CN106956486A - Thermal isolation film with high ultraviolet-resistant performance and preparation method thereof - Google Patents

Thermal isolation film with high ultraviolet-resistant performance and preparation method thereof Download PDF

Info

Publication number
CN106956486A
CN106956486A CN201710130534.XA CN201710130534A CN106956486A CN 106956486 A CN106956486 A CN 106956486A CN 201710130534 A CN201710130534 A CN 201710130534A CN 106956486 A CN106956486 A CN 106956486A
Authority
CN
China
Prior art keywords
ultraviolet
resistant
light
thermal isolation
isolation film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710130534.XA
Other languages
Chinese (zh)
Other versions
CN106956486B (en
Inventor
方官久
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU GENER NANO TECHNOLOGY Co Ltd
Original Assignee
SUZHOU GENER NANO TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU GENER NANO TECHNOLOGY Co Ltd filed Critical SUZHOU GENER NANO TECHNOLOGY Co Ltd
Priority to CN201710130534.XA priority Critical patent/CN106956486B/en
Publication of CN106956486A publication Critical patent/CN106956486A/en
Application granted granted Critical
Publication of CN106956486B publication Critical patent/CN106956486B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00—Producing flat articles, e.g. films or sheets
    • B29D7/01—Films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32—Radiation-absorbing paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/003—PET, i.e. poylethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B32B2250/244—All polymers belonging to those covered by group B32B27/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/71—Resistive to light or to UV
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2258—Oxides; Hydroxides of metals of tungsten
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention provides a kind of thermal isolation film with high ultraviolet-resistant performance and preparation method thereof, and the section of the thermal isolation film has layer structure, installs glue-line and mould release membrance including scratch-resistant layer, basement membrane, ultraviolet-resistant composite bed, basement membrane, ultraviolet-resistant successively；The ultraviolet-resistant composite bed and ultraviolet-resistant are installed glue-line and formed by UV absorption coatings, and the UV absorption coating at least includes UV absorbers, pressure sensitive adhesive and solvent；The anti-scratch series of strata are coated with and formed by photocureable coating or light curing nano insulating moulding coating, and photocureable coating or the light curing nano insulating moulding coating at least includes light-cured resin and auxiliary agent.Thermal isolation film produced by the present invention has high durable, fine definition and high ultraviolet-resistant performance, and its infrared barrier rate is more than 85%, and mist degree is less than 0.1%, UVA long-wave bands ultraviolet permeability and is less than 1%, and ultraviolet-resistant performance is in 100mw/m2UV intensity is undamped after irradiating 7 hours.

Description

Thermal isolation film with high ultraviolet-resistant performance and preparation method thereof
Technical field
The present invention relates to composite type heat-insulating film, more particularly to a kind of thermal isolation film with high ultraviolet-resistant performance, and this The preparation method of composite membrane is planted, belongs to composite membrane processing technique field.
Background technology
Sunshine membrane is also referred to as thermal isolation film, is widely used in automobile and building glass window.The major function of thermal isolation film is barrier sun Ultraviolet and infrared energy in light, the former can reduce the ultraviolet injury to skin and interior decoration, and improve thermal isolation film in itself Service life；The latter can reduce the sunlight energy got in, and then reduce summer air conditioning energy consumption.
Uv energy in sunlight is concentrated mainly on 200nm~400nm wavelength bands, be divided into UVC (200nm~280nm), The wave band such as UVB (280nm~315nm) and UVA (315nm~400nm), wherein UVC wave bands photon energy highest, the injury to people Maximum, but before earth surface is reached, absorbed substantially by atmosphere.Human body skin is long-term exposure to UVB wave bands, and severe patient can draw Play squamous cell carcinoma；Although UVA wave bands are big without UVB wave bands to the injury of people, melanoma and photodermatitis are also resulted in. The big multipotency barrier UVB wave band ultraviolet lights of presently commercially available thermal isolation film, but in some deficiencies of the barrier of UVA wave bands, transmitance is general More than 10%.
Chinese patent literature CN101831126A and CN105295279A disclose a kind of by being implanted into barrier UVB wave bands The fluorescent whitening agent of Benzophenone or benzotriazole ultraviolet absorber and barrier UVA wave bands in polymer, further melting and Stretching, which is made, can obstruct the ultraviolet polymer film of all band.Chinese patent literature CN103725218A discloses one kind in two basement membranes Between be combined one layer containing compound adhesive, absorb the benzophenone or nanometer titanic oxide material of UVB wave bands and absorb UVA wave bands The all band ultraviolet-resistant film of Yellow azo dye.Chinese patent literature CN103935098A discloses a kind of for electronic product The all band ultraviolet-resistant film of screen protection, its ultraviolet-resistant layer is compound between two basement membranes, and ultraviolet-resistant layer includes pressure-sensitive Glue, the benzotriazole ultraviolet absorber UV-P for obstructing UVB wave bands, and absorb the fluorescent whitening agent of UVA wave bands, color essence, pearl Light powder or fluorescent material.
Present inventor has found there is a larger deficiency using above technical scheme, i.e.,：Product through exposure in 1 year, UVA wave bands barriering efficiency can produce deep fades, and can not meet the requirement that optical grade fenestrated membrane mist degree is less than 0.3%.Therefore, have Necessity is to its improvement for further study.
The content of the invention
The purpose of the present invention is exactly to have high ultraviolet resistance there is provided one kind to solve the above-mentioned problems in the prior art The thermal isolation film of separating performance, and this composite membrane preparation method, make thermal isolation film while with good effect of heat insulation, can have Effect barrier UVA long-wave band uv energies, and have fine definition and high-weatherability energy concurrently.
The technology of the present invention solution is：A kind of thermal isolation film with high ultraviolet-resistant performance, the thermal isolation film is a kind of multiple Film is closed, section has layer structure, and layered structure includes scratch-resistant layer, basement membrane, ultraviolet-resistant composite bed, basement membrane, purple successively Glue-line and mould release membrance are installed in outer barrier.
Preferably, the thickness of the scratch-resistant layer is 1.5~5.0 microns, and the thickness of two layers of basement membrane is 19~100 microns, The thickness that ultraviolet-resistant composite bed and ultraviolet-resistant install glue-line is 4.5~12.5 microns, and the thickness of mould release membrance is micro- for 19~25 Rice.
It is highly preferred that the thickness of the scratch-resistant layer is 1.8~4.5 microns, the thickness of two layers of basement membrane is 23~36 microns, The thickness that ultraviolet-resistant composite bed and ultraviolet-resistant install glue-line is 5.5~8.5 microns.
More preferably, two layers basement membrane be selected from the transparent PET basement membrane through sided corona treatment or precoating treatment, primary colors PET basement membranes or Plate metal PET basement membranes.
Present invention also offers a kind of preparation method of the thermal isolation film with high ultraviolet-resistant performance, comprise the following steps：
Step one, the optical grade poly terephthalic acid second that the internal haze through corona or precoating treatment is less than 0.3% is chosen Diol ester (PET) film is used as basement membrane；
Step 2, the preparation of ultraviolet-resistant composite bed：With nick coating method by UV absorption coatings in step one Any one side of second basement membrane selected after first any one side of basement membrane of selection, coated and dried with step one is compounded to form UV absorption composite membrane；
Step 3, ultraviolet-resistant installs the preparation of glue-line：With nick coating method by UV absorption coatings in step Silicone oil face after two untapped base film surfaces, coated and dried with mould release membrance is combined；
Step 4, the preparation of scratch-resistant layer：Photocureable coating or light curing nano insulating moulding coating are coated on into step 3 does not make After base film surface, drying and nitrogen protect oxygen-free environment under ultraviolet light polymerization formation scratch-resistant layer.
Wherein：
(1) among step 2 and step 3, the UV absorption coating at least includes UV absorbers, pressure sensitive adhesive and molten Agent, the consumption of the UV absorbers is 35%~55Wt% of pressure sensitive adhesive, and the pressure sensitive adhesive is one-component esters of acrylic acid Or two-component acrylicester class pressure sensitive adhesive.
Preferably, the UV absorbers are the UV Absorption of Benzophenone class, benzotriazole or oxybenzene triazines Agent, when usage amount is 0.5g/m2When, its 360nm uv transmittance is less than 0.5%；The solvent be ethyl acetate, butanone, Isobutanol, toluene, the one or more of propylene glycol methyl ether acetate or DAA；When the solvent includes ethyl acetate, The percentage composition that ethyl acetate accounts for solvent gross weight is not less than 85%.
(2) among step 4, photocureable coating or the light curing nano insulating moulding coating at least include light-cured resin and Auxiliary agent；The light-cured resin includes difunctional light-cured resin and/or six functional groups light-cured resin, and difunctional light is consolidated Change resin and account for the 0~20% of the light-cured resin total amount, six functional groups light-cured resin accounts for the light-cured resin total amount 80~100%；The auxiliary agent includes light trigger, levelling agent and retarder thinner, wherein, the light trigger is the photocuring The 4~10% of weight resin, the levelling agent is the 1.0~2.5% of the light-cured resin weight.
The light curing nano insulating moulding coating includes nano dispersion fluid, light-cured resin and auxiliary agent, the nano dispersion fluid At least include nano material and dispersant；Wherein, the nano material is from the doped tungsten oxide or indium that particle diameter is 30~80nm Tin-oxide or lanthanum hexaboride, the dispersant are the 50~120% of the nano material weight.
(3) among the preparation method of the above-mentioned thermal isolation film with high ultraviolet-resistant performance, the light-cured resin is following One or more combinations：Propylene glycol diacrylate, the third oxidation neopentylglycol diacrylate olefin(e) acid ester, tripropylene glycol Diacrylate, ethoxy ethoxy ethoxy acrylate, hexanediyl ester, hexanediyl ester, poly- two The acrylate of pentaerythrite five/six, aliphatic urethane diacrylate, the acrylate of adoption urethane six.
(4) among the preparation method of the above-mentioned thermal isolation film with high ultraviolet-resistant performance, the light trigger is following One or more combination：2- hydroxy-2-methyl -1- phenylacetones, 1- hydroxy cyclohexylphenyl alkyl Benzophenone, 2- hydroxyls -4 '-(2- hydroxyls Ethyoxyl) -2- methyl phenyl ketones, 4- hydroxy benzophenones and (2,4,6- trimethylbenzoyl) diphenyl phosphine oxide.
Compared with prior art, advantages of the present invention is embodied in：
1st, the UV absorption composite bed and UV absorption that the present invention is provided are installed in glue-line, are up in ultraviolet absorber ratio In the case of more than 35%, ultraviolet absorber is matched well with pressure sensitive adhesive, is not produced ultraviolet absorber and is separated out problem, so clearly It is clear to spend and have good stability.
2nd, the ultraviolet absorber composition that the present invention is provided is single, will not produce between the complicated ingredient of prior art presence With problem, the problems such as definition reduction for more not using fluorescent whitening agent to be brought is shortened with service life.
3rd, the thermal isolation film for the high ultraviolet-resistant of high durable fine definition that the present invention is provided：Infrared barrier rate is more than 85%, mist Degree is less than 0.1%, and definition reaches optical grade；Ultraviolet-resistant good stability, in 100mW/cm2UV intensity (about sunlight 60 times of UV intensity) irradiation 7 hours after, barrier property is essentially unchanged；UVA wave band ultraviolet-resistant rates reach more than 99%, completely Without worrying that skin, by ultraviolet injury, is the suncream for not taking off change, with good resultant effects such as energy-conservation, skin care and safety.
Brief description of the drawings
Fig. 1 is the product structure schematic diagram of the present invention；
Fig. 2 is the product spectrogram of the embodiment of the present invention 1,2 and 3；
Fig. 3 is the ultraviolet weather-proof test light spectrogram of the product of the embodiment of the present invention 1；
Fig. 4 is the ultraviolet weather-proof test light spectrogram of the product of the embodiment of the present invention 3.
Wherein, the implication of each mark is among Fig. 1：101- scratch-resistant layers, 102- basement membranes, 103- ultraviolet-resistant composite beds, 104- basement membranes, 105- ultraviolet-resistants install glue-line, 106- mould release membrances；
Sample 1,2 and 3 among Fig. 2 corresponds respectively to embodiment 1,2 and 3；
In the weather-proof test process of Fig. 3 and Fig. 4, ultraviolet irradiation intensity is 100mW/cm2, the intensity is uv energy in sunlight 60 times.
Embodiment
The present invention provides the thermal isolation film of a kind of high durable, fine definition and high ultraviolet-resistant, and the thermal isolation film is that one kind is included The composite membrane of two layers of basement membrane, its layer structure as shown in figure 1, include successively：Scratch-resistant layer 101, basement membrane 102, ultraviolet-resistant is combined Layer 103, basement membrane 104, ultraviolet-resistant installs glue-line 105, mould release membrance 106.
Both can be with identical for basement membrane 102 and 104, can also be different, specifically can be using purchased in market through sided corona treatment or precoating Transparent PET basement membrane, primary colors PET basement membranes or the plating metal PET basement membranes of processing；The thickness of basement membrane is generally 19~100 microns, preferentially 23~36 microns of selection；Mould release membrance 106 is peeled off strong using the PET basement membranes of coating silicone oil purchased in market, preferably 19~25 microns of thickness Spend for 15~25 gram inch.
According to technical solution of the present invention, scratch-resistant layer 101 is by photocureable coating or light curing nano insulating moulding coating coating shape Into photocureable coating or the light curing nano insulating moulding coating at least includes light-cured resin and auxiliary agent；Ultraviolet-resistant composite bed 103 and ultraviolet-resistant install glue-line 105 be to be formed by UV absorption coatings, the UV absorption coating at least include it is ultraviolet Light absorber, pressure sensitive adhesive and solvent.
During specific implementation, the light-cured resin in the photocureable coating includes difunctional light-cured resin and/or six Functional group's light-cured resin, difunctional light-cured resin accounts for the 0~20% of the light-cured resin total amount, and six functional groups light is consolidated Change resin and account for the 80~100% of the light-cured resin total amount.The auxiliary agent used in photocureable coating includes：Light trigger, stream Flat agent and retarder thinner, wherein, the consumption of light trigger is the 4~6% of light-cured resin weight, and the consumption of levelling agent is that light is consolidated Change the 1.0~2.5% of weight resin.The scratch-resistant layer 101 to be formed is coated with such photocureable coating, its thickness general control exists 1.5~2.5 microns, it is preferably controlled within 1.8~2.2 micrometer ranges.
Further, the photocureable coating can also add nano dispersion fluid formation light curing nano insulating moulding coating.It is described Light curing nano insulating moulding coating includes nano dispersion fluid, light-cured resin and auxiliary agent, wherein, light-cured resin includes difunctional Light-cured resin and six functional groups light-cured resin, difunctional light-cured resin account for the light-cured resin total amount 0~ 10%, six functional groups light-cured resin accounts for the 90~100% of the light-cured resin total amount；The nano dispersion fluid at least includes Nano material and dispersant, wherein, the nano material is from doped tungsten oxide or indium tin oxidation of the particle diameter for 30~80nm Thing or lanthanum hexaboride, prioritizing selection doped tungsten oxide, the dispersant is the 50~120% of the nano material weight；It is described Light-cured resin is the 400~800% of the nano material weight；The auxiliary agent includes light trigger, levelling agent and diluted molten Agent, wherein, the consumption of light trigger is the 5~10% of light-cured resin weight, and the consumption of levelling agent is the light-cured resin The 1.0~2.5% of weight.The scratch-resistant layer 101 to be formed is coated with such light curing nano insulating moulding coating, its thickness general control At 2.5~5.0 microns, it is preferably controlled within 3.5~4.5 micrometer ranges.
Either common photocureable coating, still adds the light curing nano insulating moulding coating of nano dispersion fluid, its institute The light-cured resin used can be the combination of following one or more：Propylene glycol diacrylate, the third oxidation neopentyl glycol Diacrylate olefin(e) acid ester, tripropylene glycol diacrylate, ethoxy ethoxy ethoxy acrylate, the propylene of hexylene glycol two Acid esters, hexanediyl ester, the acrylate of dipentaerythrite five/six, aliphatic urethane diacrylate, adoption ammonia The acrylate of ester six；The combination of used light trigger concretely following one or more：2- hydroxy-2-methyl -1- benzene Benzylacetone, 1- hydroxy cyclohexylphenyl alkyl Benzophenone, 2- hydroxyls -4 '-(2- hydroxy ethoxies) -2- methyl phenyl ketones, 4- hydroxyls-hexichol first Ketone, (2,4,6- trimethylbenzoyl) diphenyl phosphine oxide, the consumption of light trigger be light-cured resin weight 4~ 10%, and, short purple light initiator and long ultraviolet initiator are applied in combination, and can improve the utilization ratio of uv energy, it is ensured that Deep cure.
In addition, the UV absorbers are the 35%~55% of the pressure sensitive adhesive weight, the UV absorbers bag The UV absorbers of Benzophenone class, benzotriazole or oxybenzene triazines are included, prioritizing selection is 0.5g/m when usage amount2Shi Qi 360nm uv transmittances are less than 0.5% ultraviolet absorber, particularly the oxybenzene triazines ultraviolet light with high-weatherability energy Absorbent；The pressure sensitive adhesive is one-component esters of acrylic acid or two-component acrylicester class；The solvent is ethyl acetate, fourth Ketone, isobutanol, toluene, the one or more of propylene glycol methyl ether acetate or DAA, preferably：Ethyl acetate with it is above-mentioned other Material is as mixed solvent, and ethyl acetate accounts for the percentage composition of solvent gross weight and is not less than 85% (it is total that other solvents account for solvent 15%) anharmonic ratio example is less than.
Ultraviolet-resistant composite bed 103 and ultraviolet-resistant install the thickness general control of glue-line 105 at 4.5~12.5 microns, It is preferably controlled within 5.5~8.5 micrometer ranges, can so avoids low peel strength and thickness caused by thickness is too thin too thick The coating defects of generation.So, it is ensured that the ultraviolet-resistant composite bed 103 and ultraviolet-resistant install the UVA ripples of glue-line 105 Section mean transmissivity is less than 1%.
According to above technical thought and requirement, with reference to step in detail below can be prepared by with high ultraviolet-resistant performance every Hotting mask：
Step one, the optical grade poly terephthalic acid second that the internal haze through corona or precoating treatment is less than 0.3% is chosen Diol ester (PET) film is used as basement membrane；
Step 2, the preparation of ultraviolet-resistant composite bed：With nick coating method by UV absorption coatings in step one Any one side of second basement membrane selected after first any one side of basement membrane of selection, coated and dried with step one is compounded to form UV absorption composite membrane；
Step 3, ultraviolet-resistant installs the preparation of glue-line：With nick coating method by UV absorption coatings in step Silicone oil face after two untapped base film surfaces, coated and dried with mould release membrance is combined；
Step 4, the preparation of scratch-resistant layer：Photocureable coating or light curing nano insulating moulding coating are coated on into step 3 does not make After base film surface, drying and nitrogen protect oxygen-free environment under ultraviolet light polymerization formation scratch-resistant layer.
Technical solution of the present invention is further elaborated with instantiation below, so that it is more readily understood and grasped.Need It is noted that be exemplified below only be technical solution of the present invention prominent example, it is all take equivalent or equivalent transformation and The technical scheme of formation, all falls within the scope of protection of present invention.
【Embodiment 1】
1st, dispensing
1.1 UV absorption coating A preparation：First weigh 4.20 parts of ultraviolet absorber hydroxyl phenol triazines, 28.45 parts Cytec one-components acrylate pressure sensitive adhesive 1159 (45% solid content), 59.46 parts of ethyl acetate, 3.32 parts of butanone, 4.57 parts of dipropyls Keto-alcohol, is then mixed 45 minutes at room temperature.
It is prepared by 1.2 photocureable coating：Weigh 20.10 parts of five/six acrylate of bipentaerythrite, hexanediyl ester 3.54 parts, 74.96 parts of ethyl acetate, 0.83 part of light trigger " 1- hydroxy cyclohexylphenyl alkyl Benzophenone ", light trigger " (2,4,6- Trimethylbenzoyl) diphenyl phosphine oxide " 0.12 part, levelling agent " Tego Rad2100 response types silicone acrylates " 0.45 part, mix 30 minutes obtained photocureable coating.
2nd, it is film-made.The thermal isolation film of the high ultraviolet-resistant of high durable fine definition is prepared according to the following steps：
Step one, it is 23 microns and the two-sided optical grade polyethylene terephthalate through precoating treatment to choose thickness (PET) film is as basement membrane 102 and basement membrane 104, and internal haze is less than 0.3%.
Step 2, the preparation of ultraviolet-resistant composite bed 103, with nick coating method by UV absorption masking liquid A with 20 ms/min Speed be coated on any one side of basement membrane 104, coating obtains 5.8 microns of thick coatings after 100 degree of oven for drying, finally and base Film 102 is combined.
Step 3, ultraviolet-resistant install glue-line 105 preparation, with nick coating method by UV absorption masking liquid A with 20 meters/ The speed divided is coated on the surface of the untapped basement membrane 104 of step 2, and coating obtains 5.8 microns of thickness after 100 degree of oven for drying Coating, be finally combined with the silicone oil face of mould release membrance 106.Selected mould release membrance 106 scribbles silicon for 23 microns of thick one sides purchased in market The PET film of oil, the gram inch of off-type force 15.
Photocuring scratch resistance resin masking liquid is coated on step by step 4, the preparation of scratch-resistant layer 101 with 25 ms/min of speed The surface of rapid three untapped basement membrane 102, the ultraviolet light polymerization after 80 degree of oven for drying and under the oxygen-free environment that nitrogen is protected The 2 microns thick dry film of coating formation.
Finished product made from embodiment 1 is sample 1, and after testing, the UVA wave bands ultraviolet permeability 0.92% of sample 1 (is shown in Table 1 And Fig. 2), mist degree 0.07% (is shown in Table 1), and in 100mW/cm2Ultraviolet light after 7 hours performance without significant change (see Fig. 3), Realize the combination properties such as fine definition, high ultraviolet-resistant and high durable.Moreover, its scratch-resistant layer is in load 500g double rubs 100 times without obvious cut, adhesive force is 0 grade.
【Embodiment 2】
1st, dispensing
1.1 UV absorption coating A preparation：It is same as Example 1.
It is prepared by 1.2 light curing nano insulating moulding coatings：Weigh 71.2 parts of nano dispersion fluid, the acrylate of aliphatic polyurethane six 25.12,1.76 parts of ethyl acetate, 0.94 part of light trigger " 1- hydroxy cyclohexylphenyl alkyl Benzophenone ", light trigger " (2,4,6- tri- Methyl benzoyl) diphenyl phosphine oxide " 0.50 part, levelling agent " Tego Rad2100 response types silicone acrylates " 0.30 part, 0.18 part of levelling agent " Tego Rad2300 response types silicone acrylates " mixes 45 minutes obtained light Curing nano insulating moulding coating.The nano dispersion fluid includes：8.37 parts of dispersant, 73.47 parts of ethyl acetate, a diameter of 50nm's 18.16 parts of doped tungsten oxide nano material.
2nd, it is film-made.The step of preparation method and flow of this implementation is with embodiment 1 one, step 2 and step 3 are identical, no Same is that step 4 is to substitute photocureable coating with light curing nano insulating moulding coating, specific as follows：
Light curing nano insulating moulding coating is coated on step by step 4, the preparation of scratch-resistant layer 101 with 20 ms/min of speed The three untapped surfaces of basement membrane 102, after 80 degree of oven for drying and under the oxygen-free environment that nitrogen is protected described in ultraviolet light polymerization The 2 microns thick dry film of coating formation.
Finished product made from embodiment 2 is sample 2, and its performance is shown in Table 1 and Fig. 2.
【Embodiment 3】
The preparation method and flow of embodiment 3 are identical with described case study on implementation 2, the difference is that the basement membrane of case study on implementation 2 104, which are averaged the primary colors film that visible light transmissivity is 15%, substitutes.Obtained finished product is sample 3, and its performance is shown in Table 1, Fig. 2 and figure 4。
【Comparative example 1】
It is prepared by UV absorption coating B：First weigh 4.20 parts of ultraviolet absorber hydroxyl phenol triazines, 28.45 parts of Cytec single groups Then part acrylate pressure sensitive adhesive 1159 (45% solid content), 67.35 parts of ethyl acetate mix 45 minutes at room temperature.
The UV absorption coating B and UV absorption coating A difference is that UV absorption coating B does not add dipropyl Keto-alcohol and butanone, so cause masking liquid compatibility low, and then viscosity is high.Film (the ratio being coated with the UV absorption coating B Compared with sample 1) produce serious coating twill and rough surface, it is impossible to meet optical film requirement (its performance parameter is shown in Table 1, under Together).
【Comparative example 2】
It is prepared by UV absorption coating C：First weigh 1.26 parts of ultraviolet absorber hydroxyl phenol triazines, 44.97 parts of Cytec single groups Then part acrylate pressure sensitive adhesive 1159 (45% solid content), 53.77 parts of ethyl acetate mix 45 minutes at room temperature.
Ultraviolet absorber in the UV absorption coating C is the 30% of the UV absorption coating B, UV absorption coating The matching of C solution is significantly improved, similar with UV absorption coating A.It is with the UV absorption coating C films being coated with Comparative sample 2.
【Comparative example 3】
It is prepared by UV absorption coating D：First weigh 4.20 parts of ultraviolet absorber hydroxyl phenol triazines, 28.45 parts of Changxing single groups Part acrylate pressure sensitive adhesive 7052 (45% solid content), 59.46 parts of ethyl acetate, 3.32 parts of isobutyl ketones, 4.57 parts of DAAs, so Mix 45 minutes at room temperature afterwards.
The UV absorption coating D is that one-component pressure sensitive adhesive is different from the difference of the UV absorption coating A, now, purple Outer absorbing coating C compatibility is destroyed completely, and solution seriously sends out mist in itself.The film being coated with the UV absorption coating D For comparative sample 3.
Table 1：Embodiment and comparative example film performance comparison

Claims (12)

1. the thermal isolation film with high ultraviolet-resistant performance, the thermal isolation film is a kind of composite membrane, and section has layer structure, its feature It is：Layered structure successively include scratch-resistant layer (101), basement membrane (102), ultraviolet-resistant composite bed (103), basement membrane (104), Ultraviolet-resistant installs glue-line (105) and mould release membrance (106).
2. the thermal isolation film according to claim 1 with high ultraviolet-resistant performance, it is characterised in that：The scratch-resistant layer (101) thickness is 1.5~5.0 microns, and the thickness of two layers of basement membrane (102,104) is 19~100 microns, and ultraviolet-resistant is combined The thickness that layer (103) and ultraviolet-resistant install glue-line (105) is 4.5~12.5 microns, and the thickness of mould release membrance (106) is 19~25 Micron.
3. the thermal isolation film according to claim 2 with high ultraviolet-resistant performance, it is characterised in that：The scratch-resistant layer (101) thickness is 1.8~4.5 microns, and the thickness of two layers of basement membrane (102,104) is 23~36 microns, and ultraviolet-resistant is combined The thickness that layer (103) and ultraviolet-resistant install glue-line (105) is 5.5~8.5 microns.
4. the thermal isolation film according to claim 1 with high ultraviolet-resistant performance, it is characterised in that：Basement membrane (102 Hes 104) it is the transparent PET basement membrane through sided corona treatment or precoating treatment, primary colors PET basement membranes or plating metal PET basement membranes.
5. according to claim 4 with high ultraviolet-resistant performance thermal isolation film preparation method, it is characterised in that including with Lower step：
Step one, the optical grade polyethylene terephthalate that the internal haze through corona or precoating treatment is less than 0.3% is chosen Ester (PET) film is used as basement membrane；
Step 2, the preparation of ultraviolet-resistant composite bed：UV absorption coatings are selected in step one with nick coating method First any one side of basement membrane, any one side of second basement membrane selected with step one after coated and dried is compounded to form ultraviolet Absorbing composite membrane；
Step 3, ultraviolet-resistant installs the preparation of glue-line：With nick coating method by UV absorption coatings in step 2 not Silicone oil face after the base film surface used, coated and dried with mould release membrance is combined；
Step 4, the preparation of scratch-resistant layer：Photocureable coating or light curing nano insulating moulding coating are coated on step 3 untapped After base film surface, drying and nitrogen protect oxygen-free environment under ultraviolet light polymerization formation scratch-resistant layer.
6. there is the preparation method of the thermal isolation film of high ultraviolet-resistant performance according to claim 5, it is characterised in that：Step 2 Among step 3, the UV absorption coating at least includes UV absorbers, pressure sensitive adhesive and solvent, the UV Absorption The consumption of agent is 35%~55Wt% of pressure sensitive adhesive, and the pressure sensitive adhesive is one-component esters of acrylic acid or two-component acrylicester class Pressure sensitive adhesive.
7. there is the preparation method of the thermal isolation film of high ultraviolet-resistant performance according to claim 6, it is characterised in that：The purple Outer light absorber is the UV absorbers of Benzophenone class, benzotriazole or oxybenzene triazines, when usage amount is 0.5g/m2 When, its 360nm uv transmittance is less than 0.5%.
8. there is the preparation method of the thermal isolation film of high ultraviolet-resistant performance according to claim 6, it is characterised in that：It is described molten Agent is the one or more of ethyl acetate, butanone, isobutanol, toluene, propylene glycol methyl ether acetate or DAA；When described molten When agent includes ethyl acetate, the percentage composition that ethyl acetate accounts for solvent gross weight is not less than 85%.
9. there is the preparation method of the thermal isolation film of high ultraviolet-resistant performance according to claim 5, it is characterised in that：Step 4 Central, photocureable coating or the light curing nano insulating moulding coating at least includes light-cured resin and auxiliary agent；The photocuring tree Fat includes difunctional light-cured resin and/or six functional groups light-cured resin, and difunctional light-cured resin accounts for the light and consolidated Change the 0~20% of resin total amount, six functional groups light-cured resin accounts for the 80~100% of the light-cured resin total amount；It is described to help Agent include light trigger, levelling agent and retarder thinner, wherein, the light trigger be the light-cured resin weight 4~ 10%, the levelling agent is the 1.0~2.5% of the light-cured resin weight.
10. there is the preparation method of the thermal isolation film of high ultraviolet-resistant performance according to claim 9, it is characterised in that：It is described Light curing nano insulating moulding coating includes nano dispersion fluid, light-cured resin and auxiliary agent, and the nano dispersion fluid at least includes nanometer Material and dispersant；Wherein, the nano material from particle diameter for 30~80nm doped tungsten oxide or indium tin oxide or Lanthanum hexaboride, the dispersant is the 50~120% of the nano material weight.
11. there is the preparation method of the thermal isolation film of high ultraviolet-resistant performance according to claim 9, it is characterised in that：It is described Light-cured resin is following one or more combinations：Propylene glycol diacrylate, the third oxidation neopentylglycol diacrylate Olefin(e) acid ester, tripropylene glycol diacrylate, ethoxy ethoxy ethoxy acrylate, hexanediyl ester, oneself two Alcohol diacrylate, the acrylate of dipentaerythrite five/six, aliphatic urethane diacrylate, the propylene of adoption urethane six Acid esters.
12. there is the preparation method of the thermal isolation film of high ultraviolet-resistant performance according to claim 9, it is characterised in that：It is described Light trigger is following one or more combinations：2- hydroxy-2-methyl -1- phenylacetones, 1- hydroxy cyclohexylphenyl alkyl Benzophenone, 2- hydroxyls -4 '-(2- hydroxy ethoxies) -2- methyl phenyl ketones, 4- hydroxy benzophenones and (2,4,6- trimethylbenzoyl) two Phenyl phosphine oxide.
CN201710130534.XA 2017-03-07 2017-03-07 Heat insulation film with high ultraviolet blocking performance and preparation method thereof Active CN106956486B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710130534.XA CN106956486B (en) 2017-03-07 2017-03-07 Heat insulation film with high ultraviolet blocking performance and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710130534.XA CN106956486B (en) 2017-03-07 2017-03-07 Heat insulation film with high ultraviolet blocking performance and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106956486A true CN106956486A (en) 2017-07-18
CN106956486B CN106956486B (en) 2020-07-17

Family

ID=59470638

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710130534.XA Active CN106956486B (en) 2017-03-07 2017-03-07 Heat insulation film with high ultraviolet blocking performance and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106956486B (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108167777A (en) * 2017-12-28 2018-06-15 江苏远洋车灯有限公司 A kind of vehicle lamp housing antiultraviolet pad pasting
CN108481869A (en) * 2018-03-15 2018-09-04 上海际光薄膜科技有限公司 A kind of fire-retardant thermal-insulation window film
CN109777314A (en) * 2019-03-06 2019-05-21 常州山由帝杉防护材料制造有限公司 A kind of outer patch building fenestrated membrane and preparation method thereof
CN109865651A (en) * 2019-02-22 2019-06-11 上海浩驰科技股份有限公司 A kind of PET optics primary colors functional membrane and its application
CN110588121A (en) * 2019-10-19 2019-12-20 浙江和顺新材料有限公司 Self-healing heat-insulation heat-preservation polyester film and preparation method thereof
CN110760273A (en) * 2018-07-27 2020-02-07 苏州今蓝纳米科技有限公司 Single-layer low-transmittance inorganic nano heat insulation film with high weather resistance and high definition and preparation method thereof
CN110760274A (en) * 2018-07-27 2020-02-07 苏州今蓝纳米科技有限公司 Nano metal heat insulation film with low light reflection rate and low light transmittance and preparation method thereof
CN111909574A (en) * 2019-05-10 2020-11-10 南亚塑胶工业股份有限公司 Energy-saving film structure
CN112210280A (en) * 2019-07-09 2021-01-12 波音公司 Paint for ultraviolet sterilization
CN112659696A (en) * 2019-10-15 2021-04-16 南亚塑胶工业股份有限公司 Heat-insulating energy-saving film
CN114989716A (en) * 2022-07-08 2022-09-02 广东本研新材料科技有限公司 Light-resistant coating composition for nail polish gel bottle surface, nail polish gel bottle and preparation method of nail polish gel bottle
CN117210151A (en) * 2023-09-12 2023-12-12 精一门(常州)光学薄膜有限公司 Blue fog-free tear-resistant automobile energy-saving film and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104149433A (en) * 2014-08-08 2014-11-19 常州山由帝杉防护材料制造有限公司 Ultraviolet-blocking window film
CN104275890A (en) * 2013-07-03 2015-01-14 上海追光科技有限公司 High-performance nano-aluminum-molybdenum trioxide composite heat insulation film and making method thereof
CN105524563A (en) * 2014-09-30 2016-04-27 湖北航天化学技术研究所 Blue-light-barrier anti-dazzle optical film and preparation method therefor
CN106183148A (en) * 2016-08-30 2016-12-07 常州山由帝杉防护材料制造有限公司 Nano ceramics heat-insulation and heat-preservation fenestrated membrane
CN106218172A (en) * 2016-08-30 2016-12-14 常州山由帝杉防护材料制造有限公司 Photochromic fenestrated membrane
CN206953702U (en) * 2017-03-07 2018-02-02 苏州今蓝纳米科技有限公司 Full ultraviolet-resistant thermal isolation film

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104275890A (en) * 2013-07-03 2015-01-14 上海追光科技有限公司 High-performance nano-aluminum-molybdenum trioxide composite heat insulation film and making method thereof
CN104149433A (en) * 2014-08-08 2014-11-19 常州山由帝杉防护材料制造有限公司 Ultraviolet-blocking window film
CN105524563A (en) * 2014-09-30 2016-04-27 湖北航天化学技术研究所 Blue-light-barrier anti-dazzle optical film and preparation method therefor
CN106183148A (en) * 2016-08-30 2016-12-07 常州山由帝杉防护材料制造有限公司 Nano ceramics heat-insulation and heat-preservation fenestrated membrane
CN106218172A (en) * 2016-08-30 2016-12-14 常州山由帝杉防护材料制造有限公司 Photochromic fenestrated membrane
CN206953702U (en) * 2017-03-07 2018-02-02 苏州今蓝纳米科技有限公司 Full ultraviolet-resistant thermal isolation film

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王国建等: "《功能高分子材料》", 31 August 2006, 上海：华东理工大学出版社 *

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108167777A (en) * 2017-12-28 2018-06-15 江苏远洋车灯有限公司 A kind of vehicle lamp housing antiultraviolet pad pasting
CN108481869A (en) * 2018-03-15 2018-09-04 上海际光薄膜科技有限公司 A kind of fire-retardant thermal-insulation window film
CN110760273A (en) * 2018-07-27 2020-02-07 苏州今蓝纳米科技有限公司 Single-layer low-transmittance inorganic nano heat insulation film with high weather resistance and high definition and preparation method thereof
CN110760273B (en) * 2018-07-27 2021-12-21 苏州今蓝纳米科技有限公司 Single-layer low-transmittance inorganic nano heat insulation film with high weather resistance and high definition and preparation method thereof
CN110760274A (en) * 2018-07-27 2020-02-07 苏州今蓝纳米科技有限公司 Nano metal heat insulation film with low light reflection rate and low light transmittance and preparation method thereof
CN109865651A (en) * 2019-02-22 2019-06-11 上海浩驰科技股份有限公司 A kind of PET optics primary colors functional membrane and its application
CN109777314A (en) * 2019-03-06 2019-05-21 常州山由帝杉防护材料制造有限公司 A kind of outer patch building fenestrated membrane and preparation method thereof
CN111909574A (en) * 2019-05-10 2020-11-10 南亚塑胶工业股份有限公司 Energy-saving film structure
CN112210280A (en) * 2019-07-09 2021-01-12 波音公司 Paint for ultraviolet sterilization
EP3763790A1 (en) * 2019-07-09 2021-01-13 The Boeing Company Coatings for sterilization with uv light
EP4342953A1 (en) * 2019-07-09 2024-03-27 The Boeing Company Coatings for sterilization with uv light
CN112659696A (en) * 2019-10-15 2021-04-16 南亚塑胶工业股份有限公司 Heat-insulating energy-saving film
CN110588121A (en) * 2019-10-19 2019-12-20 浙江和顺新材料有限公司 Self-healing heat-insulation heat-preservation polyester film and preparation method thereof
CN114989716A (en) * 2022-07-08 2022-09-02 广东本研新材料科技有限公司 Light-resistant coating composition for nail polish gel bottle surface, nail polish gel bottle and preparation method of nail polish gel bottle
CN117210151A (en) * 2023-09-12 2023-12-12 精一门(常州)光学薄膜有限公司 Blue fog-free tear-resistant automobile energy-saving film and preparation method thereof

Also Published As

Publication number Publication date
CN106956486B (en) 2020-07-17

Similar Documents

Publication Publication Date Title
CN106956486A (en) Thermal isolation film with high ultraviolet-resistant performance and preparation method thereof
CN102918093B (en) Silicone-based material
CN102702992B (en) Nano functional film and preparation method thereof
CN111607976A (en) Radiation refrigeration coating and application thereof, radiation refrigeration coating and textile
CN103930804A (en) Multiple sequenced daylight redirecting layers
CN108430769A (en) Acrylic compounds Pioloform, polyvinyl acetal film including the second layer
CN111361183A (en) Ultraviolet-resistant heat-insulating inorganic nano solar film and preparation method thereof
CN106046883A (en) Light absorption reflective paint and film adopting same
JP2015105328A (en) Transparent resin composition, coating film, and heat ray shielding film
CN201566187U (en) Uvioresistant color protecting scrapping resistance window film
CN105295757A (en) Near-infrared absorption film filter and preparation method thereof
CN201566186U (en) Wear-resistant weather-resistant window film
KR101488867B1 (en) Energy-saving type translucent glass coating composition and translucent energy-saving type glass
CN201428905Y (en) Thermal-insulation sheet
CN206953702U (en) Full ultraviolet-resistant thermal isolation film
CN106739412B (en) A kind of production method of intelligent light-controlled thermal-insulation window film
CN105061794A (en) Eye-protective automobile adhesive film and preparation method thereof
CN202986257U (en) Novel heat insulation ceramic window film
CN201784208U (en) Ultraviolet-resistant, anti-scratching window film
KR20110032677A (en) Heat and infrared ray cutting film
CN102936432B (en) A kind of infrared rays shading composition and its preparation method and application
CN112940632B (en) Prevent visible light shortwave damage window membrane
JP2015104865A (en) Heat ray shielding film, and heat ray shielding film with separator/tacky adhesive layer
CN212269961U (en) Multifunctional automobile skylight film
JP4348872B2 (en) Structure having a laminate and a visible light absorbing film, and visible light absorbing ink

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant