CN107010874A - A kind of white glass artificial quartz stone plate of colorful and its production technology - Google Patents

A kind of white glass artificial quartz stone plate of colorful and its production technology Download PDF

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Publication number
CN107010874A
CN107010874A CN201710358667.2A CN201710358667A CN107010874A CN 107010874 A CN107010874 A CN 107010874A CN 201710358667 A CN201710358667 A CN 201710358667A CN 107010874 A CN107010874 A CN 107010874A
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China
Prior art keywords
mesh
parts
white glass
colorful
stone plate
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Pending
Application number
CN201710358667.2A
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Chinese (zh)
Inventor
周军
胡国强
张韡
冯伟坚
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GUANGDONG BANNER NEW MATERIAL TECHNOLOGY Co Ltd
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GUANGDONG BANNER NEW MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201710358667.2A priority Critical patent/CN107010874A/en
Publication of CN107010874A publication Critical patent/CN107010874A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/06Acrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12Condensation polymers of aldehydes or ketones
    • C04B26/122Phenol-formaldehyde condensation polymers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/16Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/18Polyesters; Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • C04B2111/82Coloured materials

Abstract

The white glass artificial quartz stone plate of a kind of colorful of the present invention, including following raw material:White glass:68 mesh, 8 16 mesh, 16 30 mesh, 30 50 mesh, 50 80 mesh;Quartz sand:46 mesh, 68 mesh, 16 26 mesh, 20 mesh;325 mesh silica flours, silane coupler, curing agent, adhesive and colored pigment, the made artificial quartz in lump out of the present invention is handsome in appearance, and pattern is distinct, color is unique, and production efficiency is high, while effectively reducing the fraction defective of product, color is separated from each other, can mass production.

Description

A kind of white glass artificial quartz stone plate of colorful and its production technology
Technical field
The invention belongs to artificial quartz in lump preparing technical field, specifically, it is related to a kind of white glass artificial quartz in lump of colorful Sheet material and its production technology.
Background technology
Artificial quartz in lump be by quartz sand powder be main stuffing, using unsaturated polyester resin as adhesive, in vacuum shape The Novel stone that high pressure is compressing under condition, shape under the condition of high temperature, it is a kind of "dead" pollution, the repeatable ring utilized Guarantor, green building material and ornament materials.It is in the majority with the artificial quartz in lump product of monochrome type in the market, as people examine Lifting attractive in appearance, increasing cabinet business and table top processing business are more willing to the quartz product from polychrome type as first choice Ornament materials.
Conventional quartz stone product is initially based on monochrome, and with the development in market, plain quarz stone can not meet market Continuous renewal esthetic requirement, the secondary color plate and diamond plate of nearly 2 years existing imitated natural granites, but color is relatively stiff, line Reason is unnatural.Meanwhile, secondary color and pattern type quartzite slate are because complex process, low production efficiency, and sheet material are in compacting During color easily interpenetrate, fraction defective is high, so as to cause the supply of material few, price is high.
It is therefore desirable to carry out upgrading or technological transformation to existing production technology.
The content of the invention
Instant invention overcomes shortcoming of the prior art, there is provided a kind of white glass artificial quartz stone plate of colorful and its production Technique, good product performance, production efficiency is high, and qualification rate is high.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of white glass artificial quartz stone plate of colorful, it is characterised in that including following raw material:White glass particle:6-8 mesh, 8- 16 mesh, 16-30 mesh, 30-50 mesh, 50-80 mesh;Quartz sand particle:4-6 mesh, 6-8 mesh, 16-26 mesh, 20 mesh;325 mesh silica flours, Silane coupler, curing agent, adhesive and colored pigment.
Further, it is described including white glass particle according to parts by weight:5-15 parts of 6-8 mesh, 5-15 parts of 8-16 mesh, 16-30 mesh 5- 10 parts, 5-10 parts of 30-50 mesh, 5-10 parts of 50-80 mesh;Quartz sand particle:1-5 parts of 4-6 mesh, 3-8 parts of 6-8 mesh, 16-26 mesh 3-8 Part, 3-8 parts of 20 mesh;325 20-30 parts of mesh silica flours, 0.05-0.15 parts of silane coupler, 0.05-0.15 parts of curing agent, bonding 0.3-1 parts of 8-10 parts of agent and colored pigment.
Further, the colored pigment is the one or more of inorganic pigment or organic pigment or mill base.
Further, the inorganic pigment is titanium white, medium chrome yellow, iron oxide yellow, iron oxide red, barba hispanica, cadmium red, cadmium yellow, carbon black, iron oxide black etc. Inorganic pigment;Organic pigment is pigment scarlet powder, azophosphine, dark green or phthalocyanine blue.
Further, described adhesive is that unsaturated polyester resin can also be epoxy resin, phenolic resin, acrylic resin With the one or more in polyurethane resin.
Further, the curing agent is peroxidating (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, perbenzoic acid One or more in the tert-butyl ester, dibenzoyl peroxide and fat polyamine;
Further, the silane coupler is γ-methacryloxypropyl trimethoxy silane, γ-(2,3- epoxies Third oxygen) propyl trimethoxy silicane, N- β (aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, N- (β-aminoethyl)-γ- Aminopropyl triethoxysilane, N- β (aminoethyl)-γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, γ- Aminopropyl triethoxysilane, VTES, vinyltrimethoxy silane and γ-chloropropyl triethoxy silicon One or more in alkane;
A kind of production technology of the white glass artificial quartz stone plate of colorful, comprises the following steps:
(1) each component is weighed according to formula;
(2) stir:The white glass particle weighed, quartz sand particle, silane coupler are premixed in double planetary agitator Close;The curing agent mixed, decoration colored pigment and unsaturated polyester resin are poured into and mixed in double planetary agitator Close, then add silica flour and mixed, 15~55Hz of stirring frequency, 180~600s of mixing time;
(3) material mixed feeding beater is further broken up, after breaing up, enters cloth in material distributing machine through electronic measurement Material, is then sent through in making sheet mould, and making sheet mould is sent into moulding press is molded under vacuum, vibration, pressurization;
(4) by the sheet material feeding solidification case solidification of forming, solidification passes through fixed thick, polishing deep processing processing after terminating.
Compared with prior art, the beneficial effects of the invention are as follows:
White glass artificial quartz stone plate of a kind of colorful of the present invention and preparation method thereof, made synthetic quartz out Stone is handsome in appearance, and pattern is distinct, and color is unique, and production efficiency is high, while effectively reducing the fraction defective of product, color is mutually divided From can mass production.
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used In the description and interpretation present invention, it is not intended to limit the present invention.
The white glass artificial quartz stone plate of a kind of colorful of the present invention, including following raw material:According to parts by weight, it is described including White glass particle:10 parts of 6-8 mesh, 10 parts of 8-16 mesh, 8 parts of 16-30 mesh, 7 parts of 30-50 mesh, 7 parts of 50-80 mesh;Quartz sand particle:4-6 4 parts of mesh, 6 parts of 6-8 mesh, 6 parts of 16-26 mesh, 6 parts of 20 mesh;325 27 parts of mesh silica flours, 0.1 part of silane coupler, curing agent 0.1 0.6 part of part, 8.3 parts of adhesive and colored pigment;
A kind of production technology of the white glass artificial quartz stone plate of colorful, comprises the following steps:
(1) each component is weighed according to formula;
(2) stir:The white glass particle weighed, quartz sand particle, silane coupler are premixed in double planetary agitator Close;The curing agent mixed, decoration colored pigment and unsaturated polyester resin are poured into and mixed in double planetary agitator Close, then add silica flour and mixed, 15~55Hz of stirring frequency, 180~600s of mixing time;
(3) material mixed feeding beater is further broken up, after breaing up, enters cloth in material distributing machine through electronic measurement Material, is then sent through in making sheet mould, and making sheet mould is sent into moulding press is molded under vacuum, vibration, pressurization;
(4) by the sheet material feeding solidification case solidification of forming, solidification passes through fixed thick, polishing deep processing processing after terminating.
Finally it should be noted that:The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although The present invention is described in detail with reference to embodiment, for those skilled in the art, it still can be to foregoing Technical scheme described in each embodiment is modified, or to which part technical characteristic carry out equivalent substitution, but it is all Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc. should be included in the protection of the present invention Within the scope of.

Claims (8)

1. a kind of white glass artificial quartz stone plate of colorful, it is characterised in that including following raw material:White glass particle:6-8 mesh, 8-16 Mesh, 16-30 mesh, 30-50 mesh, 50-80 mesh;Quartz sand particle:4-6 mesh, 6-8 mesh, 16-26 mesh, 20 mesh;325 mesh silica flours, silicon Alkane coupling agent, curing agent, adhesive and colored pigment.
2. the white glass artificial quartz stone plate of a kind of colorful according to claim 1, it is characterised in that according to parts by weight, including White glass particle:5-15 parts of 6-8 mesh, 5-15 parts of 8-16 mesh, 5-10 parts of 16-30 mesh, 5-10 parts of 30-50 mesh, 5-10 parts of 50-80 mesh; Quartz sand particle:1-5 parts of 4-6 mesh, 3-8 parts of 6-8 mesh, 3-8 parts of 16-26 mesh, 3-8 parts of 20 mesh;325 20-30 parts of mesh silica flours, silicon 0.3-1 parts of 0.05-0.15 parts of alkane coupling agent, 0.05-0.15 parts of curing agent, 8-10 parts of adhesive and colored pigment.
3. the white glass artificial quartz stone plate of a kind of colorful according to claim 1, it is characterised in that:The colored pigment is nothing The one or more of machine pigment or organic pigment or mill base.
4. the white glass artificial quartz stone plate of a kind of colorful according to claim 3, it is characterised in that:The inorganic pigment is titanium In vain, the inorganic pigment such as medium chrome yellow, iron oxide yellow, iron oxide red, barba hispanica, cadmium red, cadmium yellow, carbon black, iron oxide black;Organic pigment is pigment scarlet powder, azo Yellow, dark green or phthalocyanine blue.
5. the white glass artificial quartz stone plate of a kind of colorful according to claim 1, it is characterised in that:The curing agent is peroxide Change (2 ethyl hexanoic acid) tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate, dibenzoyl peroxide and aliphatic polyol One or more in amine.
6. the white glass artificial quartz stone plate of a kind of colorful according to claim 1, it is characterised in that:The silane coupler is γ-methacryloxypropyl trimethoxy silane, γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane, N- β (ammonia second Base)-γ-aminopropyltriethoxy dimethoxysilane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, N- β (aminoethyl)- γ-aminopropyltrimethoxysilane, anilinomethyl triethoxysilane, gamma-aminopropyl-triethoxy-silane, the ethoxy of vinyl three One or more in base silane, vinyltrimethoxy silane and γ-chloropropyl triethoxysilane.
7. the white glass artificial quartz stone plate of a kind of colorful according to claim 1, it is characterised in that:Described adhesive is insatiable hunger Can also be the one or more in epoxy resin, phenolic resin, acrylic resin and polyurethane resin with polyester resin.
8. a kind of production technology of the white glass artificial quartz stone plate of colorful, it is characterised in that comprise the following steps:
(1) each component is weighed according to formula;
(2) stir:The white glass particle weighed, quartz sand particle, silane coupler are pre-mixed in double planetary agitator;Will Curing agent, decoration colored pigment and the unsaturated polyester resin mixed is poured into and mixed in double planetary agitator, so Add silica flour afterwards to be mixed, 15~55Hz of stirring frequency, 180~600s of mixing time;
(3) material mixed feeding beater is further broken up, after breaing up, enters cloth in material distributing machine through electronic measurement, It is then sent through in making sheet mould, making sheet mould is sent into moulding press is molded under vacuum, vibration, pressurization;
(4) by the sheet material feeding solidification case solidification of forming, solidification passes through fixed thick, polishing deep processing processing after terminating.
CN201710358667.2A 2017-05-19 2017-05-19 A kind of white glass artificial quartz stone plate of colorful and its production technology Pending CN107010874A (en)

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CN201710358667.2A CN107010874A (en) 2017-05-19 2017-05-19 A kind of white glass artificial quartz stone plate of colorful and its production technology

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107805006A (en) * 2017-11-17 2018-03-16 枣庄市博源人造石有限公司 A kind of white glass artificial quartz stone plate of colorful and preparation method thereof
CN109467336A (en) * 2018-12-24 2019-03-15 珠海色萨利健康石材有限公司 A kind of decoration artificial quartz stone and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105884259A (en) * 2016-03-14 2016-08-24 广东中旗新材料科技有限公司 Anti-bacterial artificial quartzite board and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105884259A (en) * 2016-03-14 2016-08-24 广东中旗新材料科技有限公司 Anti-bacterial artificial quartzite board and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107805006A (en) * 2017-11-17 2018-03-16 枣庄市博源人造石有限公司 A kind of white glass artificial quartz stone plate of colorful and preparation method thereof
CN109467336A (en) * 2018-12-24 2019-03-15 珠海色萨利健康石材有限公司 A kind of decoration artificial quartz stone and preparation method thereof

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Address after: 528518 No. 112 Mingcheng Second Road, Gaoming District, Foshan City, Guangdong Province

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