CN106947551A - A kind of alcohol-based fuel - Google Patents

A kind of alcohol-based fuel Download PDF

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Publication number
CN106947551A
CN106947551A CN201710321303.7A CN201710321303A CN106947551A CN 106947551 A CN106947551 A CN 106947551A CN 201710321303 A CN201710321303 A CN 201710321303A CN 106947551 A CN106947551 A CN 106947551A
Authority
CN
China
Prior art keywords
alcohol
based fuel
cosolvent
fuel
calorific value
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710321303.7A
Other languages
Chinese (zh)
Inventor
张西强
李忠海
魏立刚
孔令旭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Gold Jingda New Energy Polytron Technologies Inc
Original Assignee
Hebei Gold Jingda New Energy Polytron Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hebei Gold Jingda New Energy Polytron Technologies Inc filed Critical Hebei Gold Jingda New Energy Polytron Technologies Inc
Priority to CN201710321303.7A priority Critical patent/CN106947551A/en
Publication of CN106947551A publication Critical patent/CN106947551A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses a kind of alcohol-based fuel, it is related to clean energy resource field.The present invention stands not stratified, it is characterised in that:It is made according to following materials by weight percentage is well mixed:Methanol 45 55%;C9 25 30%;Cosolvent 15 30%.Contain C9, the full name C9 aromatics of C9 (C9 aromatics) in the alcohol-based fuel of the present invention;Refer mainly to the aromatic fraction containing nine carbon atoms of catalytic reforming and cracking ethylene preparation by-product.It is because C/Hratio is high and has higher calorific value.So C9 plays a part of increase heat energy in the case of alcohol-based fuel is clean-burning, improves calorific value.And contain cosolvent in alcohol-based fuel.Cosolvent is a kind of while having the material of close hydroxyl pole and close C-H bond, thus can and the material such as methanol, C9 dissolve each other to form co-melting body, prevent the layering of different class I liquid Is, the purpose dissolved each other played in the present invention.The calorific value of fuel can be increased substantially, improves combustibility.

Description

A kind of alcohol-based fuel
Technical field
The present invention relates to clean energy resource field.Specifically related to a kind of alcohol-based fuel.
Background technology
Alcohol-based fuel is a kind of novel energy grown up in recent years.It is more more environmentally friendly than coal, than petroleum based fuels oil more It is economical.As a kind of novel energy, the national standard that alcohol-based fuel is performed at present is《Alcohol radical liquid fuel GB1666-1996》. Environmental Protection Department letter on December 24th, 2015 (ring letter [2015] 319)《Definitely problem is performed on alcohol-based fuel boiler to answer Letter》In, it is proposed that by the boiler reference of alcohol-based fuel《Emission standard of air pollutants for boilers》(GB13271-2014) intermediate fuel oil pot The emission control of stove requires to perform.Alcohol-based fuel is limited due to component calorific value, and the regulation one-levels of GB1666-1996 are 21000kj/ Kg, two grades are 16750kj/kg, using fine in domestic fuel, for industrial use especially heat conducting oil boiler then with respect to calorific value It is relatively low.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of alcohol-based fuel, it is intended to solve alcohol-based fuel in combustion process The problem of middle calorific value can not meet particular requirement.High heating value component and co-solvent component are added in methanol fuel, can be significantly The calorific value of fuel is improved, improves combustibility.
In order to solve the above technical problems, the technical solution used in the present invention is:A kind of alcohol-based fuel, its stand regardless of Layer, it is characterised in that:It is made according to following materials by weight percentage is well mixed:
Methanol 45-55%;
C9 25-30%;
Cosolvent 15-30%.
Further technical scheme is that the methanol water content is not more than 0.1%.
Further technical scheme is that the indices index of the C9 is satisfied by alcohol-based fuel GB16663- 1996 requirement.
Further technical scheme is that the indices index of the cosolvent is satisfied by alcohol-based fuel GB16663- 1996 requirement.
Further technical scheme is also resided in, and the cosolvent is octanol.
It is using the beneficial effect produced by above-mentioned technical proposal:Contain C9, the full names of C9 in the alcohol-based fuel of the present invention C9 aromatic (C9aromatics);Refer mainly to the aromatic fraction containing nine carbon atoms of catalytic reforming and cracking ethylene preparation by-product. It is because C/Hratio is high and has higher calorific value.So C9 played in the case of alcohol-based fuel is clean-burning increase heat energy, Improve the effect of calorific value.And contain cosolvent in alcohol-based fuel.Cosolvent is a kind of while having close hydroxyl pole and close carbon-hydrogen The material of key, thus can and the material such as methanol, C9 dissolve each other to form co-melting body, prevent the layering of different class I liquid Is, in the present invention Play the purpose dissolved each other.The calorific value of fuel can be increased substantially, improves combustibility.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common The every other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model that the present invention is protected Enclose.
Many details are elaborated in the following description to fully understand the present invention, but the present invention can be with It is different from other manner described here using other to implement, those skilled in the art can be without prejudice to intension of the present invention In the case of do similar popularization, therefore the present invention is not limited by following public specific embodiment.
The invention provides a kind of liquid proportion scheme available for alcohol-based fuel.It is by weight percentage by a following group Divide mixing composition:
Methanol 45-55%;
C9 25-30%;
Cosolvent 15-30%;
This alcohol-based fuel is well mixed, and not stratified in the case of standing, alcohol-based fuel is homogeneous everywhere in container.
Wherein, methanol, its water content (percentage by weight) is not more than 0.1%.
C9, the index such as its mechanical admixture, pH value, sulfur content is satisfied by alcohol-based fuel GB16663-1996 requirement.
Cosolvent, the index such as its mechanical admixture, pH value, sulfur content is satisfied by alcohol-based fuel GB16663-1996 requirement.
Contain cosolvent in the alcohol-based fuel of the present invention.Cosolvent is a kind of while having close hydroxyl pole and close carbon-hydrogen link Material, therefore can and the material such as methanol, C9 dissolve each other to form co-melting body, prevent the layering of different class I liquid Is, rise in the present invention To the purpose dissolved each other.
Embodiment 1:
1) C9 and cosolvent are detected on request, determine that the indexs such as its mechanical admixture, pH value, sulfur content, nitrogen oxides are full Sufficient alcohol-based fuel GB16663-1996 requirement.
2) 100g alcohol-based fuels are prepared, are obtained according to following components order and content mixing (stirring at room temperature) Alcohol-based fuel.
Methanol 55g;
C9 25g;
Octanol 20g;
Mixing liquid in graduated cylinder is stirred at room temperature, is well mixed alcohol-based fuel, not stratified in the case of standing, alcohol Base fuel is homogeneous everywhere in container.
Embodiment 2:
1) C9 and octanol are detected on request, determine that the indexs such as its mechanical admixture, pH value, sulfur content, nitrogen oxides are satisfied by Alcohol-based fuel GB16663-1996 requirement.
2) 100g alcohol-based fuels are prepared, are obtained according to following components order and content mixing (stirring at room temperature) Alcohol-based fuel.
Methanol 50g;
C9 30g;
Octanol 20g;
Mixing liquid in graduated cylinder is stirred at room temperature, is well mixed alcohol-based fuel, not stratified in the case of standing, alcohol Base fuel is homogeneous everywhere in container.
Embodiment 3:
1) C9 and octanol are detected on request, determine that the indexs such as its mechanical admixture, pH value, sulfur content, nitrogen oxides are satisfied by Alcohol-based fuel GB16663-1996 requirement.
2) 100g alcohol-based fuels are prepared, are obtained according to following components order and content mixing (stirring at room temperature) Alcohol-based fuel.
Methanol 45g;
C9 30g;
Octanol 25g;
Mixing liquid in graduated cylinder is stirred at room temperature, is well mixed alcohol-based fuel, not stratified in the case of standing, alcohol Base fuel is homogeneous everywhere in container.
Detect calorific value (by automatic calorimetric respectively the alcohol-based fuel matched somebody with somebody according to embodiment 1, embodiment 2, embodiment 3 Instrument, GB384-1981), obtain relevant experimental data as shown in the table:
It can be obtained by experiment:According to a kind of liquid proportion scheme available for alcohol-based fuel of the present invention, it can adjust It is more than 7000cal/g alcohol-based fuel with calorific value, increases substantially the calorific value of fuel, improve combustibility, solves alcohol-based fuel The problem of calorific value can not meet particular requirement in combustion.

Claims (5)

1. a kind of alcohol-based fuel, its standing is not stratified, it is characterised in that:According to the well mixed system of following materials by weight percentage Into:
Methanol 45-55%;
C9 25-30%;
Cosolvent 15-30%.
2. a kind of alcohol-based fuel according to claim 1, it is characterised in that:The methanol water content is not more than 0.1%.
3. a kind of alcohol-based fuel according to claim 1, it is characterised in that:The indices index of the C9 is satisfied by Meet alcohol-based fuel GB16663-1996 requirement.
4. a kind of alcohol-based fuel according to claim 1, it is characterised in that:The indices index of the cosolvent is full Sufficient alcohol-based fuel GB16663-1996 requirement.
5. a kind of alcohol-based fuel according to claim 1, it is characterised in that:The cosolvent is octanol.
CN201710321303.7A 2017-05-09 2017-05-09 A kind of alcohol-based fuel Pending CN106947551A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710321303.7A CN106947551A (en) 2017-05-09 2017-05-09 A kind of alcohol-based fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710321303.7A CN106947551A (en) 2017-05-09 2017-05-09 A kind of alcohol-based fuel

Publications (1)

Publication Number Publication Date
CN106947551A true CN106947551A (en) 2017-07-14

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Country Status (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108179036A (en) * 2017-12-28 2018-06-19 毕超箭 A kind of clean fuel and preparation method
CN108707483A (en) * 2018-06-11 2018-10-26 河南零排方企业营销策划有限公司 A kind of high-capacity environment-protecting clean biometric alcohol-oil fuel and preparation method thereof
CN110684565A (en) * 2018-07-04 2020-01-14 白凤臣 High-calorific-value alcohol-based fuel for boiler

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1294176A (en) * 1999-10-26 2001-05-09 肖贵和 Alcohol-base liquid fuel
CN101412933A (en) * 2007-10-15 2009-04-22 李隆梅 Broadspectrum environment-protective alcohol-base liquid fuel and preparation thereof
CN102154039A (en) * 2011-03-16 2011-08-17 平煤蓝天化工股份有限公司 High-clear alcohol-based fuel oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1294176A (en) * 1999-10-26 2001-05-09 肖贵和 Alcohol-base liquid fuel
CN101412933A (en) * 2007-10-15 2009-04-22 李隆梅 Broadspectrum environment-protective alcohol-base liquid fuel and preparation thereof
CN102154039A (en) * 2011-03-16 2011-08-17 平煤蓝天化工股份有限公司 High-clear alcohol-based fuel oil

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张永芬等: "《有机化学》", 31 December 2012, 北京理工大学出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108179036A (en) * 2017-12-28 2018-06-19 毕超箭 A kind of clean fuel and preparation method
CN108707483A (en) * 2018-06-11 2018-10-26 河南零排方企业营销策划有限公司 A kind of high-capacity environment-protecting clean biometric alcohol-oil fuel and preparation method thereof
CN110684565A (en) * 2018-07-04 2020-01-14 白凤臣 High-calorific-value alcohol-based fuel for boiler

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Application publication date: 20170714