CN106853315A - Low-concentration organic exhaust gas recovery and processing system - Google Patents

Low-concentration organic exhaust gas recovery and processing system Download PDF

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Publication number
CN106853315A
CN106853315A CN201710167947.5A CN201710167947A CN106853315A CN 106853315 A CN106853315 A CN 106853315A CN 201710167947 A CN201710167947 A CN 201710167947A CN 106853315 A CN106853315 A CN 106853315A
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adsorption
low
concentration
desorption
entrance
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CN201710167947.5A
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许永童
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Shanghai Lan Bao Environmental Protection Technology Co Ltd
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Shanghai Lan Bao Environmental Protection Technology Co Ltd
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Priority to CN201710167947.5A priority Critical patent/CN106853315A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0057Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B01D2259/4009Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention provides a kind of low-concentration organic exhaust gas recovery and processing system, including a pre-processing device, concentration mechanism, at least an adsorption/desorption tower and a retracting device, one entrance of the pre-processing device connects an exhaust input tube road, the one outlet connection concentration mechanism of the pre-processing device, the concentration mechanism connects the adsorption/desorption tower, and the adsorption/desorption tower connects the retracting device.A kind of low-concentration organic exhaust gas recovery and processing system of the invention, the waste gas of low concentration Wind Volume is condensed into the waste gas of small air quantity high concentration by way of zeolite runner is concentrated, the size and number of charcoal absorption desorption column can be greatly reduced, have the advantages that equipment investment is few, floor space is small, operating cost is low, exhaust-gas treatment effect is good.

Description

Low-concentration organic exhaust gas recovery and processing system
Technical field
The present invention relates to emission-control equipment field, more particularly to a kind of low-concentration organic exhaust gas recovery and processing system.
Background technology
The technology of domestic treatment organic exhaust gas is divided into two major classes from principle at present:Reclaim and decompose.Recovery process is main It is that, with charcoal absorption, then by alternating temperature, the mode of transformation is desorbed, and reuse is condensed after desorption.This kind of recovery technology is directed to Small air quantity, the waste gas of middle and high concentration has recovering effect higher, is widely used.But it is directed to large-wind-volume low-concentration and has The organic exhaust gas of higher reclamation value can not but be applied well, main reasons is that air quantity is too big, cause the capital cost of equipment With very high, floor space is very big, and operating cost also can be very high in addition, without feasibility economically.Other traditional activity Charcoal adsorption recovery system is due to charcoal absorption limited efficacy, if the exhaust gas concentration of front end instantaneously increases, such as fixed gas return air, life Produce discharge capacity and increase etc., these situations can all cause the exhaust-gas treatment can not to reach existing discharge standard.
Generally, recyclable organic exhaust gas (middle and high concentration) will first be processed by pre-processing device, reach removal The purpose of particulate matter, soda acid waste gas and cooling.Enter charcoal absorption desorption column, absorption by pretreated organic exhaust gas Tower using multitower parallel connection by the way of, the waste gas qualified discharge for having adsorbed.The activated carbon adsorber of adsorption saturation is carried out using steam Regeneration, when normal operation, the activated carbon that can at least meet has an activated carbon adsorber after regenerative operation, regeneration is inhaled Attached tower is transferred to adsorption cycle, such cyclic switching again after drying cooling.The quantity and size of tower need air quantity according to waste gas, Concentration is determined.
Using steam heating desorption (alternating temperature principle), the mixture of desorption organic steam out and vapor leads to again for regeneration Cross condenser to be condensed, the temperature of cooling water is fixed according to different organic principles.It is condensed into the organic principle and liquid of liquid Water is separated into special separating barrel, and again by rectifying reuse, sewage enters sewage network to the organic principle after separation, enters Enter next step treatment.The principle being desorbed by charcoal absorption, realizes the recycling of organic principle in waste gas, reaches waste gas Treatment and the good combination for reclaiming, realize good economic benefit.This be in the market in most common waste gas it is organic into Divide recovery process.
The cooling water temperature that heat exchanger is used typically uses normal-temperature water or salt solution, and chilling temperature is limited, according to it is organic into The saturated vapour pressure data divided, still have substantial amounts of organic principle to exist in a gaseous form, i.e. fixed gas after cooling.Fixed gas leads to Crossing pipeline and being re-introduced into activated carbon adsorber front end carries out adsorption treatment again, and this part air quantity is smaller, but dense typically exists Every cube or so of tens of thousands of milligrams, this can also increase the load of activated carbon adsorber, cause charcoal absorption to process not up to standard.Separately Outward, many production technologies are unstable, and in extreme circumstances, the exhaust gas concentration that certain a period of time excludes can be inhaled more than activated carbon The adsorption treatment ability of attached tower, in turn results in exhaust-gas treatment not up to standard.
It can be seen that, the shortcoming of existing mainstream technology mainly has at 2 points:
1st, it is not suitable for the organic exhaust gas for having recovery value of large-wind-volume low-concentration, main reasons is that air quantity is too big, leads The investment cost of cause equipment is very high, and floor space is very big, and operating cost also can be very high in addition, without feasibility economically.
2nd, traditional in addition charcoal absorption recovery system due to charcoal absorption limited efficacy, if the exhaust gas concentration of front end Instantaneously increase, such as fixed gas return air, production discharge capacity increases etc., these situations can all cause the exhaust-gas treatment can not to reach existing row Put standard.
The content of the invention
For above-mentioned deficiency of the prior art, the present invention provides a kind of low-concentration organic exhaust gas recovery and processing system, leads to The waste gas of low concentration Wind Volume is condensed into the mode for crossing the concentration of zeolite runner the waste gas of small air quantity high concentration, can be greatly reduced The size and number of charcoal absorption desorption column, with equipment investment it is few, floor space is small, operating cost is low, exhaust-gas treatment effect Really good advantage.
To achieve these goals, the present invention provides a kind of low-concentration organic exhaust gas recovery and processing system, including a pre- place Reason equipment, concentration mechanism, at least an adsorption/desorption tower and a retracting device, the entrance connection one of the pre-processing device are given up Gas input channel, an outlet connection concentration mechanism of the pre-processing device, the concentration mechanism connection absorption is de- Attached tower, the adsorption/desorption tower connects the retracting device.
Preferably, the concentration mechanism includes that a zeolite rotary wheel device, a primary heater, a desorption blower fan and a table are cold Device, the zeolite rotary wheel device includes an adsorption zone, a cooling zone and a desorption area, an entrance of the adsorption zone and described cold But an entrance in area connects the pre-processing device respectively, and an outlet of the cooling zone connects institute by the primary heater An entrance in desorption area is stated, an outlet in the desorption area connects an entrance of the surface cooler, institute by the desorption blower fan State an outlet connection adsorption/desorption tower of surface cooler;One outlet one discharge tube of connection of the adsorption zone, the discharge An air exhauster is fixed with pipeline.
Preferably, the adsorption/desorption tower connects the entrance of the adsorption zone and the entrance of the cooling zone.
Preferably, the retracting device includes a condenser, a separating barrel, a sewage discharge device and a solvent recovery dress Put;One entrance of the condenser connects the adsorption/desorption tower, and an entrance of the separating barrel connects the condenser, described Sewage discharge device connects a sewage discharge end of the separating barrel, and the one of the solvent recovery unit connection separating barrel is molten Agent recovery end.
Preferably, a fixed gas output end of the separating barrel connects the entrance of the surface cooler.
Preferably, also including the filter, a secondary heater and the drying blower fan that are sequentially connected, the filter connects An air inlet duct road is connect, the drying blower and pipeline connects the adsorption/desorption tower.
Preferably, also including a low-pressure steam feedway, the low-pressure steam feedway connects the adsorption/desorption Tower.
The present invention makes it have following beneficial effect as a result of above technical scheme:
Pre-processing device is used to pre-process low-concentration organic exhaust gas, for remove in low-concentration organic exhaust gas The purpose of grain thing, soda acid waste gas and cool-down dehumidification etc..Realized the useless of low concentration Wind Volume by the use for concentrating mechanism Gas is condensed into the waste gas of small air quantity high concentration, can greatly reduce the size and number of charcoal absorption desorption column, so that Low-concentration organic exhaust gas recovery and processing system of the invention has that equipment investment is few, floor space is small, operating cost is low, at waste gas The good advantage of reason effect.
Brief description of the drawings
Fig. 1 is the structural representation of the low-concentration organic exhaust gas recovery and processing system of the embodiment of the present invention.
Specific embodiment
Below according to accompanying drawing 1, presently preferred embodiments of the present invention is provided, and be described in detail, make to be better understood when this The function of invention, feature.
Fig. 1 is referred to, a kind of low-concentration organic exhaust gas recovery and processing system of the embodiment of the present invention, an including pretreatment sets Standby 1, one concentration mechanism 2, at least an adsorption/desorption tower 3 and a retracting device 4, an entrance of pre-processing device 1 connect a waste gas Input channel, an outlet connection concentration mechanism 2 of pre-processing device 1, concentration mechanism 2 connects adsorption/desorption tower 3, adsorption/desorption tower 3 connection retracting devices 4.In the present embodiment, adsorption/desorption tower 3 is charcoal absorption desorption column.
Pre-processing device 1 is used to pre-process low-concentration organic exhaust gas, for removing low-concentration organic exhaust gas in The purpose of particulate matter, soda acid waste gas and cool-down dehumidification etc..By pretreated waste gas, particle concentration<1mg/m3, waste gas Humidity<80%, afterwards pretreated waste gas be passed through concentration mechanism 2, waste gas is concentrated and by the clean gas after treatment Enter air.Realized by the use for concentrating mechanism 2 and the waste gas of low concentration Wind Volume is condensed into the useless of small air quantity high concentration Gas, can greatly reduce the size and number of charcoal absorption desorption column, so that low-concentration organic exhaust gas of the invention are returned Receiving processing system has the advantages that equipment investment is few, floor space is small, operating cost is low, exhaust-gas treatment effect is good.
Wherein, concentration mechanism 2 includes a zeolite rotary wheel device 21, the desorption table of blower fan 23 and of a primary heater 22, Cooler 24, zeolite rotary wheel device 21 includes an adsorption zone 211, a cooling zone 212 and a desorption area 213, and the one of adsorption zone 211 enters One entrance of mouth and cooling zone 212 connects pre-processing device 1 respectively, and an outlet of cooling zone 212 is connected by primary heater 22 An entrance in desorption area 213 is connect, an outlet in desorption area 213 connects an entrance of surface cooler 24 by being desorbed blower fan 23, and table is cold One outlet connection adsorption/desorption tower 3 of device 24;One outlet one discharge tube of connection of adsorption zone 211, is fixed with discharge tube One air exhauster 25.The entrance of the connection adsorption zone 211 of adsorption/desorption tower 3 and the entrance of cooling zone 212.
21 points of zeolite rotary wheel device is three regions:Adsorption zone 211, cooling zone 212 and desorption area 213.Zeolite runner is filled 21 slow rotations are put, to ensure entirely to be adsorbed as a continuous process.Waste gas containing VOC passes through zeolite runner During the adsorption zone of device 21, organic principle therein is adsorbed by the adsorbent in the runner of zeolite rotary wheel device 21, clean Gas is discharged through air exhauster 25 by chimney.The organic principle that the adsorption zone of zeolite rotary wheel device 21 is adsorbed simultaneously is increasingly Many, when the runner of zeolite rotary wheel device 21 goes to desorption area 213, draw small air quantity high-temperature gas is carried out to the runner for being desorbed area 213 Desorption, runner recovers absorbability after desorption, while the organic principle concentration in the gas of small air quantity also increases, reaches concentration Purpose.Runner region after desorption goes to cooling zone 212, runner is recovered absorbability after lowering the temperature, and runner is transferred to adsorption zone again 211 are adsorbed.Whole process is a continuous process:That is adsorption and desorption, cooling, absorption, so circulation.
The waste gas of low concentration diminishes by the waste gas air quantity after runner concentration, and concentration increases, for example:Air quantity 100000m3/ H, concentration 80mg/m3Waste gas, concentrate 20 times, then concentrate after waste gas be 5000m3/ h, concentration 1600mg/m3Waste gas.Concentration Waste gas afterwards first passes through after surface cooler 24 is cooled down organic principle is reclaimed into follow-up adsorption/desorption tower 3.
Retracting device 4 includes a condenser 41, a separating barrel 42, a sewage discharge device 43 and a solvent recovery unit 44;The one entrance connection adsorption/desorption tower 3 of condenser 41, the entrance connection condenser 41 of separating barrel 42, sewage discharge device One sewage discharge end of 43 connection separating barrels 42, solvent recovery unit 44 connects a solvent recovery end of separating barrel 42.Separating barrel A 42 fixed gas output end connects the entrance of surface cooler 24.
One fixed gas output end of separating barrel 42 connects the entrance of surface cooler 24, returns to the front end of adsorption/desorption tower 3, prevents Secondary pollution is discharged, and can improve organic efficiency.The outlet exhaust of adsorption/desorption tower 3 is not discharged directly, and is to revert to thickener The front end of structure 2, is further carried out adsorption treatment, can not only so reduce the generation of secondary pollution, reaches ultra-clean discharge, and The organic principle in waste gas can farthest be reclaimed.
Also include the filter 5, a secondary heater 6 and the drying blower fan 7 that are sequentially connected, filter 5 is connected Gas input channel, drying blower fan 7 connects adsorption/desorption tower 3 by pipeline.Also include a low-pressure steam feedway 8, low pressure is steamed The connection adsorption/desorption of vapour feedway 8 tower 3.
A kind of low-concentration organic exhaust gas recovery and processing system of the invention, waste gas first passes through concentration mechanism 2 and concentrates, after concentration Middle and high concentration, small air quantity waste gas enters back into adsorption/desorption tower 3 and recycled;Fixed gas needs to return to adsorption/desorption tower 3 Leading portion enters back into adsorption treatment, and the outlet exhaust of adsorption/desorption tower 3 needs enter back into concentration mechanism 2 leading portion and further located again Reason, by two-stage return air, reaches the purpose of ultra-clean discharge, at utmost reclaims the organic principle in waste gas;Solve traditional work Skill can not process the problem of large-wind-volume low-concentration organic exhaust gas, realize investment cost, operating cost, maintaining expense, occupation of land Area is substantially reduced, and realizes good economic benefit.Meanwhile, traditional handicraft is solved because fixed gas return air and production discharge capacity increase Cause to discharge problem not up to standard greatly, realize ultra-clean discharge, reach more preferable environmental benefit.Due to there is two-stage return air, can be with Organic principle in more efficient absorption waste gas, improves the treatment effeciency of waste gas and the organic efficiency of organic principle.
The present invention is described in detail above in association with accompanying drawing embodiment, those skilled in the art can be according to upper State it is bright the present invention is made many variations example.Thus, some of embodiment details should not constitute limitation of the invention, this The scope that invention will be defined using appended claims is used as protection scope of the present invention.

Claims (7)

1. a kind of low-concentration organic exhaust gas recovery and processing system, it is characterised in that including a pre-processing device, a concentration mechanism, At least an adsorption/desorption tower and a retracting device, an entrance of the pre-processing device connect an exhaust input tube road, described pre- The one outlet connection concentration mechanism of processing equipment, the concentration mechanism connects the adsorption/desorption tower, the adsorption/desorption Tower connects the retracting device.
2. low-concentration organic exhaust gas recovery and processing system according to claim 1, it is characterised in that the concentration mechanism bag A zeolite rotary wheel device, a primary heater, desorption blower fan and a surface cooler are included, the zeolite rotary wheel device includes an absorption Area, a cooling zone and a desorption area, an entrance of the adsorption zone and an entrance of the cooling zone connect the pre- place respectively Reason equipment a, outlet of the cooling zone connects an entrance in the desorption area, the desorption area by the primary heater An outlet entrance of the surface cooler, the outlet connection absorption of the surface cooler are connected by the desorption blower fan Desorption column;One outlet one discharge tube of connection of the adsorption zone, is fixed with an air exhauster on the discharge tube.
3. low-concentration organic exhaust gas recovery and processing system according to claim 2, it is characterised in that the adsorption/desorption tower Connect the entrance of the adsorption zone and the entrance of the cooling zone.
4. low-concentration organic exhaust gas recovery and processing system according to claim 3, it is characterised in that the retracting device bag Include a condenser, a separating barrel, a sewage discharge device and a solvent recovery unit;The one entrance connection of the condenser is described Adsorption/desorption tower a, entrance of the separating barrel connects the condenser, and the sewage discharge device connects the separating barrel One sewage discharge end, the solvent recovery unit connects a solvent recovery end of the separating barrel.
5. low-concentration organic exhaust gas recovery and processing system according to claim 4, it is characterised in that the one of the separating barrel Fixed gas output end connects the entrance of the surface cooler.
6. low-concentration organic exhaust gas recovery and processing system according to claim 5, it is characterised in that also including being sequentially connected A filter, a secondary heater and a drying blower fan, the filter connects an air inlet duct road, the drying blower fan The adsorption/desorption tower is connected by pipeline.
7. low-concentration organic exhaust gas recovery and processing system according to claim 6, it is characterised in that also steamed including a low pressure Vapour feedway, the low-pressure steam feedway connects the adsorption/desorption tower.
CN201710167947.5A 2017-03-21 2017-03-21 Low-concentration organic exhaust gas recovery and processing system Pending CN106853315A (en)

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CN107308781A (en) * 2017-08-17 2017-11-03 上海赜羽环保技术有限公司 VOCs treatment process technology in printing industry
CN108079740A (en) * 2017-12-26 2018-05-29 嘉园环保有限公司 A kind of large-wind-volume low-concentration organic exhaust gas processing unit and method
CN108079766A (en) * 2018-01-30 2018-05-29 洛阳天宝环保科技有限公司 A kind of low concentration big flow organic exhaust gas closed loop multistage retracting device and recovery method
CN108187442A (en) * 2017-12-29 2018-06-22 张家港市艾尔环保工程有限公司 The method for handling volatile organic matter
CN109432812A (en) * 2018-10-08 2019-03-08 佑华制药(乐山)有限公司 A kind of pharmacy subliming furnace and its application method with tail gas recycle function
CN109745824A (en) * 2019-03-11 2019-05-14 杨松 A kind of improvement VOCs waste gas circulation regeneration technology system
CN110508097A (en) * 2019-09-05 2019-11-29 南通乐尔环保科技有限公司 A kind of new zeolite absorber VOCs solvent recovery process

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CN107308781A (en) * 2017-08-17 2017-11-03 上海赜羽环保技术有限公司 VOCs treatment process technology in printing industry
CN108079740A (en) * 2017-12-26 2018-05-29 嘉园环保有限公司 A kind of large-wind-volume low-concentration organic exhaust gas processing unit and method
CN108187442A (en) * 2017-12-29 2018-06-22 张家港市艾尔环保工程有限公司 The method for handling volatile organic matter
CN108079766A (en) * 2018-01-30 2018-05-29 洛阳天宝环保科技有限公司 A kind of low concentration big flow organic exhaust gas closed loop multistage retracting device and recovery method
CN109432812A (en) * 2018-10-08 2019-03-08 佑华制药(乐山)有限公司 A kind of pharmacy subliming furnace and its application method with tail gas recycle function
CN109745824A (en) * 2019-03-11 2019-05-14 杨松 A kind of improvement VOCs waste gas circulation regeneration technology system
CN110508097A (en) * 2019-09-05 2019-11-29 南通乐尔环保科技有限公司 A kind of new zeolite absorber VOCs solvent recovery process

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