CN106957543B - Paint capable of forming natural patterns on ceramic surface and spraying process thereof - Google Patents
Paint capable of forming natural patterns on ceramic surface and spraying process thereof Download PDFInfo
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- CN106957543B CN106957543B CN201710248279.9A CN201710248279A CN106957543B CN 106957543 B CN106957543 B CN 106957543B CN 201710248279 A CN201710248279 A CN 201710248279A CN 106957543 B CN106957543 B CN 106957543B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
Abstract
The invention discloses a coating capable of forming natural patterns on the surface of ceramic, which is prepared from the following raw materials in parts by weight: 1-3 parts of boron, 1-3 parts of phosphorus, 0.1-0.3 part of cadmium, 0.1-0.5 part of silver, 0.5-1.5 parts of silicon, 0.2-0.6 part of lead, 3-7 parts of lime powder, 3-7 parts of gelatin, 10-30 parts of water, 35-65 parts of kaolin and 8-22 parts of quartz. The patterns formed on the outer surface of the ceramic are natural and rich in three-dimensional sense and aesthetic feeling, the ornamental value of the ceramic is greatly enhanced, the defects of long manufacturing period of the traditional ceramic surface art and long cultivation and learning time and complicated manufacturing procedures of technicians are overcome, and the process flow is simple and the cost is low by combining the modern technology.
Description
Technical Field
The invention relates to the field of ceramic product preparation, in particular to a coating capable of forming natural patterns on the surface of ceramic and a spraying process thereof.
Background
The history of producing ceramics in China is long, and the history of producing ceramics in China is long and has brilliant cultural connotation, which is extremely rich and can be said to be great and exquisite. The first meaning of "CHINA" in english is that CHINA is sold worldwide for thousands of years since ancient CHINA ceramics, and since this word "CHINA" evolved to the meaning of "CHINA" in terms of reputation of abroad in sound broadcasting. Since ancient china ceramic has unique artistic charm , it has been popular to collect ancient china ceramic in the past because of its enormous influence on the world. People can pursue the long history of China and the brilliant cultural and cultural restorative ceramic temperament of the nation in the process of appreciating and researching ancient ceramic collections, enrich the spirit life of the people, form various rational feelings and improve the quality of the people.
China is also the biggest ceramic producing country in the world, ceramic products are one of the main products which are exported and created for foreign exchange in China, texture and color are added to ceramics mainly through glazing, the method is generally divided into overglaze decoration and underglaze decoration, the overglaze decoration is formed by colored drawing on a fired plain device and then firing at low temperature, the color is attached to a glaze surface, the underglaze decoration is formed by glazing and firing at high temperature after colored drawing on a green body, and the colored patterns are under the glaze.
Disclosure of Invention
The invention aims to provide a coating capable of forming natural patterns on the surface of ceramic and a spraying process thereof, which solve the problems in the existing production process, enhance the stereoscopic impression of the ceramic, increase the aesthetic feeling of the ceramic, shorten the process flow period and improve the production efficiency.
The purpose of the invention is realized by the following technical scheme
The coating capable of forming natural patterns on the surface of ceramic comprises the following raw materials in parts by weight: 1-3 parts of boron, 1-3 parts of phosphorus, 0.1-0.3 part of cadmium, 0.1-0.5 part of silver, 0.5-1.5 parts of silicon, 0.2-0.6 part of lead, 3-7 parts of lime powder, 3-7 parts of gelatin, 10-30 parts of water, 35-65 parts of kaolin and 8-22 parts of quartz.
The raw materials in the coating are preferably prepared from the following components in parts by weight: 1-1.8 parts of boron, 1.1-2.1 parts of phosphorus, 0.15-0.25 part of cadmium, 0.2-0.4 part of silver, 1.0-1.2 parts of silicon, 0.3-0.5 part of lead, 4-6 parts of lime powder, 4-6 parts of gelatin, 15-25 parts of water, 40-60 parts of kaolin and 10-20 parts of quartz.
The optimal preparation of the raw materials in the coating comprises the following components in parts by weight: 1.4 parts of boron, 1.6 parts of phosphorus, 0.2 part of cadmium, 0.3 part of silver, 1.1 part of silicon, 0.4 part of lead, 5 parts of lime powder, 5 parts of gelatin, 20 parts of water, 50 parts of kaolin and 15 parts of quartz.
The preparation and spraying process comprises the following specific steps:
step one, preparing the coating
A. Formulated paint
a. Putting raw materials of boron, phosphorus, cadmium, silver, silicon and lead powder in a container according to parts by weight, and mixing and stirring the raw materials to fully mix and stir the raw materials uniformly to prepare a mixture A;
b. putting the lime powder, the gelatin and the water in a container according to the parts by weight, and performing a mixing and stirring process to fully stir and stir the raw materials uniformly to prepare a mixture B;
c. taking the raw material mixture A and the raw material mixture B according to the parts by weight, putting the raw material mixture A and the raw material mixture B into a ceramic preparation mechanical material mixer, fully mixing and stirring, adding the pigment according to the weight ratio in the mixing and stirring process, and fully and uniformly stirring to obtain the ceramic coating.
Step two, spraying process
A. Spraying of paint
Putting a quantitative coating into a spraying bin of a ceramic preparation mechanical sprayer according to parts by weight, uniformly spraying the same amount of the ceramic outer layer in the bin in batches by three times, and continuously and respectively finishing the spraying for three times, wherein the temperature of the spraying material in each time is sequentially adjusted to 30 ℃, 50 ℃ and 80 ℃.
B. Cooling down
And naturally cooling the ceramic product after the third spraying until the surface spraying layer of the ceramic product is in a semi-solidification state.
C. Airflow orientation
And (3) conveying the ceramic product with the surface spray coating in a semi-solidified state after natural cooling in the cooling chamber into a mechanical airflow operation bin for ceramic preparation, opening an airflow directional system in the bin, and performing pattern forming directional treatment on the patterns of the spray coating on the surface of the ceramic product by using two kinds of air flows, namely cold air and hot air.
D. Color processing
The ceramic product oriented by the airflow is sent into a color processing bin of a ceramic preparation mechanical product, the color system edited by 3D software arranged in the machine is used for spraying the pigment on the ceramic product, the color of the surface spraying layer of the ceramic product is diluted, deepened or changed, and then the ceramic product is placed for 0.5 hour to enable the pigment and the layer to be fused with each other.
E. Sonication
And placing the ceramic product after color treatment into a ceramic preparation mechanical ultrasonic vibration bin, and performing sound wave treatment through different frequencies of 300-2600hz to filter oxygen and impurities in the layer.
F. Firing
And (3) putting the ceramic product obtained by the steps into a ceramic preparation mechanical furnace kiln for burning, wherein the furnace temperature is 700-800 ℃, and after 3 hours of burning, naturally cooling to obtain a ceramic product with natural patterns formed on the surface of the ceramic.
The invention has the beneficial effects that: the patterns formed on the outer surface of the ceramic are natural and rich in three-dimensional sense and aesthetic feeling, the ornamental value of the ceramic is greatly enhanced, the defects of long manufacturing period of the traditional ceramic surface art and long culture and study time and complicated manufacturing process of technicians are overcome, the process flow is simplified by combining the modern technology, the artistic effect which cannot be achieved by the traditional manual carving can be achieved, and the manufacturing cost is low.
Detailed Description
In order to make the technical solutions of the present invention more understandable to those skilled in the art, the present invention is further analyzed with reference to specific examples below.
Example 1
The coating is prepared from the following raw materials in parts by weight: 1-3 parts of boron, 1-3 parts of phosphorus, 0.1-0.3 part of cadmium, 0.1-0.5 part of silver, 0.5-1.5 parts of silicon, 0.2-0.6 part of lead, 3-7 parts of lime powder, 3-7 parts of gelatin, 10-30 parts of water, 35-65 parts of kaolin and 8-22 parts of quartz.
Example 2
The raw materials in the coating are preferably prepared from the following components in parts by weight: 1-1.8 parts of boron, 1.1-2.1 parts of phosphorus, 0.15-0.25 part of cadmium, 0.2-0.4 part of silver, 1.0-1.2 parts of silicon, 0.3-0.5 part of lead, 4-6 parts of lime powder, 4-6 parts of gelatin, 15-25 parts of water, 40-60 parts of kaolin and 10-20 parts of quartz.
Example 3
The optimal preparation of the raw materials in the coating comprises the following components in parts by weight: 1.4 parts of boron, 1.6 parts of phosphorus, 0.2 part of cadmium, 0.3 part of silver, 1.1 part of silicon, 0.4 part of lead, 5 parts of lime powder, 5 parts of gelatin, 20 parts of water, 50 parts of kaolin and 15 parts of quartz.
Example 4
The preparation and spraying process comprises the following specific steps:
step one, preparing the coating
A. Formulated paint
a. Putting raw materials of boron, phosphorus, cadmium, silver, silicon and lead powder in a container according to parts by weight, and mixing and stirring the raw materials to fully mix and stir the raw materials uniformly to prepare a mixture A;
b. putting the lime powder, the gelatin and the water in a container according to the parts by weight, and performing a mixing and stirring process to fully stir and stir the raw materials uniformly to prepare a mixture B;
c. taking the raw material mixture A and the raw material mixture B according to the parts by weight, putting the raw material mixture A and the raw material mixture B into a ceramic preparation mechanical material mixer, fully mixing and stirring, adding the pigment according to the weight ratio in the mixing and stirring process, and fully and uniformly stirring to obtain the ceramic coating.
Step two, spraying process
A. Spraying of paint
According to the weight portion, putting a quantitative spraying material into a spraying material cabin of a ceramic preparation mechanical sprayer, uniformly and equivalently spraying the ceramic outer layer in the cabin in batches by three times, and continuously and respectively finishing the spraying for three times, wherein the temperature of the spraying material in each time is sequentially adjusted to 30 ℃, 50 ℃ and 80 ℃.
B. Cooling down
And naturally cooling the ceramic product after the third spraying until the surface spraying layer of the ceramic product is in a semi-solidification state.
C. Airflow orientation
And (3) conveying the ceramic product with the surface spray coating in a semi-solidified state after natural cooling in the cooling chamber into a mechanical airflow operation bin for ceramic preparation, opening an airflow directional system in the bin, and performing pattern forming directional treatment on the patterns of the spray coating on the surface of the ceramic product by using two kinds of air flows, namely cold air and hot air.
D. Color processing
The ceramic product oriented by the airflow is sent into a color processing bin of a ceramic preparation mechanical product, the color system edited by 3D software arranged in the machine is used for spraying the pigment on the ceramic product, the color of the surface spraying layer of the ceramic product is diluted, deepened or changed, and then the ceramic product is placed for 0.5 hour to enable the pigment and the layer to be fused with each other.
E. Sonication
And placing the ceramic product after color treatment into a ceramic preparation mechanical ultrasonic vibration bin, and performing sound wave treatment through different frequencies of 300-2600hz to filter oxygen and impurities in the layer.
F. Firing
And (3) putting the ceramic product obtained by the steps into a ceramic preparation mechanical furnace kiln for burning, wherein the furnace temperature is 700-800 ℃, and after 3 hours of burning, naturally cooling to obtain a ceramic product with natural patterns formed on the surface of the ceramic.
Example 5
In the spraying process of step 2-a in example 4, the constant temperature is kept at a specified temperature, the spraying is carried out at a constant speed, the spraying can be carried out at a certain time interval each time, and the spraying at the next temperature is carried out after the surface spraying layer is cooled to room temperature.
Example 6
In the step 2-C air flow orientation process of example 4, the temperature of the hot air was controlled to be 35 ℃ to 45 ℃ and the temperature of the cold air was controlled to be in the range of-5 ℃ to-15 ℃.
Example 7
In the example 4, step 2-F firing process, the ceramic article was placed in a cool and dry place for natural cooling after firing.
Claims (3)
1. A spraying process of paint capable of forming natural patterns on the surface of ceramic is characterized in that: the coating is prepared from the following raw materials in parts by weight: 1-3 parts of boron, 1-3 parts of phosphorus, 0.1-0.3 part of cadmium, 0.1-0.5 part of silver, 0.5-1.5 parts of silicon, 0.2-0.6 part of lead, 3-7 parts of lime powder, 3-7 parts of gelatin, 10-30 parts of water, 35-65 parts of kaolin and 8-22 parts of quartz;
the paint preparation and spraying process of the spraying process comprises the following specific steps:
step one, preparing the coating
A. Formulated coating
a. Putting raw materials of boron, phosphorus, cadmium, silver, silicon and lead powder in a container according to parts by weight, and mixing and stirring the raw materials to fully mix and stir the raw materials uniformly to prepare a mixture A;
b. putting the lime powder, the gelatin and the water in a container according to the parts by weight, and performing a mixing and stirring process to fully stir and stir the raw materials uniformly to prepare a mixture B;
c. taking the raw material mixture A and the raw material mixture B according to the parts by weight, putting the raw material mixture A and the raw material mixture B into a ceramic preparation mechanical material mixer, fully mixing and stirring, adding the pigment according to the weight ratio in the mixing and stirring process, and fully and uniformly stirring to obtain the ceramic coating;
step two, spraying process
Spraying of paint
Putting a quantitative spray material into a spray material bin of a ceramic preparation mechanical sprayer according to parts by weight, uniformly spraying equivalent spray materials on the outer layer of batch ceramics in the bin for three times, sequentially adjusting the temperature of the spray materials to 30 ℃, 50 ℃ and 80 ℃ every time, and continuously and respectively finishing the spraying for three times;
cooling down
Naturally cooling the ceramic product after the third spraying until the surface spraying layer of the ceramic product is in a semi-solidification state;
airflow orientation
Feeding the ceramic product with the surface spray coating in a semi-solidified state after being naturally cooled in a cooling chamber into a mechanical airflow operation bin for ceramic preparation, opening an airflow directional system in the bin, and performing pattern forming directional treatment on the surface spray coating of the ceramic product through two airflows of cold air and hot air;
color processing
Sending the ceramic product oriented by the airflow into a ceramic preparation mechanical product color processing bin, spraying pigment on the ceramic product through a color system edited by 3D software arranged in a machine, fading, deepening or changing the color of a spraying layer on the surface of the ceramic product, and then placing for 0.5 hour to fuse the pigment and the layer;
sonication
Placing the ceramic product after color treatment into a ceramic preparation mechanical ultrasonic vibration bin, and performing sound wave treatment through different frequencies of 300-2600hz to filter oxygen and impurities in the layer;
firing
And (3) putting the ceramic product obtained by the steps into a ceramic preparation mechanical furnace kiln for burning, wherein the furnace temperature is 700-800 ℃, and naturally cooling after 3 hours of burning to obtain a ceramic product with natural patterns formed on the surface of the ceramic.
2. The process of claim 1, wherein the step of spraying the coating material for forming a natural pattern on the surface of the ceramic material comprises: the coating is prepared from the following raw materials in parts by weight: 1-1.8 parts of boron, 1.1-2.1 parts of phosphorus, 0.15-0.25 part of cadmium, 0.2-0.4 part of silver, 1.0-1.2 parts of silicon, 0.3-0.5 part of lead, 4-6 parts of lime powder, 4-6 parts of gelatin, 15-25 parts of water, 40-60 parts of kaolin and 10-20 parts of quartz.
3. The process of claim 1, wherein the step of spraying the coating material for forming a natural pattern on the surface of the ceramic material comprises: the optimal configuration of the raw materials in the coating is as follows by weight: 1.4 parts of boron, 1.6 parts of phosphorus, 0.2 part of cadmium, 0.3 part of silver, 1.1 part of silicon, 0.4 part of lead, 5 parts of lime powder, 5 parts of gelatin, 20 parts of water, 50 parts of kaolin and 15 parts of quartz.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710248279.9A CN106957543B (en) | 2017-04-17 | 2017-04-17 | Paint capable of forming natural patterns on ceramic surface and spraying process thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710248279.9A CN106957543B (en) | 2017-04-17 | 2017-04-17 | Paint capable of forming natural patterns on ceramic surface and spraying process thereof |
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| Publication Number | Publication Date |
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| CN106957543A CN106957543A (en) | 2017-07-18 |
| CN106957543B true CN106957543B (en) | 2020-01-17 |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111704435B (en) * | 2017-10-18 | 2022-03-25 | 福建省中科养生健康瓷有限公司 | Glaze for ceramic products with invisible patterns and process for manufacturing ceramic products with invisible patterns |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1318531A (en) * | 2000-04-20 | 2001-10-24 | 黄东铭 | Ceramic surface color-drawing decoration technology |
| CN1453315A (en) * | 2002-04-23 | 2003-11-05 | 蔡志强 | Method of adding nano powder material into paint and glaze |
| EP1553068A1 (en) * | 2004-01-10 | 2005-07-13 | Nanogate Coating Systems GmbH | Inorganic coating for ceramic ware |
| CN101024582A (en) * | 2007-02-02 | 2007-08-29 | 王家助 | Method for producing metal enamel |
| CN101045828A (en) * | 2006-07-03 | 2007-10-03 | 张义纲 | Phosphate film-coated powder and preparation method thereof |
| CN101348330A (en) * | 2008-09-05 | 2009-01-21 | 四川白塔新联兴陶瓷集团有限责任公司 | Preparation of low temperature metal-lustrous glaze for ceramic |
-
2017
- 2017-04-17 CN CN201710248279.9A patent/CN106957543B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1318531A (en) * | 2000-04-20 | 2001-10-24 | 黄东铭 | Ceramic surface color-drawing decoration technology |
| CN1453315A (en) * | 2002-04-23 | 2003-11-05 | 蔡志强 | Method of adding nano powder material into paint and glaze |
| EP1553068A1 (en) * | 2004-01-10 | 2005-07-13 | Nanogate Coating Systems GmbH | Inorganic coating for ceramic ware |
| CN101045828A (en) * | 2006-07-03 | 2007-10-03 | 张义纲 | Phosphate film-coated powder and preparation method thereof |
| CN101024582A (en) * | 2007-02-02 | 2007-08-29 | 王家助 | Method for producing metal enamel |
| CN101348330A (en) * | 2008-09-05 | 2009-01-21 | 四川白塔新联兴陶瓷集团有限责任公司 | Preparation of low temperature metal-lustrous glaze for ceramic |
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Effective date of registration: 20210323 Address after: 333000 No.118 Huayi new village, Guanzhuang, Lvmeng Township, Changjiang District, Jingdezhen City, Jiangxi Province Patentee after: Jingdezhen junhuai Ceramics Co.,Ltd. Address before: Room 402, unit 1, 15 Yikuang street, Nangang District, Harbin City, Heilongjiang Province Patentee before: Wang Changli |