CN106830125A - A kind of purifying agent for polluted water for processing dirty water pollutant and preparation method thereof - Google Patents

A kind of purifying agent for polluted water for processing dirty water pollutant and preparation method thereof Download PDF

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Publication number
CN106830125A
CN106830125A CN201710147381.XA CN201710147381A CN106830125A CN 106830125 A CN106830125 A CN 106830125A CN 201710147381 A CN201710147381 A CN 201710147381A CN 106830125 A CN106830125 A CN 106830125A
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China
Prior art keywords
parts
water
purifying agent
fiber
mixed liquor
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CN201710147381.XA
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Chinese (zh)
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不公告发明人
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Hefei Wisdom Longtuteng Intellectual Property Co Ltd
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Hefei Wisdom Longtuteng Intellectual Property Co Ltd
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Priority to CN201710147381.XA priority Critical patent/CN106830125A/en
Publication of CN106830125A publication Critical patent/CN106830125A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption

Abstract

The invention discloses a kind of purifying agent for polluted water for processing dirty water pollutant, it is made up of according to weight portion following raw material:0.1 0.4 parts of 45 73 parts of slag, 5 15 parts of land plaster, 38 parts of quartz, 8 16 parts of diatomite, 26 parts of oxide powder, 10 14 parts of water soluble phenol resin, 0.5 1.5 parts of fiber, 13 22 parts of ethyl acetate, 13 parts of shitosan, 35 parts of dry cow dung and egg.The present invention also disclosed the preparation method of the cleanser.Extensively, cost of material is low, preparation process is simple, it is adaptable to large-scale industrial production for raw material sources of the present invention;In the present invention using steel-making discarded object by hydrolysis reach stabilization structure and coordinate other components to prepare purifying agent for polluted water, not only turn waste into wealth, also improve the treatment effect of purifying agent for polluted water, reduce cost of sewage disposal, secondary environmental pollution is not resulted in, with good Social benefit and economic benefit.

Description

A kind of purifying agent for polluted water for processing dirty water pollutant and preparation method thereof
Technical field
The present invention relates to sewage treatment area, specifically a kind of purifying agent for polluted water for processing dirty water pollutant.
Background technology
China is one of country of water resources shortage, and particularly water resource is about 2100m per capita3, the Jin Zhanshi worlds are per capita The 28% of water resource, shortage of water resources has turned into one of the key factor of restriction through social sustainable development.In recent decades, China Industrial development is rapid.But in the past, the factory and enterprise of China does not focus on environmental protection, after generally existing will not pass through purification The situation that sewage is directly discharged.In this year, with the continuous deterioration of environment, Ministry of Environmental Protection point is also discharged into sewage Strict supervision is gone.All of factory of enterprise, after sewage has to pass through purification, after water quality meets discharging standards, can just enter Row discharge.The common method of sewage disposal has physico-chemical process and biochemical process, and physico-chemical process is good to removal colourity, heavy metal and other effects, raw Change method has good removal effect to organic pollution, nitrogen and phosphorus.Sewage-treating agent is conventional medicament in physico-chemical process, and material is held high It is expensive so that sewage treatment plant's operation cost is high, therefore efficient and cheap sewage-treating agent has wide market prospects.
The content of the invention
It is an object of the invention to provide a kind of purifying agent for polluted water for processing dirty water pollutant, to solve above-mentioned background skill The problem proposed in art.
To achieve the above object, the present invention provides following technical scheme:
A kind of purifying agent for polluted water for processing dirty water pollutant, is made up of following raw material according to weight portion:Slag 45-73 Part, land plaster 5-15 parts, quartz 3-8 parts, diatomite 8-16 parts, oxide powder 2-6 parts, water soluble phenol resin 10-14 Part, fiber 0.5-1.5 parts, ethyl acetate 13-22 parts, shitosan 1-3 parts, dry cow dung 3-5 parts and egg 0.1-0.4 parts.
As further scheme of the invention:Oxide powder uses alumina powder, lime powder and magnesia powder One or several the mixture at end.
As further scheme of the invention:Fiber is a kind of or several using bamboo-carbon fibre, flax fiber and cotton fiber The mixture planted.
The preparation method of the purifying agent for polluted water of the dirty water pollutant for the treatment of, comprises the following steps that:
Step one, carries out slag removal of impurities, crushes and except iron, and shower water is hydrolyzed 30-45 hours, Celsius in 40-56 The lower drying of degree, 150-220 mesh is milled to by dried slag using airflow milling, obtains steel slag particle;
Step 2, by diatomite, water soluble phenol resin, ethyl acetate and shitosan add deionized water in and stir Mix, obtain the first mixed liquor, during concentration added into the first mixed liquor for the ammoniacal liquor of 0.8-1.3mol/L, until the first mixed liquor PH value is 8-9, obtains the second mixed liquor;
Step 3, land plaster, quartz, oxide powder, fiber and dry cow dung are put into ball mill and ball is added Mill pearl, ball milling 80-150 minutes, obtains the first mixture;
Step 4, steel slag particle, the second mixed liquor, the first mixture and egg are mixed in double-spiral mixer Close uniform, you can obtain finished product.
As further scheme of the invention:The mass ratio of ball milling material and ball milling pearl is 1 in step 3:6-10, ball milling Temperature is 40-56 degrees Celsius.
Compared with prior art, the beneficial effects of the invention are as follows:Extensively, cost of material is low for raw material sources of the present invention, prepares Process is simple, it is adaptable to large-scale industrial production;Reached surely by hydrolysis using the discarded object of steel-making in the present invention Fixed structure and coordinate other components to prepare purifying agent for polluted water, not only turn waste into wealth, also improve the treatment of purifying agent for polluted water Effect, reduces cost of sewage disposal, does not result in secondary environmental pollution, with good Social benefit and economic benefit.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of purifying agent for polluted water for processing dirty water pollutant, is made up of following raw material according to weight portion:45 parts of slag, stone 5 parts of cream powder, 3 parts of quartz, 8 parts of diatomite, 2 parts of oxide powder, 10 parts of water soluble phenol resin, 0.5 part of fiber, acetic acid second 0.1 part of 13 parts of ester, 1 part of shitosan, 3 parts of dry cow dung and egg.Oxide powder uses alumina powder and magnesium oxide powder Mixture.
The preparation method of the purifying agent for polluted water of the dirty water pollutant for the treatment of, comprises the following steps that:
Step one, carries out slag removal of impurities, crushes and except iron, and shower water is hydrolyzed 30 hours, is dried under 40 degrees Celsius It is dry, dried slag is milled to 150 mesh using airflow milling, obtain steel slag particle;
Step 2, by diatomite, water soluble phenol resin, ethyl acetate and shitosan add deionized water in and stir Mix, obtain the first mixed liquor, by concentration for 0.8mol/L ammoniacal liquor add the first mixed liquor in, until the pH value of the first mixed liquor It is 8.2, obtains the second mixed liquor;
Step 3, land plaster, quartz, oxide powder, fiber and dry cow dung are put into ball mill and ball is added Mill pearl, ball milling 90 minutes obtains the first mixture;
Step 4, steel slag particle, the second mixed liquor, the first mixture and egg are mixed in double-spiral mixer Close uniform, you can obtain finished product.
Embodiment 2
A kind of purifying agent for polluted water for processing dirty water pollutant, is made up of following raw material according to weight portion:52 parts of slag, stone 8 parts of cream powder, 5 parts of quartz, 11 parts of diatomite, 3.5 parts of oxide powder, 11.5 parts of water soluble phenol resin, 0.7 part of fiber, 0.2 part of 16 parts of ethyl acetate, 1.5 parts of shitosan, 4 parts of dry cow dung and egg.Fiber is using bamboo-carbon fibre and flax fiber Mixture.
The preparation method of the purifying agent for polluted water of the dirty water pollutant for the treatment of, comprises the following steps that:
Step one, carries out slag removal of impurities, crushes and except iron, and shower water is hydrolyzed 36 hours, is dried under 45 degrees Celsius It is dry, dried slag is milled to 165 mesh using airflow milling, obtain steel slag particle;
Step 2, by diatomite, water soluble phenol resin, ethyl acetate and shitosan add deionized water in and stir Mix, obtain the first mixed liquor, by concentration for 1mol/L ammoniacal liquor add the first mixed liquor in, until the pH value of the first mixed liquor is 8.6, obtain the second mixed liquor;
Step 3, land plaster, quartz, oxide powder, fiber and dry cow dung are put into ball mill and ball is added The mass ratio of mill pearl, ball milling material and ball milling pearl is 1:8, ball milling temperature is 43 degrees Celsius and ball milling 110 minutes, obtains first Mixture;
Step 4, steel slag particle, the second mixed liquor, the first mixture and egg are mixed in double-spiral mixer Close uniform, you can obtain finished product.
Embodiment 3
A kind of purifying agent for polluted water for processing dirty water pollutant, is made up of following raw material according to weight portion:64 parts of slag, stone 12 parts of cream powder, 7 parts of quartz, 14 parts of diatomite, 5 parts of oxide powder, 13 parts of water soluble phenol resin, 1.2 parts of fiber, acetic acid 0.3 part of 19 parts of ethyl ester, 2.5 parts of shitosan, 4.5 parts of dry cow dung and egg.Oxide powder uses alumina powder.Fiber is adopted With flax fiber and the mixture of cotton fiber.
The preparation method of the purifying agent for polluted water of the dirty water pollutant for the treatment of, comprises the following steps that:
Step one, carries out slag removal of impurities, crushes and except iron, and shower water is hydrolyzed 41 hours, dries at 50 c It is dry, dried slag is milled to 190 mesh using airflow milling, obtain steel slag particle;
Step 2, by diatomite, water soluble phenol resin, ethyl acetate and shitosan add deionized water in and stir Mix, obtain the first mixed liquor, by concentration for 1.2mol/L ammoniacal liquor add the first mixed liquor in, until the pH value of the first mixed liquor It is 8.8, obtains the second mixed liquor;
Step 3, land plaster, quartz, oxide powder, fiber and dry cow dung are put into ball mill and ball is added Mill pearl, ball milling 135 minutes obtains the first mixture;
Step 4, steel slag particle, the second mixed liquor, the first mixture and egg are mixed in double-spiral mixer Close uniform, you can obtain finished product.
Embodiment 4
A kind of purifying agent for polluted water for processing dirty water pollutant, is made up of following raw material according to weight portion:72 parts of slag, stone 13 parts of cream powder, 7 parts of quartz, 15 parts of diatomite, 6 parts of oxide powder, 14 parts of water soluble phenol resin, 1.4 parts of fiber, acetic acid 0.4 part of 21 parts of ethyl ester, 3 parts of shitosan, 5 parts of dry cow dung and egg.Oxide powder uses alumina powder, lime powder With the mixture of magnesium oxide powder.Fiber uses the mixture of bamboo-carbon fibre, flax fiber and cotton fiber.
The preparation method of the purifying agent for polluted water of the dirty water pollutant for the treatment of, comprises the following steps that:
Step one, carries out slag removal of impurities, crushes and except iron, and shower water is hydrolyzed 42 hours, is dried under 54 degrees Celsius It is dry, dried slag is milled to 210 mesh using airflow milling, obtain steel slag particle;
Step 2, by diatomite, water soluble phenol resin, ethyl acetate and shitosan add deionized water in and stir Mix, obtain the first mixed liquor, by concentration for 1.2mol/L ammoniacal liquor add the first mixed liquor in, until the pH value of the first mixed liquor It is 9, obtains the second mixed liquor;
Step 3, land plaster, quartz, oxide powder, fiber and dry cow dung are put into ball mill and ball is added The mass ratio of mill pearl, ball milling material and ball milling pearl is 1:9, ball milling temperature is 52 degrees Celsius and ball milling 140 minutes, obtains first Mixture;
Step 4, steel slag particle, the second mixed liquor, the first mixture and egg are mixed in double-spiral mixer Close uniform, you can obtain finished product.
Slag fills diatomite, fiber, dry cow dung and egg by hydrolyzing and coordinating with macroporous gypsum, Possess porosity higher, specific surface area and adsorption capacity, therefore for the adsorptivity of the material such as pigment, heavy metal ion in water Stronger, quartz can greatly improve the intensity of material, and can also improve the toughness of material simultaneously, play a supporting role, Water soluble phenol resin not only has adhesive effect, and its water resistance, mechanical strength and the resistance to shrinkage that can improve material, Purifying agent for polluted water is enabled to for a long time in underwater work.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires to be limited rather than described above, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined May be appreciated other embodiment.

Claims (5)

1. a kind of purifying agent for polluted water for processing dirty water pollutant, it is characterised in that be made up of according to weight portion following raw material:Steel Slag 45-73 parts, land plaster 5-15 parts, quartz 3-8 parts, diatomite 8-16 parts, oxide powder 2-6 parts, water soluble phenolic resin Fat 10-14 parts, fiber 0.5-1.5 parts, ethyl acetate 13-22 parts, shitosan 1-3 parts, dry cow dung 3-5 parts and egg 0.1- 0.4 part.
2. the purifying agent for polluted water of the dirty water pollutant for the treatment of according to claim 1, it is characterised in that the oxidate powder End uses one or several mixture of alumina powder, lime powder and magnesium oxide powder.
3. the purifying agent for polluted water of the dirty water pollutant for the treatment of according to claim 1 and 2, it is characterised in that the fiber Using one or several mixture of bamboo-carbon fibre, flax fiber and cotton fiber.
4. the preparation method of the purifying agent for polluted water of a kind of dirty water pollutant for the treatment of as described in claim 1-3 is any, it is special Levy and be, comprise the following steps that:
Step one, carries out slag removal of impurities, crushes and except iron, and shower water is hydrolyzed 30-45 hours, under 40-56 degrees Celsius Drying, 150-220 mesh is milled to by dried slag using airflow milling, obtains steel slag particle;
Step 2, by diatomite, water soluble phenol resin, ethyl acetate and shitosan add deionized water in and stir, obtain To the first mixed liquor, during concentration added into the first mixed liquor for the ammoniacal liquor of 0.8-1.3mol/L, until the pH value of the first mixed liquor It is 8-9, obtains the second mixed liquor;
Step 3, land plaster, quartz, oxide powder, fiber and dry cow dung are put into ball mill and ball milling pearl is added, Ball milling 80-150 minutes, obtain the first mixture;
Step 4, steel slag particle, the second mixed liquor, the first mixture and egg are carried out in double-spiral mixer to mix It is even, you can to obtain finished product.
5. the preparation method of the purifying agent for polluted water of the dirty water pollutant for the treatment of according to claim 4, it is characterised in that institute The mass ratio for stating ball milling material and ball milling pearl in step 3 is 1:6-10, ball milling temperature is 40-56 degrees Celsius.
CN201710147381.XA 2017-03-13 2017-03-13 A kind of purifying agent for polluted water for processing dirty water pollutant and preparation method thereof Pending CN106830125A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107670638A (en) * 2017-09-30 2018-02-09 武汉金钢新材料有限公司 Steel mill's waste residue composition for filtration treatment sewage and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN105289487A (en) * 2015-10-19 2016-02-03 丁玉琴 Method for preparing red-mud-based heavy metal ion adsorbing material
CN106277100A (en) * 2016-08-31 2017-01-04 四川达文西科技有限公司 A kind of quickly purifying agent for polluted water
CN106348363A (en) * 2016-11-08 2017-01-25 郑州诚合信息技术有限公司 Sewage treatment agent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105289487A (en) * 2015-10-19 2016-02-03 丁玉琴 Method for preparing red-mud-based heavy metal ion adsorbing material
CN106277100A (en) * 2016-08-31 2017-01-04 四川达文西科技有限公司 A kind of quickly purifying agent for polluted water
CN106348363A (en) * 2016-11-08 2017-01-25 郑州诚合信息技术有限公司 Sewage treatment agent and preparation method thereof

Non-Patent Citations (1)

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Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107670638A (en) * 2017-09-30 2018-02-09 武汉金钢新材料有限公司 Steel mill's waste residue composition for filtration treatment sewage and preparation method thereof

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Application publication date: 20170613