CN106746916A - Bio-based polyurethane composite concrete material and application method - Google Patents
Bio-based polyurethane composite concrete material and application method Download PDFInfo
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- CN106746916A CN106746916A CN201611206904.5A CN201611206904A CN106746916A CN 106746916 A CN106746916 A CN 106746916A CN 201611206904 A CN201611206904 A CN 201611206904A CN 106746916 A CN106746916 A CN 106746916A
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- bio
- concrete material
- crosslinking agent
- composite concrete
- based polyurethane
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- 229920002635 polyurethane Polymers 0.000 title claims abstract description 31
- 239000004814 polyurethane Substances 0.000 title claims abstract description 31
- 239000000463 material Substances 0.000 title claims abstract description 30
- 239000004567 concrete Substances 0.000 title claims abstract description 25
- 239000002131 composite material Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims abstract description 9
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 20
- 229920005862 polyol Polymers 0.000 claims abstract description 18
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 15
- 150000003077 polyols Chemical class 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 13
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 9
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 9
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
- 239000004570 mortar (masonry) Substances 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 6
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 5
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- -1 isooctyl Chemical group 0.000 claims description 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000005056 compaction Methods 0.000 claims description 2
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims description 2
- 230000003116 impacting effect Effects 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 abstract description 2
- 235000010469 Glycine max Nutrition 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 239000004568 cement Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 235000012424 soybean oil Nutrition 0.000 description 3
- 239000003549 soybean oil Substances 0.000 description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 208000012659 Joint disease Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/3278—Hydroxyamines containing at least three hydroxy groups
- C08G18/3281—Hydroxyamines containing at least three hydroxy groups containing three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/36—Hydroxylated esters of higher fatty acids
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01D—CONSTRUCTION OF BRIDGES, ELEVATED ROADWAYS OR VIADUCTS; ASSEMBLY OF BRIDGES
- E01D19/00—Structural or constructional details of bridges
- E01D19/08—Damp-proof or other insulating layers; Drainage arrangements or devices ; Bridge deck surfacings
- E01D19/083—Waterproofing of bridge decks; Other insulations for bridges, e.g. thermal ; Bridge deck surfacings
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
Abstract
The present invention relates to a kind of bio-based polyurethane composite concrete material and application method, it is characterised in that including following weight composition：The ﹪ of polyurethane resin 10~30, compound sandstone 70~90%；Particle diameter between 0~0.15mm is 12~26wt% in the compound sandstone, between 0.15~0.6mm is 14~27wt%, particle diameter between 0.6~1.18mm is 18~28wt%, particle diameter between 1.18~2.36mm is 12~29wt%, and particle diameter between 2.36~4.75mm is 17~35wt%；Wherein, the preparation method of the polyurethane resin is as follows：Soy Polyol, polyisocyanates, crosslinking agent and accelerator are mixed, is stirred and is obtained polyurethane resin；Wherein the mass content of soy Polyol is 30~60 ﹪；The mass content of crosslinking agent is 0~10 ﹪, and the content of polyisocyanates, with isocyanate groups mole to count, is the 100 120% of the oh group sum of soy Polyol and crosslinking agent；The mass content of catalyst is 0.1~1 ﹪.
Description
Technical field
The present invention relates to engineering material, especially bio-based polyurethane composite concrete material and application method.
Background technology
A large amount of science of bridge building as shown by data, it is one of typical disease of bridge structure that pave-load layer is damaged, and drastically influence bridge
The service life and safety of girder construction.Material used by current paving bridge floor is generally pitch mixing material, often because easily
The factor of corrosion, frost and carbonization, causes bridge floor to split, pit, influence bridge structure and uses safety.Over time,
These damages can extend to the internal structure of bridge, accelerate the infiltration of rainwater, cause reinforcement corrosion, shorten bridge life.
Chen Huifan exists《Application of the elastic polyurethane concrete in even high speed deck expansion joint disease is repaired suddenly》(《Construction
Technology》, 06 phase in 2011) and a kind of polyurethane deck expansion joint material for repairing is reported, Luo Zhipeng exists《Elastic polyurethane type coagulation
Native road joint glue development and application》(《Guangzhou chemistry》, 02 phase in 2004) and report a kind of polyurethane caulking material and Wei
Burn it is refined《The experimental study of early-strong-fast-hard polyurethane concrete》Report a kind of containing polyurethane, curing agent and sand, stone, cement
Material for road repair.But its compression strength of this several concrete is low, only 10 MPas or so, it is impossible to as deck paving material
Material.
The content of the invention
The present situation that the technical problems to be solved by the invention are directed to prior art provides a kind of wearability good high intensity
Bio-based polyurethane composite concrete material, so as to avoid corrosion failure of the bridge floor under complex environment, extension bridge from using the longevity
Life, reduces the maintenance cost of bridge operation.
Present situation a kind of wearability of offer that another technical problem to be solved by this invention is directed to prior art is good
The application method of high intensity bio-based polyurethane composite concrete material.
The present invention solve the technical scheme that is used of above-mentioned technical problem for：The bio-based polyurethane composite concrete material
Material, it is characterised in that including following weight composition：
The ﹪ of polyurethane resin 10~30
Compound sandstone 70~90%
Particle diameter between 0~0.15mm is 12~26wt% in the compound sandstone, and between 0.15~0.6mm is 14
~27wt%, particle diameter between 0.6~1.18mm is 18~28wt%, particle diameter between 1.18~2.36mm for 12~
29wt%, particle diameter between 2.36~4.75mm is 17~35wt%；
Wherein, the preparation method of the polyurethane resin is as follows：
Soy Polyol, polyisocyanates, crosslinking agent and accelerator are mixed, is stirred and is obtained polyurethane resin；
Wherein the mass content of soy Polyol is 30~60 ﹪；The mass content of crosslinking agent is 0~10 ﹪, polyisocyanic acid
The content of ester, with isocyanate groups mole to count, is the 100- of the oh group sum of soy Polyol and crosslinking agent
120%；The mass content of catalyst is 0.1~1 ﹪.
It is preferred that the soy Polyol hydroxy functionality is 3~4, hydroxyl value is 100-450；
The polyisocyanates preferably is selected from methyl diphenylene diisocyanate (MDI), and toluene di-isocyanate(TDI) (TDI) gathers
At least one in methyl diphenylene diisocyanate (PMDI) and IPDI (IPDI)；
The accelerator preferably is selected from being at least one in triethylamine, dibutyl tin laurate and isooctyl acid bismuth；
The crosslinking agent is the polyalcohol of reactive functionality number >=3.
Preferably, the hydroxyl value of the soy Polyol is 200-360.
It is preferred that the content of polyisocyanates is with isocyanate groups to count, it is the hydroxyl of soy Polyol and the crosslinking agent
The 100-110% of group sum.
In above-mentioned each scheme, the crosslinking agent preferably is selected from glycerine, pentaerythrite, triethanolamine and trimethylolpropane
It is at least one.
The application method of above-mentioned bio-based polyurethane composite concrete material, it is characterised in that comprise the steps：
To the compound sandstone is added in the polyurethane resin, mortar is uniformly mixing to obtain；
Mortar is poured into Marshall die trial, reality is hit through Apparatus for Impacting at low-temp, reacted 10-1440 minutes at 0~40 DEG C, it is also possible to
Mortar is layered on road surface or bridge floor, through vibrated roller vibration compaction test, obtains polyurethane concrete pave-load layer；
It is preferred that the pavement material reacts 30~720 minutes at 5~40 DEG C.
Compared with prior art, polyurethane provided by the present invention meets concrete material has excellent abrasion resistance properties
And weatherability, intensity is high, and low temperature flexibility is good, and adhesive property is excellent, bearing capacity, good endurance, and with excellent preparation
It is easy with application method, it is especially suitable for large span, life requirement is high or repairs difficult high load capacity bridge deck structure
In pavement material, the corrosion and destruction of reinforcing bar can be delayed, extend bridge service life, and it is cheap, volatility is low, nontoxic, holds
Easily regeneration, it is environment-friendly.
Brief description of the drawings
Fig. 1 be the embodiment of the present invention 1 in polyurethane resin hardness with glycerine ratio change curve；
Fig. 2 be the embodiment of the present invention 2 in polyurethane resin compressive strength with glycerine ratio change curve；
Fig. 3 be the embodiment of the present invention 2 in polyurethane cement compressive strength with sand fraction change curve.
Specific embodiment
The present invention is described in further detail below in conjunction with accompanying drawing embodiment.
In embodiment 1 to the compound sandstone used in embodiment 3, the particle diameter of sandstone is as shown in table 1.
Table 1
| Screen size (mm) | 9.5 | 4.75 | 2.36 | 1.18 | 0.6 | 0.3 | 0.15 | 0.075 |
| Percent of pass (%) | 100 | 100 | 72 | 55 | 43 | 30 | 22 | 16 |
Embodiment 1
The preparation of polyurethane resin and hardness are characterized：
It is the weight portion of 200 soybean oil polyol 40 by hydroxyl value, hydroxyl value is 1937 glycerine, mixing is equal in adding plastic beaker
Even, qualities of glycerin gradually increases from 0-20pph, and the poly- isocyanide of diphenyl methane two is added by degree of functionality mol ratio NCO/OH=1.05
Acid esters (PMDI), is stirred, and is subsequently adding 0.3 milliliter of accelerator isooctyl acid bismuth, and polyurethane resin is obtained after stirring.
20 parts by weight of polyurethane resins and the compound sandstone of 80 weight portions are taken, is poured into mould, 300 points are reacted at 40 DEG C
Clock, obtains compression verification sample.
Hardness test is carried out to the sample for obtaining using the standard methods of ASTM D 2240-03, as a result as shown in Figure 1.
The hardness of polyurethane material rises with the increase of glycerol content as seen from Figure 1, when content reaches 15-
When 20%, shore hardness D is up to 70 or so.
Embodiment 2
45 grams of the soybean oil polyol that hydroxyl value is 300 is taken, hydroxyl value is 1,937 4 grams of glycerine, add mixing in plastic beaker
Uniformly, 49.7 grams of methyl diphenylene diisocyanate (MDI), stirring, mixing are added by degree of functionality mol ratio NCO/OH=1.05
Uniformly, that is, polyurethane resin is obtained.
To compound 756 grams of sandstone is added in polyurethane resin, mortar is obtained after being uniformly mixed.
During mortar is imported into a diameter of 10cm highly for 8 centimetres of circular die, both ends of the surface are respectively tapped 50 times through sampling machine
Obtain prefabricated component.
Prefabricated component stands 20 hours at room temperature, obtains polyurethane concrete finished material.
With the compressive strength of the ASTMD 395-02 standard testings sample on universal tensile machine.Test result such as Fig. 2 and
Shown in Fig. 3.
The compressive strength of polyurethane concrete composite rises with the increase of glycerol content as seen from Figure 2,
Compressive strength reaches 60-80 MPas, reaches road with requiring.
As seen from Figure 3 the compressive strength of polyurethane concrete composite with the increase of compound gravel content on
Rise, compressive strength reaches 40-90 MPas, reach road with requiring.
Embodiment 3
It is 1 gram of triethanolamine and trimethylolpropane 4 for 1128 by 45 grams of the soybean oil polyol that hydroxyl value is 280, hydroxyl value
Gram liquid mixture, add in plastic beaker, add IPDI 44.6 grams of (IPDI), be sufficiently stirred for, make
It is well mixed, and obtains polyurethane resin.
To 756 grams of compound sandstones are added in polyurethane resin, it is sufficiently stirred for, is allowed to well mixed, obtains mortar.
During mortar is imported into a diameter of 10cm highly for 8 centimetres of circular die, both ends of the surface are respectively tapped 50 times through sampling machine
Obtain prefabricated component.
Prefabricated component is stood 10 hours at room temperature, polyurethane concrete finished material is obtained.
Stabilily parameter is carried out to finished product with the standards of ASTM D 1559, gained polyurethane cement sample stability is
65.3KN, flow valuve is 1.1mm, and with ASTMD 395-02 standard testings, the sample compression strength is on universal tensile machine
65.7MPa。
Claims (7)
1. bio-based polyurethane composite concrete material, it is characterised in that including following weight composition：
The ﹪ of polyurethane resin 10~30
Compound sandstone 70~90%
Particle diameter between 0~0.15mm is 12~26wt% in the compound sandstone, between 0.15~0.6mm for 14~
27wt%, particle diameter between 0.6~1.18mm is 18~28wt%, particle diameter between 1.18~2.36mm for 12~
29wt%, particle diameter between 2.36~4.75mm is 17~35wt%；
Wherein, the preparation method of the polyurethane resin is as follows：
Soy Polyol, polyisocyanates, crosslinking agent and accelerator are mixed, is stirred and is obtained polyurethane resin；
Wherein the mass content of soy Polyol is 30~60 ﹪；The mass content of crosslinking agent is 0~10 ﹪, polyisocyanates
Content, with isocyanate groups mole to count, is the 100-120% of the oh group sum of soy Polyol and crosslinking agent；Urge
The mass content of agent is 0.1~1 ﹪.
2. bio-based polyurethane composite concrete material according to claim 1, it is characterised in that the soy Polyol
Hydroxy functionality is 3~4, and hydroxyl value is 100-450；
The polyisocyanates is selected from methyl diphenylene diisocyanate, toluene di-isocyanate(TDI), the isocyanide of poly- diphenyl methane two
At least one in acid esters and IPDI；
It is at least one in triethylamine, dibutyl tin laurate and isooctyl acid bismuth that the accelerator is selected from；
The crosslinking agent is the polyalcohol of reactive functionality number >=3.
3. bio-based polyurethane composite concrete material according to claim 2, it is characterised in that the soy Polyol
Hydroxyl value be 200-360.
4. bio-based polyurethane composite concrete material according to claim 3, it is characterised in that the polyisocyanates
Content with isocyanate groups to count, be the 100-110% of the oh group sum of soy Polyol and the crosslinking agent.
5. bio-based polyurethane composite concrete material according to claim 4, it is characterised in that the crosslinking agent selection
At least one in glycerine, pentaerythrite, triethanolamine and trimethylolpropane.
6. the application method of the bio-based polyurethane composite concrete material as described in claim 1 to 5 any claim, its
It is characterised by comprising the steps：
To the compound sandstone is added in the polyurethane resin, mortar is uniformly mixing to obtain；
Mortar is poured into Marshall die trial, product is formed after hitting reality through Apparatus for Impacting at low-temp, curing reaction 10-1440 points at 0~40 DEG C
Clock obtains sample；Or mortar is layered on road surface or bridge floor, through vibrated roller vibration compaction test, obtain polyurethane concrete paving
Dress layer.
7. the application method of bio-based polyurethane composite concrete material according to claim 6, it is characterised in that described
Product reacts 30~720 minutes at 5~40 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611206904.5A CN106746916A (en) | 2016-12-23 | 2016-12-23 | Bio-based polyurethane composite concrete material and application method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611206904.5A CN106746916A (en) | 2016-12-23 | 2016-12-23 | Bio-based polyurethane composite concrete material and application method |
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| Publication Number | Publication Date |
|---|---|
| CN106746916A true CN106746916A (en) | 2017-05-31 |
Family
ID=58920863
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611206904.5A Pending CN106746916A (en) | 2016-12-23 | 2016-12-23 | Bio-based polyurethane composite concrete material and application method |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117822A (en) * | 2007-06-22 | 2008-02-06 | 林玲 | Vegetable oil radical polyurethane composite panels and continuous production method |
| CN102140327A (en) * | 2011-02-28 | 2011-08-03 | 中国科学院宁波材料技术与工程研究所 | Storable plant oil-based polyurethane wood adhesive and preparation method and application thereof |
| CN103215006A (en) * | 2013-03-19 | 2013-07-24 | 华南理工大学 | Low viscosity solvent-free polyurethane laminating adhesive and preparation method thereof |
| CN104876474A (en) * | 2015-04-22 | 2015-09-02 | 哈尔滨工程大学 | Bridge deck slab waterborne polyurethane polymer concrete and preparation method thereof |
-
2016
- 2016-12-23 CN CN201611206904.5A patent/CN106746916A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117822A (en) * | 2007-06-22 | 2008-02-06 | 林玲 | Vegetable oil radical polyurethane composite panels and continuous production method |
| CN102140327A (en) * | 2011-02-28 | 2011-08-03 | 中国科学院宁波材料技术与工程研究所 | Storable plant oil-based polyurethane wood adhesive and preparation method and application thereof |
| CN103215006A (en) * | 2013-03-19 | 2013-07-24 | 华南理工大学 | Low viscosity solvent-free polyurethane laminating adhesive and preparation method thereof |
| CN104876474A (en) * | 2015-04-22 | 2015-09-02 | 哈尔滨工程大学 | Bridge deck slab waterborne polyurethane polymer concrete and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 刘益军: "《聚氨酯原料及助剂手册 第2版》", 31 January 2013 * |
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