CN106832421A - A kind of polyvinyl chloride wall decoration thin-film material fire retardant and preparation method thereof - Google Patents

A kind of polyvinyl chloride wall decoration thin-film material fire retardant and preparation method thereof Download PDF

Info

Publication number
CN106832421A
CN106832421A CN201710005936.7A CN201710005936A CN106832421A CN 106832421 A CN106832421 A CN 106832421A CN 201710005936 A CN201710005936 A CN 201710005936A CN 106832421 A CN106832421 A CN 106832421A
Authority
CN
China
Prior art keywords
fire retardant
polyvinyl chloride
film material
wall decoration
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710005936.7A
Other languages
Chinese (zh)
Inventor
潘凯宏
刘伟明
李余聘
黄起渊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan Hongtaiji Flame Retardant Material Co Ltd
Original Assignee
Dongguan Hongtaiji Flame Retardant Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Hongtaiji Flame Retardant Material Co Ltd filed Critical Dongguan Hongtaiji Flame Retardant Material Co Ltd
Priority to CN201710005936.7A priority Critical patent/CN106832421A/en
Publication of CN106832421A publication Critical patent/CN106832421A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/12Adsorbed ingredients, e.g. ingredients on carriers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/22Halogen free composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films

Abstract

The invention belongs to technical field of flame retardant, a kind of polyvinyl chloride wall decoration thin-film material fire retardant, including following raw material components are specifically disclosed:Bismuth compound, adsorbent, inorganic mineral fire retardant, bactericide, antioxidant and calcium stearate.The preparation method of above-mentioned fire retardant is also disclosed, is comprised the following steps:Bactericide is prepared first;Then adsorbent is ground to form into absorbent particles;The surface of bismuth compound, inorganic mineral fire retardant is processed using silane coupler again, finally by bactericide, absorbent particles, silane coupler modified bismuth compound and silane coupler modified inorganic mineral fire retardant input high-speed mixer, and add antioxidant, calcium stearate, after mixing 15 minutes, obtain final product.Polyvinyl chloride wall decoration thin-film material fire retardant Halogen of the invention, without antimony, without phosphate, without boron, be a kind of high-performance refractory agent of environmentally friendly non-volatility.

Description

A kind of polyvinyl chloride wall decoration thin-film material fire retardant and preparation method thereof
Technical field
The present invention relates to technical field of flame retardant, and in particular to a kind of polyvinyl chloride wall decoration thin-film material fire retardant And preparation method thereof.
Background technology
PVC is polyvinyl chloride, and it has the good feature of environmental protection, resistance to ag(e)ing and ductility, the thin-film material surface being made Bright and clean, nontoxic, water resistant, is the ideal material of indoor wall decoration.With the development of social economy, people are to life living environment Requirement more and more higher, including visual perception, on olfactory organoleptic, and health existence living environment is for security.Polyvinyl chloride It is a kind of high performance material friendly to human body, environmental protection, it has good anti-flammability, in daily life using more, It is a kind of macromolecular material for being difficult to and forgetting.In usually used PVC material, in order to obtain other physical properties, often Plasticizer is added wherein, reduces its anti-flammability.
Traditional fire-retardant mode is to add antimony oxide, phosphate flame retardant or other brominated boracic resistances in the material Combustion agent.Antimony oxide belongs to one of eight big heavy metals, there are some researches show the mankind live in the ring containing antimony oxide for a long time In border, stimulation can be produced to the skin of the respiratory system of human body, vision system and humidity, and there may be potential carcinogenic wind Danger.And boron and boron-containing compound and human body Long Term Contact, then there are cause gene mutation, carcinogenic risk;Phosphate has volatility, If the mankind hang up one's hat in the environment with volatile chemical component, greatly harm can be caused to health.Easily Cause various malignant disorders.
In recent years, as people are to the cry more and more higher of living environment health, every profession and trade has all formulated corresponding management and control Measure and examination criteria, such as indoor formaldehyde examination criteria, indoor climate detection, VOC standard detections etc. in Automobile.Polychlorostyrene second Although alkene have a preferable flame retardant effect, but flame retardant effect in its wall decoration film 0.05mm-0.1mm seems and pays no attention to Think, and pure polyvinyl chloride can reach the flame retardant effect of 0.25mm V-0.Therefore, exploitation is friendly to human body, and flame-retarded efficiency is excellent Polyvinyl chloride film fire retardant, it appears particularly important.
The content of the invention
For problems of the prior art, it is an object of the invention to provide a kind of polyvinyl chloride wall decoration film Materials with flame retardant and preparation method thereof, the fire retardant Halogen, without antimony, without phosphate, without boron is a kind of environmentally friendly non-volatility High-performance refractory agent, for the fire-retardant of polyvinyl chloride wall decoration thin-film material, its fire resistance can reach wall decoration film The flame-retardancy requirements of V-0 grades required of 0.05-0.1mm thickness.
In order to achieve the above object, the present invention is achieved using following technical scheme.
(One)A kind of polyvinyl chloride wall decoration thin-film material fire retardant, it is characterised in that including following raw material components: Bismuth compound, adsorbent, inorganic mineral fire retardant, bactericide, antioxidant and calcium stearate.
Preferably, the weight portion of the raw material components is:Bismuth compound 0-20 parts, adsorbent 1-15 parts, inorganic mineral resistance 1-20 parts, bactericide 1-5 parts, antioxidant 0.1-2 parts, calcium stearate 1-2 parts of agent of combustion.
Preferably, the bismuth compound is bismuth oxide or basic bismuth carbonate.
Preferably, the adsorbent is one or more in artificial zeolite, sepiolite or diatomite.
Preferably, the inorganic mineral fire retardant is aluminium hydroxide, kaolin, aluminum oxide, hydromagnesite or Magnesiumaluminumsilicate In one or more.
Preferably, the bactericide is load iron ion zeolite.
Preferably, the antioxidant is at least one in antioxidant 1010 or irgasfos 168.
(Two)The preparation method of above-mentioned polyvinyl chloride wall decoration thin-film material fire retardant, it is characterised in that including with Lower step:
Step 1, prepares bactericide, standby;
Step 2, adsorbent is ground to the particle of 0.002-0.005mm in Gas grinding machine respectively, obtains absorbent particles, standby With;
Step 3, the surface using silane coupler respectively to bismuth compound, inorganic mineral fire retardant is processed, and obtains silane idol Connection agent modified bismuth compound and silane coupler modified inorganic mineral fire retardant, it is standby;
Step 4, by the bactericide, absorbent particles, silane coupler modified bismuth compound and silane coupler modified inorganic In mineral flame retardants input high-speed mixer, and antioxidant, calcium stearate are added, after mixing 15 minutes, obtained final product.
Preferably, in step 1, the bactericide is load iron ion zeolite.
Preferably, the preparation of the load iron ion zeolite is followed the steps below:Ferrous sulfate is dissolved in water first In, obtain copperas solution, and zeolite powder added into the copperas solution, mix, treat that the zeolite powder is uniform After infiltration, drying is crushed, grinding, obtains final product load iron ion zeolite.
Polyvinyl chloride wall decoration thin-film material fire retardant provided by the present invention is white powder, is slightly soluble in water, heat More than 300 DEG C, particle diameter is 0.003-0.01mm to weightless 1% temperature;And Pb Han Liang≤100 ppm, Cd Han Liang≤5 therein Ppm, Hg Han Liang≤2 ppm, Cr Han Liang≤2 ppm, PBBs Han Liang≤2 ppm, PBDEs Han Liang≤2 ppm, arsenic trioxide contain Liang≤2 ppm.
Compared with prior art, beneficial effects of the present invention are:
Polyvinyl chloride wall decoration thin-film material fire retardant Halogen provided by the present invention, without antimony, without phosphate, without boron, and Bismuth compound in its raw material components has to human body, is a kind of high-performance refractory agent of environmentally friendly non-volatility, for polychlorostyrene second Alkene wall decoration thin-film material it is fire-retardant, its fire resistance can reach wall decoration film required for 0.05-0.1mm thickness V- 0 grade of flame-retardancy requirements.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will It will be appreciated that the following example is merely to illustrate the present invention, and it is not construed as limiting the scope of the present invention.
Embodiment 1
A kind of polyvinyl chloride wall decoration thin-film material fire retardant, its preparation method is comprised the following steps:
Step 1, ferrous sulfate is soluble in water, obtain copperas solution, and zeolite powder added into the copperas solution, Mix, after after the zeolite powder homogeneous immersion, drying is crushed, and grinding must load iron ion zeolite.
Step 2, takes 1 part of sepiolite, and it is ground to 0.002- by 10 parts of artificial zeolite in Gas grinding machine respectively The particle of 0.005mm, obtains sepiolite particle and artificial zeolite particle respectively, standby.
Step 3, takes 3.8 parts of basic bismuth carbonate, and surface is carried out to basic bismuth carbonate using silane coupler KH570 is modified, Obtain the modified basic bismuth carbonates of KH570;5 parts of kaolin is taken, surface is carried out to kaolin using KH570 is modified, and obtains the modified height of KH570 Ridge soil.
Step 4, in taking 4 parts of load iron ion zeolites input high-speed mixers, then puts into sepiolite particle, artificial zeolite Grain, KH570 modified basic bismuth carbonate and KH570 modified kaolins, and 0.5 part of antioxidant 1010 and 1 part of calcium stearate are added, mix After closing 15 minutes, obtain final product.
Fire retardant manufactured in the present embodiment is taken for polyvinyl chloride wall decoration thin-film material, and detects the fire-retardant of the material Performance, specific detection method and testing result are as follows.
Detection method:10 parts of the fire retardant is taken, in 90 parts of pvc materials, being opened after dual-screw pelletizer granulation Mill compressing tablet 0.1mm diaphragms, film are cut according to UL-94 flame-retardancy requirements, and hindered according to UL-94 method of testings Combustion test, recording detection data.
Testing result:PVC film test result containing the environmental protection fire retarding agent is that 0.1mm flame retardant ratings are UL-94 V-0 Rank.
Experiment shows that fire retardant obtained in above flame retardant formulations has good flame retardant effect in polyvinyl chloride film, Completely can be as new environmentally friendly polyvinyl chloride fire retardant.
Embodiment 2
A kind of polyvinyl chloride wall decoration thin-film material fire retardant, its preparation method is comprised the following steps:
Step 1, ferrous sulfate is soluble in water, obtain copperas solution, and zeolite powder added into the copperas solution, Mix, after after the zeolite powder homogeneous immersion, drying is crushed, and grinding must load iron ion zeolite.
Step 2, takes 10 parts of diatomite, and it is ground to the particle of 0.002-0.005mm in Gas grinding machine, obtains diatom Soil particle, it is standby.
Step 3, takes 6 parts of basic bismuth carbonate, and surface is carried out to basic bismuth carbonate using silane coupler KH570 is modified, and obtains KH570 is modified basic bismuth carbonate;4 parts of kaolin is taken, surface is carried out to kaolin using KH570 is modified, and obtains the modified kaolinites of KH570 Soil;1 part of magnesite of water intaking, carries out surface to hydromagnesite and is modified using KH570, obtains the modified hydromagnesites of KH570.
Step 4, in taking 2 parts of load iron ion zeolites input high-speed mixers, then puts into diatomite particle, KH570 and is modified Basic bismuth carbonate, KH570 modified kaolins and KH570 are modified hydromagnesite, and add 0.5 part of antioxidant 1010 and 1 part of tristearin Sour calcium, after mixing 15 minutes, obtains final product.
Fire retardant manufactured in the present embodiment is taken for polyvinyl chloride wall decoration thin-film material, and detects the fire-retardant of the material Performance, specific detection method and testing result are as follows.
Detection method:10 parts of the fire retardant is taken, in 90 parts of pvc materials, being opened after dual-screw pelletizer granulation Mill compressing tablet 0.1mm diaphragms, film are cut according to UL-94 flame-retardancy requirements, and hindered according to UL-94 method of testings Combustion test, recording detection data.
Testing result:PVC film test result containing the environmental protection fire retarding agent is that 0.1mm flame retardant ratings are UL-94 V-0 Rank.
Experiment shows that fire retardant obtained in above flame retardant formulations has good flame retardant effect in polyvinyl chloride film, Completely can be as new environmentally friendly polyvinyl chloride fire retardant.
Embodiment 3
A kind of polyvinyl chloride wall decoration thin-film material fire retardant, its preparation method is comprised the following steps:
Step 1, ferrous sulfate is soluble in water, obtain copperas solution, and zeolite powder added into the copperas solution, Mix, after after the zeolite powder homogeneous immersion, drying is crushed, and grinding must load iron ion zeolite.
Step 2, takes 5 parts of sepiolite, and it is ground to 0.002- by 5 parts of artificial zeolite in Gas grinding machine respectively The particle of 0.005mm, obtains sepiolite particle and artificial zeolite particle respectively, standby.
Step 3, takes 6 parts of bismuth oxide, and surface is carried out to bismuth oxide using silane coupler KH570 is modified, and obtains KH570 and is modified Bismuth oxide;3 parts of magnesite of water intaking, carries out surface to hydromagnesite and is modified using silane coupler KH570, obtains KH570 modified waters Magnesite;9 parts of aluminum oxide is taken, surface is carried out to aluminum oxide using silane coupler KH570 is modified, and obtains KH570 modified aluminas.
Step 4, in taking 4 parts of load iron ion zeolites input high-speed mixers, then puts into sepiolite particle, artificial zeolite The modified basic bismuth carbonate of grain, KH570, KH570 modified hydromagnesite and KH570 modified aluminas, and add 0.5 part of antioxidant 1010 and 1 parts of calcium stearates, after mixing 15 minutes, obtain final product.
Fire retardant manufactured in the present embodiment is taken for polyvinyl chloride wall decoration thin-film material, and detects the fire-retardant of the material Performance, specific detection method and testing result are as follows.
Detection method:9 parts of the fire retardant is taken, in 91 parts of pvc materials, being opened after dual-screw pelletizer granulation Mill compressing tablet 0.1mm diaphragms, film are cut according to UL-94 flame-retardancy requirements, and hindered according to UL-94 method of testings Combustion test, recording detection data.
Testing result:PVC film test result containing the environmental protection fire retarding agent is that 0.1mm flame retardant ratings are UL-94 V-0 Rank.
Experiment shows that fire retardant obtained in above flame retardant formulations has good flame retardant effect in polyvinyl chloride film, Completely can be as new environmentally friendly polyvinyl chloride fire retardant.
Embodiment 4
A kind of polyvinyl chloride wall decoration thin-film material fire retardant, its preparation method is comprised the following steps:
Step 1, ferrous sulfate is soluble in water, obtain copperas solution, and zeolite powder added into the copperas solution, Mix, after after the zeolite powder homogeneous immersion, drying is crushed, and grinding must load iron ion zeolite.
Step 2, takes 10 parts of diatomite, 5 parts of sepiolite, and it is ground into 0.002- in Gas grinding machine respectively The particle of 0.005mm, obtains diatomite particle and sepiolite particle, standby.
Step 3, takes 8 parts of bismuth oxide, and surface is carried out to bismuth oxide using silane coupler KH540 is modified, and obtains KH540 and is modified Bismuth oxide;8 parts of magnesite of water intaking, carries out surface to hydromagnesite and is modified using silane coupler KH540, obtains KH540 modified waters Magnesite;9 parts of aluminum oxide is taken, surface is carried out to aluminum oxide using KH540 is modified, and obtains KH540 modified aluminas.
Step 4, in taking 3 parts of load iron ion zeolites input high-speed mixers, then puts into sepiolite particle, diatomite Grain, the modified oxidized bismuths of KH540, KH540 modified hydromagnesite and KH540 modified aluminas, and add 1 part of antioxidant 1010,0.4 Part irgasfos 168 and 2 parts of calcium stearates, after mixing 15 minutes, obtain final product.
Fire retardant manufactured in the present embodiment is taken for polyvinyl chloride wall decoration thin-film material, and detects the fire-retardant of the material Performance, specific detection method and testing result are as follows.
Detection method:12 parts of the fire retardant is taken, in 88 parts of pvc materials, being opened after dual-screw pelletizer granulation Mill compressing tablet 0.1mm diaphragms, film are cut according to UL-94 flame-retardancy requirements, and hindered according to UL-94 method of testings Combustion test, recording detection data.
Testing result:PVC film test result containing the environmental protection fire retarding agent is that 0.1mm flame retardant ratings are UL-94 V-0 Rank.
Experiment shows that fire retardant obtained in above flame retardant formulations has good flame retardant effect in polyvinyl chloride film, Completely can be as new environmentally friendly polyvinyl chloride fire retardant.
Embodiment 5
A kind of polyvinyl chloride wall decoration thin-film material fire retardant, its preparation method is comprised the following steps:
Step 1, ferrous sulfate is soluble in water, obtain copperas solution, and zeolite powder added into the copperas solution, Mix, after after the zeolite powder homogeneous immersion, drying is crushed, and grinding must load iron ion zeolite.
Step 2, takes 1 part of sepiolite, and it is ground to the particle of 0.002-0.005mm in Gas grinding machine, respectively Sepiolite particle, it is standby.
Step 3, takes 20 parts of basic bismuth carbonate, and surface is carried out to basic bismuth carbonate using silane coupler KH540 is modified, and obtains KH540 is modified basic bismuth carbonate;10 parts of aluminium hydroxide, 10 parts of Magnesiumaluminumsilicate are taken, using silane coupler KH540 respectively to hydrogen-oxygen Changing aluminium and Magnesiumaluminumsilicate carries out surface and is modified, and obtains KH540 modified aluminium hydroxides and KH540 modified magnesium aluminium silicates.
Step 4, in taking 1 part of load iron ion zeolite input high-speed mixer, then puts into sepiolite particle, KH540 and is modified Basic bismuth carbonate, KH540 modified aluminium hydroxides and KH540 modified magnesium aluminium silicates, and add 1 part of antioxidant 1010 and 1 part of tristearin Sour calcium, after mixing 15 minutes, obtains final product.
Fire retardant manufactured in the present embodiment is taken for polyvinyl chloride wall decoration thin-film material, and detects the fire-retardant of the material Performance, specific detection method and testing result are as follows.
Detection method:10 parts of the fire retardant is taken, in 90 parts of pvc materials, being opened after dual-screw pelletizer granulation Mill compressing tablet 0.1mm diaphragms, film are cut according to UL-94 flame-retardancy requirements, and hindered according to UL-94 method of testings Combustion test, recording detection data.
Testing result:PVC film test result containing the environmental protection fire retarding agent is that 0.1mm flame retardant ratings are UL-94 V-0 Rank.
Experiment shows that fire retardant obtained in above flame retardant formulations has good flame retardant effect in polyvinyl chloride film, Completely can be as new environmentally friendly polyvinyl chloride fire retardant.
Embodiment 6
A kind of polyvinyl chloride wall decoration thin-film material fire retardant, its preparation method is comprised the following steps:
Step 1, ferrous sulfate is soluble in water, obtain copperas solution, and zeolite powder added into the copperas solution, Mix, after after the zeolite powder homogeneous immersion, drying is crushed, and grinding must load iron ion zeolite.
Step 2, takes 8 parts of sepiolite, and it is ground to the particle of 0.002-0.005mm in Gas grinding machine, respectively Sepiolite particle, it is standby.
Step 3, takes 10 parts of aluminium hydroxide, and carrying out surface to aluminium hydroxide respectively using silane coupler KH570 is modified, and obtains KH570 modified aluminium hydroxides.
Step 4, in taking 5 parts of load iron ion zeolites input high-speed mixers, then puts into sepiolite particle, KH570 and is modified Aluminium hydroxide, and 1 part of antioxidant 1010 and 1 part of calcium stearate are added, after mixing 15 minutes, obtain final product.
Fire retardant manufactured in the present embodiment is taken for polyvinyl chloride wall decoration thin-film material, and detects the fire-retardant of the material Performance, specific detection method and testing result are as follows.
Detection method:10 parts of the fire retardant is taken, in 90 parts of pvc materials, being opened after dual-screw pelletizer granulation Mill compressing tablet 0.1mm diaphragms, film are cut according to UL-94 flame-retardancy requirements, and hindered according to UL-94 method of testings Combustion test, recording detection data.
Testing result:PVC film test result containing the environmental protection fire retarding agent is that 0.1mm flame retardant ratings are UL-94 V-0 Rank.
Experiment shows that fire retardant obtained in above flame retardant formulations has good flame retardant effect in polyvinyl chloride film, Completely can be as new environmentally friendly polyvinyl chloride fire retardant.
Embodiment 7
A kind of polyvinyl chloride wall decoration thin-film material fire retardant, its preparation method is comprised the following steps:
Step 1, ferrous sulfate is soluble in water, obtain copperas solution, and zeolite powder added into the copperas solution, Mix, after after the zeolite powder homogeneous immersion, drying is crushed, and grinding must load iron ion zeolite.
Step 2, takes 8 parts of sepiolite, and it is ground to the particle of 0.002-0.005mm in Gas grinding machine, respectively Sepiolite particle, it is standby.
Step 3, takes 10 parts of basic bismuth carbonate, and surface is carried out to basic bismuth carbonate using silane coupler KH570 is modified, and obtains KH570 is modified basic bismuth carbonate;10 parts of aluminium hydroxide is taken, surface is carried out to aluminium hydroxide using KH570 is modified, and obtains KH570 and changes Property aluminium hydroxide.
Step 4, in taking 5 parts of load iron ion zeolites input high-speed mixers, then puts into sepiolite particle, KH570 and is modified Basic bismuth carbonate and KH570 modified aluminium hydroxides, and 1 part of irgasfos 168 and 1 part of calcium stearate are added, after mixing 15 minutes, i.e., .
Fire retardant manufactured in the present embodiment is taken for polyvinyl chloride wall decoration thin-film material, and detects the fire-retardant of the material Performance, specific detection method and testing result are as follows.
Detection method:10 parts of the fire retardant is taken, in 90 parts of pvc materials, being opened after dual-screw pelletizer granulation Mill compressing tablet 0.1mm diaphragms, film are cut according to UL-94 flame-retardancy requirements, and hindered according to UL-94 method of testings Combustion test, recording detection data.
Testing result:PVC film test result containing the environmental protection fire retarding agent is that 0.1mm flame retardant ratings are UL-94 V-0 Rank.
Experiment shows that fire retardant obtained in above flame retardant formulations has good flame retardant effect in polyvinyl chloride film, Completely can be as new environmentally friendly polyvinyl chloride fire retardant.
Embodiment 8
A kind of polyvinyl chloride wall decoration thin-film material fire retardant, its preparation method is comprised the following steps:
Step 1, ferrous sulfate is soluble in water, obtain copperas solution, and zeolite powder added into the copperas solution, Mix, after after the zeolite powder homogeneous immersion, drying is crushed, and grinding must load iron ion zeolite.
Step 2, takes 10 parts of diatomite, 5 parts of artificial zeolite, and it is ground into 0.002- in Gas grinding machine respectively The particle of 0.005mm, obtains diatomite particle and artificial zeolite particle, standby.
Step 3, takes 10 parts of bismuth oxide, and surface is carried out to bismuth oxide using silane coupler KH570 is modified, and obtains KH570 and changes Property bismuth oxide;8 parts of magnesite of water intaking, carries out surface to hydromagnesite and is modified using KH570, obtains the modified hydromagnesites of KH570;Take 9 parts of Magnesiumaluminumsilicate, carries out surface to aluminum oxide and is modified using KH570, obtains KH570 modified magnesium aluminium silicates.
Step 4, in taking 3 parts of load iron ion zeolites input high-speed mixers, then puts into diatomite particle, artificial zeolite Grain, the modified oxidized bismuths of KH570, KH570 modified hydromagnesite and KH570 modified magnesium aluminium silicates, and 1 part of antioxidant 1010 of addition, 0.5 part of irgasfos 168 and 2 parts of calcium stearates, after mixing 15 minutes, obtain final product.
Fire retardant manufactured in the present embodiment is taken for polyvinyl chloride wall decoration thin-film material, and detects the fire-retardant of the material Performance, specific detection method and testing result are as follows.
Detection method:12 parts of the fire retardant is taken, in 88 parts of pvc materials, being opened after dual-screw pelletizer granulation Mill compressing tablet 0.1mm diaphragms, film are cut according to UL-94 flame-retardancy requirements, and hindered according to UL-94 method of testings Combustion test, recording detection data.
Testing result:PVC film test result containing the environmental protection fire retarding agent is that 0.1mm flame retardant ratings are UL-94 V-0 Rank.
Experiment shows that fire retardant obtained in above flame retardant formulations has good flame retardant effect in polyvinyl chloride film, Completely can be as new environmentally friendly polyvinyl chloride fire retardant.
Although the present invention is described in detail with a general description of the specific embodiments in this specification, But on the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art. Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to claimed model Enclose.

Claims (10)

1. a kind of polyvinyl chloride wall decoration thin-film material fire retardant, it is characterised in that including following raw material components:Bismuth chemical combination Thing, adsorbent, inorganic mineral fire retardant, bactericide, antioxidant and calcium stearate.
2. polyvinyl chloride wall decoration thin-film material fire retardant according to claim 1, it is characterised in that the raw material The weight portion of component is:Bismuth compound 0-20 parts, adsorbent 1-15 parts, 1-20 parts of inorganic mineral fire retardant, bactericide 1-5 parts, Antioxidant 0.1-2 parts, calcium stearate 1-2 parts.
3. polyvinyl chloride wall decoration thin-film material fire retardant according to claim 1, it is characterised in that the bismuth Compound is bismuth oxide or basic bismuth carbonate.
4. polyvinyl chloride wall decoration thin-film material fire retardant according to claim 1, it is characterised in that the absorption Agent is one or more in artificial zeolite, sepiolite or diatomite.
5. polyvinyl chloride wall decoration thin-film material fire retardant according to claim 1, it is characterised in that described inorganic Mineral flame retardants are one or more in aluminium hydroxide, kaolin, aluminum oxide, hydromagnesite or Magnesiumaluminumsilicate.
6. polyvinyl chloride wall decoration thin-film material fire retardant according to claim 1, it is characterised in that the sterilization Agent is load iron ion zeolite.
7. polyvinyl chloride wall decoration thin-film material fire retardant according to claim 1, it is characterised in that the antioxygen Agent is at least one in antioxidant 1010 or irgasfos 168.
8. the preparation method of the polyvinyl chloride wall decoration thin-film material fire retardant described in claim 1, it is characterised in that bag Include following steps:
Step 1, prepares bactericide, standby;
Step 2, adsorbent is ground to the particle of 0.002-0.005mm in Gas grinding machine respectively, obtains absorbent particles, standby With;
Step 3, the surface using silane coupler respectively to bismuth compound, inorganic mineral fire retardant is processed, and obtains silane idol Connection agent modified bismuth compound and silane coupler modified inorganic mineral fire retardant, it is standby;
Step 4, by the bactericide, absorbent particles, silane coupler modified bismuth compound and silane coupler modified inorganic In mineral flame retardants input high-speed mixer, and antioxidant, calcium stearate are added, after mixing 15 minutes, obtained final product.
9. polyvinyl chloride wall decoration thin-film material fire retardant according to claim 8, it is characterised in that in step 1, The bactericide is load iron ion zeolite.
10. polyvinyl chloride wall decoration thin-film material fire retardant according to claim 9, it is characterised in that described negative The preparation for carrying iron ion zeolite is followed the steps below:It is first that ferrous sulfate is soluble in water, copperas solution is obtained, and will Zeolite powder is added in the copperas solution, is mixed, and after after the zeolite powder homogeneous immersion, drying is crushed, grinding, Obtain final product load iron ion zeolite.
CN201710005936.7A 2017-01-05 2017-01-05 A kind of polyvinyl chloride wall decoration thin-film material fire retardant and preparation method thereof Pending CN106832421A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710005936.7A CN106832421A (en) 2017-01-05 2017-01-05 A kind of polyvinyl chloride wall decoration thin-film material fire retardant and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710005936.7A CN106832421A (en) 2017-01-05 2017-01-05 A kind of polyvinyl chloride wall decoration thin-film material fire retardant and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106832421A true CN106832421A (en) 2017-06-13

Family

ID=59116965

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710005936.7A Pending CN106832421A (en) 2017-01-05 2017-01-05 A kind of polyvinyl chloride wall decoration thin-film material fire retardant and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106832421A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107698897A (en) * 2017-10-30 2018-02-16 佛山威明塑胶有限公司 A kind of mould proof PVC film and its production method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1288021A (en) * 2000-10-27 2001-03-21 陈伟瑜 Fire-retardant and smoke-inhibiting type polyvinyl-chloride/calcium carbonate composite material and its prepn. method
WO2003066956A1 (en) * 2002-02-05 2003-08-14 Ykk Corporation Flame-retardant molded article and fabric product
CN102504433A (en) * 2011-10-09 2012-06-20 南京大学 Nano attapulgite composite PVC (Poly Vinyl Chloride) flame retardant and PVC flame retardant material and preparation methods of nano attapulgite composite PVC flame retardant and PVC flame retardant material
CN102511502A (en) * 2011-11-22 2012-06-27 周奇迪 Heterotrophic-bacterium antibacterial agent, preparation method thereof and water purifying device
CN102942750A (en) * 2012-10-23 2013-02-27 中南大学 Environment-friendly type flame retardant additive used for soft PVC product, and preparation method and application thereof
CN105579503A (en) * 2013-09-27 2016-05-11 巴斯夫欧洲公司 Polyolefin compositions for building materials

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1288021A (en) * 2000-10-27 2001-03-21 陈伟瑜 Fire-retardant and smoke-inhibiting type polyvinyl-chloride/calcium carbonate composite material and its prepn. method
WO2003066956A1 (en) * 2002-02-05 2003-08-14 Ykk Corporation Flame-retardant molded article and fabric product
CN102504433A (en) * 2011-10-09 2012-06-20 南京大学 Nano attapulgite composite PVC (Poly Vinyl Chloride) flame retardant and PVC flame retardant material and preparation methods of nano attapulgite composite PVC flame retardant and PVC flame retardant material
CN102511502A (en) * 2011-11-22 2012-06-27 周奇迪 Heterotrophic-bacterium antibacterial agent, preparation method thereof and water purifying device
CN102942750A (en) * 2012-10-23 2013-02-27 中南大学 Environment-friendly type flame retardant additive used for soft PVC product, and preparation method and application thereof
CN105579503A (en) * 2013-09-27 2016-05-11 巴斯夫欧洲公司 Polyolefin compositions for building materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107698897A (en) * 2017-10-30 2018-02-16 佛山威明塑胶有限公司 A kind of mould proof PVC film and its production method

Similar Documents

Publication Publication Date Title
CN105838147A (en) Negative ion wall brick ceramic ink and preparation method thereof
CN107118627A (en) Ultralow radiation removes formaldehyde low-carbon health coating
CN104671738A (en) Shale diatom ooze wall material and preparation method thereof
CN104497772B (en) Anion environmental protection coating
CN106566087A (en) Preparation method of base material for anion wall plates and floors capable of purifying indoor air
WO2018186605A1 (en) Antibacterial resin and manufacturing method therefor
WO2007004713A1 (en) Antibacterial agent comprising silver-containing aluminum sulfate hydroxide particle and use thereof
JP5515106B2 (en) Antibacterial products and powder antibacterial agents
CN104073072A (en) Nano functional ecological environmental-friendly coating
CN106966680B (en) A kind of purely inorganic anion function coating and preparation method
CN104059449A (en) Environmental-protection coating and preparation method
JPH062843B2 (en) Flame retardant and flame retardant resin composition
KR20190089665A (en) Method For preparing Inorganic Antimicrobial And Inorganic Antimicrobial Prepared By The Same Method
CN107936652A (en) Anti-fog haze low-carbon health coating
CN103571289A (en) Research and development of scrubbing-resistant odor-removal paint for internal walls
CN106832421A (en) A kind of polyvinyl chloride wall decoration thin-film material fire retardant and preparation method thereof
WO2018143782A1 (en) Highly functional solid oxygen composition and method for preparing same
CN107641416A (en) A kind of antibacterial powder paint
KR101561883B1 (en) Eco-friendly hybrid composition for coating of food packing paper
CN107868522A (en) A kind of inexpensive multifunction negative ion vinylacetate decorative energy-saving coating
CN106938164A (en) A kind of anti-haze immunologic function film and preparation method and application
CN106947348A (en) A kind of antibacterial is except emulsion paint of aldehyde and preparation method thereof
CN109337426A (en) With the energy composition and preparation method thereof for improving finishing properties of product
Pittol et al. Evaluation of commercial Mg (OH) 2, Al (OH) 3 and TiO2 as antimicrobial additives in thermoplastic elastomers
CN103007891A (en) Method for preparing air purification material

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170613