CN106883815A - One kind can meet beer bottle and reclaim wash bottle quickly de- target Labeling Adhesive with Super and preparation method - Google Patents
One kind can meet beer bottle and reclaim wash bottle quickly de- target Labeling Adhesive with Super and preparation method Download PDFInfo
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- CN106883815A CN106883815A CN201710158495.4A CN201710158495A CN106883815A CN 106883815 A CN106883815 A CN 106883815A CN 201710158495 A CN201710158495 A CN 201710158495A CN 106883815 A CN106883815 A CN 106883815A
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- China
- Prior art keywords
- parts
- mark
- bottle
- super
- labeling adhesive
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J189/00—Adhesives based on proteins; Adhesives based on derivatives thereof
- C09J189/005—Casein
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
- C08L2205/20—Hollow spheres
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Can meet beer bottle the invention discloses one kind and reclaim wash bottle quickly de- target Labeling Adhesive with Super and preparation method thereof, in parts by weight, be made up of following component：48 52 parts of water, 46 parts of urea, 15 17 parts of casein, 0.5 1 parts of defoamer, 0.5 1 parts of preservative, 12 parts of ammoniacal liquor, 57 parts of oxidized starch, 24 parts of polyvinyl alcohol, 0.5 1.5 parts of crosslinking agent, 5 20 parts of the hollow polymer of acrylate, 15 parts of montmorillonite.The present invention, 50000 bottles/hour of viscous mark at a high speed can not only met, do not get rid of mark, not alice, cull easy cleaning, without chemical contamination, while frozen water immersion does not take off the technical requirements such as mark in 15 days, quick de- mark treatment 10 15 seconds can also be done, beer bottle after being processed through quick de- mark will not pollute bottle-washing water into bottle washing machine, reduce the waste of water resource, and the aluminium mark and paper mark after de- mark are also used as Resource recovery recycling.
Description
Technical field
Can meet beer bottle the present invention relates to one kind and reclaim quickly de- target Labeling Adhesive with Super and preparation method thereof.
Background technology
Beer grand is in the world current rule as the explanation of the correlated identities and commodity that meet product, to reduce carbon
It is also the conventional way of industry that discharge beer empty bottle is recycled, and current wash bottle method is that returnable bottle is delivered directly into wash bottle
Machine is cleaned, and in order to meet de- mark and sterilized requirement, the technical scheme for being given is 2.5% sodium hydrate aqueous solution, 85 to bottle washing machine
At a temperature of DEG C, empty bottle enters this environment, and aluminium foil rotating savings is reacted away generation tetrahydroxy sodium aluminate, the ink on aluminium mark surface quickly
Whole levitatings, some can be salvaged after paper mark comes off, but the ink on surface also can levitating.Although improving a part now
Protect the mark of ink, but little helped to the pollution of whole bottle washing machine, using the Labeling Adhesive with Super of prior art after, after the de- mark of bottle washing machine,
Some is rotted in water paper rotating savings, and the ink being printed on two kinds of trade marks is floated on the water surface, in the presence of temperature and alkali
Bottle-washing water is polluted, substantial amounts of water resource waste is caused, is unfavorable for environmental protection, increased water pollution processing load and cost.
The content of the invention
For above-mentioned problem, the present invention is intended to provide one kind can meet beer bottle reclaims quickly de- target Labeling Adhesive with Super
And preparation method thereof, the performance that the quick de- mark glue can not only reach existing Labeling Adhesive with Super can also realize quick de- mark, and
After Labeling Adhesive with Super of the invention, beer bottle does not result in substantial amounts of water resource waste and pollution when wash bottle is reclaimed, beneficial to ring
Protect.
To achieve these goals, the technical solution adopted in the present invention is as follows：One kind can meet beer bottle and reclaim wash bottle
Quickly de- target Labeling Adhesive with Super, in parts by weight, is made up of following component：Water 48-52 parts, urea 4-6 parts, casein 15-17 parts,
Defoamer 0.5-1 parts, preservative 0.5-1 parts, ammoniacal liquor 1-2 parts, oxidized starch 5-7 parts, polyvinyl alcohol 2-4 parts, crosslinking agent 0.5-
1.5 parts, hollow polymer 5-20 parts of acrylate, montmorillonite 1-5 parts.
Described defoamer is polysiloxanes, and preservative is OIT, and crosslinking agent is borax.
Preparation method of the invention, comprises the following steps：
1）, by water 48-52 parts, urea 4-6 parts is added to reactor, and turn on agitator is stirred and is heated to 75 DEG C, treats that urea is complete
After CL, casein 15-17 parts is gradually added into, is stirred in charging, be made glue；
2）, keep 75 DEG C of temperature in the reactor under conditions of, to adding 0.5-1 parts of polysiloxane defoaming agent, different thiophene in glue
0.5-1 parts of oxazoline ketone preservative and ammoniacal liquor 1-2 part, after the pH value of adjustment glue to 7.8-8.2, add 5-7 parts of oxidized starch,
2-4 parts of polyvinyl alcohol and 0.5-1.5 parts of borax crosslinkers, stirring form material；
3）, the material in reactor is gradually cooled to 40 DEG C after, add 5-20 parts of hollow polymer and 1-5 of acrylate
Part montmorillonite, is Labeling Adhesive with Super after stirring；
4）, blowing packaging.
The step 3）In material cool down with the speed cooling down of 1.5-2 DEG C/min.
The present invention：50000 bottles/hour of viscous mark at a high speed can not only met, mark, not alice, cull easy cleaning, ice are not being got rid of
While water soaks 15 days and do not take off the technical requirements such as mark, wash bottle can also be done and quickly take off mark treatment, after quick de- mark treatment
Beer bottle will not pollute bottle-washing water into bottle washing machine, reduce the waste of water resource, and the aluminium mark and paper mark after de- mark can also be made
For Resource recovery is recycled.
Specific embodiment
One kind can meet beer bottle and reclaim wash bottle quickly de- target Labeling Adhesive with Super, in parts by weight, be made up of following component：Water
48-52 parts, urea 4-6 parts, casein 15-17 parts, defoamer 0.5-1 parts, preservative 0.5-1 parts, ammoniacal liquor 1-2 parts, oxidation is formed sediment
Powder 5-7 parts, polyvinyl alcohol 2-4 parts, crosslinking agent 0.5-1.5 parts, hollow polymer 5-20 parts of acrylate, montmorillonite 1-5 parts.
Embodiment 1：
One kind can meet beer bottle and reclaim wash bottle quickly de- target Labeling Adhesive with Super, and the Labeling Adhesive with Super includes water 50 according to parts by weight
Part, 6 parts of urea, 16 parts of casein, 0.5 part of polysiloxane defoaming agent, 0.8 part of OIT preservative, 1 part of ammoniacal liquor, oxidation
7 parts of starch, 2 parts of polyvinyl alcohol, 1 part of borax crosslinkers, 12 parts of the hollow polymer of acrylate, 3 parts of montmorillonite.
Above-mentioned Labeling Adhesive with Super is specifically to be prepared from by following several steps：
1st, by 50 parts of water, 6 parts of urea is added to reactor, and turn on agitator is stirred and is heated to 75 DEG C, treats that urea is completely dissolved
Afterwards, 16 parts of casein is gradually added into, is stirred in charging, be made glue；
2nd, then to 1 part of 0.5 part of polysiloxane defoaming agent of addition, 0.8 part of OIT preservative and ammoniacal liquor in reactor,
The pH value of glue is adjusted after 8,1 part of 7 parts of oxidized starch, 2 parts of polyvinyl alcohol and borax crosslinkers, stirring reaction are added；
3rd, step 2 reaction after the completion of, after the material in reactor is gradually cooled into 40 DEG C, material cooling be with 1.5-2 DEG C/
The cooling rate of min cools, and adds 3 parts of 12 parts of hollow polymer and the montmorillonite of acrylate, stirs；
4th, blowing packaging.
Embodiment 2：
One kind can meet beer bottle and reclaim wash bottle quickly de- target Labeling Adhesive with Super, and the Labeling Adhesive with Super includes water 48 according to parts by weight
Part, 4 parts of urea, 17 parts of casein, 0.8 part of polysiloxane defoaming agent, 1 part of OIT preservative, 2 parts of ammoniacal liquor, 6 parts of oxidations
Starch, 3 parts of polyvinyl alcohol, 0.5 part of borax crosslinkers, 20 parts of the hollow polymer of acrylate, 1 part of montmorillonite；
1st, by 48 parts of water, 4 parts of urea is added to reactor, and turn on agitator is stirred and is heated to 75 DEG C, treats that urea is completely dissolved
Afterwards, 17 parts of casein is gradually added into, is stirred in charging, be made glue；
2nd, then to 2 parts of 0.8 part of polysiloxane defoaming agent of addition, 0.5 part of OIT preservative and ammoniacal liquor in reactor,
The pH value of glue is adjusted after 7.8,6 parts of oxidized starch are added, 3 parts of polyvinyl alcohol and 0.5 part of borax crosslinkers, stirring are added
Reaction；
3rd, step 2 reaction after the completion of, after the material in reactor is gradually cooled into 40 DEG C, material cooling be with 1.5-2 DEG C/
The cooling rate of min is cooled, and the hollow polymer of 20 parts of acrylate of addition and 1 part of montmorillonite are reacted, and are stirred；
4th, blowing and packaging.
Embodiment 3：
One kind can meet beer bottle and reclaim wash bottle quickly de- target Labeling Adhesive with Super, and the Labeling Adhesive with Super includes water 52 according to parts by weight
Part, 5 parts of urea, 15 parts of casein, 1 part of polysiloxane defoaming agent, 0.5 part of OIT preservative, 1.5 parts of ammoniacal liquor, 5 parts of oxygen
Change starch, 4 parts of polyvinyl alcohol, 1.5 parts of borax crosslinkers, 5 parts of the hollow polymer of acrylate, 5 parts of montmorillonite.
1）By 52 parts of water, 5 parts of urea is added to reactor, and turn on agitator is stirred and is heated to 75 DEG C, treats that urea is complete
After dissolving, 15 parts of casein is gradually added into, is stirred in charging, be made glue；
2nd, then to 1.5 parts of 1 part of polysiloxane defoaming agent of addition, 0.5 part of OIT preservative and ammoniacal liquor in reactor,
The pH value of glue is adjusted after 8.2,5 parts of oxidized starch are added, 4 parts of polyvinyl alcohol and 1.5 parts of borax crosslinkers, stirring are added
Reaction；
3rd, step（2）After the completion of reaction, after the material in reactor is gradually cooled into 40 DEG C, material cooling be with 1.5-2 DEG C/
The cooling rate of min is cooled, and the hollow polymer of 5 parts of acrylate of addition and 5 parts of montmorillonites are reacted, and are stirred；
4th, blowing and packaging.
The present invention is reclaimed in wash bottle groove for beer bottle and is mixed to form the aqueous solution with water, can be with a temperature of 80-98 DEG C
Realize quick de- mark.
The quick de- mark test data of embodiment 1-4：
| Embodiment | Beer bottle reclaims wash bottle groove water temperature DEG C | Between de- timestamp（Second） |
| 1 | 80 | 35 |
| 2 | 85 | 30 |
| 3 | 90 | 20 |
| 4 | 98 | 10 |
General principle of the invention, principal character and advantages of the present invention has been shown and described above.The technical staff of the industry
It should be appreciated that the present invention is not limited to the above embodiments, the present invention is simply illustrated described in above-described embodiment and specification
Principle, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these change and
Improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appending claims and its equivalent
Thing is defined.
Claims (4)
1. one kind can meet beer bottle recovery wash bottle quickly de- target Labeling Adhesive with Super, in parts by weight, be made up of following component：Water
48-52 parts, urea 4-6 parts, casein 15-17 parts, defoamer 0.5-1 parts, preservative 0.5-1 parts, ammoniacal liquor 1-2 parts, oxidation is formed sediment
Powder 5-7 parts, polyvinyl alcohol 2-4 parts, crosslinking agent 0.5-1.5 parts, hollow polymer 5-20 parts of acrylate, montmorillonite 1-5 parts.
2. one kind according to claim 1 can meet beer bottle recovery wash bottle quickly de- target Labeling Adhesive with Super and its preparation side
Method, it is characterised in that：Described defoamer is polysiloxanes, and preservative is OIT, and crosslinking agent is borax.
3. it is a kind of it is according to claim 1 can meet beer bottle and reclaim the preparation method that wash bottle quickly takes off target Labeling Adhesive with Super,
In parts by weight, it is characterised in that：Comprise the following steps：
1）, by water 48-52 parts, urea 4-6 parts is added to reactor, and turn on agitator is stirred and is heated to 75 DEG C, treats that urea is complete
After CL, casein 15-17 parts is gradually added into, is stirred in charging, be made glue；
2）, in glue in reactor add 0.5-1 parts of polysiloxane defoaming agent, 0.5-1 parts of OIT preservative and
, the pH value of glue is adjusted after 7.8-8.2, add 5-7 parts of oxidized starch, 2-4 parts of polyvinyl alcohol and 0.5-1.5 by ammoniacal liquor 1-2 parts
Part borax crosslinkers, stirring forms material；
3）, the material in reactor is gradually cooled to 40 DEG C after, add 5-20 parts of hollow polymer and 1-5 part of acrylate
Montmorillonite, is Labeling Adhesive with Super after stirring；
4）, blowing and packaging.
4. a kind of according to claim 3 can meet beer bottle and reclaim the preparation method that wash bottle quickly takes off target Labeling Adhesive with Super,
It is characterized in that：The step 3）In material cooling cooled with the speed of 1.5-2 DEG C/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710158495.4A CN106883815A (en) | 2017-03-17 | 2017-03-17 | One kind can meet beer bottle and reclaim wash bottle quickly de- target Labeling Adhesive with Super and preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710158495.4A CN106883815A (en) | 2017-03-17 | 2017-03-17 | One kind can meet beer bottle and reclaim wash bottle quickly de- target Labeling Adhesive with Super and preparation method |
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| Publication Number | Publication Date |
|---|---|
| CN106883815A true CN106883815A (en) | 2017-06-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710158495.4A Pending CN106883815A (en) | 2017-03-17 | 2017-03-17 | One kind can meet beer bottle and reclaim wash bottle quickly de- target Labeling Adhesive with Super and preparation method |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107746686A (en) * | 2017-10-31 | 2018-03-02 | 温州市稳泰轻化科技有限公司 | A kind of efficiently Beer rubberizing and preparation method thereof |
| CN109251725A (en) * | 2018-09-21 | 2019-01-22 | 佛山市森昂生物科技有限公司 | A kind of trademark adhesive and preparation method thereof |
| CN111471430A (en) * | 2020-05-13 | 2020-07-31 | 中山金诚粘合剂有限公司 | Labeling glue for glass bottle and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1212985A (en) * | 1997-09-29 | 1999-04-07 | 中国科学院福建物质结构研究所 | Water-resistant adhesive for label |
| CN103242734A (en) * | 2013-05-15 | 2013-08-14 | 丹阳市宏森仪表化工有限公司 | Acrylic acid hybrid emulsion capable of preventing printing ink from falling from beer trademark in bottle washing |
-
2017
- 2017-03-17 CN CN201710158495.4A patent/CN106883815A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1212985A (en) * | 1997-09-29 | 1999-04-07 | 中国科学院福建物质结构研究所 | Water-resistant adhesive for label |
| CN103242734A (en) * | 2013-05-15 | 2013-08-14 | 丹阳市宏森仪表化工有限公司 | Acrylic acid hybrid emulsion capable of preventing printing ink from falling from beer trademark in bottle washing |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107746686A (en) * | 2017-10-31 | 2018-03-02 | 温州市稳泰轻化科技有限公司 | A kind of efficiently Beer rubberizing and preparation method thereof |
| CN109251725A (en) * | 2018-09-21 | 2019-01-22 | 佛山市森昂生物科技有限公司 | A kind of trademark adhesive and preparation method thereof |
| CN111471430A (en) * | 2020-05-13 | 2020-07-31 | 中山金诚粘合剂有限公司 | Labeling glue for glass bottle and preparation method thereof |
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Application publication date: 20170623 |