CN106753096A - A kind of building board binding agent - Google Patents
A kind of building board binding agent Download PDFInfo
- Publication number
- CN106753096A CN106753096A CN201611185909.4A CN201611185909A CN106753096A CN 106753096 A CN106753096 A CN 106753096A CN 201611185909 A CN201611185909 A CN 201611185909A CN 106753096 A CN106753096 A CN 106753096A
- Authority
- CN
- China
- Prior art keywords
- parts
- binding agent
- rubbers
- zinc oxide
- calcium carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of building board binding agent, it is related to building material technical field.It is made up of the raw material of following weight parts:10 15 parts of phenolic resin, 5 15 parts of polyacrylate salts, 10 20 parts of talcum powder, 5 10 parts of shitosan, 5 15 parts of calcium carbonate, 5 20 parts of zinc oxide, 5 10 parts of propylene glycol methyl ether acetate, 10 20 parts of special-purpose organic silicon coupling agent, 10 30 parts of ethyl acetate, 5 10 parts of polyethylene glycol, 5 10 parts of ammonium chloride, 20 30 parts of tetraethyl orthosilicate, 5 10 parts of polyvinyl alcohol, 5 10 parts of 5 10 part, nanometer rubber powder of EP rubbers, 5 20 parts of borax.The present invention takes full advantage of these waste materials, realizes the recovery of waste material, turns waste into wealth, and saves raw material data, is a kind of environment-friendlybinder binder;Its cohesive is good, and adhesive strength is high, and water-resistance is good, can be used for the bonding of glued board, fiberboard, metal, ceramics, glass material.
Description
Technical field
The present invention relates to a kind of building board binding agent, it is related to building material technical field.
Background technology
Current adhesive has many types, and due to the difference of its raw material, the performance of glue is different according to respective composition
Have in very big difference, but most of adhesive, such as benzene,toluene,xylene, formaldehyde nuisance are contained such as in phenolic resin glue
Matter composition, long-term use is not only polluted to environment, and damages the health of people, in addition, the manufacturing process of these binding agents
It is complex, it is relatively costly.The consumption of China's polystyrene foam plastics and rubber is increasing, and major part is all one
Secondary property is used, and millions of ton of white garbage and waste rubber goodses dissipate can neither rot to convert in nature, again can not be certainly
So degraded, forms serious pollution, and the processing mode current for these pollutants is usually to burn and fill, wherein landfill will
Substantial amounts of place is taken, and burning can then produce new air pollution problems inherent.
The content of the invention
1. the technical problem to be solved:
The technical problem to be solved in the present invention is directed to above-mentioned technical problem, there is provided a kind of building board binding agent, and it glues
Conjunction property is good, and adhesive strength is high, and water-resistance is good, can be used for the bonding of glued board, fiberboard, metal, ceramics, glass material.
2. technical scheme:
The technical scheme that the present invention solves its technical problem is as follows:
A kind of building board binding agent, it is made up of the raw material of following weight parts:Phenolic resin 10-15 parts, polypropylene
Hydrochlorate 5-15 parts, talcum powder 10-20 parts, shitosan 5-10 parts, calcium carbonate 5-15 parts, zinc oxide 5-20 parts, propylene glycol monomethyl ether vinegar
Acid esters 5-10 parts, 10-20 parts of special-purpose organic silicon coupling agent, ethyl acetate 10-30 parts, polyethylene glycol 5-10 parts, ammonium chloride 5-10
Part, tetraethyl orthosilicate 20-30 parts, polyvinyl alcohol 5-10 parts, EP rubbers 5-10 parts, 5-10 parts, borax 5-20 parts of nanometer rubber powder.
It is made up of the raw material of following weight parts:10 parts of phenolic resin, 5 parts of polyacrylate salts, 10 parts of talcum powder, shell gather
5 parts of sugar, 5 parts of calcium carbonate, 5 parts of zinc oxide, 5 parts of propylene glycol methyl ether acetate, 10 parts of special-purpose organic silicon coupling agent, ethyl acetate 10
Part, 5 parts of polyethylene glycol, 5 parts of ammonium chloride, 20 parts of tetraethyl orthosilicate, 5 parts of polyvinyl alcohol, 5 parts of 5 part, nanometer rubber powder of EP rubbers,
5 parts of borax.
It is made up of the raw material of following weight parts:15 parts of phenolic resin, 15 parts of polyacrylate salts, 20 parts of talcum powder, shell
10 parts of glycan, 15 parts of calcium carbonate, 20 parts of zinc oxide, 10 parts of propylene glycol methyl ether acetate, 20 parts of special-purpose organic silicon coupling agent, acetic acid
30 parts of ethyl ester, 10 parts of polyethylene glycol, 10 parts of ammonium chloride, 30 parts of tetraethyl orthosilicate, 10 parts of polyvinyl alcohol, 10 parts of EP rubbers, receive
10 parts of rice glue powder, 20 parts of borax.
It is made up of the raw material of following weight parts:12 parts of phenolic resin, 10 parts of polyacrylate salts, 15 parts of talcum powder, shell
8 parts of glycan, 10 parts of calcium carbonate, 12 parts of zinc oxide, 8 parts of propylene glycol methyl ether acetate, 15 parts of special-purpose organic silicon coupling agent, acetic acid second
20 parts of ester, 8 parts of polyethylene glycol, 8 parts of ammonium chloride, 25 parts of tetraethyl orthosilicate, 8 parts of polyvinyl alcohol, part, nanometer rubber powder 8 of EP rubbers 8
Part, 12 parts of borax.
Its preparation method is as follows:(1) phenolic resin and polyacrylate salts are well mixed, are heated to 50 degrees Celsius, then add
Enter talcum powder, zinc oxide, shitosan and calcium carbonate, stirring 10min is sufficiently mixed, uniformly after microwave frequency 2000MHz, power
Microwave treatment 20min under 600W, obtains final product material I;(2) while hot to addition propylene glycol methyl ether acetate, special-purpose organic silicon in material I
Coupling agent, ethyl acetate, sealing and standing 15min, obtains final product material II after being well mixed;(3) to adding polyethylene glycol in material II
And ammonium chloride, stirring forming 6h at be placed in 10-25 DEG C after even slurry, being subsequently adding tetraethyl orthosilicate, polyvinyl alcohol, the rubber of second third
Glue, nanometer rubber powder, borax, are sufficiently mixed uniform, then are heated up to 100 degrees Celsius, continue 60min, then cool down at normal temperatures again,
Obtain final product binding agent of the present invention.
3. beneficial effect:
Beneficial effects of the present invention:
(1) these waste materials are taken full advantage of, the recovery of waste material is realized, is turned waste into wealth, save raw material money
Material, is a kind of environment-friendlybinder binder;
(2) its cohesive is good, and adhesive strength is high, and water-resistance is good, can be used for glued board, fiberboard, metal, ceramics, glass
The bonding of material.
Specific embodiment
With reference to embodiment, the present invention is further detailed explanation:
A kind of building board binding agent, it is made up of the raw material of following weight parts:Phenolic resin 10-15 parts, polypropylene
Hydrochlorate 5-15 parts, talcum powder 10-20 parts, shitosan 5-10 parts, calcium carbonate 5-15 parts, zinc oxide 5-20 parts, propylene glycol monomethyl ether vinegar
Acid esters 5-10 parts, 10-20 parts of special-purpose organic silicon coupling agent, ethyl acetate 10-30 parts, polyethylene glycol 5-10 parts, ammonium chloride 5-10
Part, tetraethyl orthosilicate 20-30 parts, polyvinyl alcohol 5-10 parts, EP rubbers 5-10 parts, 5-10 parts, borax 5-20 parts of nanometer rubber powder.
It is made up of the raw material of following weight parts:10 parts of phenolic resin, 5 parts of polyacrylate salts, 10 parts of talcum powder, shell gather
5 parts of sugar, 5 parts of calcium carbonate, 5 parts of zinc oxide, 5 parts of propylene glycol methyl ether acetate, 10 parts of special-purpose organic silicon coupling agent, ethyl acetate 10
Part, 5 parts of polyethylene glycol, 5 parts of ammonium chloride, 20 parts of tetraethyl orthosilicate, 5 parts of polyvinyl alcohol, 5 parts of 5 part, nanometer rubber powder of EP rubbers,
5 parts of borax.
It is made up of the raw material of following weight parts:15 parts of phenolic resin, 15 parts of polyacrylate salts, 20 parts of talcum powder, shell
10 parts of glycan, 15 parts of calcium carbonate, 20 parts of zinc oxide, 10 parts of propylene glycol methyl ether acetate, 20 parts of special-purpose organic silicon coupling agent, acetic acid
30 parts of ethyl ester, 10 parts of polyethylene glycol, 10 parts of ammonium chloride, 30 parts of tetraethyl orthosilicate, 10 parts of polyvinyl alcohol, 10 parts of EP rubbers, receive
10 parts of rice glue powder, 20 parts of borax.
It is made up of the raw material of following weight parts:12 parts of phenolic resin, 10 parts of polyacrylate salts, 15 parts of talcum powder, shell
8 parts of glycan, 10 parts of calcium carbonate, 12 parts of zinc oxide, 8 parts of propylene glycol methyl ether acetate, 15 parts of special-purpose organic silicon coupling agent, acetic acid second
20 parts of ester, 8 parts of polyethylene glycol, 8 parts of ammonium chloride, 25 parts of tetraethyl orthosilicate, 8 parts of polyvinyl alcohol, part, nanometer rubber powder 8 of EP rubbers 8
Part, 12 parts of borax.
Its preparation method is as follows:(1) phenolic resin and polyacrylate salts are well mixed, are heated to 50 degrees Celsius, then add
Enter talcum powder, zinc oxide, shitosan and calcium carbonate, stirring 10min is sufficiently mixed, uniformly after microwave frequency 2000MHz, power
Microwave treatment 20min under 600W, obtains final product material I;(2) while hot to addition propylene glycol methyl ether acetate, special-purpose organic silicon in material I
Coupling agent, ethyl acetate, sealing and standing 15min, obtains final product material II after being well mixed;(3) to adding polyethylene glycol in material II
And ammonium chloride, stirring forming 6h at be placed in 10-25 DEG C after even slurry, being subsequently adding tetraethyl orthosilicate, polyvinyl alcohol, the rubber of second third
Glue, nanometer rubber powder, borax, are sufficiently mixed uniform, then are heated up to 100 degrees Celsius, continue 60min, then cool down at normal temperatures again,
Obtain final product binding agent of the present invention.
Claims (5)
1. a kind of building board binding agent, it is characterised in that:It is made up of the raw material of following weight parts:Phenolic resin 10-15
Part, polyacrylate salts 5-15 parts, talcum powder 10-20 parts, shitosan 5-10 parts, calcium carbonate 5-15 parts, zinc oxide 5-20 parts, the third two
5-10 parts of alcohol methyl ether acetate, 10-20 parts of special-purpose organic silicon coupling agent, ethyl acetate 10-30 parts, polyethylene glycol 5-10 parts, chlorine
Change 5-10 parts of ammonium, tetraethyl orthosilicate 20-30 parts, polyvinyl alcohol 5-10 parts, EP rubbers 5-10 parts, 5-10 parts of nanometer rubber powder, boron
Sand 5-20 parts.
2. a kind of building board binding agent according to claim 1, it is characterised in that:It is by the raw material of following weight parts
Composition:10 parts of phenolic resin, 5 parts of polyacrylate salts, 10 parts of talcum powder, 5 parts of shitosan, 5 parts of calcium carbonate, 5 parts of zinc oxide, the third two
5 parts of alcohol methyl ether acetate, 10 parts of special-purpose organic silicon coupling agent, 10 parts of ethyl acetate, 5 parts of polyethylene glycol, 5 parts of ammonium chloride, positive silicon
20 parts of acetoacetic ester, 5 parts of polyvinyl alcohol, 5 parts of 5 part, nanometer rubber powder of EP rubbers, 5 parts of borax.
3. a kind of building board binding agent according to claim 1, it is characterised in that:It is by the raw material of following weight parts
Composition:15 parts of phenolic resin, 15 parts of polyacrylate salts, 20 parts of talcum powder, 10 parts of shitosan, 15 parts of calcium carbonate, 20 parts of zinc oxide,
10 parts of propylene glycol methyl ether acetate, 20 parts of special-purpose organic silicon coupling agent, 30 parts of ethyl acetate, 10 parts of polyethylene glycol, ammonium chloride 10
Part, 30 parts of tetraethyl orthosilicate, 10 parts of polyvinyl alcohol, 10 parts of 10 part, nanometer rubber powder of EP rubbers, 20 parts of borax.
4. a kind of building board binding agent according to claim 1, it is characterised in that:It is by the raw material of following weight parts
Composition:12 parts of phenolic resin, 10 parts of polyacrylate salts, 15 parts of talcum powder, 8 parts of shitosan, 10 parts of calcium carbonate, 12 parts of zinc oxide,
8 parts of propylene glycol methyl ether acetate, 15 parts of special-purpose organic silicon coupling agent, 20 parts of ethyl acetate, 8 parts of polyethylene glycol, 8 parts of ammonium chloride,
25 parts of tetraethyl orthosilicate, 8 parts of polyvinyl alcohol, 8 parts of 8 part, nanometer rubber powder of EP rubbers, 12 parts of borax.
5. a kind of building board binding agent according to claim 1, it is characterised in that:Its preparation method is as follows:(1) by phenol
Urea formaldehyde and polyacrylate salts are well mixed, are heated to 50 degrees Celsius, add talcum powder, zinc oxide, shitosan and calcium carbonate,
Stirring 10min is sufficiently mixed, uniformly after microwave treatment 20min under microwave frequency 2000MHz, power 600W, material I is obtained final product;
(2) while hot to propylene glycol methyl ether acetate, special-purpose organic silicon coupling agent, ethyl acetate is added in material I, sealed after being well mixed
15min is stood, material II is obtained final product;(3) to polyethylene glycol and ammonium chloride is added in material II, stir and be placed in after forming even slurry
6h at 10-25 DEG C, is subsequently adding tetraethyl orthosilicate, polyvinyl alcohol, EP rubbers, nanometer rubber powder, borax, is sufficiently mixed uniformly,
100 degrees Celsius are heated up to again, continue 60min, then cooled down at normal temperatures again, obtain final product binding agent of the present invention.
Priority Applications (1)
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CN201611185909.4A CN106753096A (en) | 2016-12-12 | 2016-12-12 | A kind of building board binding agent |
Applications Claiming Priority (1)
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CN201611185909.4A CN106753096A (en) | 2016-12-12 | 2016-12-12 | A kind of building board binding agent |
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CN106753096A true CN106753096A (en) | 2017-05-31 |
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CN201611185909.4A Pending CN106753096A (en) | 2016-12-12 | 2016-12-12 | A kind of building board binding agent |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113416379A (en) * | 2021-07-09 | 2021-09-21 | 动向国际科技股份有限公司 | Organic covering pad and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1821334A (en) * | 2006-04-05 | 2006-08-23 | 北京林业大学 | Phenolic resin glue for veneer board and its preparing method |
-
2016
- 2016-12-12 CN CN201611185909.4A patent/CN106753096A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1821334A (en) * | 2006-04-05 | 2006-08-23 | 北京林业大学 | Phenolic resin glue for veneer board and its preparing method |
Non-Patent Citations (2)
Title |
---|
万仁浦 等: "《采油技术手册》", 30 November 1991, 石油工业出版社 * |
赵渠森: "《先进复合材料手册》", 31 May 2003, 机械工业出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113416379A (en) * | 2021-07-09 | 2021-09-21 | 动向国际科技股份有限公司 | Organic covering pad and preparation method thereof |
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Application publication date: 20170531 |
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