CN106747906A - A kind of organic fertilizer prepared as raw material with charcoal and marine alga - Google Patents
A kind of organic fertilizer prepared as raw material with charcoal and marine alga Download PDFInfo
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- CN106747906A CN106747906A CN201611014219.2A CN201611014219A CN106747906A CN 106747906 A CN106747906 A CN 106747906A CN 201611014219 A CN201611014219 A CN 201611014219A CN 106747906 A CN106747906 A CN 106747906A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Abstract
The invention discloses a kind of organic fertilizer prepared as raw material with charcoal and marine alga, it is made up of following components：550~650 kilograms of charcoal, 280~320 kilograms of marine algae extract, 25~35 kilograms of mixed bacteria liquid, 55~65 kilograms of chitosan hydrolyzate liquid；The charcoal is prepared by the following method and obtains：Cotton stem, maize straw or/and ground melon seedling are dried to water content below 20%, is then cut or is smashed, in input carbide furnace, be carbonized 2.5~3.5 hours at 420 DEG C~480 DEG C；After the completion of carbonization, go out charcoal, room temperature is cooled to water filtration, then dry charcoal, crush, obtain final product charcoal.The organic fertilizer prepared as raw material with charcoal and marine alga of the invention, it is nutritious, comprehensive, without adding other chemical fertilizer again, it is possible to provide nutrition needed for plant growth, promote plant growth, improve percentage of fertile fruit.It is proven, there is obvious production-increasing function to cucumber.
Description
Technical field
The present invention relates to a kind of organic fertilizer prepared as raw material with charcoal and marine alga.
Background technology
Worldwide aquaculture, planting industry promote dynamic plant mostly by means of chemical classes antibiotic, growth regulator, agricultural chemicals etc.
Growth, prevention plant epidemic disease of thing etc., although effect substantially, but often causes agrochemical to remain exceeded, environmental pollution
Etc. adverse consequences, the qualitative effects to crops are also very big.It is especially excessive to apply chemical fertilizer of simple substance such as nitrogen manure, make soil plate
Knot aggravation, soil fertility declines, and the need for making the quality of crop products and nutrition be difficult to meet people, green food is not reached more
The requirement of product, and cause serious environmental pollution.
Alga fertilizer belongs to natural seaweed extract, harmless to people, animal, environmentally safe, and organic food is put into abroad
Production dedicated fertilizer, is natural, efficient, new organic fertilizer.Contain algal polysaccharides, phenols, heteropolymer, sweet dew in marine alga
The element such as alcohol, glycine betaine, alginic acid, plant growth regulating substance and nitrogen, phosphorus, potassium and iron, boron, molybdenum, iodine, rather than chemical synthesis,
It is harmless to people, animal, after large area use, the pollution to environment can be substantially reduced, can reach green nothing with its agricultural product planted
The standard of public hazards.Therefore, alga fertilizer complies fully with Trends for modern agricultural development, and the market space is boundless.At present, alga fertilizer etc.
Natural organic fertilizer material is widely used in developed countries and regions such as America and Europes, and in progressively replacing fertilizer.
Alga fertilizer has bioactivity very high, and few consumption can stimulate plant growth, increase the nutrition of agricultural product
Component content and sugar content, improve yield, improve local flavor, color and luster and the resistant storage properties of fruit.Alga fertilizer can improve in many-side
The health status of crop, meets crop to some micro- particular/special requirements, the effectively physiological disease of preventing and treating plant, and raising is made
The cold-resistant of thing, drought resisting, anti-adversity ability.Alga fertilizer can also play an important role on protecting agriculture ecological environment, self-restraint soil.Its
The spontaneous growth Auto-regulator for containing, it is easy to which plant absorption conducts, chronic administration can directly make the soil (or make soil by plant
Increase organic matter) activation soil in various beneficial microbes, making the biopotency of soil increases.In addition, it contain it is natural
Compound such as Sodium Alginate is natural soil regulator, can promote the formation of soil granular structure, improves soil internal void empty
Between, coordinate solid, liquid, gas proportions in soil, can recover due to soil that over-burden and chemical contamination and the natural gum that loses
Matter is balanced, and soil is ventilated more preferable, and root system of plant is deeper, increases geobiont activity, increases the release of available nutrient, is improved and is made
The resistance of thing, sets up optimal plant-soil ecosystem.Therefore, alga fertilizer can make up China as novel organic fertilizer material
The deficiency of traditional organic fertilizer, the sustainable development to agricultural provides sound assurance, significant to improving the ecological environment.
The marine algae resource that the only large-scale economical alga of China just has the coastal areas such as kind more than 100, Yantai, Weihai, Qingdao is even more
It is abundant, wherein being no lack of the seaweed species for having fertilizer efficiency high.Additionally, the marine alga such as the coastal area such as Yantai, Weihai, Qingdao Enteromorpha in recent years
Spread unchecked, severe contamination environment even more influences coastal landscape.
At present, overwhelming majority producer mainly produces alga fertilizer using chemical hydrolysis both at home and abroad, i.e., existed using strong acid, highly basic
Marine alga is processed under the drastic conditions of HTHP, this method technique is complex, condition is harsh, and destroys sea
Substantial amounts of active ingredient in algae.In addition, there is not yet the compoundings such as marine alga and charcoal to be prepared the report of organic fertilizer.
The content of the invention
For above-mentioned prior art, the invention provides a kind of organic fertilizer prepared as raw material with charcoal and marine alga, its
With charcoal and marine alga as primary raw material, it is of high nutritive value, the growth and development of crops, industrial crops can be effectively facilitated, carries
High yield.
The present invention is achieved by the following technical solutions：
A kind of organic fertilizer prepared as raw material with charcoal and marine alga, is made up of following components：Charcoal 550~
650 kilograms, 280~320 kilograms of marine algae extract, 25~35 kilograms of mixed bacteria liquid, 55~65 kilograms of chitosan hydrolyzate liquid.
The charcoal is prepared by the following method and obtains：By cotton stem, maize straw or/and ground melon seedling dry to
Water content is cut (being cut to segment of the length in below 5cm) or is smashed below, then in 20% (percetage by weight), puts into carbon
Change in stove, be carbonized 2.5~3.5 hours under 420 DEG C~480 DEG C (preferably 450 DEG C)；After the completion of carbonization, go out charcoal, dropped with water filtration
Warm to room temperature, then dry charcoal, crush (being preferably crushed to 80 mesh), obtain final product charcoal.
The marine algae extract, is prepared by the following method and obtains：By marine alga shakeout, dry or 50~70 DEG C of bakings
It is dry, make the content of moisture less than 10% (mass percent), crush, (granularity of marine alga is not more than in seawood meal to obtain seawood meal
0.5cm × 0.5cm), then by seawood meal and water with mass ratio 1：The ratio mixing of (15~25), with hydrochloric acid (preferably 0.1mol/
The hydrochloric acid of L) pH is adjusted to 2~3, temperature is adjusted to 45~50 DEG C, supersonic wave wall breaking (6~12min of broken time, ultrasonic power
100~125w)；After broken wall, pH is adjusted to 4~5 with NaOH solution (the preferably NaOH solution of 0.1mol/L), then carried with ultrasonic wave
40~60min (125~200w of ultrasonic power) is taken, is filtered, obtain algae leaching liquor, concentrate (45~50 DEG C of thickening temperature of control,
Reduced vapor pressure is maintained at 0.03~0.05Mpa), the content of solid content is concentrated into 20%~50% (mass percent),
Dry, obtain marine algae extract.
The marine alga is Enteromorpha [Enteromorpha prolifera (Muller) J.Agardh], undaria pinnitafida [Undaria
Pinnatifida (Harvey) Suringar], sargassum fusifome [Sargassum fusiforme (Harvey) Setch] or/and sea
Band [Laminaria japonica Areschoug] etc..
The mixed bacteria liquid is prepared by the following method and obtains：
(1) Bacillus subtilis strain is accessed into the hair equipped with zymotic fluid with the inoculum concentration of 0.3%~0.5% (volume ratio)
In fermentation tank, aerobic fermentation 45~50 hours (preferably 48 hours), obtains final product bacillus subtilis bacterium solution at 35~38 DEG C；The hair
The composition of zymotic fluid is：Glucose 6%, soy meal 5%, dipotassium hydrogen phosphate 1%, yeast extract 1%, magnesium sulfate 0.03%, calcium carbonate
0.5%, balance of water, by weight percentage；
(2) Bacillus licheniformis strain is accessed into the hair equipped with zymotic fluid with the inoculum concentration of 0.3%~0.5% (volume ratio)
In fermentation tank, aerobic fermentation 45~50 hours (preferably 48 hours), obtains final product Bacillus licheniformis liquid at 35~38 DEG C；The hair
The composition of zymotic fluid is：Cornstarch 10%, glucose 6%, molasses 15%, balance of water, by weight percentage；
(3) bacillus thuringiensis strain is accessed equipped with zymotic fluid with the inoculum concentration of 0.3%~0.5% (volume ratio)
In fermentation tank, aerobic fermentation 45~50 hours (preferably 48 hours), obtains final product bacillus thuringiensis bacterium solution at 35~38 DEG C；Institute
The composition for stating zymotic fluid is：Potassium hydroxide 4%, phosphoric acid 3%, urea 2%, beef extract 1%, molasses 15%, magnesium sulfate 0.1%,
Zinc sulfate 0.1%, balance of water, by weight percentage；
(4) bacillus subtilis bacterium solution by volume：Bacillus licheniformis liquid：Bacillus thuringiensis bacterium solution=1:1:
Above-mentioned three kinds of bacterium solutions are mixed mixing by 1 ratio, obtain mixed bacteria liquid.
Further, above-mentioned involved zymotic fluid, reuses after being sterilized 2 hours at 121 DEG C.
Bacillus subtilis, bacillus licheniformis used by the present invention, bacillus thuringiensis are in the prior art
Some conventional bacterial classifications, can conventional market be commercially available, such as, be purchased from Chinese Academy of Agricultural Sciences's agricultural Microbiological Culture Collection pipe
Reason center (public offering), wherein, the numbering ACCC04177 of bacillus subtilis, the numbering of bacillus licheniformis is
ACCC02936, the numbering of bacillus thuringiensis is ACCC11075.
Component in zymotic fluid involved in the present invention is existing conventional constituents in the prior art, according to conventional side
Method is prepared, such as, and soy meal, cornstarch, molasses, yeast extract, beef extract etc..
The chitosan hydrolyzate liquid is prepared by the following method and obtains：Taking 45~55 kilograms of shitosans (can conventional city
Field is commercially available, such as, be purchased from Weifang Ke Hai chitins Co., Ltd), 865~835 kilograms of water are added, mix, it is warming up to
95~100 DEG C (preferably 96 DEG C), add 0~110 kilogram of phosphatase 79, are sufficiently stirred for being allowed to mix (preferably 2 hours), obtain final product shell
Glycan hydrolyzate.
The preparation method of the organic fertilizer prepared as raw material with charcoal and marine alga is：Each component is taken, mixing is mixed,
At 33~38 DEG C freeze-day with constant temperature to water content 20% (percetage by weight) below, obtain final product.
The organic fertilizer prepared as raw material with charcoal and marine alga of the invention, is bottom application type fertilizer, and fertilising opportunity is to plant
Thing initial planting is applied.The organic fertilizer prepared as raw material with charcoal and marine alga of the invention, it is nutritious, comprehensive, without again
Add other chemical fertilizer (such as urea, ammonium phosphate etc., ammonium hydrogen carbonate etc.), it is possible to provide nutrition needed for plant growth, promote to plant
Thing grows, and improves percentage of fertile fruit, and plays prevention and elimination of disease and pests, overcomes soil acidification, hardened, continuous cropping obstacle etc. to act on；Addition
Microorganism, can more efficiently decompose the nutritional ingredient in fertilizer, soil, the more conducively absorption and conversion of plant.Through practice
Prove, there is obvious production-increasing function to cucumber.
Specific embodiment
With reference to embodiment, the present invention is further illustrated.
Embodiment 1 prepares organic fertilizer
It is formulated and is：600 kilograms of charcoal, 300 kilograms of marine algae extract, 30 kilograms of mixed bacteria liquid, chitosan hydrolyzate liquid 50
Kilogram.
The charcoal is prepared by the following method and obtains：Ground melon seedling is dried to water content in 18% (weight hundred
Fraction), (being cut to segment of the length in below 5cm) then is cut, in input carbide furnace, it is carbonized 3 hours at 450 DEG C；Carbon
After the completion of change, go out charcoal, room temperature is cooled to water filtration, then dry charcoal, be crushed to 80 mesh, obtain final product charcoal.
The marine algae extract, is prepared by the following method and obtains：By marine alga shakeout, dry, make the content of moisture
Less than 10% (mass percent), crush, obtain seawood meal (granularity of marine alga is not more than 0.5cm × 0.5cm in seawood meal), then
By seawood meal and water with mass ratio 1：20 ratio mixing, 3 are adjusted to the hydrochloric acid of 0.1mol/L by pH, and temperature is adjusted to 50 DEG C, surpasses
Sound wave broken wall (broken time 10min, ultrasonic power 125w)；After broken wall, pH is adjusted to 5 with the NaOH solution of 0.1mol/L,
Ultrasonic wave extraction 60min (ultrasonic power 1250w) is used again, and filtering obtains algae leaching liquor, concentrate (50 DEG C of thickening temperature of control,
Reduced vapor pressure is maintained at 0.03~0.05Mpa), the content of solid content is concentrated into 40% (mass percent), dry, obtain
Marine algae extract.
In the present embodiment marine alga used be sea-tangle [Laminaria japonica Areschoug], by Yantai, Weihai,
Collected in the offshore floating marine alga of Qingdao.
The bacterium solution is prepared by the following method and obtains：
(1) Bacillus subtilis strain is accessed with the inoculum concentration of 0.5% (volume ratio) and is equipped with the fermentation tank of zymotic fluid,
Aerobic fermentation 48 hours at 35~38 DEG C, obtain final product bacillus subtilis bacterium solution；The composition of the zymotic fluid is：Glucose 6%,
Soy meal 5%, dipotassium hydrogen phosphate 1%, yeast extract 1%, magnesium sulfate 0.03%, calcium carbonate 0.5%, balance of water, by weight hundred
Divide than meter；
(2) Bacillus licheniformis strain is accessed with the inoculum concentration of 0.5% (volume ratio) and is equipped with the fermentation tank of zymotic fluid,
Aerobic fermentation 48 hours at 35~38 DEG C, obtain final product Bacillus licheniformis liquid；The composition of the zymotic fluid is：Cornstarch
10%, glucose 6%, molasses 15%, balance of water, by weight percentage；
(3) bacillus thuringiensis strain is accessed into the fermentation tank equipped with zymotic fluid with the inoculum concentration of 0.5% (volume ratio)
In, aerobic fermentation 48 hours at 35~38 DEG C obtain final product bacillus thuringiensis bacterium solution；The composition of the zymotic fluid is：Hydrogen-oxygen
Change potassium 4%, phosphoric acid 3%, urea 2%, beef extract 1%, molasses 15%, magnesium sulfate 0.1%, zinc sulfate 0.1%, balance of water,
By weight percentage；
(4) bacillus subtilis bacterium solution by volume：Bacillus licheniformis liquid：Bacillus thuringiensis bacterium solution=1:1:
Above-mentioned three kinds of bacterium solutions are mixed mixing by 1 ratio, obtain mixed bacteria liquid.
Above-mentioned involved zymotic fluid, reuses after being sterilized 2 hours at 121 DEG C.
Strain used of the invention is purchased from agricultural Microbiological Culture Collection administrative center of the Chinese Academy of Agricultural Sciences, wherein, it is withered
The numbering ACCC04177 of careless bacillus, the numbering of bacillus licheniformis is ACCC02936, the numbering of bacillus thuringiensis
It is ACCC11075.
The chitosan hydrolyzate liquid is prepared by the following method and obtains：Take 50 kilograms of shitosans (present invention shell used
Glycan is purchased from Weifang Ke Hai chitins Co., Ltd), 850 kilograms of water are added, mix, 96 DEG C are warming up to, add phosphatase 11 00,000
Gram, it is sufficiently stirred for being allowed to mix (2 hours), obtain final product chitosan hydrolyzate liquid.
The preparation method of the organic fertilizer is：Take each component, mixing is mixed, freeze-day with constant temperature is to water content 15% at 35 DEG C
(percetage by weight), obtains final product.
1 pair of effect of cucumber of experiment
Test period：On September 30th, 2014 --- on January 20th, 2015.Test site：Liaocheng of Shandong Province.
Experimental group：Fertilizer prepared by 40 kilograms of embodiments 1 of every mu of administration.
Control group：40 kilograms of Stanley composite fertilizers of every mu of administration (nitrogen 15%- phosphorus 15%- potassium 15%).
Each 3 mu of experimental group, control group (is respectively divided into tri- groups of A, B, C, 1 mu of each group).Fertilising opportunity is：Plantation
Before.
Influence to cucumber yield：
Experimental group A：7740 kilograms of yield；Experimental group B：7860 kilograms of yield；Experimental group C：7690 kilograms；Experimental group is average
Per mu yield：7763 kilograms.
Control group A：6760 kilograms of yield；Experimental group B：6710 kilograms of yield；Experimental group C：6850 kilograms；Experimental group is average
Per mu yield：6773 kilograms.
Contrast is visible, and yield of the experimental group substantially than control group is high, is higher by 14.6%, organic fertilizer of the invention, volume increase
Effect is significant.
Embodiment 2 prepares organic fertilizer
It is formulated and is：550 kilograms of charcoal, 320 kilograms of marine algae extract, 25 kilograms of mixed bacteria liquid, chitosan hydrolyzate liquid 65
Kilogram.
The other the same as in Example 1.
Embodiment 3 prepares organic fertilizer
It is formulated and is：650 kilograms of charcoal, 280 kilograms of marine algae extract, 35 kilograms of mixed bacteria liquid, chitosan hydrolyzate liquid 55
Kilogram.
The other the same as in Example 1.
Embodiment 4 prepares organic fertilizer
It is formulated and is：600 kilograms of charcoal, 300 kilograms of marine algae extract, 35 kilograms of mixed bacteria liquid, chitosan hydrolyzate liquid 65
Kilogram.
The other the same as in Example 1.
Embodiment 5 prepares organic fertilizer
It is formulated and is：530 kilograms of charcoal, 320 kilograms of marine algae extract, 30 kilograms of mixed bacteria liquid, chitosan hydrolyzate liquid 65
Kilogram.
The other the same as in Example 1.
Claims (6)
1. a kind of organic fertilizer prepared as raw material with charcoal and marine alga, it is characterised in that：It is made up of following components：It is biological
550~650 kilograms of charcoal, 280~320 kilograms of marine algae extract, 25~35 kilograms of mixed bacteria liquid, chitosan hydrolyzate liquid 55~65,000
Gram；
The charcoal is prepared by the following method and obtains：Cotton stem, maize straw or/and ground melon seedling are dried to aqueous
Then amount is cut or is smashed below 20%, in input carbide furnace, is carbonized 2.5~3.5 hours at 420 DEG C~480 DEG C；Carbon
After the completion of change, go out charcoal, room temperature is cooled to water filtration, then dry charcoal, crush, obtain final product charcoal.
2. the organic fertilizer prepared as raw material with charcoal and marine alga according to claim 1, it is characterised in that：The marine alga
Extract, is prepared by the following method and obtains：By marine alga shakeout, dry or 50~70 DEG C of drying, make the content of moisture low
In 10%, crush, obtain seawood meal, then by seawood meal and water with mass ratio 1：The ratio mixing of (15~25), with hydrochloric acid by pH
2~3 are adjusted to, temperature is adjusted to 45~50 DEG C, supersonic wave wall breaking；After broken wall, pH is adjusted to 4~5 with NaOH solution, then use ultrasonic wave
40~60min is extracted, filtering obtains algae leaching liquor, concentrates, dries, and obtains marine algae extract.
3. the organic fertilizer prepared as raw material with charcoal and marine alga according to claim 2, it is characterised in that：The marine alga
It is Enteromorpha [Enteromorpha prolifera (Muller) J.Agardh], undaria pinnitafida [Undaria pinnatifida
(Harvey) Suringar], sargassum fusifome [Sargassumfusiforme (Harvey) Setch] or/and sea-tangle [Laminaria
Japonica Areschoug] etc..
4. the organic fertilizer prepared as raw material with charcoal and marine alga according to claim 1 and 2, it is characterised in that：It is described
Mixed bacteria liquid is prepared by the following method and obtains：
(1) Bacillus subtilis strain is accessed with 0.3%~0.5% inoculum concentration and is equipped with the fermentation tank of zymotic fluid, 35
Aerobic fermentation 45~50 hours at~38 DEG C, obtain final product bacillus subtilis bacterium solution；The composition of the zymotic fluid is：Glucose 6%,
Soy meal 5%, dipotassium hydrogen phosphate 1%, yeast extract 1%, magnesium sulfate 0.03%, calcium carbonate 0.5%, balance of water, by weight hundred
Divide than meter；
(2) Bacillus licheniformis strain is accessed with 0.3%~0.5% inoculum concentration and is equipped with the fermentation tank of zymotic fluid, 35
Aerobic fermentation 45~50 hours at~38 DEG C, obtain final product Bacillus licheniformis liquid；The composition of the zymotic fluid is：Cornstarch
10%, glucose 6%, molasses 15%, balance of water, by weight percentage；
(3) bacillus thuringiensis strain is accessed with 0.3%~0.5% inoculum concentration and is equipped with the fermentation tank of zymotic fluid,
Aerobic fermentation 45~50 hours at 35~38 DEG C, obtain final product bacillus thuringiensis bacterium solution；The composition of the zymotic fluid is：Hydroxide
Potassium 4%, phosphoric acid 3%, urea 2%, beef extract 1%, molasses 15%, magnesium sulfate 0.1%, zinc sulfate 0.1%, balance of water is pressed
Percentage by weight meter；
(4) bacillus subtilis bacterium solution by volume：Bacillus licheniformis liquid：Bacillus thuringiensis bacterium solution=1:1:1
Above-mentioned three kinds of bacterium solutions are mixed mixing by ratio, obtain mixed bacteria liquid.
5. the organic fertilizer prepared as raw material with charcoal and marine alga according to claim 1 or 2 or 4, it is characterised in that：Institute
State chitosan hydrolyzate liquid and be prepared by the following method and obtain：45~55 kilograms of shitosans are taken, 865~835 kilograms of water are added,
Mix, be warming up to 95~100 DEG C, add 0~110 kilogram of phosphatase 79, be sufficiently stirred for being allowed to mix, obtain final product chitosan hydrolyzate liquid.
6. the preparation method of the organic fertilizer prepared as raw material with charcoal and marine alga any one of Claims 1 to 5, its
It is characterised by：Each component is taken, mixing is mixed, and freeze-day with constant temperature below 20%, is obtained final product to water content at 33~38 DEG C.
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| CN107188765A (en) * | 2017-07-13 | 2017-09-22 | 全椒县赤镇龙虾经济专业合作社 | It is a kind of to chelate the preparation method that diisocyanate is modified lobster shell powder liquid fertilizer |
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