CN106756755B - The carburization quenching method of large excavator gear - Google Patents

The carburization quenching method of large excavator gear Download PDF

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Publication number
CN106756755B
CN106756755B CN201611141404.8A CN201611141404A CN106756755B CN 106756755 B CN106756755 B CN 106756755B CN 201611141404 A CN201611141404 A CN 201611141404A CN 106756755 B CN106756755 B CN 106756755B
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gear
carburizing
carburizer
temperature
force
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CN106756755A (en
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刘聪敏
黄星
王晓华
周冰
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CRRC Qishuyan Institute Co Ltd
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CRRC Qishuyan Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/20Carburising
    • C23C8/22Carburising of ferrous surfaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/32Soft annealing, e.g. spheroidising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/32Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for gear wheels, worm wheels, or the like

Abstract

The present invention relates to a kind of carburization quenching methods of large excavator gear, include the following steps:Heat up samming step;Ooze step by force;Diffusing step;Cool down samming step;Primary quenching step;Isothermal spheroidizing step;Secondary quenching step;Lonneal step.The large excavator gear carburizing quenching method of the present invention can substantially shorten the carburizing and quenching time, obtain high carburizing speed, save energy consumption, improve production efficiency, simultaneously again can effective crystal grain thinning, obtain the acinous carbide of Dispersed precipitate, improve the metallographic structure of gear surface, the tooth face hardness and wearability for improving gear, improve the service life of gear.

Description

The carburization quenching method of large excavator gear
Technical field
The present invention relates to a kind of carburization quenching methods of large excavator gear, belong to technical field of heat treatment.
Background technology
Excavator is usually to realize continuous work with speed reduction gear box power by motor operation acting by electric drive The engineering machinery of industry.As China is in the swift and violent hair of the various aspects infrastructure construction such as road traffic, energy-water, urban construction Exhibition, large excavator market demand rise year by year, and development prospect is powerful.But large excavator working environment is more complicated, Reduction box internal gear is easy to be influenced and fail by load impacting and mechanical oscillation.Therefore, large excavator gear is not only held Load-carrying, impact force is strong, and security performance requires high, and when use requires to have excellent case hardness, wear-resisting property and overload-resistant Ability had both required the case depth of gear teeth face deeper, and required the center portion good mechanical properties of gear.
Currently, the raw material of large excavator gear are frequently with 18Cr2Ni4WA steel alloys, carburization quenching method such as Fig. 2 institutes Show, large excavator gear, which is placed on carburizing in-furnace temperature, increases 920 ± 5 DEG C, and progress is oozed 10-12 hours by force, synthermal Under be diffused 10-12 hours, in strong ooze carbon potential CP controls 1.20 ± 0.05%, and carbon potential CP when spreading be 0.85 ± 0.05%, oil hardening is carried out after being then down to 830 ± 5 DEG C of heat preservations 1-2 hours with stove, then gear is placed in tempering furnace and is heated to 160-220 DEG C of progress lonneal, soaking time 2-3h;Then it comes out of the stove and is air-cooled to room temperature.The carburizing temperature of this method is low, by force Carburizing gesture is high, and a large amount of carbon blacks are easily deposited in stove, causes carbon potential in stove to fluctuate, is created great difficulties to carbon-potential control.Meanwhile the party Method carburizing time is long, and is in same temperature, since the carbide formers such as Cr, W in steel can form stable conjunction with carbon Golden carbide, it is strong to inhale carbon ability, so that carburized layer concentration of carbon is increased, is unfavorable for the diffusion of carbon, carburized layer concentration gradient steepening, Easily there is big blocky, net carbide, destroys the continuity of matrix, seriously affected quality of carburized layer, gear is made to exist It is also easy to produce grinding crack in follow-up Grinding Process, and gear is made to be easy to fatigue under periodic contact stress, is formed Point and surface layer peeling.
Invention content
The object of the present invention is to provide a kind of carburization quenching methods of large excavator gear, can substantially shorten carburizing and quenching Time obtains high carburizing speed, saves energy consumption, moreover it is possible to and objectionable carbides are eliminated, the acinous carbide of Dispersed precipitate is obtained, And improve production efficiency.
The technical solution of the present invention in order to achieve the above objectives is:A kind of carburization quenching method of large excavator gear, It is characterized in that:Include the following steps,
(1), heat up samming step, first gear is placed in carburizer and is heated to 750 ± 10 DEG C, keeps the temperature 3-4h;
(2), step oozed by force, carburizer heating, with stove heat to 960-980 DEG C, into carburizer be passed through carburizer oozes gear Carbon, control carbon potential CP maintain one section of carburizing time t to ooze by force in 1.30 ± 0.05C%;
(3), diffusing step, carburizer heating, gear, to 1040-1060 DEG C, carburizer are passed through into carburizer with stove heat Carburizing, control carbon potential CP is 0.90 ± 0.05C%, and the diffusion of diffusion time t is carburizing time t oozes by force when oozing by force 1.5 times;
(4), cool down samming step, reduce furnace temperature, and gear is down to 840 ± 10 DEG C with stove, carburizing is passed through into carburizer Agent carburizing maintains carbon potential CP in stove and to keep the temperature 2-3h in 0.90 ± 0.05C% in temperature-fall period,;
(5) 840 ± 10 DEG C of gear is carried out oil quenching, and quenches oil temperature at 65-95 DEG C by, primary quenching step;
(6) quenched gear for the first time is heated to 650 ± 10 DEG C, heat preservation 3- by, isothermal spheroidizing step in stove 4h;Gear heating is heated to 720 ± 10 DEG C, heat preservation 3-4h again;Gear is then cooled to 650 ± 10 DEG C, heat preservation 5-6h;Most Backgear cools to 550 DEG C with the furnace, comes out of the stove and is air-cooled to room temperature;
(7) the gear after isothermal spheroidizing is heated to 760 ± 10 DEG C, heat preservation by, secondary quenching step in stove 3-4h;Gear is warming up to 820 ± 10 DEG C, heat preservation 2-3h with stove again;Then oil quenching will be carried out in 820 ± 10 DEG C of gear, quenched Kerosene temperature is 65-95 DEG C;
(8) gear is placed in tempering furnace and is heated to 180-260 DEG C of progress lonneal, when heat preservation by, lonneal step Between be 3-4h;Then it comes out of the stove and is air-cooled to room temperature.
It is wherein, described that strong to ooze the sum of the diffusion time t diffusion that the carburizing time t in step is blended by force in diffusing step be total Carburizing time t carburizings, and total carburizing time t carburizings=(δ/K) 2, wherein δ is depth of penetration (mm), and K is carburizing temperature coefficient.
The strong carburizing time t oozed in step oozes by force in 8-10h.
In the diffusing step, diffusion time, t was diffused in 12-15h.
Between the first time quenching Step and isothermal spheroidizing step and second of quenching Step and lonneal Further include cleaning step between step, cleaning removal gear component surface oil stain, the temperature of cleaning solution is controlled in 50- when cleaning 60℃。
It is described it is strong ooze in step, diffusing step and cooling samming step, the carburizer used for methanol, ethane, propane, Any one or more of ethyl alcohol, propyl alcohol, ethyl acetate.
It is described it is strong ooze in step, diffusing step and cooling samming step, the carbon potential by adjust carburizing agent flux come Control.
In the lonneal step, the number of lonneal is twice.
The large excavator gear steel material is 18Cr2Ni4WA.
The present invention gear is carried out successively heating samming, ooze by force, spread, the samming that cools down, quenching for the first time, isothermal spheroidizing moves back It fire and second quenches, due to greatly improved carburizing temperature, and diffusion temperature higher than oozing temperature, diffusion time t by forceDiffusionIt is Carburizing time t when oozing by forceIt oozes by force1.5 times, because carbon penetrate into steel in maximum speed by carbon, the diffusion velocity in austenite is limited, And this diffusion velocity and temperature direct proportionality, therefore, carburization quenching method of the present invention passes through the high strong temperature and strong of oozing Carburizing gesture forms very high concentration of carbon in workpiece surface within a short period of time, by higher diffusion temperature and longer Diffusion time makes the carbon for oozing the carbon-rich zone of section by force gradually be elapsed to deep layer, to obtain high carburizing speed, when shortening heat treatment Between, reduce energy consumption, also can effective gentle carburized layer carbon profile, reduce the big bulk that gear surface carburized layer easily occurs Carbide obtains acinous carbide, improves the metallographic structure of gear surface, improve the tooth face hardness and wearability of gear.This Invention carries out isothermal spheroidizing to the gear after carburizing, makes its elder generation 20 DEG C of austenitizings more than Ac1 temperature, carbide is made to fill Divide dissolving, then 50 DEG C of generation isothermal transformation below Ac1 temperature obtain the equally distributed fine grained carbonization of disperse of nodularization Object, for the Refined Carbide Particle of this Dispersed precipitate in subsequent quenching process, the spread is more perfect, is not only final quenching Heating has prepared a large amount of crystallization nuclei, and Quench heating austenite can be made further to homogenize, and can obviously refine and quench Fire tissue, significantly improves the comprehensive performances such as the intensity after gear quenching, hardness.Present invention employs heating quenchings twice, can have Crystal grain thinning is imitated, crystal grain, which is grown up, caused by being improved to carburizing temperature plays good optimization function.
Description of the drawings
The embodiment of the present invention is described in further detail below in conjunction with the accompanying drawings.
Fig. 1 is artwork of the present invention to the carburization quenching method of large excavator gear.
Fig. 2 is schematic diagram of the prior art to the carburization quenching method of large excavator gear.
Specific implementation mode
As shown in Figure 1, the carburization quenching method of large excavator gear of the invention, includes the following steps.
(1), heat up samming step, first gear is placed in carburizer and is heated to 750 ± 10 DEG C, keeps the temperature 3-4h.
(2), step oozed by force, carburizer heating, with stove heat to 960-980 DEG C, into carburizer be passed through carburizer oozes gear Carbon, control carbon potential CP are controlled in 1.30 ± 0.05C%, carbon potential by adjusting carburizing agent flux, maintain one section of carburizing time tIt oozes by force, the carburizing time t when present invention is oozed by forceIt oozes by forceCan be controlled in 8-10h, by improving the temperature oozed by force and strong carburizing gesture, compared with Very high concentration of carbon is formd in workpiece surface in short time.
(3), diffusing step, carburizer heating, with stove heat to 1040-1060 DEG C, diffusion heating rate is can be controlled in gear 150-350 DEG C/h, it is passed through carburizer carburizing into carburizer, control carbon potential CP is in 0.90 ± 0.05C%, and diffusion time tDiffusion It is carburizing time t when oozing by forceIt oozes by force1.5 times, same carbon potential is controlled by adjusting carburizing agent flux, and diffusion time tDiffusionIt keeps 12-15h.The present invention makes the carbon for oozing the carbon-rich zone of section by force gradually to deep layer by higher diffusion temperature and long diffusion time Passage, to obtain high carburizing speed, also can effective gentle carburized layer carbon profile, reduce gear surface carburized layer The big massive carbide easily occurred obtains acinous carbide, improves the metallographic structure of gear surface, the flank of tooth for improving gear is hard Degree and wearability.
(4), cool down samming step, reduce furnace temperature, and gear is down to 840 ± 10 DEG C with stove, and cooling rate is can be controlled in 120-240 DEG C/h, carburizer carburizing is passed through into carburizer, carbon potential is controlled by adjusting carburizing agent flux, in temperature-fall period Carbon potential CP keeps the temperature 2-3h in 0.90 ± 0.05C% in middle maintenance stove, to keep the concentration of carbon of carburized layer, and is quenched by controlling Temperature, to obtain the carburized layer of high quality.
(5) 840 ± 10 DEG C of gear is carried out oil quenching, and quenches oil temperature at 65-95 DEG C by, primary quenching step, makes Austria Family name's body changes.
(6) quenched gear for the first time is heated to 650 ± 10 DEG C, heat preservation 3- by, isothermal spheroidizing step in stove 4h;Gear heating is heated to 720 ± 10 DEG C, heat preservation 3-4h again;Gear is then cooled to 650 ± 10 DEG C, heat preservation 5-6h;Most Backgear cools to 550 DEG C with the furnace, comes out of the stove and is air-cooled to room temperature.The present invention carries out isothermal spheroidizing to the gear after carburizing, can Carbide is set fully to dissolve, then 50 DEG C of generation isothermal transformation below Ac1 temperature, the disperse for obtaining nodularization is equally distributed thin Granule carbonide.
(7) the gear after isothermal spheroidizing is heated to 760 ± 10 DEG C, heat preservation by, secondary quenching step in stove 3-4h;Gear is warming up to 820 ± 10 DEG C, heat preservation 2-3h again;Then oil quenching, quenching oil will be carried out in 820 ± 10 DEG C of gear Temperature is 65-95 DEG C, and the present invention makes the thin of Dispersed precipitate by carrying out quenching treatment again to the gear after isothermal spheroidizing Granule carbonide spread in quenching process is more perfect, so that Quench heating austenite further homogenizes, it can be apparent Quenching structure is refined, improves the metallographic structure of gear surface, significantly improves the comprehensive performances such as the intensity after gear quenching, hardness.
(8) gear is placed in tempering furnace and is heated to 180-260 DEG C of progress lonneal, when heat preservation by, lonneal step Between be 3-4h;Then it comes out of the stove and is air-cooled to room temperature.In the lonneal step of the present invention, the number of lonneal is twice, to pass through Multiple lonneal keeps the high rigidity and wearability of quenching workpiece, reduces quenching residual stress and brittleness.
The present invention oozes by force the carburizing time t in stepIt oozes by forceWith the diffusion time t in diffusing stepDiffusionThe sum of be total carburizing when Between tCarburizing, and total carburizing time tCarburizing=(δ/K)2, wherein δ is depth of penetration (mm), and K is carburizing temperature coefficient, therefore can basis The depth of penetration of design requirement setting gear and the carburizing temperature coefficient of selection control total carburizing time tCarburizing
The present invention is between first time quenching Step and isothermal spheroidizing step and second of quenching Step and low temperature Further include cleaning step between tempering step, cleaning removal gear component surface oil stain, the temperature control of cleaning solution when cleaning At 50-60 DEG C, and cleaning solution uses conventional cleaning solution, such as kerosene etc..
The present invention is in oozing by force step and diffusing step and carburizer used by cooling samming step is methanol, second Any one or more of alkane, propane, ethyl alcohol, propyl alcohol, ethyl acetate.
Large excavator gear of the present invention uses steel material for 18Cr2Ni4WA, with carburization quenching method pair of the present invention Gear made from 18Cr2Ni4WA carries out carburizing and quenching processing, and specific carburizing and quenching Processing Example is shown in Table 1.
Table 1
Test specimen made from carburization quenching method using the present invention is detected, specifically by GB/T228, GB/T229 standard Data are shown in Table 2.
Table 2
Project Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6
Tensile strength (MPa) 1450 1480 1420 1420 1450 1460
Yield strength (MPa) 950 975 955 960 955 960
Elongation after fracture (%) 14 13.5 14 14.5 14 13.5
The contraction percentage of area (%) 58 54 57 59 57 57
As can be seen that the case depth of gear teeth face is deeper, and the center portion good mechanical properties of gear are required, had Excellent case hardness, wear-resisting property and anti-overload ability.

Claims (8)

1. a kind of carburization quenching method of large excavator gear, it is characterised in that:Include the following steps,
(1), heat up samming step, first gear is placed in carburizer and is heated to 750 ± 10 DEG C, keeps the temperature 3-4h;
(2), step, carburizer heating are oozed by force, gear, to 960-980 DEG C, carburizer carburizing is passed through into carburizer with stove heat, Carbon potential CP is controlled in 1.30 ± 0.05C%, maintains one section of carburizing time tIt oozes by force
(3), diffusing step, carburizer heating, with stove heat to 1040-1060 DEG C, into carburizer be passed through carburizer oozes gear Carbon controls carbon potential CP as 0.90 ± 0.05C%, and diffusion time tDiffusionIt is carburizing time t when oozing by forceIt oozes by force1.5 times;Wherein, institute The strong carburizing time t oozed in step statedIt oozes by forceWith the diffusion time t in diffusing stepDiffusionThe sum of be total carburizing time tCarburizing, and it is total Carburizing time tCarburizing=(δ/K)2, wherein δ is depth of penetration (mm), and K is carburizing temperature coefficient;
(4), cool down samming step, reduce furnace temperature, and gear is down to 840 ± 10 DEG C with stove, carburizer is passed through into carburizer and is oozed Carbon maintains carbon potential CP in stove and to keep the temperature 2-3h in 0.90 ± 0.05C% in temperature-fall period;
(5) 840 ± 10 DEG C of gear is carried out oil quenching, and quenches oil temperature at 65-95 DEG C by, primary quenching step;
(6) quenched gear for the first time is heated to 650 ± 10 DEG C, heat preservation 3-4h by, isothermal spheroidizing step in stove;Again Gear heating is heated to 720 ± 10 DEG C, heat preservation 3-4h;Gear is then cooled to 650 ± 10 DEG C, heat preservation 5-6h;Last tooth Wheel cools to 550 DEG C with the furnace, comes out of the stove and is air-cooled to room temperature;
(7) the gear after isothermal spheroidizing is heated to 760 ± 10 DEG C, heat preservation 3-4h by, secondary quenching step in stove; Gear is warming up to 820 ± 10 DEG C, heat preservation 2-3h with stove again;Then oil quenching will be carried out in 820 ± 10 DEG C of gear, and will quench oil temperature Degree is 65-95 DEG C;
(8), lonneal step, gear is placed in tempering furnace and is heated to 180-260 DEG C of progress lonneal, and soaking time is 3-4h;Then it comes out of the stove and is air-cooled to room temperature.
2. the carburization quenching method of large excavator gear according to claim 1, it is characterised in that:It is described to ooze step by force In carburizing time tIt oozes by forceIn 8-10h.
3. the carburization quenching method of large excavator gear according to claim 1, it is characterised in that:The diffusion step In rapid, diffusion time tDiffusionIn 12-15h.
4. the carburization quenching method of large excavator gear according to claim 1, it is characterised in that:The first time quenches It further include cleaning step between fiery step and isothermal spheroidizing step and between second of quenching Step and lonneal step Suddenly, cleaning removal gear component surface oil stain, the temperature of cleaning solution is controlled at 50-60 DEG C when cleaning.
5. the carburization quenching method of large excavator gear according to claim 1, it is characterised in that:It is described to ooze step by force Suddenly, diffusing step and cooling samming step in, the carburizer used is methanol, ethane, propane, ethyl alcohol, propyl alcohol, ethyl acetate Any one or more.
6. the carburization quenching method of large excavator gear according to claim 1, it is characterised in that:It is described to ooze step by force Suddenly, in diffusing step and cooling samming step, the carbon potential is controlled by adjusting carburizing agent flux.
7. the carburization quenching method of large excavator gear according to claim 1, it is characterised in that:The low temperature returns In fiery step, the number of lonneal is twice.
8. the carburization quenching method of large excavator gear according to claim 1, it is characterised in that:The large-scale excavation Machine gear steel material is 18Cr2Ni4WA.
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