
Adhesive layer 225, the second substrate layer 226 and the second hardened layer 227 described in the second hardened layer 227 are arranged far from the of IM films 21
On the optical surface of two substrate layer 226 1, second substrate layer 226 is the PET of 125 μm of thickness, and second hardened layer 227 is
Thickness is 100nm, and refractive index is the hardened layer of 1.50 esters of acrylic acid prepolymer cures formation.The IM films 21 are passed through into protection
The adhesive layer 225 of film 22 is bonded together with diaphragm 22, finally by sputtering technology on the surface of high refractive index layer 2112 once
It is 1.42 to sputter refractive index, and thickness is 25nm low-index layer 2111.The preparation of the esters of acrylic acid prepolymer：Anti-
Answer the initiator 2 that 10 parts by weight are added in kettle, 2 '-azo two (2- methyl propionitrile), the parts by weight of propylene glycol methyl ether third of solvent 400
Acid esters, 140 weight parts of methacrylic acid ethylene oxidic esters, the styrene of 60 parts by weight, is heated to 90 DEG C under nitrogen protection
7h is stirred, oligomer M is obtained, then by the oligomer M of 100 parts by weight and the 3- glycidoxypropyls of 25 parts by weight
Diethoxy silane, the curing agent hexahydrophthalic anhydride of 50 parts by weight, the curing accelerator 2- phenyl miaows of 0.1 parts by weight
Azoles and 0.1 parts surfactant, solid content is obtained after a certain amount of diluent methyl proxitol propionic ester stirring mixing
For 30% (weight) esters of acrylic acid prepolymer.
Embodiment 2
A kind of composite membrane, comprising IM films 21 and diaphragm 22, the base material of the IM films 21 is 50 μm of bases of PET first of thickness
Material layer 213, the first base material layer 213 includes the first optical surface and the second optical surface, is coated with and reflects in first optical surface
Rate is 1.65 hardened glue, and it is 1.5 μm of first hardened layer that thickness is formed after solidification, and refractive index is coated with second optical surface
To form the high refractive index layer 2112 that thickness is 1.2 μm after 1.70 high index of refraction glue curings；The diaphragm 22 includes bonding
The 225, second substrate layer 226 of layer and the second hardened layer 227, second hardened layer 227 are arranged far from the second of IM films 21
On the optical surface of substrate layer 226 1, second substrate layer 226 is the PET of 125 μm of thickness, and second hardened layer 227 is
Thickness is 100nm, and refractive index is the hardened layer of 1.65 esters of acrylic acid prepolymer cures formation.The IM films 21 are passed through into protection
The adhesive layer 225 of film 22 is bonded together with diaphragm 22, finally by sputtering technology on the surface of high refractive index layer 2112 once
It is 1.52 to sputter refractive index, and thickness is 25nm low-index layer 2111.The preparation of the esters of acrylic acid prepolymer：In reaction
The initiator 2 of 10 parts by weight, 2 '-azo two (2- methyl propionitrile), the parts by weight of propylene glycol methyl ether propionic acid of solvent 400 are added in kettle
Ester, 160 parts by weight methyl 3- ethyls -3- (methyl) acryloxies, 40 parts of styrene, is heated to 90 under nitrogen protection
DEG C stirring 7h, oligomer M is obtained, then by the oligomer M of 100 parts by weight and the 3- glycidoxypropyl group first of 25 parts by weight
Base diethoxy silane, the curing agent hexahydrophthalic anhydride of 50 parts by weight, the curing accelerator 2- phenyl of 0.1 parts by weight
Imidazoles and 0.1 parts surfactant, are contained admittedly after a certain amount of diluent methyl proxitol propionic ester stirring mixing
Measure as 30% (weight) esters of acrylic acid prepolymer.
Embodiment 3
A kind of composite membrane, comprising IM films 21 and diaphragm 22, the base material of the IM films 21 is 125 μm of bases of PET first of thickness
Material layer 213, the first base material layer 213 includes the first optical surface and the second optical surface, is coated with and reflects in first optical surface
Rate is 1.65 hardened glue, and it is 1.5 μm of first hardened layer 214 that thickness is formed after solidification, is coated with and rolls in second optical surface
The rate of penetrating is that the high refractive index layer 2112 that thickness is 1.2 μm is formed after 1.70 high index of refraction glue curings；The diaphragm 22 is included
Adhesive layer 225, the second substrate layer 226 and the second hardened layer 227 described in the second hardened layer 227 are arranged far from the of IM films 21
On the optical surface of two substrate layer 226 1, second substrate layer 226 is the PET of 50 μm of thickness, and second hardened layer 227 is
Thickness is 100nm, and refractive index is the hardened layer of 1.65 esters of acrylic acid prepolymer cures formation.The IM films 21 are passed through into protection
The adhesive layer 225 of film 22 is bonded together with diaphragm 22, finally by sputtering technology on the surface of high refractive index layer 2112 once
It is 1.52 to sputter refractive index, and thickness is 25nm low-index layer 2111.The preparation of the esters of acrylic acid prepolymer：Anti-
Answer the initiator 2 that 10 parts by weight are added in kettle, 2 '-azo two (2- methyl propionitrile), the parts by weight of propylene glycol methyl ether third of solvent 400
Acid esters, 160 parts by weight are heated to 90 under nitrogen protection to vinylbenzyl glycidyl base ether, the styrene of 40 parts by weight
DEG C stirring 7h, oligomer M is obtained, then by the oligomer M of 100 parts by weight and the 3- glycidoxypropyls of 25 parts by weight
Diethoxy silane, the curing agent hexahydrophthalic anhydride of 50 parts by weight, the curing accelerator 2- phenyl miaows of 0.1 parts by weight
Azoles and 0.1 parts surfactant, solid content is obtained after a certain amount of diluent methyl proxitol propionic ester stirring mixing
For 30% (weight) esters of acrylic acid prepolymer.
Embodiment 4
A kind of composite membrane, comprising IM films 21 and diaphragm 22, the base material of the IM films 21 is 125 μm of bases of COP first of thickness
Material layer 213, the first base material layer 213 includes the first optical surface and the second optical surface, is coated with and reflects in first optical surface
Rate is 1.50 hardened glue, and it is 1.5 μm of first hardened layer 214 that thickness is formed after solidification, is coated with and rolls in second optical surface
The rate of penetrating is that the high refractive index layer that thickness is 1.2 μm is formed after 1.52 high index of refraction glue curings；The diaphragm 22 includes bonding
Second hardened layer 227 described in the 225, second substrate layer 226 of layer and the second hardened layer 227 is arranged far from the second of IM films 21
On the optical surface of substrate layer 226 1, second substrate layer 226 is the PET of 50 μm of thickness, and second hardened layer 227 is
Thickness is 100nm, and refractive index is the hardened layer of 1.50 esters of acrylic acid prepolymer cures formation.The IM films 21 are passed through into protection
The adhesive layer 225 of film 22 is bonded together with diaphragm 22, finally by sputtering technology on the surface of high refractive index layer 2112 once
It is 1.42 to sputter refractive index, and thickness is 25nm low-index layer 2111.The preparation of the esters of acrylic acid prepolymer：In reaction
The initiator 2 of 10 parts by weight, 2 '-azo two (2- methyl propionitrile), the parts by weight of propylene glycol methyl ether third of solvent 400 are added in kettle
Acid esters, 160 parts by weight methyl 3- ethyls -3- (methyl) acryloxies, the styrene of 20 parts by weight, N- cyclohexyl maleimides
Amine, is heated to 90 DEG C of stirring 7h, oligomer M is obtained, then by the oligomer M and 25 weight of 100 parts by weight under nitrogen protection
The 3- glycidoxypropyl diethoxy silanes of part, 50 parts by weight curing agent hexahydrophthalic anhydrides, 0.1 parts by weight
Curing accelerator 2- phenylimidazoles and 0.1 parts surfactant, a certain amount of diluent methyl proxitol propionic ester
Solid content is obtained after stirring mixing for 30% (weight) esters of acrylic acid prepolymer.
Transmissivities of the embodiment 1-4 under spectrophotometric determination 400-800nm：
Toasted 1 hour at 200 DEG C in baking oven, determine diaphragm heat resistance.In an oven, entered with the condition of 1 hour at 250 DEG C
Row heating, determines the thickness before and after heating, and the resistance to thermal dimensional stability calculated by following formula is as shown in table 1.The value be 95% with
When upper, it may be said that resistance to thermal dimensional stability is good.
Resistance to thermal dimensional stability=(thickness after heating)/(thickness after heating) * 100%
Mist degree instrument determines the haze value of diaphragm.
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Very property | It is excellent | It is excellent | It is excellent | It is excellent |
| Transmissivity % | 94 | 92 | 92 | 94 |
| Mist degree | 1 | 2 | 2 | 1 |
| Heat resistance % | 98 | 97 | 99 | 98 |
From the foregoing, the application provides a kind of composite membrane, protected by being fitted in one sides of the IM away from refractive index matching layers
Cuticula come solve IM very property difference the problem of, by the solution of the problem substantially increase IM films surface sputter silica or
ITO flatness, and a hardened layer its specific component, silicone compounds, curing agent, solidification are set on the outside of diaphragm
The surface that accelerator, surfactant effectively prevent low molecule and Solvent migration to diaphragm in the second substrate layer reduces its table
Face mist degree, improves its outward appearance.
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
The foregoing is only the preferred embodiment of invention, be not intended to limit the present invention, it is all the spirit and principles in the present invention it
Interior made modifications, equivalent substitutions and improvements etc., should be included in the scope of the protection.Attempt according to this to the present invention
Make any formal limitation, therefore it is all have made under identical spirit
Any modification or change of the relevant present invention, should all be included in that the invention is intended to the category protected.
Claims (14)
1. a kind of composite membrane (100), comprising IM films (21) and diaphragm (22), the IM films (21) include refractive index matching layers
(211), the first base material layer (213) and the first hardened layer (214), it is characterised in that the first hardened layer (214) surface passes through
Adhesive layer (225) is bonded with diaphragm (22).
2. composite membrane (100) according to claim 1, it is characterised in that the diaphragm (22) includes adhesive layer
(225), the second substrate layer (226) and the second hardened layer (227), second hardened layer (227) are arranged far from IM films
(21) on the optical surface of the second substrate layer (226) one, the thickness of second hardened layer (227) is 80-120nm.
3. composite membrane (100) according to claim 1, it is characterised in that the IM films (21) and diaphragm (22) it is total
Thickness is 150-200 μm.
4. composite membrane (100) according to claim 1, it is characterised in that the thickness of the IM films (21) is 50-125 μm,
Diaphragm (22) thickness is 50-125 μm.
5. composite membrane (100) according to claim 1, it is characterised in that refractive index matching layers (211) the refractive index model
Enclose for 1.4-1.52.
6. composite membrane (100) according to claim 1, it is characterised in that refractive index matching layers (211) the refractive index model
Enclose for 1.4-1.75.
7. composite membrane (100) according to claim 1, it is characterised in that the refractive index matching layers (211) include low folding
Rate layer (2111) and high refractive index layer (2112) are penetrated, the ranges of indices of refraction of the low-index layer (2111) is 1.4-1.49, institute
The ranges of indices of refraction for stating high refractive index layer (2112) is 1.50-1.52.
8. composite membrane (100) according to claim 1, it is characterised in that the refractive index matching layers (211) include low folding
Rate layer (2111) and high refractive index layer (2112) are penetrated, the ranges of indices of refraction of the low-index layer (2111) is 1.4-1.55, institute
The ranges of indices of refraction for stating high refractive index layer (2112) is 1.60-1.75.
9. composite membrane (100) according to claim 1, it is characterised in that the first base material layer (213) be selected from PET,
COP and POP.
10. composite membrane (100) according to claim 2, it is characterised in that second hardened layer (226) includes propylene
Esters of gallic acid prepolymer resin.
11. composite membrane (100) according to claim 10, it is characterised in that the esters of acrylic acid prepolymer resin bag
Containing oligomer M, silicone compounds, curing agent, curing accelerator, the surfactant being polymerized by a components, b components；
The oligomer M, silicone compounds, curing agent, curing accelerator and surfactant weight percentage ranges are
(800~1250)：(160~250)：(0.8~1.2)：(0.8~1.2)：(0.8~1.2)；
The a components are selected from methy oxetane, GMA, methacrylic acid 6,7- epoxy radicals heptan
Ester, to vinylbenzyl glycidyl base ether, 3- methyl -3- (methyl) acryloyloxymethyls oxetanes, 3- ethyls -3-
(methyl) acryloxy, allyl methacrylate；
The b components are selected from (methyl) hydroxyalkyl acrylates, methyl methacrylate, Tert-butyl Methacrylate, propylene
Sour cyclohexyl, methacrylic acid bicyclopentyl ester, propylene 2- methyl cyclohexyls, N-phenylmaleimide, N- cyclohexyl Malaysia
Acid imide, styrene, to methoxy styrene, 1,3-butadiene.
12. composite membrane (100) according to claim 11, it is characterised in that the silicone compounds are selected from 3- epoxies
Propoxypropyl trimethoxy silane, 3- glycidoxypropyl groups triethoxysilane, 3- glycidoxypropyl diformazans
TMOS, 3- glycidoxypropyls diethoxy silane, (3- Ethyloxetane -3- bases) propyl trimethoxy
Silane, (3- Ethyloxetane -3- bases) propyl-triethoxysilicane, tetramethoxy-silicane, tetraethoxysilane, methyl three
Methoxy silane, MTES, phenyltrimethoxysila,e, phenyl triethoxysilane, dimethylformamide dimethyl epoxide
Silane, dimethyldiethoxysilane, dimethoxydiphenylsilane, diphenyl diethoxy silane, 3- (methyl) acryloyl
Epoxide MTMS, 3- (methyl) acryloyloxymethyls triethoxysilane, 3- (methyl) acryloxy first
The positive propoxy silane of base three.
13. composite membrane (100) according to claim 11, it is characterised in that the curing agent is selected from hexahydro O-phthalic
Acid anhydrides, dicarboxylic anhydride, the trimellitic anhydride of glycerine three, methyl tetrahydrophthalic anhydride, pentamethylene tetracarboxylic dianhydride, 1,2,3,4-
The double trimellitic anhydrides of butane tetracarboxylic acid dianhydride, ethylene glycol.
14. composite membrane according to claim 11, it is characterised in that the surfactant is selected from polyxyethylated
Ether, polyoxyethylene aryl ether, polyoxyethylene dialkyl group, polyoxyethylene lauryl ether, polyoxyethylene stearyl base ether, polyoxyethylene oil
Base ether, polyoxyethylene aryl ether NONIN HS 240, ethylene nonyl phenyl ether.It is polyoxyethylene dialkyl ester, poly-
Oxygen ethene dilaurate, polyoxyethylene distearate.
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| CN201710287335.XA CN107031154A (en) | 2017-04-27 | 2017-04-27 | A kind of composite membrane |
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| CN201710287335.XA CN107031154A (en) | 2017-04-27 | 2017-04-27 | A kind of composite membrane |
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| CN1546755A (en) * | 2003-12-01 | 2004-11-17 | 中国人民解放军总后勤部军需装备研究 | Processing method for durable antibiotic deodorant fibre fabric |
| CN103203932A (en) * | 2012-01-16 | 2013-07-17 | 上海石路信息科技有限公司 | Novel dust-free, anti-static and chrome-plated protective film |
| CN203805433U (en) * | 2014-03-05 | 2014-09-03 | 佛山佛塑科技集团股份有限公司 | Highly-transparent hardened film for displaying touch panel |
| CN106459239A (en) * | 2014-05-30 | 2017-02-22 | 理研科技株式会社 | Actinic-ray-curable resin composition, layered film including hardcoat formed therefrom, and layered transparent resin product |
| CN204667902U (en) * | 2015-06-08 | 2015-09-23 | 汕头万顺包装材料股份有限公司 | Nesa coating and there is the coiled strip of this nesa coating |
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Application publication date: 20170811 |