CN106861340B - Multifunctional air purifying device - Google Patents

Multifunctional air purifying device Download PDF

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CN106861340B
CN106861340B CN201710177764.1A CN201710177764A CN106861340B CN 106861340 B CN106861340 B CN 106861340B CN 201710177764 A CN201710177764 A CN 201710177764A CN 106861340 B CN106861340 B CN 106861340B
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CN106861340A (en
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陈玉洁
李华
郭益平
段华南
刘河洲
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Shanghai Jiao Tong University
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
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Abstract

本发明涉及一种多功能空气净化装置,该装置包括依序排列的灰尘颗粒充电区域(4)、预过滤网(2)、强平行电场集尘部分(1)和光催化分解层(3),所述的灰尘颗粒充电区域(4)由电晕极(5)和带孔道金属板(8)组成;所述的强平行电场集尘部分(1)为电极层(7)与网格状塑料板(6)交替排布构成的平行强电场;所述的光催化分解层(3)设置在强平行电场集尘部分(1)后面。与现有技术相比,本发明装置小巧紧凑,除尘、除菌效率高,石墨烯气凝胶层具有强大的吸附能力且易于官能化,能够有效吸附甲醛等有机污染,而且石墨烯气凝胶的孔隙比表面积大,光触媒的负载量高,且在空气流动中光触媒负载稳定度更高,也能够消除静电集尘过程中产生的臭氧。

The invention relates to a multifunctional air purification device, which comprises a dust particle charging area (4), a pre-filter (2), a strong parallel electric field dust collection part (1) and a photocatalytic decomposition layer (3) arranged in sequence, The dust particle charging area (4) is composed of a corona electrode (5) and a metal plate with holes (8); the strong parallel electric field dust collection part (1) is composed of an electrode layer (7) and a mesh plastic The plates (6) are alternately arranged to form a parallel strong electric field; the photocatalytic decomposition layer (3) is arranged behind the strong parallel electric field dust collection part (1). Compared with the prior art, the device of the present invention is small and compact, has high dust removal and sterilization efficiency, and the graphene airgel layer has strong adsorption capacity and is easy to be functionalized, and can effectively absorb organic pollution such as formaldehyde, and the graphene airgel The pore specific surface area is large, the photocatalyst loading capacity is high, and the photocatalyst loading stability is higher in the air flow, and it can also eliminate the ozone generated during the electrostatic dust collection process.

Description

一种多功能空气净化装置A multifunctional air purification device

技术领域technical field

本发明涉及一种空气净化装置,尤其是涉及一种以负载光触媒的石墨烯气凝胶为光催化分解层的多功能空气净化装置。The invention relates to an air purification device, in particular to a multifunctional air purification device with graphene airgel loaded with photocatalyst as the photocatalytic decomposition layer.

背景技术Background technique

静电除尘技术是一种气体在静电场中电离,与粉尘颗粒相遇,使尘粒带电,再被吸附于集尘板上的除尘方式,其优点包括:(1)除尘装置结构简单,造价低廉,耗电量少;(2)产生的大量空气负离子有助于改善室内空气,使人精神充沛、不易疲劳;(3)可以捕集直径小于0.1μm的灰尘颗粒,能够高效去除空气中的PM2.5污染颗粒。但是传统静电除尘技术的缺陷,限制了其在空气净化设备中的使用效果。Electrostatic dust removal technology is a dust removal method in which gas is ionized in an electrostatic field, meets dust particles, charges the dust particles, and is then adsorbed on the dust collection plate. Its advantages include: (1) The structure of the dust removal device is simple and the cost is low. Low power consumption; (2) The large amount of air negative ions produced can help improve indoor air, making people energetic and less prone to fatigue; (3) It can capture dust particles with a diameter of less than 0.1 μm, and can efficiently remove PM2 in the air. 5 pollution particles. However, the defects of traditional electrostatic precipitating technology limit its application effect in air purification equipment.

静电除尘技术伴随着电晕放电,不可避免地会产生臭氧,有二次污染的潜在危害,而且不适宜净化甲醛等气态有机污染物,杀菌消毒效果也不明显。而光催化技术虽然对颗粒物净化效果不佳,但能够有效去除臭氧和甲醛等气态有机污染物,因此将静电除尘技术与光催化技术结合,是净化装置的重要发展趋势之一。Along with corona discharge, electrostatic dust removal technology will inevitably produce ozone, which has the potential hazard of secondary pollution, and is not suitable for purifying gaseous organic pollutants such as formaldehyde, and the sterilization and disinfection effect is not obvious. Although photocatalytic technology is not effective in purifying particulate matter, it can effectively remove gaseous organic pollutants such as ozone and formaldehyde. Therefore, the combination of electrostatic dust removal technology and photocatalytic technology is one of the important development trends of purification devices.

石墨烯气凝胶材料具有多孔性(>99%)和大比表面积的优点,且极易官能化,能够吸附甲醛等有机污染物。另外当光触媒颗粒均匀负载在石墨烯气凝胶上时,实际参与反应的光触媒与反应物的接触面积大于单纯的光触媒纳米颗粒,气凝胶将纳米颗粒从团聚状态变为分散状态,其负载光触媒的能力高于活性炭,其固定光触媒的能力更远高于将光触媒直接涂覆在电极板的方法。采用负载光触媒的石墨烯气凝胶作为光催化分解层将大大减小层厚,高效吸附有机污染物和分解臭氧。Graphene airgel materials have the advantages of porosity (>99%) and large specific surface area, and are extremely easy to functionalize, capable of adsorbing organic pollutants such as formaldehyde. In addition, when the photocatalyst particles are evenly loaded on the graphene airgel, the contact area between the photocatalyst and the reactant actually participating in the reaction is larger than that of the pure photocatalyst nanoparticle, and the aerogel changes the nanoparticle from the agglomerated state to the dispersed state. The ability of it is higher than that of activated carbon, and its ability to fix photocatalyst is much higher than that of directly coating photocatalyst on the electrode plate. Using graphene airgel loaded with photocatalyst as the photocatalytic decomposition layer will greatly reduce the layer thickness, efficiently adsorb organic pollutants and decompose ozone.

因此综合石墨烯气凝胶负载光触媒纳米颗粒的光催化技术和静电除尘技术的优点,可以解决现有空气净化装置的缺陷,能够真正满足人们对于空气净化的急切需求。Therefore, integrating the advantages of photocatalytic technology and electrostatic precipitating technology of graphene airgel-loaded photocatalyst nanoparticles can solve the defects of existing air purification devices and can truly meet people's urgent needs for air purification.

发明内容Contents of the invention

本发明的目的就是为了克服上述现有技术存在的缺陷而提供一种多功能空气净化装置。The object of the present invention is to provide a multi-functional air cleaning device in order to overcome the above-mentioned defects in the prior art.

本发明的目的可以通过以下技术方案来实现:一种多功能空气净化装置,其特征在于,该装置包括依序排列的灰尘颗粒充电区域、预过滤网、强平行电场集尘部分和光催化分解层,所述的灰尘颗粒充电区域由电晕极和带孔道金属板组成;所述的强平行电场集尘部分为电极层与网格状塑料板交替排布构成的平行强电场;所述的光催化分解层设置在强平行电场集尘部分后面。装置小巧紧凑,除尘、除菌效率高,能够有效吸附甲醛等有机污染,也能够消除静电集尘过程中产生的臭氧。The purpose of the present invention can be achieved through the following technical solutions: a multifunctional air purification device, characterized in that the device includes a dust particle charging area, a pre-filter, a strong parallel electric field dust collection part and a photocatalytic decomposition layer arranged in sequence , the dust particle charging area is composed of a corona electrode and a metal plate with holes; the strong parallel electric field dust collection part is a parallel strong electric field formed by alternating arrangement of electrode layers and grid-like plastic plates; the light The catalytic decomposition layer is arranged behind the strong parallel electric field dust collecting part. The device is small and compact, with high dust removal and sterilization efficiency, can effectively absorb organic pollution such as formaldehyde, and can also eliminate ozone generated during electrostatic dust collection.

所述的电晕极为前端带有整流罩的导电棒。The corona pole is a conductive rod with a fairing at the front end.

所述的电晕极前端的整流罩呈两段式结构:圆筒-圆锥状,圆筒段直径为1-10mm,圆锥段的直径为1-10mm;整流罩使得气流自然避开了电晕电晕区,减少粉尘在电晕极上的吸附沉积。所述的电晕极为带有三角齿发射极触针的细导电棒。所述的发射极长度为1-20mm。发射极的长度小于整流罩的尺寸。电晕发射利用三角形齿尖锐的导电点来实现,为颗粒充电所产生的空气负离子都在发射极触针的电晕中产生。整个电离平面内存在多个电晕极,提高了空气电离效率和集尘速度。The fairing at the front end of the corona pole has a two-stage structure: a cylinder-cone shape, the diameter of the cylinder section is 1-10mm, and the diameter of the cone section is 1-10mm; the fairing makes the airflow naturally avoid the corona The corona area reduces the adsorption and deposition of dust on the corona electrode. The corona pole is a thin conductive rod with a triangular tooth emitter contact pin. The length of the emitter is 1-20mm. The length of the emitter is less than the size of the fairing. The corona emission is realized by using the sharp conductive points of the triangular teeth, and the negative air ions generated by charging the particles are all generated in the corona of the emitter pin. There are multiple corona electrodes in the entire ionization plane, which improves the air ionization efficiency and dust collection speed.

所述的整流罩位于带孔道金属板的孔道金属板的孔道平面中央,带孔道金属板的孔道直径为1-5cm,引导空气定向聚集到电晕极负离子高浓度、激烈碰撞区域。The fairing is positioned at the center of the channel plane of the channel metal plate with the channel metal plate, and the channel diameter of the metal plate with the channel channel is 1-5cm, which guides the air directionally to gather in the high-concentration and violent collision area of the corona pole negative ions.

所述的电晕极有多个,都位于带孔道金属板孔道平面的中央。There are multiple corona electrodes, all of which are located in the center of the hole plane of the metal plate with holes.

所述的预过滤网由胶化棉制成,不仅能够实现对空气中的飘尘或者花粉等物质的吸附,而且胶化棉表面富含AV-990阳离子基团,也能够实现高效杀菌的作用。预过滤网对大颗粒粉尘进行了初步过滤,减少了静电集尘器由于沉积过量灰尘颗粒而产生大量副产物,对空气进行二次污染的几率。The pre-filter is made of gelatinized cotton, which can not only achieve the adsorption of dust or pollen in the air, but also has a high-efficiency sterilization effect because the surface of the gelled cotton is rich in AV-990 cationic groups. The pre-filter screen preliminarily filters the large particle dust, which reduces the probability of secondary pollution of the air due to the large amount of by-products produced by the electrostatic precipitator due to the deposition of excessive dust particles.

所述的预过滤网的深度为0.2-2cm之间。The depth of the pre-filter is between 0.2-2cm.

所述的强平行电场集尘部分以石墨或石墨烯导电层为电极层,以网格状塑料板为气体通道,电极层与网格状塑料板交替排布,电极层通高压电后构成平行强电场集尘,能够实现对空气中20微米以下的粉尘,尤其是PM2.5的吸附。The strong parallel electric field dust collection part uses graphite or graphene conductive layer as the electrode layer, and uses grid-shaped plastic plates as gas channels. The electrode layers and grid-like plastic plates are arranged alternately, and the electrode layers are formed after high voltage The parallel strong electric field dust collection can realize the adsorption of dust below 20 microns in the air, especially PM2.5.

所述的网格状塑料板的高度为1-5mm,塑料板是不导电的,密集的网格提高了过滤效率。The height of the grid-shaped plastic plate is 1-5 mm, the plastic plate is non-conductive, and the dense grid improves the filtration efficiency.

所述的光催化分解层为负载光触媒的石墨烯气凝胶,气凝胶的孔隙直径在0.1~100微米,光触媒材料包括纳米二氧化钛颗粒或纳米钒酸铋颗粒。The photocatalytic decomposition layer is graphene airgel loaded with photocatalyst, the airgel has a pore diameter of 0.1-100 microns, and the photocatalyst material includes nano titanium dioxide particles or nano bismuth vanadate particles.

所述的光催化分解层厚度为0.2-10mm。高孔隙率的石墨烯气凝胶能够实现对光触媒纳米颗粒的高负载,高效分解臭氧,进一步杀灭多种细菌。同时由于石墨烯气凝胶中通过官能化,可含有大量氨基、羟基等极性基团,也能够吸附甲醛、甲苯等有机污染物。The thickness of the photocatalytic decomposition layer is 0.2-10mm. Graphene airgel with high porosity can achieve high loading of photocatalyst nanoparticles, efficiently decompose ozone, and further kill a variety of bacteria. At the same time, due to the functionalization of graphene airgel, it can contain a large number of polar groups such as amino groups and hydroxyl groups, and can also adsorb organic pollutants such as formaldehyde and toluene.

与现有技术相比,本发明装置小巧紧凑,除尘、除菌效率高,石墨烯气凝胶层具有强大的吸附能力且易于官能化,能够有效吸附甲醛等有机污染,而且石墨烯气凝胶的孔隙比表面积大,光触媒的负载量高,且在空气流动中光触媒负载稳定度更高,也能够消除静电集尘过程中产生的臭氧。Compared with the prior art, the device of the present invention is small and compact, has high dust removal and sterilization efficiency, and the graphene airgel layer has a strong adsorption capacity and is easy to be functionalized, and can effectively absorb organic pollution such as formaldehyde, and the graphene airgel The pore specific surface area is large, the photocatalyst loading capacity is high, and the photocatalyst loading stability is higher in the air flow, and it can also eliminate the ozone generated during the electrostatic dust collection process.

附图说明Description of drawings

图1多功能空气净化装置的架构示意图;Figure 1 is a schematic diagram of the structure of the multifunctional air purification device;

图2平行电场集尘部分正面示意图;Figure 2 is a schematic front view of the parallel electric field dust collection part;

图3石墨烯气凝胶的扫描电镜图片。Figure 3 SEM image of graphene airgel.

具体实施方式Detailed ways

下面通过实施例对本发明进行具体描述。有必要在此指出的是,以下实施例只用于对本发明作进一步说明,不能理解为对本发明保护范围的限制,该领域的专业技术人员根据本发明的内容做出地一些非本质的改进和调整,仍属于本发明的保护范围。The present invention is specifically described below by way of examples. It is necessary to point out that the following examples are only used to further illustrate the present invention, and can not be interpreted as limiting the protection scope of the present invention, some non-essential improvements and improvements made by those skilled in the art according to the contents of the present invention Adjustment still belongs to the protection scope of the present invention.

如图1所示,一种多功能空气净化装置,该装置具有依序排列的灰尘颗粒充电区域4、预过滤网2、强平行电场集尘部分1和光催化分解层3。As shown in Figure 1, a multi-functional air purification device has a dust particle charging area 4, a pre-filter 2, a strong parallel electric field dust collection part 1 and a photocatalytic decomposition layer 3 arranged in sequence.

所述的灰尘颗粒充电区域4由电晕极5和带孔道金属板8组成;所述的电晕极5位于带孔道金属板8的正中间,可以设置多个。电晕极5为前端带有整流罩的导电棒,所述的电晕极5前端的整流罩呈两段式结构:圆锥-圆筒状,圆筒段直径为1-10mm,圆锥段的直径为1-10mm;整流罩位于带孔道金属板8的孔道平面中央,带孔道金属板8的孔道直径为1-5cm。所述的电晕极5为带有三角齿发射极触针的细导电棒,发射极长度为1-20mm。发射极的长度小于整流罩的尺寸。The dust particle charging area 4 is composed of a corona electrode 5 and a metal plate 8 with holes; the corona electrode 5 is located in the middle of the metal plate 8 with holes, and multiple can be provided. The corona pole 5 is a conductive rod with a fairing at the front end, and the fairing at the front end of the corona pole 5 is a two-stage structure: conical-cylindrical, the diameter of the cylindrical section is 1-10mm, and the diameter of the conical section is 1-10mm; the fairing is located in the center of the channel plane of the metal plate 8 with the channel, and the diameter of the channel of the metal plate 8 with the channel is 1-5cm. The corona electrode 5 is a thin conductive rod with a triangular-teeth emitter contact pin, and the length of the emitter is 1-20mm. The length of the emitter is less than the size of the fairing.

所述的预过滤网2由胶化棉制成,深度在0.2-2cm之间,吸附空气中粒径较大的飘尘或者花粉等物质颗粒,对大颗粒粉尘进行初步过滤。The pre-filter 2 is made of gelatinized cotton, with a depth of 0.2-2 cm, which absorbs material particles such as floating dust or pollen with a larger particle size in the air, and performs preliminary filtration of large-particle dust.

如图2所示,所述的强平行电场集尘部分1以石墨或石墨烯导电层为电极层7,以网格状塑料板6为气体通道,电极层7与网格状塑料板6交替排布,电极层7通高压电后构成平行强电场集尘,网格状塑料板6的高度为1-5mm,吸附空气中直径20微米以下的粉尘颗粒。As shown in Figure 2, the described strong parallel electric field dust collection part 1 uses graphite or graphene conductive layer as the electrode layer 7, and uses the grid-like plastic plate 6 as the gas channel, and the electrode layer 7 alternates with the grid-like plastic plate 6 Arrangement, the electrode layer 7 forms a parallel strong electric field to collect dust after the high voltage is applied, and the height of the grid-like plastic plate 6 is 1-5mm, which absorbs dust particles with a diameter of less than 20 microns in the air.

所述的光催化分解层3为负载光触媒的石墨烯气凝胶,气凝胶的孔隙直径在0.1~100微米,其扫描电镜图片如图3所示,可以看到气凝胶丰富的微孔结构。所述的光触媒材料包括纳米二氧化钛颗粒或纳米钒酸铋颗粒。将石墨烯气凝胶浸润在光触媒颗粒的均匀混合液中,再取出自然干燥,即可实现石墨烯气凝胶对于光触媒的负载。光催化分解层的厚度为0.2-10mm。The photocatalytic decomposition layer 3 is a graphene airgel loaded with a photocatalyst, and the airgel has a pore diameter of 0.1 to 100 microns, and its scanning electron microscope picture is shown in Figure 3, and the abundant micropores of the airgel can be seen structure. The photocatalyst material includes nano titanium dioxide particles or nano bismuth vanadate particles. The graphene airgel is soaked in the homogeneous mixture of photocatalyst particles, and then taken out to dry naturally, the graphene airgel can realize the loading of the photocatalyst. The thickness of the photocatalytic decomposition layer is 0.2-10mm.

应用上述多功能空气净化装置的具体实施方式如下:The specific embodiment of applying the above-mentioned multifunctional air cleaning device is as follows:

实施例1Example 1

在30m2房间内,使用甲醛气体污染物发生装置将一定量的甲醛气态污染物气体添加到房间内,使甲醛初始浓度达到1.0mg/m3;测试房间内初始PM2.5初始含量0.05mg/m3,PM10初始含量为1.0mg/m3,存在一定量的可吸入颗粒物;同时测试臭氧初始含量为0.06mg/m3,为安全含量。In a 30m 2 room, use a formaldehyde gas pollutant generating device to add a certain amount of formaldehyde gaseous pollutant gas into the room, so that the initial concentration of formaldehyde reaches 1.0mg/m 3 ; the initial PM2.5 content in the test room is 0.05mg/m m 3 , the initial content of PM10 is 1.0mg/m 3 , and there is a certain amount of inhalable particulate matter; at the same time, the initial content of ozone is 0.06mg/m 3 , which is a safe content.

多功能空气净化装置的电晕极有5个,带孔道金属板的孔道直径为2cm,发射极长度为2cm,整流罩圆筒段直径为5mm,圆锥段的直径为5mm;预过滤网由胶化棉制成,深度为0.5cm;以石墨导电层为电极层,以网格状塑料板为气体通道,电极层与塑料板交替排布,电极层通高压电后构成平行强电场集尘,网格状塑料板的高度为3mm;石墨烯气凝胶负载二氧化钛纳米颗粒的光触媒作为光催化分解层,厚度为0.2mm。There are 5 corona poles in the multifunctional air purification device, the diameter of the hole of the metal plate with holes is 2cm, the length of the emitter is 2cm, the diameter of the fairing cylinder section is 5mm, and the diameter of the cone section is 5mm; the pre-filter is made of glue Made of chemical cotton, the depth is 0.5cm; the graphite conductive layer is used as the electrode layer, and the grid-like plastic plate is used as the gas channel. The electrode layer and the plastic plate are arranged alternately. After the electrode layer is passed through high voltage, a parallel strong electric field is formed to collect dust. , the height of the mesh plastic plate is 3 mm; the photocatalyst of graphene airgel loaded with titanium dioxide nanoparticles is used as the photocatalytic decomposition layer, and the thickness is 0.2 mm.

在多功能空气净化装置的前端放置风机以及紫外灯,并打开开关,含尘粒与甲醛的气流随着风机进入空气净化装置,通过预过滤网进行初步过滤,过滤掉粉尘颗粒并初步杀菌,再进入平行强电场的集尘板,荷电粉尘被集尘板捕获,最后再经过光催化分解层,分解臭氧,吸附甲醛等有机污染物。经检测,多功能空气净化装置工作1h后,空气中的甲醛含量减少95%,PM2.5含量减少97%,PM1.0含量减少99%,臭氧含量减少5%。Place a fan and an ultraviolet lamp at the front end of the multi-functional air purification device, and turn on the switch. The airflow containing dust particles and formaldehyde enters the air purification device along with the fan, and is preliminarily filtered through the pre-filter to filter out the dust particles and preliminarily sterilize them. Entering the dust collection plate with parallel strong electric field, the charged dust is captured by the dust collection plate, and finally passes through the photocatalytic decomposition layer to decompose ozone and absorb organic pollutants such as formaldehyde. After testing, after the multifunctional air purification device works for 1 hour, the formaldehyde content in the air is reduced by 95%, the PM2.5 content is reduced by 97%, the PM1.0 content is reduced by 99%, and the ozone content is reduced by 5%.

实施例2Example 2

在狭小汽车内部,甲醛初始浓度为0.15mg/m3,初始PM2.5初始含量0.10mg/m3,PM10初始含量为1.2mg/m3,测试臭氧初始含量为0.05mg/m3,为安全含量。Inside the narrow car, the initial concentration of formaldehyde is 0.15mg/m 3 , the initial content of PM2.5 is 0.10 mg/m 3 , the initial content of PM10 is 1.2 mg/m 3 , and the initial content of ozone is 0.05 mg/m 3 , which is safe content.

多功能空气净化装置的电晕极有10个,带孔道金属板的孔道直径为1cm,发射极长度为1cm,整流罩圆筒段直径为8mm,圆锥段的直径为8mm;预过滤网由胶化棉制成,深度为1.0cm;以石墨导电层为电极层,以网格状塑料板为气体通道,电极层与塑料板交替排布,电极层通高压电后构成平行强电场集尘,网格状塑料板的高度为4mm;石墨烯气凝胶负载二氧化钛纳米颗粒的光触媒作为光催化分解层,厚度为0.5mm。There are 10 corona poles of the multifunctional air purification device, the diameter of the hole of the metal plate with holes is 1cm, the length of the emitter is 1cm, the diameter of the fairing cylinder section is 8mm, and the diameter of the cone section is 8mm; the pre-filter is made of glue Made of chemical cotton, the depth is 1.0cm; the graphite conductive layer is used as the electrode layer, and the grid-shaped plastic plate is used as the gas channel. The electrode layer and the plastic plate are arranged alternately. After the electrode layer is passed through high voltage, a parallel strong electric field is formed to collect dust. , the height of the mesh plastic plate is 4 mm; the photocatalyst of graphene airgel loaded titanium dioxide nanoparticles is used as the photocatalytic decomposition layer, and the thickness is 0.5 mm.

在多功能空气净化装置的前端放置风机以及紫外灯,并打开开关,含尘粒与甲醛的气流随着风机进入空气净化装置,通过预过滤网进行初步过滤,过滤掉粉尘颗粒并初步杀菌,再进入平行强电场的集尘板,荷电粉尘被集尘板捕获,最后再经过光催化分解层,分解臭氧,吸附甲醛等有机污染物。经检测,多功能空气净化装置工作1h后,空气中的甲醛含量减少98%,PM2.5含量减少98%,PM1.0含量减少97%,臭氧含量增加2%(在安全范围)。Place a fan and an ultraviolet lamp at the front end of the multi-functional air purification device, and turn on the switch. The airflow containing dust particles and formaldehyde enters the air purification device along with the fan, and is preliminarily filtered through the pre-filter to filter out the dust particles and preliminarily sterilize them. Entering the dust collection plate with parallel strong electric field, the charged dust is captured by the dust collection plate, and finally passes through the photocatalytic decomposition layer to decompose ozone and absorb organic pollutants such as formaldehyde. After testing, after the multifunctional air purification device works for 1 hour, the formaldehyde content in the air is reduced by 98%, the PM2.5 content is reduced by 98%, the PM1.0 content is reduced by 97%, and the ozone content is increased by 2% (in the safe range).

实施例3Example 3

在23m2房间内,使用甲醛气体污染物发生装置将一定量的甲醛气态污染物气体添加到房间内,使甲醛初始浓度达到1.2mg/m3;测试房间内初始PM2.5初始含量0.06mg/m3,PM10初始含量为1.2mg/m3,存在一定量的可吸入颗粒物;同时测试臭氧初始含量为0.04mg/m3,为安全含量。In a 23m 2 room, a certain amount of formaldehyde gaseous pollutant gas is added to the room using a formaldehyde gas pollutant generating device, so that the initial concentration of formaldehyde reaches 1.2mg/m 3 ; the initial PM2.5 content in the test room is 0.06mg/m m 3 , the initial content of PM10 is 1.2mg/m 3 , and there is a certain amount of inhalable particulate matter; at the same time, the initial content of ozone is 0.04mg/m 3 , which is a safe content.

多功能空气净化装置的电晕极有5个,带孔道金属板的孔道直径为2cm,发射极长度为2cm,整流罩圆筒段直径为5mm,圆锥段的直径为5mm;预过滤网由胶化棉制成,深度为0.5cm;以石墨烯导电层为电极层,以网格状塑料板为气体通道,电极层与塑料板交替排布,电极层通高压电后构成平行强电场集尘,网格状塑料板的高度为3mm;石墨烯气凝胶负载钒酸铋纳米颗粒的光触媒作为光催化分解层,厚度为0.2mm。There are 5 corona poles in the multifunctional air purification device, the diameter of the hole of the metal plate with holes is 2cm, the length of the emitter is 2cm, the diameter of the fairing cylinder section is 5mm, and the diameter of the cone section is 5mm; the pre-filter is made of glue Made of chemical cotton, the depth is 0.5cm; the graphene conductive layer is used as the electrode layer, and the grid-shaped plastic plate is used as the gas channel. The electrode layer and the plastic plate are arranged alternately. Dust, the height of the grid-shaped plastic plate is 3mm; the photocatalyst of graphene airgel loaded with bismuth vanadate nanoparticles is used as the photocatalytic decomposition layer, and the thickness is 0.2mm.

在多功能空气净化装置的前端放置风机以及紫外灯,并打开开关,含尘粒与甲醛的气流随着风机进入空气净化装置,通过预过滤网进行初步过滤,过滤掉粉尘颗粒并初步杀菌,再进入平行强电场的集尘板,荷电粉尘被集尘板捕获,最后再经过光催化分解层,分解臭氧,吸附甲醛等有机污染物。经检测,多功能空气净化装置工作1h后,空气中的甲醛含量减少94%,PM2.5含量减少96%,PM1.0含量减少97%,臭氧含量增加5%(在安全范围)。Place a fan and an ultraviolet lamp at the front end of the multi-functional air purification device, and turn on the switch. The airflow containing dust particles and formaldehyde enters the air purification device along with the fan, and is preliminarily filtered through the pre-filter to filter out the dust particles and preliminarily sterilize them. Entering the dust collection plate with parallel strong electric field, the charged dust is captured by the dust collection plate, and finally passes through the photocatalytic decomposition layer to decompose ozone and absorb organic pollutants such as formaldehyde. After testing, after the multifunctional air purification device works for 1 hour, the formaldehyde content in the air is reduced by 94%, the PM2.5 content is reduced by 96%, the PM1.0 content is reduced by 97%, and the ozone content is increased by 5% (in a safe range).

Claims (7)

1.一种多功能空气净化装置,其特征在于,该装置包括依序排列的灰尘颗粒充电区域(4)、预过滤网(2)、强平行电场集尘部分(1)和光催化分解层(3),所述的灰尘颗粒充电区域(4)由电晕极(5)和带孔道金属板(8)组成;所述的强平行电场集尘部分(1)为电极层(7)与网格状塑料板(6)交替排布构成的平行强电场;所述的光催化分解层(3)设置在强平行电场集尘部分(1)后面;1. A multifunctional air cleaning device is characterized in that the device includes a dust particle charging area (4), a pre-filter (2), a strong parallel electric field dust collection part (1) and a photocatalytic decomposition layer ( 3), the dust particle charging area (4) is composed of a corona electrode (5) and a metal plate with holes (8); the strong parallel electric field dust collection part (1) is an electrode layer (7) and a mesh A parallel strong electric field formed by alternate arrangement of grid-shaped plastic plates (6); the photocatalytic decomposition layer (3) is arranged behind the strong parallel electric field dust collection part (1); 所述的预过滤网(2)由胶化棉制成,而且胶化棉表面富含AV-990阳离子基团;The pre-filter (2) is made of gelled cotton, and the surface of the gelled cotton is rich in AV-990 cationic groups; 所述的光催化分解层(3)为负载光触媒的石墨烯气凝胶,气凝胶的孔隙直径在0.1~100微米,光触媒材料包括纳米二氧化钛颗粒或纳米钒酸铋颗粒;The photocatalytic decomposition layer (3) is a graphene airgel loaded with a photocatalyst, the airgel has a pore diameter of 0.1 to 100 microns, and the photocatalyst material includes nano-titanium dioxide particles or nano-bismuth vanadate particles; 所述的电晕极(5)为前端带有整流罩的导电棒;所述的电晕极(5)前端的整流罩呈两段式结构:圆筒-圆锥状,圆筒段直径为1-10mm,圆锥段的直径为1-10mm;整流罩使得气流自然避开了电晕电晕区,减少粉尘在电晕极上的吸附沉积,所述的电晕极为带有三角齿发射极触针的细导电棒,所述的发射极长度为1-20mm,发射极的长度小于整流罩的尺寸,电晕发射利用三角形齿尖锐的导电点来实现,为颗粒充电所产生的空气负离子都在发射极触针的电晕中产生,整个电离平面内存在多个电晕极,提高了空气电离效率和集尘速度。The corona pole (5) is a conductive rod with a fairing at the front end; the fairing at the front end of the corona pole (5) is a two-stage structure: cylinder-conical, and the diameter of the cylinder section is 1 -10mm, the diameter of the conical section is 1-10mm; the fairing makes the airflow naturally avoid the corona corona area, reducing the adsorption and deposition of dust on the corona electrode, which has a triangular tooth emitter contact The thin conductive rod of the needle, the length of the emitter is 1-20mm, and the length of the emitter is smaller than the size of the fairing. The corona emission is realized by the sharp conductive point of the triangular teeth, and the air negative ions generated by charging the particles are all in the Generated in the corona of the emitter contact pin, there are multiple corona electrodes in the entire ionization plane, which improves the air ionization efficiency and dust collection speed. 2.根据权利要求1所述的一种多功能空气净化装置,其特征在于,所述的整流罩位于带孔道金属板(8)的孔道金属板的孔道平面中央,带孔道金属板(8)的孔道直径为1-5cm。2. A kind of multifunctional air cleaning device according to claim 1, characterized in that, the fairing is located at the center of the channel plane of the channel metal plate of the band channel metal plate (8), and the band channel metal plate (8) The channel diameter is 1-5cm. 3.根据权利要求1或2所述的一种多功能空气净化装置,其特征在于,所述的电晕极(5)有多个,都位于带孔道金属板(8)孔道平面的中央。3. A multifunctional air cleaning device according to claim 1 or 2, characterized in that there are multiple corona electrodes (5), all located in the center of the hole plane of the metal plate (8) with holes. 4.根据权利要求1所述的一种多功能空气净化装置,其特征在于,所述的预过滤网(2)的深度为0.2-2cm之间。4. A multifunctional air cleaning device according to claim 1, characterized in that, the depth of the pre-filter (2) is between 0.2-2cm. 5.根据权利要求1所述的一种多功能空气净化装置,其特征在于,所述的强平行电场集尘部分(1)以石墨或石墨烯导电层为电极层(7),以网格状塑料板(6)为气体通道,电极层(7)与网格状塑料板(6)交替排布,电极层(7)通高压电后构成平行强电场集尘。5. A kind of multifunctional air cleaning device according to claim 1, characterized in that, said strong parallel electric field dust collection part (1) is electrode layer (7) with graphite or graphene conductive layer, with grid Shaped plastic plates (6) are gas passages, electrode layers (7) and grid-shaped plastic plates (6) are alternately arranged, and electrode layers (7) form a parallel strong electric field to collect dust after passing high voltage. 6.根据权利要求5所述的一种多功能空气净化装置,其特征在于,所述的网格状塑料板(6)的高度为1-5mm。6. A multifunctional air cleaning device according to claim 5, characterized in that, the height of the grid-shaped plastic plate (6) is 1-5mm. 7.根据权利要求1所述的一种多功能空气净化装置,其特征在于,所述的光催化分解层(3)厚度为0.2-10mm。7. A multifunctional air purification device according to claim 1, characterized in that, the photocatalytic decomposition layer (3) has a thickness of 0.2-10mm.
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CN105498649A (en) * 2015-12-24 2016-04-20 四川大学 Graphene nano particle compound aerogel microspheres and preparation method thereof
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CN105772221A (en) * 2016-03-08 2016-07-20 上海交通大学 Multifunctional air purifying device

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