CN106830722B - Organic wastewater cooperates with the system and method for Industrial Solid Waste preparation ultrahigh water filler - Google Patents
Organic wastewater cooperates with the system and method for Industrial Solid Waste preparation ultrahigh water filler Download PDFInfo
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- CN106830722B CN106830722B CN201710163740.0A CN201710163740A CN106830722B CN 106830722 B CN106830722 B CN 106830722B CN 201710163740 A CN201710163740 A CN 201710163740A CN 106830722 B CN106830722 B CN 106830722B
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- 239000002351 wastewater Substances 0.000 title claims abstract description 81
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 239000000945 filler Substances 0.000 title claims abstract description 36
- 239000002910 solid waste Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 69
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000002002 slurry Substances 0.000 claims abstract description 25
- 239000010440 gypsum Substances 0.000 claims abstract description 22
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 22
- 238000001238 wet grinding Methods 0.000 claims abstract description 19
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 18
- 239000004411 aluminium Substances 0.000 claims abstract description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002893 slag Substances 0.000 claims abstract description 18
- 239000002270 dispersing agent Substances 0.000 claims abstract description 16
- 229910052742 iron Inorganic materials 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 15
- 230000002522 swelling Effects 0.000 claims abstract description 14
- 238000003837 high-temperature calcination Methods 0.000 claims abstract description 13
- 238000003825 pressing Methods 0.000 claims abstract description 13
- 239000002817 coal dust Substances 0.000 claims abstract description 7
- 238000004064 recycling Methods 0.000 claims abstract description 7
- 238000002485 combustion reaction Methods 0.000 claims abstract description 5
- 239000011268 mixed slurry Substances 0.000 claims abstract description 4
- 238000006297 dehydration reaction Methods 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 3
- 239000002918 waste heat Substances 0.000 claims description 24
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 21
- 239000003546 flue gas Substances 0.000 claims description 21
- 238000011084 recovery Methods 0.000 claims description 20
- 230000005591 charge neutralization Effects 0.000 claims description 14
- 238000006386 neutralization reaction Methods 0.000 claims description 14
- 239000010815 organic waste Substances 0.000 claims description 11
- 238000001354 calcination Methods 0.000 claims description 10
- 230000001264 neutralization Effects 0.000 claims description 10
- -1 gangue Substances 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 8
- 239000000706 filtrate Substances 0.000 claims description 6
- 239000000779 smoke Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 239000003245 coal Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 239000003517 fume Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims 1
- 238000011049 filling Methods 0.000 description 22
- 239000002956 ash Substances 0.000 description 13
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000292 calcium oxide Substances 0.000 description 5
- 235000012255 calcium oxide Nutrition 0.000 description 5
- 239000004568 cement Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 229910052681 coesite Inorganic materials 0.000 description 4
- 229910052906 cristobalite Inorganic materials 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 238000005065 mining Methods 0.000 description 4
- 229910052904 quartz Inorganic materials 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229910052682 stishovite Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 229910052905 tridymite Inorganic materials 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 210000002356 Skeleton Anatomy 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 229910052918 calcium silicate Inorganic materials 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000032258 transport Effects 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- JHLNERQLKQQLRZ-UHFFFAOYSA-N Calcium silicate Chemical compound [Ca+2].[Ca+2].[O-][Si]([O-])([O-])[O-] JHLNERQLKQQLRZ-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 230000003487 anti-permeability Effects 0.000 description 2
- 235000012241 calcium silicate Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000010881 fly ash Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000276438 Gadus morhua Species 0.000 description 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N Potassium oxide Chemical compound [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 1
- 210000002966 Serum Anatomy 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- YVKMMZAFUFUAAX-UHFFFAOYSA-N aluminum;tetrahydrate Chemical compound O.O.O.O.[Al] YVKMMZAFUFUAAX-UHFFFAOYSA-N 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 230000001580 bacterial Effects 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 235000019516 cod Nutrition 0.000 description 1
- 230000002860 competitive Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 231100000078 corrosive Toxicity 0.000 description 1
- 231100001010 corrosive Toxicity 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000005712 crystallization Effects 0.000 description 1
- 239000010840 domestic wastewater Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000001418 larval Effects 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000036961 partial Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000001954 sterilising Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/24—Cements from oil shales, residues or waste other than slag
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Abstract
The invention discloses the system and methods of organic wastewater collaboration Industrial Solid Waste preparation ultrahigh water filler, system includes wet grinding machine, filter press, balancing reservoir, rotary kiln and indirect heat exchanger, by desulfurized gypsum, aluminium ash, carbide slag, gangue, mixed liquor is obtained after iron tailings and the mixing of a part of organic wastewater, be in the mixed liquor moisture content be 60%~70% (quality), wet grinding is carried out to mixed liquor again, then the material after wet grinding is homogenized processing and obtains slurries, the slurries obtain slurry by mechanism filter-pressing dehydration, another part organic wastewater, which enters after concentration together with the slurry in rotary kiln, carries out high-temperature calcination acquisition basis material, coal dust is sprayed into high-temperature burning process into rotary kiln, make the organic compound combustion in coal dust and mixed slurry, finally by basis material and accelerator, Dispersing agent, swelling agent and water are configured to ultrahigh water filler.The system and method realize that Industrial Solid Waste recycling prepares brand-new material ultrahigh water filler.
Description
Technical field
The present invention relates to the system and methods of organic wastewater collaboration Industrial Solid Waste preparation ultrahigh water filler.
Background technique
The backfill technology development in the goafs such as coal mine all relatively lags behind all the time, reduces the efficiency of mining, increases
The cost of mining causes the security risk of reduction to society and environment.Ultrahigh water filler is as a kind of emerging backfill
Material causes more and more to pay close attention to.Ultrahigh water filler must have good performance, could be used for goaf filling and set
Change exploitation, should specifically have following basic performance: 1, the compression strength of the filler after solidifying should be more than 2MPa；2,
There must be good fluid ability, just be able to satisfy long distance delivery requirement；3, suitable curing characteristics (is primarily referred to as material
Presetting period and final setting time)；4, compared with mining costs, there is lower cost；5, higher safety and stability.With
On five kinds of basic performances be tradition preparation ultrahigh water filler problem in need of consideration, but with resource exploitations such as coal mines
Go deep into, these types of basic performance is no longer satisfied actual demand.Such as, pollute now increasingly severe, roof drain is to be in
If acid, permeate the ground, then can cause certain corrosion function to filler；Ultrahigh water filler solidifying body is exposed to sky
By slacking in gas, its support strength can be also seriously affected；When the underwater constructions such as ocean, filler is needed to have enough
Anti-permeability performance and erosion-resisting characteristics etc..In addition, the primary raw material of existing ultrahigh water filler is flyash, cement, raw stone
Ash, gypsum, foaming agent and water etc., various composition require higher cost, so, the filling mining of high water filling material is difficult to
Obtain considerable economic benefit.
China's economic development is rapid, and a large amount of energy consumption produces a large amount of industrial solid castoff (abbreviation Industrial Solid
It is useless), Industrial Solid Waste mainly includes red mud, desulfurized gypsum, metallurgical slag, CHARACTERISTICS OF TAILINGS SAND and gangue etc..The Eleventh Five-Year Plan period Industrial Solid
Useless 11,800,000,000 tons of total growth, always increases 19,000,000,000 tons of storage newly.15,000,000,000 tons of Industrial Solid Waste total growth during " 12th Five-Year Plan " are total new
Increase 27,000,000,000 tons of storage.With the continuous quickening of China's process of industrialization, these Industrial Solid Wastes account for a large amount of soils and exist simultaneously at any time
Pollute the danger of environment.
Meanwhile from urban domestic wastewater to petrochemical industry, metallurgy, papermaking, ferment wine brewing, pharmacy, textile printing and dyeing wastewater all
Belong to organic wastewater, organic wastewater be with organic pollutant and by bacterial virus pollute based on waste water, organic wastewater easily causes
Water Eutrophication.Organic wastewater direct emission can cause serious pollution to environment, pose a serious threat to health of human body,
So organic wastewater has to pass through effective processing and could discharge.With the increase of China human mortality quantity, urbanization process adds
Fastly, the trend that quantity is more, concentration is high, toxicity is big is presented in industrial rapid development and plant-scale continuous expansion, organic wastewater.
Incineration method is to handle organic wastewater with air deep oxidation under high temperature, is most effective most thorough means, and high
Warm deep oxidation method processing organic wastewater most easily realizes industrialized method.Usual COD > 100g/L, calorific value > 10500kJ/kg
High-concentration waste water is handled more reasonable than other methods, more economical with incineration method.In general, content of organics is greater than 10%
Organic harmful waste liquid mostly makees final process using burning.Using incineration method can exhaustive oxidation divides at high temperature by harmful organic substance
Solution, generates carbon dioxide and water, and the removal rate of the organic matter in waste liquid is up to 99.99% or more, and short processing time, investment
It is few, it takes up little area.
But incineration method has the shortcomings that equipment investment is big, processing cost is high, in addition to certain special water (such as hospital wastewaters
Need sterilization) must be using outside the method, the processing of general organic wastewater is difficult to be handled using incineration method.
Summary of the invention
It is an object of the invention to handle the preparation ultrahigh water filling of the solid wastes cooperative disposal organic wastewater such as red mud, desulfurized gypsum
Material provides the system and method for organic wastewater collaboration Industrial Solid Waste preparation ultrahigh water filler, it both handled red mud, taken off
The solid wastes cooperative disposal organic wastewater such as sulphur gypsum is able to produce ultrahigh water filler again simultaneously.The system and method are not only realized
Comprehensive utilization and the zero emission of Industrial Solid Waste recycling, Industrial Solid Waste and organic wastewater materialization, also reduce ultrahigh water and fill
The production cost of filling chock material.
To achieve the above object, the technical solution of the present invention is as follows:
Organic wastewater cooperate with Industrial Solid Waste preparation ultrahigh water filler method, by desulfurized gypsum, aluminium ash, carbide slag,
Gangue, iron tailings and a part of organic wastewater mixing after obtain mixed liquor, be in the mixed liquor moisture content be 60%~
70% (quality), then wet grinding is carried out to mixed liquor, the material after wet grinding is then homogenized processing and obtains slurries,
The slurries obtain slurry by mechanism filter-pressing dehydration, and another part organic wastewater enters together with the slurry after concentration
High-temperature calcination is carried out in rotary kiln and obtains basis material, sprays into coal dust into rotary kiln in high-temperature burning process, is made coal dust and is mixed
The organic compound combustion in slurry is closed, basis material and accelerator, dispersing agent, swelling agent and water are finally configured to ultrahigh water filling
Material.
Firstly, present invention utilizes the Industrial Solid Wastes such as gangue, iron tailings, desulfurized gypsum, aluminium ash and carbide slag instead of excellent
Matter mineral resources avoid solid waste to the occupancy and pollution of land resource to prepare high water filling material, realize big
The comprehensive utilization of resources of ancestor's industrial solid castoff, greatly reduces the cost of high water filling material preparation, improves coal mine
The economic benefit of equal exploitations of mineral resources.It is burnt secondly, the present invention realizes organic wastewater using the equipment of preparation ultrahigh water filler
The application of burning method, meanwhile, it is capable to which the equipment for making full use of preparation ultrahigh water filler handles organic waste aquatic products using incineration method
Raw energy realizes the recovery energy of organic wastewater, reduces the use of coal dust, to not only handle organic wastewater but also reduce
The cost of production ultrahigh water filler.Third, the present invention are mixed using a part of organic wastewater with Industrial Solid Waste, no
It reduced by only the dosage of industry water, and mixed in homogenization process in Industrial Solid Waste with organic wastewater, part debirs quilt
It is fixed in Industrial Solid Waste, enables combustion of the fixed debirs as high-temperature calcination during calcining cement clinker
Material, to reduce the use of coal dust, reduces production cost.Another part organic wastewater after concentration by directly carrying out simultaneously
High-temperature calcination not only provides fuel to high-temperature calcination, but also is sufficiently handled debirs in organic wastewater.
Moisture content in heretofore described mixed liquor is that 60~70% (quality) are conducive to the abundant of above-mentioned raw material
The removal of homogenizing and harmful magazine.Meanwhile wet grinding may make sufficiently to carry out, moisture content is too small to be not easy abundant grinding, water
The excessive energy consumption of point content increases.
The purpose of heretofore described homogenizing processing is the soluble impurity removed in material, and is removed in dealkalize red mud
Sodium oxide molybdena and potassium oxide, so that raw material is carried out further dealkalize.
Heretofore described wet grinding is the method that water-containing materials are carried out grinding.
Preferably, the mass ratio of desulfurized gypsum, aluminium ash, carbide slag, gangue and iron tailings are as follows: 13~20:15~20:30
~35:20~25:8~16.
Preferably, the slurries stirring carries out filters pressing after a certain period of time.Mix each component in material abundant.
It is further preferred that the certain time is 12h.
Preferably, the filtrate after mechanism filter-pressing flows back into organic wastewater.So that the organic waste that do not fixed by Industrial Solid Waste
Object can be carried out to be handled again, prevents the zero-emission of debirs.
Preferably, the organic wastewater is pre-processed before concentration.
It is further preferred that the pretreatment includes filtering.Remove the suspended matter in organic wastewater.
Still more preferably, the partial size of the solia particle after filtering in organic wastewater is less than 40 meshes.
It is further preferred that the pretreatment includes neutralisation treatment.Corrosion concentrator is prevented, while it is rotten for preventing from burning
Lose rotary kiln or the slagging in rotary kiln.
Still more preferably, the pH of organic wastewater is 6~8 after neutralisation treatment.
It is further preferred that the pretreatment successively includes filtering, neutralisation treatment.
Preferably, the thickening temperature of the organic wastewater is 85~95 DEG C.
Preferably, the moisture content in the mixed serum is 20~25% (quality).Moisture content is in 20~25% models
The needs of subsequent production can be met in enclosing, and be suitble to the processing capacity of abovementioned steps, moreover it is possible to fuel when calcining can be saved
It uses.
Preferably, the temperature of the calcining is 1250~1300 DEG C, and calcination time is 60~80min.
Preferably, the high-temperature flue gas that the rotary kiln generates generates high-temperature steam by waste heat recycling.
It is further preferred that the heat source that the high-temperature steam is concentrated as organic wastewater.
It is further preferred that the high-temperature steam is cooled to 85~95 DEG C of heat sources as organic wastewater concentration.
It is further preferred that being discharged after dedusting by fume treatment through waste heat flue gas after the recovery.
Preferably, in described matrix material, basicity factor CmIt is 0.95~0.98；Aluminium-sulfur ratio P is 2.1~3.5.
Al in formula2O3、SO3、SiO2、CaO、TiO2、Fe2O3It is the percentage composition of each oxide in clinker (other than formula
The Al2O3、SO3、SiO2、CaO、TiO2、Fe2O3Respectively corresponding chemical ingredient).
It is further preferred that the chemical composition of described matrix material is as shown in table 1.
The chemical composition (wt%) of 1 basis material of table
| Kind | SiO2 | Al2O3 | CaO | SO3 | Fe2O3 |
| Content % | 5~13 | 29~35 | 30~42 | 8~16 | 11~12.5 |
By verification experimental verification, the iron-content in basis material is larger, and prepared precursor material contains more iron aluminium
Hydrochlorate mineral (such as calcium aluminoferrite) generate aquation calcium aluminoferrite after aquation, and aquation calcium aluminoferrite has compact texture, not with atmosphere
In the corrosive ions such as sulfate radical, carbonate generate chemical reaction, and voidage is very low, can block other molecules or
Ion intrusion, can infringement to avoid air to hydrated product, air can also be reduced to the crystallization water in high water filling material
It influences, therefore the corrosion resistance of the high water filling material of basis material preparation is stronger, especially has stronger resistance to weathering energy.
In addition, the high water filling material of basis material preparation has preferable anti-permeability performance, it is underwater to be more suitable for ocean etc.
Construction.
It is not necessary that cement is added in the basis material, compression strength can reach 2~3MPa in 2 hours, have enough
Support strength, later strength is high.
It is further preferred that the essential mineral composition of described matrix material is as shown in table 2.
The essential mineral of 2 basis material of table forms (wt%)
The basis material of acquisition is with calcium sulphoaluminate (3CaO3Al2O3·CaSO4, skeleton symbol), dicalcium silicate
(2CaO·SiO2, skeleton symbol C2) and iron phase (predominantly 4CaOAl S2O3·Fe2O3, skeleton symbol C4It AF) is essential mineral.
Preferably, in step 4), accelerator, dispersing agent and the swelling agent of addition account for the mass percent of basis material respectively
It is 0.1~1%, 0.5~2% and 0.5~2%, the quality of the water of addition is the 95~97% of high water filling material gross mass.
The clinker that accelerator main component is aluminum oxide clinker, soda ash, quick lime are fired into proportion, is made through levigate,
It is to mix the additive that concrete can be made to condense hardening rapidly in concrete, which can accelerate the end of high water filling material
Solidifying speed can solidify in a relatively short period of time after filling high water filling material, provide enough support strengths.
Dispersing agent is one kind in the molecule while having lipophilic and two kinds of opposite natures of hydrophily interfacial agent, is
Promote material particles to be dispersed in medium, forms the medicament of stable suspension.
Swelling agent can cause volume expansion by physical and chemical reaction, be added in high water filling material, work as high water filling material
When condensation hardening, volume expansion therewith plays a part of to be sufficient filling with cement gap, and the filling effect of high water filling material can be improved
Fruit.It preferably, further include carrying out heating to water using the high-temperature flue gas discharged in rotary kiln to obtain high-temperature steam in step 3),
And the step of high-temperature steam is subjected to heating, drying to material.
The basis material that the above method is prepared.
A kind of ultrahigh water filler, it is composed of the following components: above-mentioned 1~3 parts by weight of basis material, 95~97 weight of water
Part, accelerator, dispersing agent and swelling agent, the quality of accelerator, dispersing agent and swelling agent be respectively basis material quality 0.1~
1%, 0.5~2% and 0.5~2%.
Organic wastewater cooperate with Industrial Solid Waste preparation ultrahigh water filler system, including wet grinding machine, filter press,
Change pond, rotary kiln and indirect heat exchanger, desulfurized gypsum, aluminium ash, carbide slag, gangue, iron tailings and comes from organic waste pond
A part of organic wastewater enter wet grinding machine carry out wet grinding, then sequentially enter balancing reservoir, filter press is homogenized place
Reason and filters pressing obtain slurry, another part organic wastewater in organic waste pond enter after indirect heat exchanger is concentrated with
The slurry enters rotary kiln together and carries out high-temperature calcination, the basis material obtained after high-temperature calcination and accelerator, dispersing agent, swollen
Swollen dose is configured to ultrahigh water filler with water.
Preferably, the filtrate generated after the filter press filters pressing enters the organic waste pond.It is further processed in filtrate
Debirs.
Preferably, including filter device, another part organic wastewater enter back into indirectly after entering filter device filtering
Heat exchanger.
Preferably, including neutralization pond, another part organic wastewater, which enters after neutralization pond is neutralized, enters back into indirectly
Heat exchanger.
Preferably, including filter device and neutralization pond, another part organic wastewater sequentially enter filter device in
Indirect heat exchanger is entered back into after being filtered and neutralize respectively with pond.
Preferably, including waste heat recovery apparatus, the high-temperature flue gas that rotary kiln generates enter waste heat recovery apparatus and carry out waste heat
Recycling.
It is further preferred that heat source of the waste heat high-temperature steam after the recovery as indirect heat exchanger.
It is further preferred that including cooler, waste heat high-temperature steam after the recovery enters indirectly after entering cooler cooling
Heat exchanger.
It is further preferred that including deduster, waste heat flue gas after the recovery enters deduster and is dusted.
Still more preferably, including smoke processing system, flue gas enters smoke processing system and carries out at flue gas after dedusting
It is discharged after reason.
The invention has the benefit that
(1) basic raw material of ultrahigh water filler preparation method is flyash, cement, quick lime, gypsum, generally using outer
The mode of purchase solves, and higher price causes cost of manufacture to rise, and competitive pressure is huge.The present invention can rely on Industrial Solid completely
Useless that it is replaced to make raw material, cost of manufacture declines to a great extent, and solves conventional ultra high while solving the problems, such as that solid waste is difficult to be utilized
The deficiency of water filler production.
(2) the solid waste raw material of present invention production ultrahigh water filler is gangue, desulfurized gypsum, aluminium are grey and carbide slag,
It solves a series of problems, such as land seizure, environmental pollution, wasting of resources, them is made to turn waste into wealth.These solid wastes are produced and are looked forward to
The burden of solid waste problem is not only solved for industry, but also brings economic interests.
(3) in present invention process, by wet processing, using the comprehensive utilization of solid waste and organic wastewater materialization, rationally
The organic wastewater that concentration is added in raw material, reduce the dosage of part industry water.And using concentration organic wastewater can
Combustion property, burning of coal amount can be reduced by burning heat release in rotary furnace.The heat of flue gas can be recycled for the vacuum to organic wastewater
Concentration.Realize that the saving of fuel utilizes.
Detailed description of the invention
Fig. 1 is process flow chart of the invention.
Specific embodiment
The present invention will be further explained below with reference to the attached drawings.
Organic wastewater cooperate with Industrial Solid Waste preparation ultrahigh water filler system, including wet grinding machine, filter press,
Change pond, rotary kiln and indirect heat exchanger, desulfurized gypsum, aluminium ash, carbide slag, gangue, iron tailings and comes from organic waste pond
A part of organic wastewater enter wet grinding machine carry out wet grinding, then sequentially enter balancing reservoir, filter press is homogenized place
Reason and filters pressing obtain slurry, another part organic wastewater in organic waste pond enter after indirect heat exchanger is concentrated with
The slurry enters rotary kiln together and carries out high-temperature calcination, the basis material obtained after high-temperature calcination and accelerator, dispersing agent, swollen
Swollen dose is configured to ultrahigh water filler with water.
Including filter device and neutralization pond, another part organic wastewater sequentially enters filter device and carries out respectively with neutralization pond
Indirect heat exchanger is entered back into after filtering and neutralization.
Including waste heat recovery apparatus, the high-temperature flue gas that rotary kiln generates enters waste heat recovery apparatus and carries out waste heat recycling.
Including cooler, waste heat high-temperature steam after the recovery enters indirect heat exchanger after entering cooler cooling.
Including deduster, waste heat flue gas after the recovery enters deduster and is dusted.
Including smoke processing system, flue gas enters after smoke processing system carries out fume treatment and discharges after dedusting.
As shown in Figure 1, its technique is as follows:
1. desulfurized gypsum, aluminium ash, carbide slag, gangue, iron tailings are mixed matching in proportion, it is added in organic waste pond
A part of organic wastewater formed mixed liquor, make the moisture content of mixed liquor 60%~70%, and be sufficiently stirred.
2. uniformly mixed slurries are carried out grinding by wet grinding mill.
3. stirring 12h by the slurries after mill after balancing reservoir is homogenized except alkali, obtaining the uniform slurries of ingredient.
4. uniform slurries are dehydrated by mechanism filter-pressing and obtain slurry, the filtrate after filters pressing is delivered to organic waste pond
In.
5. another part organic wastewater in organic wastewater wastewater disposal basin is handled, that is, pre-process.It is filtered contained by making
Solia particle is in 40 meshes hereinafter, removing the suspended matter in the part organic wastewater.
6. then neutralizing to filtered organic wastewater, organic wastewater is made to reach neutral or close to neutrality, prevent
Slagging in kiln body or kiln can be corroded when burning.
7. neutralized organic wastewater is sent to indirect heat exchanger, 85 are cooled to using the steam that waste heat recovery apparatus generates
~95 DEG C are concentrated organic wastewater indirectly, and make its moisture content below 30%.
8. the organic wastewater after concentration is sent into rotary kiln with the slurry that step 4 obtains, (1250 DEG C of high-temperature calcination are carried out
~1350 DEG C).
It burns 9. pulverized bituminous coal is sprayed into rotary kiln burner.
10. rotary kiln flue gas is connected to flue gas waste heat recovery equipment, the high-temperature steam of generation is cooled to 85 DEG C~95 DEG C, leads to
It crosses indirect heat exchanger and indirect concentration is carried out to organic wastewater.
11. being passed through bag filter by the flue gas of waste heat recovery apparatus to be dusted.Finally it is passed through smoke processing system
Desulphurization denitration is carried out, is emitted into atmosphere after fume treatment is qualified.
12. the basis material generated in rotary kiln, is cooled down by cooler, obtained basis material is with sulphur aluminic acid
CalciumDicalcium silicate (C2) and iron phase (predominantly C S4It AF) is essential mineral.
13. addition accelerator, dispersing agent, swelling agent and water are configured to ultrahigh water filling material by basis material after cooling
Material.
Embodiment 1
It is prepared according to using above system and above-mentioned technique, design parameter is as follows: gangue is crushed, with
Aluminium ash, carbide slag, desulfurized gypsum carry out ingredient, and in terms of solid matter, gangue accounts for 25 parts by weight, and desulfurized gypsum accounts for 17 weight
Part, carbide slag accounts for 40 parts by weight, and aluminium ash accounts for 18 parts by weight, and iron tailings accounts for 8 parts by weight.Grinding homogenizing, pressure are carried out after material cooperation
It directly transports in rotary kiln and calcines after filter, firing temperature is 1270 DEG C, and calcination time is 80 minutes.Clinker after firing is main
Object is mutually calcium sulphoaluminate and dicalcium silicate.Take above-mentioned basis material, be added basis material quality 1.0% accelerator, 1.5%
Swelling agent, 1.5% dispersing agent, separately take 96 parts of water, the quality of every part of water is identical in quality with above-mentioned basis material, is sufficiently mixed
Prepare ultrahigh water filler.Presetting period is 30 minutes, and final setting time 2.5h, intensity reaches 2.5MPa within 3 hours.
Embodiment 2
It is prepared according to using above system and above-mentioned technique, design parameter is as follows: gangue is crushed, with
Aluminium ash, carbide slag, desulfurized gypsum carry out ingredient, and in terms of solid matter, gangue is 23 parts by weight, and desulfurized gypsum is 22 weight
Part, carbide slag is 35 parts by weight, and aluminium ash accounts for 20 parts by weight, and iron tailings accounts for 11 parts by weight.Grinding homogenizing, pressure are carried out after material cooperation
It directly transports in rotary kiln and calcines after filter, calcination temperature is 1350 DEG C, and calcination time is 80 minutes.Above-mentioned basis material is taken,
The accelerator of basis material quality 0.5%, 1.5% swelling agent is added, 1.0% dispersing agent separately takes 97 parts of water, every 2 parts of water
Quality and above-mentioned basis material it is identical in quality, be sufficiently mixed preparation ultrahigh water filler.Presetting period is 10 minutes, eventually
The solidifying time is 2h, and intensity reaches 3.2MPa within 3 hours.
Embodiment 3
It is prepared according to using above system and above-mentioned technique, design parameter is as follows: gangue is crushed, with
Aluminium ash, carbide slag, desulfurized gypsum carry out ingredient, and in terms of solid matter, gangue is 21 parts by weight, and desulfurized gypsum is 20 weight
Part, carbide slag is 37 parts by weight, and aluminium ash accounts for 15 parts by weight, and iron tailings accounts for 15 parts by weight.Grinding homogenizing, pressure are carried out after material cooperation
It directly transports in rotary kiln and calcines after filter, calcination temperature is 1350 DEG C, and calcination time is 75 minutes.Above-mentioned basis material is taken,
The accelerator of basis material quality 1.0%, 0.5% swelling agent is added, 1.5% dispersing agent separately takes 97 parts of water, every 2 parts of water
Quality and above-mentioned basis material it is identical in quality, be sufficiently mixed preparation ultrahigh water filler.Presetting period is 20 minutes, eventually
The solidifying time is 3h, and intensity reaches 2.9MPa within 3 hours.
Anti-erosion test:
Each embodiment 1-3 high water filling material prepared is divided into two groups and tests: one group be placed in curing box into
Row maintenance, as test group, embodiment 1-3 respectively corresponds test group one, test group two and test group three；One group of sky disposed within
Allow its weathering in gas, as a control group, embodiment 1-3 respectively corresponds control group one, control group two and control group three.Test
When, normal maintenance block and the compression strength for being carried out different larval instar by weathering block are measured, the results are shown in Table 1.
Table 1
Above-mentioned, although the foregoing specific embodiments of the present invention is described with reference to the accompanying drawings, not to invention protection scope
Limitation, those skilled in the art should understand that, based on the technical solutions of the present invention, those skilled in the art are not required to
It is still within the scope of the present invention to make the creative labor the various modifications or changes that can be made.
Claims (25)
1. organic wastewater cooperate with Industrial Solid Waste preparation ultrahigh water filler method, characterized in that by desulfurized gypsum, aluminium ash,
Mixed liquor is obtained after carbide slag, gangue, iron tailings and the mixing of a part of organic wastewater, is that moisture content is in the mixed liquor
60%~70% mass percent, then wet grinding is carried out to mixed liquor, the material after wet grinding is then homogenized place
Reason obtains slurries, and the slurries obtain slurry by mechanism filter-pressing dehydration, another part organic wastewater after concentration with it is described
Slurry, which enters together in rotary kiln, carries out high-temperature calcination acquisition basis material, and coal is sprayed into rotary kiln in high-temperature burning process
Powder makes the organic compound combustion in coal dust and mixed slurry, finally matches basis material and accelerator, dispersing agent, swelling agent and water
Ultrahigh water filler is made；
Desulfurized gypsum, aluminium ash, carbide slag, gangue and iron tailings mass ratio are as follows: 13~20:15~20:30~35:20~
25:8~16.
2. the method as described in claim 1, characterized in that the filtrate after mechanism filter-pressing flows back into organic wastewater.
3. the method as described in claim 1, characterized in that the organic wastewater is pre-processed before concentration.
4. method as claimed in claim 3, characterized in that the pretreatment includes filtering.
5. method as claimed in claim 3, characterized in that the pretreatment includes neutralisation treatment.
6. method as claimed in claim 3, characterized in that the pretreatment successively includes filtering, neutralisation treatment.
7. the method as described in claim 1, characterized in that the thickening temperature of the organic wastewater is 85~95 DEG C.
8. the method as described in claim 1, characterized in that the moisture content in the mixed slurry is 20~25% mass hundred
Score.
9. the method as described in claim 1, characterized in that the temperature of the calcining is 1250~1300 DEG C.
10. the method as described in claim 1, characterized in that the high-temperature flue gas that the rotary kiln generates is produced by waste heat recycling
Raw high-temperature steam.
11. method as claimed in claim 10, characterized in that the heat source that the high-temperature steam is concentrated as organic wastewater.
12. method as claimed in claim 10, characterized in that the high-temperature steam is cooled to 85~95 DEG C as organic wastewater
The heat source of concentration.
13. method as claimed in claim 10, characterized in that through waste heat flue gas after the recovery after dedusting by flue gas at
Reason is discharged.
14. the basis material that the method as described in claim 1 is prepared.
15. a kind of ultrahigh water filler, characterized in that composed of the following components: basis material 1 described in claim 14~
3 parts by weight, 95~97 parts by weight of water, accelerator, dispersing agent and swelling agent, the quality difference of accelerator, dispersing agent and swelling agent
It is 0.1~1%, 0.5~2% and the 0.5~2% of basis material quality.
16. organic wastewater cooperate with Industrial Solid Waste preparation ultrahigh water filler system, characterized in that including wet grinding machine,
Filter press, balancing reservoir, rotary kiln and indirect heat exchanger, desulfurized gypsum, aluminium ash, carbide slag, gangue, iron tailings and from organic
A part of organic wastewater in wastewater disposal basin enter wet grinding machine carry out wet grinding, then sequentially enter balancing reservoir, filter press into
The processing of row homogenizing and filters pressing obtain slurry, and another part organic wastewater in organic waste pond enters indirect heat exchanger progress
Enter rotary kiln after concentration together with the slurry and carries out high-temperature calcination, the basis material obtained after high-temperature calcination and accelerator,
Dispersing agent, swelling agent and water are configured to ultrahigh water filler.
17. system as claimed in claim 16, characterized in that the filtrate generated after the filter press filters pressing enters described organic
Wastewater disposal basin.
18. system as claimed in claim 16, characterized in that including filter device, another part organic wastewater enters
Indirect heat exchanger is entered back into after filter device filtering.
19. system as claimed in claim 16, characterized in that including neutralization pond, in another part organic wastewater entrance
Indirect heat exchanger is entered back into after being neutralized with pond.
20. system as claimed in claim 16, characterized in that including filter device and neutralization pond, described another part is organic
Waste water sequentially enters after filter device is filtered and neutralizes respectively with neutralization pond and enters back into indirect heat exchanger.
21. system as claimed in claim 16, characterized in that the high-temperature flue gas generated including waste heat recovery apparatus, rotary kiln
Waste heat recycling is carried out into waste heat recovery apparatus.
22. system as claimed in claim 21, characterized in that heat of the waste heat high-temperature steam after the recovery as indirect heat exchanger
Source.
23. system as claimed in claim 21, characterized in that including cooler, waste heat high-temperature steam after the recovery enters cold
But enter indirect heat exchanger after device is cooling.
24. system as claimed in claim 21, characterized in that including deduster, waste heat flue gas after the recovery enters deduster
It is dusted.
25. system as claimed in claim 21, characterized in that including smoke processing system, flue gas enters at flue gas after dedusting
Reason system is discharged after carrying out fume treatment.
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| CN201710163740.0A CN106830722B (en) | 2017-03-17 | 2017-03-17 | Organic wastewater cooperates with the system and method for Industrial Solid Waste preparation ultrahigh water filler |
| PCT/CN2017/109613 WO2018166221A1 (en) | 2017-03-17 | 2017-11-07 | System and method for co-treating organic wastewater and industrial solid waste |
| ZA2019/06734A ZA201906734B (en) | 2017-03-17 | 2019-10-11 | System and method for co-treating organic wastewater and industrial solid waste |
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| WO2018166221A1 (en) * | 2017-03-17 | 2018-09-20 | 山东大学 | System and method for co-treating organic wastewater and industrial solid waste |
| CN108424090B (en) * | 2018-03-16 | 2020-02-11 | 山东大学 | Method for preparing ultrahigh water filling material by using iron-aluminum high-activity material in cooperation with industrial solid waste |
| CN110282941A (en) * | 2019-05-29 | 2019-09-27 | 昌鑫生态科技(陕西)有限公司 | Utilize the technology of Industrial Solid Waste processing environmental friendly material |
| CN110357463B (en) * | 2019-06-25 | 2021-11-09 | 成都华寰环保科技有限公司 | Wet processing method for drilling oil-based mud rock debris |
| CN110228990A (en) * | 2019-07-08 | 2019-09-13 | 山东大学 | A kind of preparation method of full solid waste upper flow regime Paste-like body filler |
| CN111072299B (en) * | 2019-12-19 | 2021-12-28 | 江苏盐砼新材料科技有限公司 | Concrete mineral admixture based on steel slag flotation tail mud and preparation method thereof |
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| CN1166465A (en) * | 1997-01-08 | 1997-12-03 | 中国建筑材料科学研究院水泥所阳泉联营特种水泥厂 | High-moisture quick-setting mono-slurry |
| CN1915881A (en) * | 2006-09-07 | 2007-02-21 | 朱建伟 | Method for producing chamotte of silicate cement by using from dyeing wastewater |
| CN103922622A (en) * | 2014-03-20 | 2014-07-16 | 山东大学 | Process for producing sulphoaluminate cement by using aluminum ash |
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| CN1166465A (en) * | 1997-01-08 | 1997-12-03 | 中国建筑材料科学研究院水泥所阳泉联营特种水泥厂 | High-moisture quick-setting mono-slurry |
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